CRYSTALLINE

WATERPROOFING IN
CONCRETE

SUBMITTED BY
GUIDED BY VISHNU P
S8 CE
Department Of Civil Engineering
 OVERVIEW
• INTRODUCTION
• NATURE OF CONCRETE
• MOISTURE RELATED PROBLEMS
• WATER PROOFING
• METHODS
• CRYSTALLINE TECHNOLOGY
• METHOD OF APPLICATION
• TEST ON CRYSTALLINE SEALER
• CASE STUDY
• CONCLUSION
• REFERENCES
 INTRODUCTION
 Concrete is a composite construction material
 It is porous & permeable
 To make it workable more water is added
 Extra water bleed out of concrete
 If not waterproofed it can absorb water and
aggressive chemicals
 Crystalline waterproofing: blocks the movement of
water
 THE NATURE OF CONCRETE
Concrete is a heterogeneous composite of coarse and fine
aggregate particles held together by cement paste.

Cement paste ordinarily constitutes about 25 to 40 % of the total

volume of concrete.

To make it workable more water is

added extra water, known as the
water of convenience, will bleed
out of the concrete, leaving behind
pores and capillary tracts corrode
steel reinforcement and
deteriorate concrete.
 THE POROUS AND PERMEABLE NATURE
OF CONCRETE

 Concrete as a porous and permeable material.

 Porosity refers to the Amount of holes or voids left in concrete, is
expressed as a percentage of the total volume of a material.
 Permeability is an expression of how well the voids are connected

To make concrete workable

This extra water will bleed out of
concrete leaving behind pores and
capillary tracts.
Resistance to water permeability
is essential requirement for
durability. Hence waterproofing .
 MOISTURE RELATED PROBLEMS

Freeze-thaw damage
 The change in the volume of water inside the pores of concrete
causes stresses on particles adjacent to these pores
 Dependent on internal factors such as water content, pore
structure, and distribution , also hydraulic pressure and osmotic
pressure
 Different thermal contraction of the constituents, the
temperature gradient
Alkali silica reaction (ASR)
 Water is considered to be a catalyst for the alkali silica reaction
 Most important factors that affect the ASR are amount of
available moisture, the nature of the reactive silica, the amount
of reactive silica and the particle size of the reactive material
 cont.
 Acidic attack
Water can be considered to be acidic, when compared to concrete;
therefore, the penetration of water can cause an acid-base reaction
that can damage the concrete.
 Chloride ion diffusion.
Corrode the reinforcement of the concrete
 Sulfate attack
Sulphates can attack concrete by reacting with hydrated compounds
in the hardened cement paste.
These expansive reactions can induce sufficient pressure to disrupt
the cement paste, resulting in disintegration of the concrete
 WATERPROOFING
Damp proofing vs. Waterproofing
 Damp proofing products that get applied to the surface are coatings
and form a physical barrier against water.
 Damp proofing admixtures are typically hydrophobic
 Damp proofing products will not resist water under pressure.
 For structures exposed to water under hydrostatic pressure,
waterproofing is required.
 Surface applied or admixtures, form a strong physical barrier to
water and will prevent water from entering the concrete even
under a significant head pressure.
Hydrophilic vs. Hydrophobic

Hydrophobic or water repellent

products such as fatty acid
derivatives (stearates), soaps, oils ,
silicones and finely divided solids
(bentonite, siliceous powders,
etc.), repel water by increasing
hydrophobicity

Hydrophilic chemicals absorb

and utilize water to catalyze
and react with cement
particles to produce elongated
crystalline structures
Positive And Negative-Side Waterproofing
 “positive” side of a waterproofing application
the side where the water will be coming in contact with the
concrete
 Negative side waterproofing is applied to the inside (dry) face of
a structure
 WATERPROOFING METHODS
Fluid Applied Membranes
Fluid-applied waterproof products are
liquid coatings containing a base of
urethanes, rubbers, plastics, vinyl’s,
polymeric asphalts, or combinations
thereof, which are applied to the surface
usually by spraying or rolling.

Sheet Membranes
Sheet membrane products are normally
made from thermoplastics, vulcanized
rubbers, and rubberized asphalts. The
sheeting membranes can be applied as fully
bonded to the substrate or unbonded.
 Internal Waterproofing
 Also known as integral waterproofing, are products that perform
their function within the pores of the concrete as opposed to on
the surface

 Significant advantage of being extremely durable

 Two major groups: reactive or un-reactive.

 Examples of unreactive products include sodium silicate,

bentonite, water repellents, pozzolans etc.

 Reactive products are crystalline in nature and grow crystal

formations to block cracks, pores.
 EARLIER TECHNOLOGIES AND ITS DEMERITS

Barrier systems
 Mainly polymeric systems (epoxy resin, acrylic resins, bitumen
systems, etc.)
 Drawback on barrier systems is the one-sided protection
Silicate solution
 Gel will absorb internal moisture from the concrete and begin to
swell
 Produce extreme internal pressures and stresses
 Damaged quite severely
Siiane/ siloxane products

 Waterproofing materials for large concrete structures, such as

airports, bridges, and marine applications
 Moisture-repellent nature to minimize the water penetration
increasing environmental concerns
 Because of the use of solvent-based products
 CRYSTALLINE WATERPROOFING
TECHNOLOGY
 Contrast to conventional methods
 Has been used in Europe & North
America for many years
 Method of waterproofing has been
proven effective
 Prevent movement by filling the
pores , capillaries & micro cracks.
 Become integral part of the
structure
 CRYSTALLINE CHEMICALS

oCrystalline chemicals create a reaction that causes long , narrow

crystals to form and fill the pores , capillaries and hairline cracks of
the concrete mass

oCrystalline growth continues till moisture is available

oOnce the concrete is cured & dried the chemicals sit dormant until
other dose of water cause the chemical reaction to begin again &
grow crystals to shut off water
 WORKING OF CRYSYALLINE
TECHNOLOGY
Waterproofing effect is based on 2 reaction
1. Physical
2. Chemical
• Chemical diffusion is the physical reaction.
• Soln of high chemical density will migrate
through a soln of low chemical density until the
2 equalizes.
• Water the low chemical density liquid is
applied to concrete before crystalline chemicals.
WORKING ( CONTIUE)…
• Chemical reaction takes place between the crystalline water
proofing chemicals & by products of cement hydration in
the presence of moisture.

• Crystalline formation

• Reaction continue until the crystalline chemicals are either

depleted or run out of the water.

• The crystalline formation fills and plugs the voids in concrete

becoming an integral and permanent part of the structure.
CRYSTALLIZATION PROCESS
COMPARISON WITH TRADITIONAL
METHODS
 SELF SEALING
• Concrete can crack due to drying shrinkage , settling , seismic activity

• Concrete is able to seal itself off without the help of crystalline

materials . Cracks can become blocked by deposited lime salts or loose
material carried by the flow of water. This is called autogenous healing
and can occur if cracks are very tight – less than 0.2mm

• Seal much wider cracks

• Once the concrete is cured & dried the chemicals sit dormant until
other dose of water cause the chemical reaction to begin again & grow
crystals to shut off water.
 SELF SEALING

Crystalline materials can seal these cracks plus much wider

cracks. Most manufacturers claim crack sealing up to 0.4 or
0.5mm
 STABILITY

• Resistant to chemicals with ph

between 3 & 11 under constant
contact
• Resistant to chemicals
• with ph between 2 & 12 under
periodic contact
• Tolerate temperature between -
32 & 130 degree Celsius
• Humidity , UV & oxygen levels
have no effect on the ability to
perform
 CRYSTALLINE TECHNOLOGY
APPLICATIONS

3 different application methods

1. Applied as a coating to surface of an existing structure

2. Mixed directly at the batch plant as an admixture

3. Shaken as a dry powder to fresh concrete and trowelled into

surface
 BRUSH ON METHOD/SURFACE
COATING
 Crystalline product are supplied as a dry powder

 Mixed with water to form slurry

 Applied to inner or outer structure

 Best to apply on negative side

 Crystalline chemicals are absorbed into the

cement by capillary action

 Majority of chemicals migrate into concrete in 28

days
 Stages of Application
1. Surface preparation
 Have an open pore texture to allow the transfer of the reactive
crystalline chemicals
 Be clean and free of form oil, laitance and other foreign matter
2. Wetting the surface
 Concrete be in a saturated, surface damp condition
 Diffusing medium that allows the chemicals to transfer from the
coating into the capillary tracts
3.Coating application
 With a brush, broom, or spray equipment.
4.Curing
 Evaporation will first dry out the coating and then begin to pull
moisture from out of the concrete
 Hardens and bonds properly to the concrete
 DRY SHAKE METHOD
When placing concrete slab
crystalline product as a dry powder is
applied on surface just prior to
finishing

Material is troweled into the surface

New concrete has high moisture

content –accelerates the reaction

Becomes part of the concrete the

surface can be finished smooth
 ADMIXTURE METHOD
• For new construction

• Crystalline admixture is added into

the concrete mix

• Result in complete even and

immediate distribution of
crystalline product

• Material time and labour required

to apply on surface can be avoided
 BENEFITS
• Integrated -Penetrate into the concrete-will not crack ,peal, tear or
wear away
• Self sealing
• Environmental friendly
• Can be used from negative side
• Unaffected by climate and remain effective
• Saves time
• Protects reinforcing steel
• Perfect for blind wall application
• Inhibits the effects of CO, C02, S02 and N02
• Protects concrete against alkali aggregate reactions
 APPLICATIONS
• Potable water tanks

• Waste water treatment plants

• Tunnels

• Elevator pits

• Manholes

• Foundations

• Below grade waterproofing

TEST ON CRYSTALLINE PENETRATION SEALER MATERIAL
The study conducted by Department of Harbor and River Engineering,
National Taiwan Ocean University.

Water Permeability Test and Rapid Chloride Permeability Test (RCPT)

Permeability method intended to compare the CPSM coated and

uncoated groups with each other

Recording 20.62% of less water permeability and 18.71% of lower

current measured when estimating the resistance of the specimen to
chloride ion penetration.
In other words, the CPSM treated samples show less water
penetration.
X-Ray Diffraction (XRD)

 The XRD analyses were performed to investigate CPSM’s topping

 Acicular-structured substance, and two layers of substance at 5 and

20 mm beneath the topping respectively.

 The XRD show that the main hydration products of CPSM are C-S-H

gel and CaCO3.

Scanning Electron Microscope (SEM)

 To see an interaction between CPSM and substrate, SEM

photographs (1000× magnification) of the substrate sample

the sample surface of cross-sections at 5 mm beneath the

surface.

 Shows that an indefinite number

of acicular-like crystals were

substantially and uniformly

distributed to the surface of the

substrate.
 Mercury Intrusion Porosimetry (MIP)

 The ASTM D4404-10 [13]

standard test method

 In determining the volume and
the volume distribution of pores
 The values of porosity are
smaller for the CPSM coating
samples, giving a total sum of
nearly 20%.
 Partially seals the capillary
channels and micro cracks

Volume change of pores

 Thermogravimetric Analysis (TGA)

 The TGA has been applied to the examination of water of

crystallization and comparison of varnishes and other surface
coatings

 Depth of penetration capability is within 0–10 mm of the sealer

layer beneath the concrete surface, identified by the TGA result.
 CASE STUDY: AS AN ADMIXTURE
o New headquarters for Maybank by architect Hajis kasturi

o Situated in Kuala lumpur, Malaysia

o Crystalline technology was selected to reduce shrinkage cracks, For

better Self healing capacity, Water proofing, Increase strength and
durability

o Basement slab required 24000cubic meters of concrete with

crystalline admixture

o Initial pour of 13200cubic meters over 60 hour is the 3rd largest

continuous concrete pour
EXCAVATION AND DIAPHRAM WALL
FOR MAYBANK HEADQUARTERS
 CASE STUDY : AS AN APPLIED COAT
National aeronautics and space
administration (NASA)

For neutral buoyancy tank

2 coat application of white

crystalline waterproofing for
50000sqfttank

To train astronauts for space walk

For longer life span & lower

maintenance
 CASE STUDY 3: DRY SHAKE
APPLICATION
 In Cleveland, Tennessee

 Slab of 110000sqft
distribution facility for
Duracell

 Dry shake application with

floor hardener

 For waterproofing
 CONCLUSION

Crystalline waterproofing technology will reduce porosity and

permeability

Provide high performance and benefits

Crystals of this salt grows relatively fast and, therefore,

minimize pore volumes inside the concrete.

 Cost-effective, when compared with short-service-life barrier

systems.
 Becomes an integral part of the concrete to increase the service
life of the concrete.

 Also eliminates major demerits of earlier systems like barrier

system, silicate solution etc.

 Various experiments used to investigate the water-resisting

capability of concrete crystalline penetration sealer materials
shows that
• It has acicular-structured crystals filling capillary pores for mortar
substrate and
• It reduces porosity and appears more effective in sealing pores
or cracks
 REFERENCES

• Li-Wei Teng et. al, “A Study of Crystalline Mechanism of Penetration

Sealer Materials”, International Journal of Molecular Sciences,2014,
ISSN 1996-1944, 7, 399-412
• Awni Al-Otoom et. al, “Crystallization Technology for Reducing Water
Permeability into Concrete”, Ind. Eng. Chem. Res,2010, 46, 5463-5467
• Md. Safiuddin and K. A. Soudki, “Sealer and coating systems for the
protection of
• Concrete bridge structures”, International Journal of the Physical
Sciences, 2012, Vol. 6(37), pp. 8188-8199
• Geetha And P .Perumal, “Experimental Study on The Roll of
Waterproofing Admixtures on the Strength and Durability of
concrete” , Journal of engineering and applied sciences,2009,4(1):41-
45
THANKS
QUESTIONS