Dr RoswoniraAbdul Wohab

Tutorial1
Alkane,AlkeneandAlkynes

L. Drawthe structuresbelow:

ethylhexane
a . 4-ethyl-2-m b. Cyclopentylethene

C.4lrCt{
>
Iael =etla
-+t' cl+fu_,Qt ul q
L+sG,
u,
c. Trans-L,3-dimethylcyclohexane 3-bromo-2-fl pent-1-ene
uoro-3-methyl

,Lrtrr., 6.F
5+ll
\l __rrotra(rH UzC,tl"Q:c-- cHa
2 t
l'
r Ut
e . 2,3,4-trimethylpentane f. ethylpentane
3-ethyl-3-m
Ult
ft?*u ,
cHus
Lt+l(|1qH
'l cHara cH*ea3
"7
Ur, C'H
tU t
t-butylcyclohexane ethylcyclopentane
h . Trans-1,3-dimethyl-4=

2Ue
r\- eurru/€!,
L,}
*r'F'
CHs

2. Givethe IUPACnamefor the followingcompounds

a. b. czHs
,y'
*
ll /-.t&abui|-(- 4 - "t'f"/.Ge-"t cn'Ve "/"
fux aKQ-
U
t

-'l-n' scxo"ua'
J2--- dW-
0 t ' 6 ' @W
4,5,
0
 Dr RoswaniraAbdul Wohob

e. *&.t. f. jH2cH3
l-ltcHrH. e'"++?c'{oYu"Ia"z
ct's-1,3-
a
Y
cH2cH3
t-nM*t,:'dtw
alkylgroups.Drawthem andgivetheir names
3. there are8 typesof S-carbon
i, * c*,u*;-d,ur^
- r it, t? ?A'?-rt*\rls
n-ft^W LH3
l'n"P14-'/A'lW
, L 5 +
it -casf'ar,uu iy -/.HJU,?/ttH,
2-'#,rttry
y *?
l2-e
HCHoc't13 vL fil'
UrU z *^<.*Al e Ul s
t_Q4tur(Yf ,,,-h^h4ryf
rl
C,t(t & r"-V)
C,ll.z
YyaH-??'
a+>
vY- * U'-\- I
cotI
t,)-**H*tr*[,VL c-tl 3
J, ?-d,;#^fV*F#
4. Proposea mechanismfor the free radicalchlorinationof ethane

3HC-CH3 * € 3HC-CH2C| + HCI

AClz

T,Tw'iloL,o^N:, I Qc(,
n, %pof -C
$ A'] JE ryca"^+ Hq r 'cltsc+s
I o"-t*;
6 .dA- uue*e+ "cL
fr, {u-rurnalron a, C?'* ') C! a
J- ()"-)Y-, uous C,lr-c-+r.u{
z
o. uz4r4\" c)6ut c4zc.,tlr-errGr
s
K
 Dr RoswoniroAbdul Wohab

5. Writestructuralformulasfor eachof the followingcompounds:

a. 6-isopropyl-2,3-dimethylnonane b. Cyclobutylcyclopentane

cycloheptane
sec-butyl 1-dimethylcyclohexane
d. 4-isobutyl-1,
(

AA
\t\
tl
\/

6. Pristaneis an alkane that is present at about L4o/oin the liver oil of sharks.lts
name is 2,6,LO,L4-tetramethylpentadecane. Write its structuralformula.

;x
7.

5- aiffi -e,6 - dr,\4L{%,('*,^a.i,Lz-

How many methyl, methyleneand methanegroupsare presentin the above

alkane?
n^!.*-t',r( qwups , ( *C]l ,)
rulrry!9* (--^4,*)
lpff'-- 3! (-9Ll ^--
f^!{-LLi^Q- )
T"-,*{rt
\

tertiaryandquarternary?
Howmanycarbonsthat are primary,secondary,

loc = ,
Joe =t
3oc : 3
ttoc = O
 Dr Roswanira Abdul Wahab

7.

a. How manymethyl,methyleneand methanegroupsare presentin the above

alkane?

tertiaryand quarternary
b. Howmanycarbonsthatare primary,secondary, ?

8. In the followingpair of compounds,whichcompoundhas the higherboilingpoint?

hexane or nonane
2,2,S-lrimethyl
RtALent s (ccvw LlS tr\, (")

of thesealkanesin
9. Writethe balanceequationto showthe combustion
oxygen.
a. butane
C+Ht + ,l^oo 4a, + JHro
b. pentane

CE H,^ + ,Z*" -) S@- * 6/l,o

c. decane

c,oil,, + br o, /o(9t + tlffoo

2