MATERIAL BALANCE

BIODIESEL
 NO RECYCLE WITH RECYCLE
Feed Output (S6) Feed Output (S6)
Comp. MW kmol/h kg/h kmol/h kg/h kmol/h kg/h kmol/h kg/h S28
TG(S27) 885.43 3 2656.29 0.15 132.8145 3 2656.29 0.15 132.8145 S6
MeOH(S28) 32.042 30 961.26 21.45 687.3009 138.8285 4448.343 130.2785 4174.384
FAME 296.495 0 0 8.55 2535.032 0 0 8.55 2535.032
GLY 92.094 0 0 2.85 262.4679 0 0 2.85 262.4679 S27
H2SO4(S28) 98.079 0.03 2.94237 0.03 2.94237 0.03 2.94237 0.03 2.94237
TOTAL 33.03 3620.492 33.03 3620.558 141.8585 7107.575 141.8585 7107.641

Extend of reaction
2.85
Stoichiometric reaction
TG MeOH GLY FAME
1 3 1 3
 Output S8
Feed (S7) Top (S8) Bottom (9)
Comp. MW kmol/h kg/h kmol/h kg/h kmol/h kg/h
TG 885.43 0.15 132.8145 0 0 0.15 132.8145 S7
MeOH 32.042 21.45 687.3009 18.6615 597.9518 2.7885 89.34912
FAME 296.495 8.55 2535.032 0 0 8.55 2535.032
GLY 92.094 2.85 262.4679 0 0 2.85 262.4679 S9
H2SO4 98.079 0.03 2.94237 0.00669 0.656149 0.02331 2.286221
T-101
TOTAL 33.03 3620.558 18.66819 598.6079 14.36181 3021.95
3620.55792

SPLIT FRACTION @ TOP

TG 0
MeOH 0.87
FAME 0
GLY 0
H2SO4 0.223
 Output
Feed (S29) Top (S12) Bottom (15) S32 S12
Comp. MW kmol/h kg/h kmol/h kg/h kmol/h kg/h
TG 885.43 0.15 132.8145 0.15 132.8145 0 0
MeOH 32.042 2.7885 89.34912 0 0 2.7885 89.34912
FAME 296.495 8.55 2535.032 8.55 2535.032 0 0 S29
GLY 92.094 2.85 262.4679 0 0 2.85 262.4679
H2SO4 98.079 0.02331 2.286221 0 0 0.02331 2.286221
H2O (S32) 18.015 148.0903 2667.847 0.592361 10.67139 147.4979 2657.175 S-101
TOTAL 162.4521 5689.797 9.292361 2678.518 153.1597 3011.279
S15
5689.79673849

SPLIT FRACTION
TG 1
MeOH 0
FAME 1
GLY 0
H2SO4 0
H2O 0.004
 Output
Feed (S12) Top (S13) Bottom (S22)
S13
Comp. MW kmol/h kg/h kmol/h kg/h kmol/h kg/h
TG 885.43 0.15 132.8145 0 0 0.15 132.8145
MeOH 32.042 0 0 0 0 0 0
FAME 296.495 8.55 2535.032 8.45595 2507.147 0.09405 27.88535 S12
GLY 92.094 0 0 0 0 0 0
H2SO4 98.079 0 0 0 0 0 0
H2O 18.015 0.592361 10.67139 0.592361 10.67139 0 0
TOTAL 9.292361 2678.518 9.048311 2517.818 0.24405 160.6999
2678.518137 T-102 S22

SPLIT FRACTION
TG 0
MeOH 0
FAME 0.989
GLY 0
H2SO4 0
H2O 1
 Feed (S15) Output (S17)
Comp. MW kmol/h kg/h kmol/h kg/h
TG 885.43 0 0 0 0
S16
MeOH 32.042 2.7885 89.34912 2.7885 89.34912
FAME 296.495 0 0 0 0 S17
GLY 92.094 2.85 262.4679 2.85 262.4679
S15
H2SO4 98.079 0.02331 2.286221 0 0
H2O 18.015 147.4979 2657.175 147.5446 2658.015
NaOH (S16) 40 0.1 4 0.05338 2.1352
R-102
Na2SO4 142.04 0 0 0.02331 3.310952
TOTAL 153.1597 3015.279 153.1831 3015.278

Stoichiometric reaction
NaOH H2SO4 Na2SO4 H2O
2 1 1 2
 Output S18
Feed (S17) Top (S18) Bottom (S24)
Comp. MW kmol/h kg/h kmol/h kg/h kmol/h kg/h
TG 885.43 0 0 0 0 0 0
MeOH 32.042 2.7885 89.34912 2.760615 88.45563 0.027885 0.893491
FAME 296.495 0 0 0 0 0 0
GLY 92.094 2.85 262.4679 2.8215 259.8432 0.0285 2.624679
H2SO4 98.079 0 0 0 0 0 0
S17
H2O 18.015 147.5446 2658.015 146.0691 2631.435 1.475446 26.58015
NaOH (S18) 40 0.05338 2.1352 0 0 0.05338 2.1352
Na2SO4 142.04 0.02331 3.310952 0.023077 3.277843 0.000233 0.03311
TOTAL 153.1831 3015.278 151.6512 2983.012 1.531831 32.26663
3015.2783917 S-102
S24
SPLIT FRACTION
TG 0
MeOH 0.99
FAME 0
GLY 0.99
H2SO4 0.01
H2O 0.99
NaOH (S18) 0
Na2SO4 0.99
 Output
Feed (S31) Top (S25) Bottom (S19)
Comp. MW kmol/h kg/h kmol/h kg/h kmol/h kg/h
TG 885.43 0 0 0 0 0 0 S25
MeOH 32.042 2.760615 88.45562583 2.733009 87.57107 0.027606 0.884556
FAME 296.495 0 0 0 0 0 0
GLY 92.094 2.8215 259.843221 0 0 2.8215 259.8432 S31
H2SO4 98.079 0 0 0 0 0 0
H2O 18.015 146.0691 2631.43507 123.3942 2222.947 22.67489 408.4882
NaOH (S18) 40 0 0 0 0 0 0
Na2SO4 142.04 0.023077 3.277842876 0.019495 2.76901 0.003582 0.508833
D-103 S19
TOTAL 151.6512 2983.01176 126.1272 2313.287 25.524 669.7248
2983.011759783

SPLIT FRACTION
TG 0
MeOH 0.99
FAME 0
GLY 0
H2SO4 0.844764
H2O 0.844766
NaOH (S18) 0
Na2SO4 0.844766