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Molar Conductivity of Aqueous HF, HCL, HBR, and Hi Reference

The document presents data on the molar conductivity of hydrohalogenic acids (HF, HCl, HBr, HI) in aqueous solutions at different concentrations and temperatures. It provides tables showing the molar conductivity in S cm2 mol-1 of each acid across a range of concentrations from infinite dilution to 10 mol/L at 25°C. Additional tables show the temperature dependence of molar conductivity for HCl and HBr solutions at concentrations from 0.5 to 5 mol/L and temperatures from -20°C to 50°C. The molar conductivity generally decreases with increasing concentration and temperature.

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161 views1 page

Molar Conductivity of Aqueous HF, HCL, HBR, and Hi Reference

The document presents data on the molar conductivity of hydrohalogenic acids (HF, HCl, HBr, HI) in aqueous solutions at different concentrations and temperatures. It provides tables showing the molar conductivity in S cm2 mol-1 of each acid across a range of concentrations from infinite dilution to 10 mol/L at 25°C. Additional tables show the temperature dependence of molar conductivity for HCl and HBr solutions at concentrations from 0.5 to 5 mol/L and temperatures from -20°C to 50°C. The molar conductivity generally decreases with increasing concentration and temperature.

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antonio
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© © All Rights Reserved
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Molar Conductivity of Aqueous HF, HCl, HBr, and HI

The molar conductivity Λ of an electrolyte solution is defined as Reference


the conductivity divided by amount-of-substance concentration.
The customary unit is S cm2 mol–1 (i.e., Ω–1 cm2 mol–1). The first Hamer, W. J., and DeWane, H. J., Electrolytic Conductance and the
part of this table gives the molar conductivity of the hydrohalogen Conductances of the Hydrohalogen Acids in Water, Natl. Stand. Ref.
Data Sys.- Natl. Bur. Standards (U.S.), No. 33, 1970.
acids at 25  °C as a function of the concentration in mol/L. The
second part gives the temperature dependence of Λ for HCl and
HBr. More extensive tables and mathematical representations may
be found in the reference.

c/mol L–1 HF HCl HBr HI c/mol L–1 HF HCl HBr HI


Inf. dil. 405.1 426.1 427.7 426.4 3.5 218.3 217.5 215.4
0.0001 424.5 425.9 424.6 4.0 200.0 199.4 195.1
0.0005 422.6 424.3 423.0 4.5 183.1 182.4 176.8
0.001 421.2 422.9 421.7 5.0 167.4 166.5 160.4
0.005 128.1 415.7 417.6 416.4 5.5 152.9 151.8 145.5
0.01 96.1 411.9 413.7 412.8 6.0 139.7 138.2 131.7
0.05 50.1 398.9 400.4 400.8 6.5 127.7 125.7 118.6
0.10 39.1 391.1 391.9 394.0 7.0 116.9 114.2 105.7
0.5 26.3 360.7 361.9 369.8 7.5 107.0 103.8
1.0 24.3 332.2 334.5 343.9 8.0 98.2 94.4
1.5 305.8 307.6 316.4 8.5 90.3 85.8
2.0 281.4 281.7 288.9 9.0 83.1
2.5 258.9 257.8 262.5 9.5 76.6
3.0 237.6 236.8 237.9 10.0 70.7

c/ c/
mol L–1 –20 °C –10 °C 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C mol L–1 –20 °C –10 °C 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C

HCl HBr
0.5 228.7 283.0 336.4 386.8 436.9 482.4 0.5 240.9 295.9 347.0 398.9 453.6 496.8
1.0 211.7 261.6 312.2 359.0 402.9 445.3 1.0 229.6 276.0 329.0 380.4 418.6 465.2
1.5 196.2 241.5 287.5 331.1 371.6 410.8 1.5 209.5 254.9 298.9 340.6 381.8 421.4
2.0 182.0 222.7 262.9 303.3 342.4 378.2 2.0 150.8 188.6 231.3 271.8 314.1 350.5 387.4
2.5 131.7 168.5 205.1 239.8 277.0 315.2 347.6 2.5 136.8 171.7 208.3 244.8 281.7 316.0 349.1
3.0 120.8 154.6 188.5 219.3 253.3 289.3 319.0 3.0 125.7 157.2 189.5 222.2 255.0 287.8 318.6
3.5 85.5 111.3 139.6 172.2 201.6 232.9 263.9 292.1 3.5 116.1 144.1 174.6 203.2 234.4 263.7 291.9
4.0 79.3 102.7 129.2 158.1 185.6 214.2 242.2 268.2 4.0 84.0 107.5 132.3 160.2 186.8 214.2 239.7 266.9
4.5 73.7 94.9 119.5 145.4 170.6 196.6 222.5 246.7 4.5 78.0 99.0 123.0 146.4 171.2 195.1 218.8 242.6
5.0 68.5 87.8 110.3 133.5 156.6 180.2 204.1 226.5 5.0 72.3 91.4 112.6 134.0 155.7 178.2 199.6 221.3
5.5 63.6 81.1 101.7 122.5 143.6 165.0 187.1 207.7 5.5 67.0 84.2 103.1 122.7 142.1 162.8 181.4 201.8
6.0 58.9 74.9 93.7 112.3 131.5 151.0 171.3 190.3 6.0 61.8 77.2 94.3 112.0 129.6 148.0 165.4 183.4
6.5 54.4 69.1 86.2 103.0 120.4 138.2 156.9 174.3 6.5 56.8 70.7 86.0 102.0 118.0 134.1 150.5 166.3
7.0 50.2 63.7 79.3 94.4 110.2 126.4 143.3 159.7 7.0 51.9 64.6 78.4 92.6 107.1 121.4 136.3 150.8
7.5 46.3 58.6 73.0 86.5 100.9 115.7 131.6 146.2
8.0 42.7 54.0 67.1 79.4 92.4 106.1 120.6 134.0
8.5 39.4 49.8 61.7 72.9 84.7 97.3 110.7 123.0
9.0 36.4 45.9 56.8 67.1 77.8 89.4 101.7 112.9
9.5 33.6 42.3 52.3 61.8 71.5 82.3 93.6 103.9
10.0 31.2 39.1 48.2 57.0 65.8 75.9 86.3 95.7
10.5 28.9 36.1 44.5 52.7 60.7 70.1 79.6 88.4
11.0 26.8 33.4 41.1 48.8 56.1 64.9 73.6 81.7
11.5 24.9 31.0 38.0 45.3 51.9 60.1 68.0 75.6
12.0 23.1 28.7 35.3 42.0 48.0 55.6 62.8 70.0
12.5 21.4 26.7 32.7 39.0 44.4 51.4 57.9 64.8

5-75

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