Sensitivity Analysis: Production of Ammonium Nitrate From Ammonia and Nitric Acid
Sensitivity Analysis: Production of Ammonium Nitrate From Ammonia and Nitric Acid
Sensitivity Analysis: Production of Ammonium Nitrate From Ammonia and Nitric Acid
SENSITIVITY
ANALYSIS
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SENSITIVITY ANALYSIS
Sensitivity analysis is a technique used to determine the performance of each process and
how varied weight values of the attributes: Economics, Manufacturability, Sustainability,
Environmental Impact and Safety will impact the chosen process. This is done to compare the
response of various processes upon changing conditions. The Single-Factor and the Two-Factor
Analysis are employed in this analysis.
The worst – case benchmark are the lowest weighted scores from each attribute while the
best – score benchmark for each attribute are designated by the process with the highest weighted
score in that attribute. Table 3.1 shows the worst – case and best – case benchmark for each attribute
based on the scores used in the process selection.
The level of importance of each attribute had been predetermined based on the significance
of each attribute to the process. Economics was deemed the most significant attribute and is scored
as 100. The scores for the succeeding attributes are calculated by getting of the difference of the
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best value and worst value for that attribute divided by the best value for that attribute multiplied by
one hundred. The scores for each attribute are presented in Table 3.2.
The three proposed process were rated from 0 to 1. The process with the highest score for
each attribute was rated as 1. On the other hand, the attribute that has the lowest score is rated as
0. The rate of the process in between the highest and the lowest is computed by the difference of
the highest score and the middle score divided by the difference of the middle score and the lowest
score. The corresponding rate for each process for each attribute is shown in Table 3.3. The total
score for each process is calculated as the sum product of the score and weight.
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Sensitivity Analysis
Single-Factor Method
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The results in Table 3.4 indicate that the chosen process would still be Process 1 even if the
Best-Economics score is changed from the base case score of 100. Further increasing the scores
even up to 1000, the choice of process is still Process 1. This implies that the most economical
among the three processes is Process 1 and is the best route for the production of ammonium nitrate.
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BEST SUSTAINABILITY
SCORE CHOICE
10 P1
20 P1
30 P1
40 P1
50 P1
60 P1
70 P1
80 P1
90 P1
100 P1
200 P2
300 P2
400 P2
500 P2
600 P2
700 P2
800 P2
900 P2
1000 P2
*Base score 10.00
Table 3.6 shows that a Sustainability score of 200 the chosen process changes from Process
1 to Process 2. Moreover, increasing the value further to 1000 the model still chooses Process 2 as
the best process. It can be assumed that at an analysis considering sustainability and holding other
attributes constant the most sustainable process is Process 2.
Table 3.7. Threshold Values for Sensitivity Analysis of Best-Sustainability Score
BEST SUSTAINABILITY
SCORE CHOICE
110 P1
120 P1
130 P2
140 P2
150 P2
160 P2
170 P2
180 P2
190 P2
200 P2
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Table 3.7 shows that at Sustainability value of 130.00 the choice of process changes from
Process 1 to Process 2. And continuously chooses Process 2 upon further increased value.
Table 3.8 shows the ranking of attributes at increased score of Sustainability. At this
condition the weight percentage of Sustainability increased from 5.22% to 41.74% edging Economics
with only 32.11%. This leaves Manufacturability at 6.88%, Environmental Impact at 6.42% and Safety
at 12.84%. Based on the weight calculated, the expected process would have:
1. Low cost due to low raw material cost as suggested by the high sustainability score
percentage.
2. High revenue due to high economic percentage.
3. Compromised safety and environmental conditions based on score percentage less than
10%.
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The results in Table 3.9 indicate that the chosen process would still be Process 1 even if the
Best-Environmental Impact score is changed from the base case score of 100. Further increasing
the scores even up to 1000, the choice of process is still Process 1. This implies that the most
environment - friendly among the three processes is Process 1 and is the best route for the
production of ammonium nitrate.
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The results in Table 3.10 indicate that the chosen process would still be Process 1 even if
the Best-Safety score is changed from the base case score of 100. Further increasing the scores
even up to 1000, the choice of process is still Process 1. This implies that the safest among the three
processes is Process 1 and is the best route for the production of ammonium nitrate.
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Sensitivity Analysis
Two-Factor Method
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Table 3.12 shows that at Economics value of 80 to 100 with corresponding Sustainability
value of 10 to 100 and even higher, the chosen process is constantly Process 1. Though passing
when score mark for Economics is at 10 to 70 with changes in score of Sustainability from 40 to
100, the process shifts from Process 1 to Process 2.
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Economics Score
Sustainability
10 20 30 40 50 60 70 80 90 100
Score
40 P2 P1 P1 P1 P1 P1 P1 P1 P1 P1
41 P2 P1 P1 P1 P1 P1 P1 P1 P1 P1
42 P2 P1 P1 P1 P1 P1 P1 P1 P1 P1
43 P2 P1 P1 P1 P1 P1 P1 P1 P1 P1
44 P2 P1 P1 P1 P1 P1 P1 P1 P1 P1
45 P2 P1 P1 P1 P1 P1 P1 P1 P1 P1
46 P2 P1 P1 P1 P1 P1 P1 P1 P1 P1
47 P2 P1 P1 P1 P1 P1 P1 P1 P1 P1
48 P2 P1 P1 P1 P1 P1 P1 P1 P1 P1
49 P2 P1 P1 P1 P1 P1 P1 P1 P1 P1
50 P2 P2 P1 P1 P1 P1 P1 P1 P1 P1
51 P2 P2 P1 P1 P1 P1 P1 P1 P1 P1
52 P2 P2 P1 P1 P1 P1 P1 P1 P1 P1
53 P2 P2 P1 P1 P1 P1 P1 P1 P1 P1
54 P2 P2 P1 P1 P1 P1 P1 P1 P1 P1
55 P2 P2 P1 P1 P1 P1 P1 P1 P1 P1
56 P2 P2 P1 P1 P1 P1 P1 P1 P1 P1
57 P2 P2 P1 P1 P1 P1 P1 P1 P1 P1
58 P2 P2 P1 P1 P1 P1 P1 P1 P1 P1
59 P2 P2 P1 P1 P1 P1 P1 P1 P1 P1
60 P2 P2 P1 P1 P1 P1 P1 P1 P1 P1
61 P2 P2 P1 P1 P1 P1 P1 P1 P1 P1
62 P2 P2 P2 P1 P1 P1 P1 P1 P1 P1
63 P2 P2 P2 P1 P1 P1 P1 P1 P1 P1
64 P2 P2 P2 P1 P1 P1 P1 P1 P1 P1
65 P2 P2 P2 P1 P1 P1 P1 P1 P1 P1
66 P2 P2 P2 P1 P1 P1 P1 P1 P1 P1
67 P2 P2 P2 P1 P1 P1 P1 P1 P1 P1
68 P2 P2 P2 P1 P1 P1 P1 P1 P1 P1
69 P2 P2 P2 P1 P1 P1 P1 P1 P1 P1
70 P2 P2 P2 P1 P1 P1 P1 P1 P1 P1
71 P2 P2 P2 P1 P1 P1 P1 P1 P1 P1
72 P2 P2 P2 P2 P1 P1 P1 P1 P1 P1
73 P2 P2 P2 P2 P1 P1 P1 P1 P1 P1
74 P2 P2 P2 P2 P1 P1 P1 P1 P1 P1
75 P2 P2 P2 P2 P1 P1 P1 P1 P1 P1
76 P2 P2 P2 P2 P1 P1 P1 P1 P1 P1
77 P2 P2 P2 P2 P1 P1 P1 P1 P1 P1
78 P2 P2 P2 P2 P1 P1 P1 P1 P1 P1
79 P2 P2 P2 P2 P1 P1 P1 P1 P1 P1
80 P2 P2 P2 P2 P1 P1 P1 P1 P1 P1
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Table 3.13 shows the exact threshold values at which Process 1 would change to Process
2 based on the Economics-Sustainability combination. In Table 3.12, it is shown that the process will
change at different points from an economics score of 10 to 70 and sustainability score of 40 to 100,
but further lowering of the sustainability score at certain points for a corresponding economics score
the choice would change to Process 2. However, the combination of the assessed scores are way
far from the base case score of 100 and 13, thus Process 1 is still the appropriate choice.
Table 3.14 shows the new ranking of the level of importance after Economics - Sustainability
score variation. The weight as Process 1 shifts to Process 2 are as follows; Economics decreases
from 52.24% to 7.61%, followed by Environmental Impact and Sustainability tied at 30.43%, Safety
at a decreased value of 6.00% and Manufacturability also at an increased weight of 16.31%. The
new ranking obtained is similar to the base ranking where Economics has the lowest weight which
means that you would have less profit in this combination. Also, it jeopardizes the overall safety of
the workers, but is environment – friendly due to an increase in weight. Again, although Process 2 is
the best choice it should still possess a balance value for all the attributes considered.
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The varied values of Manufacturability – Sustainability score shows that the most important
attribute would be Sustainability at 42.99% followed by Economics at 23.75%, Manufacturability at
19.00% Environmental Impact at 4.75% and Safety at 9.50%.
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Based on Single – factor Sensitivity Analysis it may observed that generally only Process 1
and Process 2 via for the process to be utilized. Each base score for each attribute are changed with
values ranging from 0% up to 1000%. Considering the Economics attribute the is constant to Process
1. With regards to Manufacturability Score, Safety Score, and Environmental Impact when raised to
1000% it still chooses Process 1 over the other two. However, in Sustainability Score, it shifts when
the score is raised to 200% to Process 2. Therefore, based on the scores in single factor analysis,
Process 1 is more appropriate in the long run, than the two other processes.
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2 over Process 1 at increased Sustainability and lowered Manufacturability and lowered Economics
compared to base scores.
In conclusion, using the sensitivity analysis as basis for choosing a process for the optimum
production of Ammonium Nitrate, bearing in mind that the most important attribute considered is
Economics and considering that other attributes must still be in a balance with each other, the chosen
process is Process 1.