First Law of Thermodynamic Calculations

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Solved Problem 3.

7 - An ideal air-standard Otto cycle engine has a compression ratio of


8. At the beginning of the compression process, the working fluid is at 100 kPa, 27°C (300 K),
and 800 kJ/kg heat is supplied during the constant volume heat addition process. Neatly sketch
the pressure-volume [P-v] diagram for this cycle, and using the specific heat values for air at a
typical average cycle temperaure of 900K determine:

 a) the temperature and pressure of the air at the end of each process
 b) the net work output/cycle [kj/kg], and
 c) the thermal efficiency [ηth] of this engine cycle.

Solution Approach:

The first step is to draw the P-v diagram of the complete cycle, including all the relevant
information. We notice that neither volume nor mass have been provided, hence the diagram
and solution will be in terms of specific quantities.

We assume that the fuel-air mixture is represented by pure air. The relevant equations of state,
internal energy and adiabatic process for air follow:

We recall from the previous section that the nominal specific heat capacity values used for air at
300K are Cv = 0.717 kJ/kg.K,, and k = 1.4. However they are all functions of temperature, and
with the extremely high temperature range experienced in internal combustion engines one can
obtain significant errors. In this problem we use a typical average cycle temperature of 900K
taken from the table of Specific Heat Capacities of Air.

We now go through all four processes in order to determine the temperature and pressure at the
end of each process, as well as the work done and heat transferred during each process.
Note that the pressure P4 (as well as P2 above) could also be evaluated from the adiabatic
process equation. We do so below as a vailidity check, however we find it more convenient to
use the ideal gas equation of state wherever possible. Either method is satisfactory.
We continue with the final process to determine the heat rejected:

Notice that we have applied the energy equation to all four processes allowing us two alternative
means of evaluating the "net work output per cycle" and the thermal efficiency, as follows:

Note that using constant specific heat values over the cycle we can determine the thermal
efficiency directly from the ratio of specific heat capacities k with the following formula:

where r is the compression ratio

Quick Quiz: Using the heat and work energy equations derived above, derive this relation
Problem 3.8 - This is an extension of Solved Problem 3.7, in which we wish to use
throughout all four processes the nominal standard specific heat capacity values for air at 300K.
Using the values Cv = 0.717 kJ/kg.K, and k = 1.4, determine:

 a) the temperature and pressure of the air at the end of each process [P2 = 1838 kPa, T2 =
689K, T3 = 1805K, P3 = 4815 kPa, P4 = 262 kPa, T4 = 786K]
 b) the net work output/cycle [451.5 kJ/kg], and
 c) the thermal efficiency of this engine cycle. [ηth = 56%]

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