a)

equilibrio solido- vapor Datos de equilibrio Líquido - Vapor

P (kpa) T(K) Lnp) 1/T p
0.6108 273.15 -0.4929857 0.00366099 0.01228
0.4375 269.15 -0.8266786 0.0037154 0.02339
0.3102 265.15 -1.170538 0.00377145 0.04246
0.2176 261.15 -1.5250968 0.00382922 0.07384
0.151 257.15 -1.8904754 0.00388878 0.1235
0.1035 253.15 -2.2681837 0.00395023 0.1994

CALCULO DEL PUNTO TRIPLE CON EL SOLVER

T F(T) LN(P) P
275.439147 -1.421085E-14 -0.3061466 0.7362787
solido-vapor
0
0.0036 0.00365 0.0037 0.00375 0.0038 0.00385 0.0039 0.0

-0.5
f(x) = - 6137.1082770572x + 21.975
-1
R² = 0.9999998841

-1.5

-2

-2.5
librio Líquido - Vapor
P (kPa) T (°K) Ln(P) 1/T dh sub
10 1.228 283.15 0.20538683 0.0035317 45677.116
20 2.339 293.15 0.84972349 0.00341122
30 4.246 303.15 1.44597736 0.0032987
40 7.384 313.15 1.9993155 0.00319336
50 12.35 323.15 2.51365606 0.00309454
60 19.94 333.15 2.99272776 0.00300165

lido-vapor liquido-vapor
5 0.0038 0.00385 0.0039 0.00395 0.004 3.5

3
f(x) = - 5259.0161528385x + 18.7869154702
.1082770572x + 21.9751197707 2.5 R² = 0.9999566804
98841
2

1.5

0.5

0
0.0029 0.003 0.0031 0.0032 0.0033 0.0034 0.0035 0.0036
 dh fus dh vap
-5429.042 51106.158

7869154702

0.0034 0.0035 0.0036

T P T(K) P (kpa) 1/T Lnp)
80 0.0888 353.15 0.01183903 0.00283166 -4.436353913
100 0.2729 373.15 0.03638367 0.00267989 -3.313635135
120 0.7457 393.15 0.09941849 0.00254356 -2.308417188
140 1.845 413.15 0.24597976 0.00242043 -1.402506006

0 Chart Title
0.0024 0.0025 0.0026 0.0027 0.0028
-0.5
-1 ∆H vap EN J/MOL
-1.5 61336.535
f(x) = - 7377.5262022047x + 16.455650325
-2 R² = 0.9999984865 presion de vapor a 160 °c
-2.5 temperatura P(Kpa)
-3 433.15 0.562026693
-3.5
Tb(K) Pb(Kpa)
-4
623.186401 101.2555947
-4.5
CALCULO DEL PUNTO TRIPLE CON EL SOLVER
-5
T F(T)
275.439147 -1.42109E-14
 temperatura f presion fp
433.15 0.562026693 0.56202676 433.150003
de vapor a 160 °c

UNTO TRIPLE CON EL SOLVER

LN(P) P
-0.3061466 0.7362787
T P T(K) P (kpa) 1/T Lnp)
-120 9.81 153.15 1.3078924 0.00652955 0.26841699
-110 34.63 163.15 4.61695351 0.00612933 1.52973507
-100 104.81 173.15 13.9735171 0.00577534 2.6371639
-90 279.5 183.15 37.2636011 0.00546001 3.61801701

Chart Title
4

3.5
f(x) = - 3131.9655788139x + 20.7223017277
3 R² = 0.9999913207
2.5

1.5

0.5

0
0.0054 0.0056 0.0058 0.006 0.0062 0.0064 0.0066
respuestas
a) ∆H vap EN kJ/MOL
26.039448
b) presion de saturacion a -75°C
T(K) P(kpa)
198.15 136.427395

temperatura f presion fp
198.15 136.427397 136.427395 198.15
 respuesta
T(k) P(mmHg) 1/T lnP ∆Hde vaporizacion
293 14.551237 0.00341297 2.67767601 46.7687442 kJ/mol
343 238.970312 0.00291545 5.47633933

lnP vs 1/T
6

f(x) = - 5625.2572988417x + 21.8765063787

5 R² = 1

0
0.0028 0.0029 0.003 0.0031 0.0032 0.0033 0.0034 0.0035
 R ∆H fus
T(K) P(mmHg) 1/T lnP (kcal/molK) (Kcal/mol)
1879.15 0.1 0.00053216 -2.3025851 0.0019872 4.25
2078.15 1 0.0004812 0

T(k) ecuacion P(torr) lnP

3103.63406 1.0724E-07 1318.08897 7.18393822 Chart Title
0
0.00047 0.00048f(x) =0.00049 0.0005
- 45185.6935028197x 0.00051 0.00052
+ 21.7432300377 0.0
R² = 1
-0.5

-1

-1.5

-2

-2.5
 repuesta
presion para 1200°C
c lnp P(mmHg)
22.4320914 -9.6927347 6.173E-05

∆Hvap(kcal/ ∆Hsub
mol) (Kcal/mol) ecuacion de clauss clapeiron para fusion
89.7936192 94.0436192 7.87302953 lnP=-2138.6876x+7.87302953

2138.6876 47324.6876

Chart Title ecuacion de claus clapeiron para sublimacion

lnP=-47324.6876x+22.4320914
0.0005
6935028197x 0.00051 0.00052
+ 21.7432300377 0.00053 0.00054
punto triple
ecuacion T(k) P(mmHg)
-7.0179E-10 195.19774 44.6216857
 Datos para el isobutano obtenidos experimentalmente a 25°F
P(bar) v(cm3/mol) v(m3/mol) v-rt/p areas integral Ø
1 24644.673 0.024644673 0.000272182 0.000136091 0.00013609 1.0055994137
2 12250.097 0.012250097 6.38515E-05 0.0001680168 0.00030411 1.0125556685
4 6052.0811 0.0060520811 -4.104165E-05 2.280985E-05 0.00032692 1.0135037478
6 3985.397 0.003985397 -7.6684833E-05 -0.000117726 0.00020919 1.0086200234
8 2951.5201 0.0029515201 -9.5041275E-05 -0.000171726 3.7465E-05 1.0015383663
10 2330.7432 0.0023307432 -0.0001065059 -0.000201547 -0.0001641 0.9932903419
12 1916.4951 0.0019164951 -0.0001145458 -0.000221052 -0.0003851 0.9843222054
15 1501.6115 0.0015016115 -0.0001232212 -0.000356651 -0.0008779 0.9646218584

V-f3/lb molECUACION DE S-R-K

P(bar) srk fsrk b a tr fw
1 0.00419763 -1.258153844 0.1024876730 0.0000046723 1.0384 0.618896152
2 0.00419763 -2.258153844
4 0.00419763 -4.258153844
6 0.00419763 -6.258153844
8 0.00419763 -8.258153844
10 0.00419763 -10.25815384
12 0.00419763 -12.25815384
15 0.00419763 -15.25815384

V-f3/lb mol relich kwong

P(psia) rk frk b a v-rt/p areas
1 0.02422421 -3.434419E-07 0.00004034677 0.000078500 -0.0001483 -7.414188E-05
2 0.01203742 -1.256142E-09 -0.0001488 -0.000148554
4 0.00594321 8.120166E-09 -0.0001499 -0.000298738
6 0.00391104 -1.182514E-08 -0.000151 -0.000300959
8 0.00289434 -9.341823E-09 -0.0001522 -0.000303264
 10 0.00228381 -2.142231E-08 -0.0001534 -0.000305657
12 0.00187633 -2.535917E-07 -0.0001547 -0.000308146
15 0.00146812 -6.247071E-07 -0.0001567 -0.000467131

V-f3/lb mol vander waals

P(psia) rk frk b a v-rt/p areas
1 0.02424096 -8.326527E-07 0.0001 0.00000461 -0.0001315 -0.000065764
2 0.01205412 -0.000000741 -0.0001321 -0.000131826
4 0.0059598 -2.865755E-07 -0.0001333 -0.000265445
6 0.00392752 -7.34079E-07 -0.0001346 -0.00026788
8 0.00291071 -5.715029E-07 -0.0001358 -0.000270407
10 0.00230006 -5.832402E-07 -0.0001372 -0.000273037
12 0.00189245 -5.337294E-07 -0.0001386 -0.000275776
15 0.00148403 -1.570604E-07 -0.0001408 -0.000419086
fp propiedades del isobutano
1.0055994137 T(k) R(bar m3/molPc bar Tc(k) P(bar) T(k)
2.025111337 293.15 0.00008314 50.4 282.3 50.4 282.3
4.0540149912
6.0517201405
8.0123069303
9.9329034191
11.811866465
14.469327876

α v-rt/p areas integral Ø fp

0.9766 -0.0201749 -0.010087431 -0.0100874 0.66107635 0.66107635
-0.0079886 -0.01408174 -0.0241692 0.3709612 0.74192239
-0.0018955 -0.009884112 -0.0340533 0.24728801 0.98915206
0.00013555 -0.001759948 -0.0358132 0.23006072 1.38036433
0.00115107 0.0012866131 -0.0345266 0.2425318 1.94025441
0.00176038 0.0029114457 -0.0316152 0.27330518 2.73305184
0.00216659 0.0039269662 -0.0276882 0.32108695 3.85304337
0.0025728 0.0071090739 -0.0104917 0.65020144 9.75302161

integral Ø fp
-7.414188E-05 0.99696259 0.9969625908
-0.000222695 0.99090445 1.9818089062
-0.000521433 0.97883291 3.9153316361
-0.000822392 0.96682029 5.8009217312
-0.001125656 0.9548648 7.6389183871
 -0.000909881 0.96335598 9.6335598418
-0.00173946 0.9311175 11.173410026
-0.002132449 0.91622428 13.743364254

integral Ø fp
-0.000065764 0.99730535 0.997305351
-0.00019759 0.99192569 1.983851377
-0.000463035 0.98118108 3.9247243244
-0.000730915 0.97045588 5.8227352548
-0.001001322 0.9597484 7.6779871785
-0.000811324 0.96725944 9.6725944407
-0.001550135 0.93837856 11.260542704
-0.001903457 0.92487324 13.873098539
w
0.087
equilibrio punto de burbuja
parametros de antonnie
k A B C P(Kpa) x Tsat t supuesta
1 14.5463 2940.46 237.22 85 0.3 53.8095 74.065
2 14.2724 2945.47 224 0.45 75.6485543 70.917
3 14.2043 2972.64 209 0.25 95.5223279 70.498
4 0 70.441
70.434
70.433
70.433
70.433
70.433
P1sat Psat2 p3sat P4sat α14 α24 α34 α44
164.040 80.676 40.556 1.000 4.04473277 1.9892209 1
148.950 72.600 36.039 1.000 4.13303979 2.01448515 1
147.026 71.575 35.469 1.000 4.14515655 2.01793482 1
146.767 71.437 35.393 1.000 4.14680563 2.018404 1
146.732 71.418 35.382 1.000 4.14702982 2.01846778 1
146.727 71.416 35.381 1.000 4.14706029 2.01847645 1
146.726 71.415 35.381 1.000 4.14706443 2.01847763 1
146.726 71.415 35.381 1.000 4.147065 2.01847779 1
146.726 71.415 35.381 1.000 4.14706507 2.01847781 1
P(Kpa) T1 Ts-Tc y
36.0387979 70.9174 3.1479 0.51785783
35.4694237 70.4983 0.4191 0.37808107
35.3928114 70.4415 0.0568 0.10406111
35.3824122 70.4337 0.0077
 35.380999 70.4327 0.0010
35.3808069 70.4326 0.0001
35.3807808 70.4325 0.0000
35.3807772 70.4325 0.0000
35.3807768 70.4325 0.0000
A)
k A B C T(°C) x1 0.25 P1(Kpa)
1 14.5463 2940.46 237.22 85 x2 0.35 P2(Kpa)
2 14.2724 2945.47 224 x3 0.4 P3(Kpa)
3 14.2043 2972.64 209 x4 0 P4(Kpa)
4
B)
k A B C T(°C) Y1 0.5 Psat1
1 14.5463 2940.46 237.22 75 Y2 0.3 Psat2
2 14.2724 2945.47 224 Y3 0.2 Psat3
3 14.2043 2972.64 209 Y4 0 Psat4

c)
k A B C P(Kpa) x Tsat t supuesta
1 14.5463 2940.46 237.22 85 0.3 53.8095 74.065
2 14.2724 2945.47 224 0.45 75.6485543 70.917
3 14.2043 2972.64 209 0.25 95.5223279 70.498
4 0 70.441
70.434
70.433
70.433
70.433
70.433
D)
A B C P(Kpa) Y Tsat Tsup P1
14.5463 2940.46 237.22 90 0.6 55.4652964 68.2226 136.92282
14.2724 2945.47 224 0.2 77.4011537 73.4610 161.053527
14.2043 2972.64 209 0.2 97.315932 73.9100 163.2683
0 0 73.9478 163.455717
73.9509 163.471467
73.9512 163.47279
73.9512 163.472901
73.9512 163.47291
226.030862 P(Kpa) Y1 0.4687899
114.449609 120.540 Y3 0.33231722
59.9361358 Y4 0.19889288
1 y4

168.745144 P(Kpa) x1 0.261

83.2068575 88.243 x2 0.318
41.9827049 X3 0.420
1 X4

P1sat Psat2 p3sat P4sat α14 α24 α34 α44

164.040 80.676 40.556 1.000 4.04473277 1.9892209 1
148.950 72.600 36.039 1.000 4.13303979 2.01448515 1
147.026 71.575 35.469 1.000 4.14515655 2.01793482 1
146.767 71.437 35.393 1.000 4.14680563 2.018404 1
146.732 71.418 35.382 1.000 4.14702982 2.01846778 1
146.727 71.416 35.381 1.000 4.14706029 2.01847645 1
146.726 71.415 35.381 1.000 4.14706443 2.01847763 1
146.726 71.415 35.381 1.000 4.147065 2.01847779 1
146.726 71.415 35.381 1.000 4.14706507 2.01847781 1
P2 P3 P4 α14 α12 α13 P1sat Tcal
66.2117358 32.5040442 1 4.21248566 2.0370307 1 39.6554 73.4610
79.0722934 39.6554259 1 4.06132386 1.99398422 1 40.3233 73.9100
80.2611773 40.3233098 1 4.04898062 1.99044121 1 40.3799 73.9478
80.3618442 40.3799113 1 4.04794641 1.99014415 1 40.3847 73.9509
80.3703044 40.3846685 1 4.04785957 1.99011921 1 40.3851 73.9512
80.371015 40.3850681 1 4.04785228 1.99011711 1 40.3851 73.9512
80.3710746 40.3851016 1 4.04785167 1.99011693 1 40.3851 73.9512
80.3710797 40.3851044 1 4.04785162 1.99011692 1 40.3851 73.9512
P(Kpa) T1 Ts-Tc y
36.0387979 70.9174 3.1479 0.51785783
35.4694237 70.4983 0.4191 0.37808107
35.3928114 70.4415 0.0568 0.10406111
35.3824122 70.4337 0.0077
35.380999 70.4327 0.0010
35.3808069 70.4326 0.0001
35.3807808 70.4325 0.0000
35.3807772 70.4325 0.0000
35.3807768 70.4325 0.0000
abs(tsup-tcal)x
5.23840859 0.3303
0.44898411 0.2240
0.03777284 0.4457
0.00317276
0.00026646
2.2378E-05
1.8794E-06
1.5784E-07
T P
60 125 condicio de flasheo Procio<P<Pburbuja no flashea
Kpa
I Z A B C Pisat Procio Pburbuja
N-pentanol 0.5 13.8183 2477.07 233.21 214.90394 49.6605137 121.488947
n-heptano 0.5 13.8587 2911.32 216.64 28.073955