100.

0%

90.0% f(x) = 0.936669081 exp( - 0.0045818474 x )

R² = 0.9319469638
80.0%

70.0%

60.0%
A%

A%
50.0% Exponential (A
%)

40.0%

30.0%

20.0%

10.0%

0.0%
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
 70.00

f(x) = - 0.0039207111x^2 + 1.0200931884x - 0.9304807086

60.00 R² = 0.997888805
q (mg/g)

50.00

40.00
q
Polynomial (q)
30.00

20.00

10.00

0.00
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
 0.06

0.05
k (min-1)

f(x) = - 6.81249461814651E-05x + 0.0442417575

0.04 R² = 0.3719274885

k
0.03 Linear (k)

0.02

0.01

0
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
 80.00

70.00
f(x) = 0.0039207111x^2 - 0.0200931884x + 0.9304807086
Ce (mg/L)

R² = 0.9980825119
60.00

50.00

Ce
40.00 Polynomial (Ce)

30.00

20.00

10.00

0.00
0.00 20.00 40.00 60.00Co80.00
(mg/L)
100.00 120.00 140.00 160.00
A4 A3 A2 A1 methylene blue 1st-3rd αραιωση 5:100 20
0.2941 -1.1677 1.6979 2.9839 4th-6th αραιωση 100:100 1
Pretreated Wheat Straw H2O: Βρύσης

1 lt methylene blue αχυρο (g) 1.00

προσρόφηση σε θ=23C V (L) 1.00
ημερομηνια 4/16/2015
αραιώσεις 1000:1000 500:1000 200:1000 90:1000 50:1000
t (min) abs 1 abs 2 abs 3 abs 1 abs 2 abs 3 abs1 abs3 abs1 abs 2 abs3 abs1 abs 2 abs3
0 1.749 1.740 1.735 0.983 1.012 0.986 0.404 0.406 0.437 2.585 2.580 1.818 1.791
5 1.645 1.644 1.719 0.991 1.111 1.081 0.400 0.423 0.437 2.515 2.513 1.724 1.733
10 1.739 1.736 1.750 1.002 1.099 1.004 0.418 0.410 0.476 2.441 2.451 1.664 1.667
15 1.754 1.765 1.902 1.053 1.182 1.057 0.414 0.409 0.481 2.408 2.395 1.631 1.629
20 1.751 1.758 1.816 1.025 1.100 1.039 0.408 0.406 0.435 2.389 2.392 1.592 1.591
25 1.719 1.719 1.742 0.990 1.093 1.129 0.410 0.418 0.450 2.354 2.369 1.545 1.557
30 1.767 1.760 1.812 0.994 1.101 1.101 0.435 0.426 0.400 2.322 2.343 1.531 1.536
35 1.740 1.748 1.741 0.991 1.047 1.056 0.409 0.407 0.407 2.303 2.306 1.477 1.489
40 1.719 1.711 1.764 1.010 1.134 1.011 0.392 0.402 0.410 2.284 2.271 1.456 1.470
45 1.716 1.715 1.758 0.989 1.158 0.985 0.404 0.418 0.400 2.236 2.246 1.438 1.446
50 1.727 1.732 1.805 0.961 1.041 1.020 0.405 0.400 0.401 2.218 2.220 1.414 1.416
55 1.714 1.712 1.770 1.095 1.093 1.116 0.400 0.416 0.428 2.207 2.189 1.384 1.387
60 1.726 1.717 1.730 0.998 1.194 0.986 0.409 0.384 0.397 2.160 2.155 1.358 1.356
65 1.706 1.706 1.764 0.969 1.005 1.016 0.387 0.374 0.369 2.144 2.143 1.339 1.340
70 1.727 1.719 1.756 0.955 1.081 0.985 0.402 0.405 0.404 2.114 2.105 1.329 1.327
75 1.706 1.701 1.779 0.946 1.017 1.034 0.403 0.416 0.430 2.075 2.077 1.292 1.288
80 1.729 1.730 1.748 0.952 1.028 0.978 0.429 0.415 0.388 2.060 2.054 1.257 1.263
85 1.703 1.705 1.734 0.949 0.997 1.007 0.411 0.389 0.396 2.032 2.050 1.244 1.223
90 1.715 1.718 1.730 0.936 1.060 0.985 0.390 0.386 0.386 2.004 2.014 1.217 1.226
95 1.669 1.664 1.715 0.914 1.050 0.982 0.376 0.382 0.377 1.985 1.994 1.192 1.203

t (min) ABS Φ1 ABS Φ2 ABS Φ3 ABS Φ4 ABS Φ5 ABS Φ6

0 1.741 0.994 0.416 2.583 1.805 0.782
5 1.669 1.061 0.420 2.514 1.729 0.781
10 1.742 1.035 0.435 2.446 1.666 0.717
15 1.807 1.097 0.435 2.402 1.630 0.714
20 1.775 1.055 0.416 2.391 1.591 0.712
25 1.727 1.071 0.426 2.362 1.551 0.689
30 1.780 1.065 0.420 2.333 1.534 0.676
35 1.743 1.031 0.408 2.305 1.483 0.671
40 1.731 1.052 0.401 2.278 1.463 0.644
 45 1.730 1.044 0.407 2.241 1.442 0.634
50 1.755 1.007 0.402 2.219 1.415 0.616
55 1.732 1.101 0.415 2.198 1.386 0.616
60 1.724 1.059 0.397 2.158 1.357 0.607
65 1.725 0.997 0.377 2.144 1.340 0.590
70 1.734 1.007 0.404 2.110 1.328 0.588
75 1.729 0.999 0.416 2.076 1.290 0.579
80 1.736 0.986 0.411 2.057 1.260 0.573
85 1.714 0.984 0.399 2.041 1.234 0.559
90 1.721 0.994 0.387 2.009 1.222 0.547
95 1.683 0.982 0.378 1.990 1.198 0.541

t (min) C1 C2 C3 C4 C5 C6
0 137.66 75.65 29.17 12.00 7.17 2.92
5 131.29 81.11 29.51 11.43 6.83 2.92
10 137.69 79.00 30.65 10.90 6.55 2.66
15 143.64 84.05 30.65 10.57 6.39 2.65
20 140.70 80.59 29.22 10.49 6.23 2.64
25 136.35 81.89 29.97 10.28 6.06 2.54
30 141.13 81.46 29.53 10.08 5.98 2.49 αραιώσεις 1000 500 200 90 50 20
35 137.81 78.70 28.55 9.90 5.77 2.47 1000 1000 1000 1000 1000 1000
40 136.76 80.35 28.06 9.72 5.69 2.36 Co 156.0 78.0 31.2 14.0 7.8 3.1
45 136.61 79.73 28.53 9.49 5.60 2.32
50 138.86 76.76 28.11 9.35 5.49 2.25
55 136.82 84.37 29.09 9.23 5.37 2.25
60 136.14 80.97 27.70 8.99 5.26 2.22
65 136.23 75.89 26.17 8.91 5.18 2.15
70 137.00 76.73 28.24 8.71 5.14 2.14
75 136.52 76.08 29.22 8.53 4.98 2.10
80 137.15 75.03 28.78 8.42 4.86 2.08
85 135.22 74.89 27.86 8.34 4.75 2.02
90 135.84 75.65 26.99 8.17 4.70 1.98
95 132.46 74.70 26.29 8.07 4.61 1.95

t (min) T(oC) 1 T(oC) 2 T(oC) 3 T(oC) 4 T(oC) 5 T(oC) 6

0 23.0 23.0 23.0 23.0 23.0 23.0
5 23.0 23.0 23.0 23.0 23.0 23.0
10 23.0 23.0 23.0 23.0 23.0 23.0
15 23.0 23.0 23.0 23.0 23.0 23.0
 20 23.0 23.0 23.0 23.0 23.0 23.0
25 23.0 23.0 23.0 23.0 23.0 23.0
30 23.0 23.0 23.0 23.0 23.0 23.0
35 23.0 23.0 23.0 23.0 23.0 23.0
40 23.0 23.0 23.0 23.0 23.0 23.0
45 23.0 23.0 23.0 23.0 23.0 23.0
50 23.0 23.0 23.0 23.0 23.0 23.0
55 23.0 23.0 23.0 23.0 23.0 23.0
60 23.0 23.0 23.0 23.0 23.0 23.0
65 23.0 23.0 23.0 23.0 23.0 23.0
70 23.0 23.0 23.0 23.0 23.0 23.0
75 23.0 23.0 23.0 23.0 23.0 23.0
80 23.0 23.0 23.0 23.0 23.0 23.0
85 23.0 23.0 23.0 23.0 23.0 23.0
90 23.0 23.0 23.0 23.0 23.0 23.0
95 23.0 23.0 23.0 23.0 23.0 23.0
μ.ο. 23 23 23 66 66 23

t (min) pH 1 pH 2 pH 3 pH 4 pH 5 pH 6
0 8.00 8.00 8.00 8.00 8.00 8.00
5 8.00 8.00 8.00 8.00 8.00 8.00
10 8.00 8.00 8.00 8.00 8.00 8.00
15 8.00 8.00 8.00 8.00 8.00 8.00
20 8.00 8.00 8.00 8.00 8.00 8.00
25 8.00 8.00 8.00 8.00 8.00 8.00
30 8.00 8.00 8.00 8.00 8.00 8.00
35 8.00 8.00 8.00 8.00 8.00 8.00
40 8.00 8.00 8.00 8.00 8.00 8.00
45 8.00 8.00 8.00 8.00 8.00 8.00
50 8.00 8.00 8.00 8.00 8.00 8.00
55 8.00 8.00 8.00 8.00 8.00 8.00
60 8.00 8.00 8.00 8.00 8.00 8.00
65 8.00 8.00 8.00 8.00 8.00 8.00
70 8.00 8.00 8.00 8.00 8.00 8.00
75 8.00 8.00 8.00 8.00 8.00 8.00
80 8.00 8.00 8.00 8.00 8.00 8.00
85 8.00 8.00 8.00 8.00 8.00 8.00
90 8.00 8.00 8.00 8.00 8.00 8.00
95 8.00 8.00 8.00 8.00 8.00 8.00
μ.ο. 8 8 8 8 8 8
20:1000
abs1 abs 2 abs3
0.787 0.777
0.791 0.770
0.747 0.686
0.715 0.713
0.719 0.704
0.692 0.685
0.682 0.670
0.672 0.669
0.654 0.634
0.650 0.618
0.610 0.622
0.613 0.618
0.608 0.606
0.591 0.589
0.586 0.590
0.581 0.577
0.576 0.569
0.561 0.557
0.545 0.549
0.544 0.538
 C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14
t (min) mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l
0 137.7 75.7 29.2 12.0 7.2 2.9 137.8 82.2 30.5 12.8 7.8 3.2 0.001105 0.079625 0.044595 0.061709
5 131.3 81.1 29.5 11.4 6.8 2.9 137.7 81.6 30.2 12.1 7.4 3.0 0.047317 0.013257 0.03359 0.106477
10 137.7 79.0 30.6 10.9 6.5 2.7 137.5 81.0 29.9 11.6 7.0 2.9 0.000888 0.038874 -0.00375 0.147982
15 143.6 84.0 30.6 10.6 6.4 2.6 137.4 80.5 29.7 11.1 6.6 2.8 -0.04228 -0.02252 -0.00375 0.173684
20 140.7 80.6 29.2 10.5 6.2 2.6 137.3 80.0 29.4 10.7 6.4 2.6 -0.02098 0.019496 0.042903 0.179869
25 136.3 81.9 30.0 10.3 6.1 2.5 137.2 79.5 29.2 10.3 6.1 2.5 0.010625 0.003735 0.018331 0.19587
30 141.1 81.5 29.5 10.1 6.0 2.5 137.0 79.1 28.9 10.0 5.9 2.5 -0.02406 0.008988 0.032743 0.211441
35 137.8 78.7 28.6 9.9 5.8 2.5 136.9 78.7 28.7 9.7 5.7 2.4 1.91E-05 0.042488 0.064875 0.226084
40 136.8 80.3 28.1 9.7 5.7 2.4 136.8 78.3 28.5 9.5 5.5 2.3 0.007602 0.022451 0.080898 0.239856
45 136.6 79.7 28.5 9.5 5.6 2.3 136.7 77.9 28.3 9.2 5.4 2.3 0.008682 0.030005 0.065719 0.257956
50 138.9 76.8 28.1 9.4 5.5 2.3 136.6 77.6 28.2 9.1 5.3 2.2 -0.0076 0.066147 0.079212 0.268591
55 136.8 84.4 29.1 9.2 5.4 2.2 136.4 77.3 28.0 8.9 5.2 2.2 0.00717 -0.02646 0.047132 0.278557
60 136.1 81.0 27.7 9.0 5.3 2.2 136.3 77.0 27.9 8.8 5.1 2.1 0.012134 0.014898 0.092684 0.297293
65 136.2 75.9 26.2 8.9 5.2 2.1 136.2 76.8 27.7 8.7 5.0 2.1 0.011488 0.076666 0.143004 0.303627
70 137.0 76.7 28.2 8.7 5.1 2.1 136.1 76.5 27.6 8.6 4.9 2.1 0.005872 0.066476 0.074998 0.318719
75 136.5 76.1 29.2 8.5 5.0 2.1 136.0 76.3 27.5 8.5 4.9 2.1 0.00933 0.074365 0.042903 0.333207
80 137.1 75.0 28.8 8.4 4.9 2.1 135.9 76.1 27.3 8.4 4.8 2.0 0.00479 0.087187 0.057276 0.341265
85 135.2 74.9 27.9 8.3 4.8 2.0 135.8 75.9 27.2 8.3 4.8 2.0 0.018801 0.088831 0.087635 0.347964
90 135.8 75.7 27.0 8.2 4.7 2.0 135.7 75.7 27.1 8.3 4.8 2.0 0.014288 0.079625 0.116206 0.361136
95 132.5 74.7 26.3 8.1 4.6 2.0 135.6 75.5 27.0 8.2 4.7 2.0 0.038854 0.091133 0.138823 0.369022

Ce 128.7 73.2 25.6 7.9 4.5 1.9 7% 3% 12% 34% 37% 35%
Co 137.8 82.2 30.5 12.8 7.8 3.2
k 0.0030 0.0143 0.0132 0.0287 0.0289 0.0288
sum 127.6966 148.9397 15.39105 2.397004 1.206209 0.193801
n-p 18 18 18 18 18 18
s 2.663505 2.87653 0.924694 0.36492 0.258866 0.103763

Co Ce k q A%
135.07 69.98 0.033049 65.09 48.2%
69.73 17.41 0.04212 52.31 75.0%
26.58 5.43 0.043876 21.14 79.6%
12.25 0.86 0.04912 11.40 93.0%
7.01 0.60 0.043631 6.41 91.4%
2.84 0.39 0.036387 2.45 86.4%
C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1
mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l D1 D2 D3 D4 D5 D6
0.080686 0.089086 0 0 0 0.390108 0.588546 0.999656 0.023173 42.83451 1.85403 0.622787 0.396044 0.081735
0.124897 0.090983 0.000975 0.007529 0.010234 0.424674 0.610821 0.985256 40.78679 0.221627 0.508574 0.502661 0.283131 0.013982
0.160504 0.171873 0.001935 0.01454 0.019814 0.454587 0.630112 0.999723 0.020833 4.000698 0.517792 0.454758 0.182563 0.051698
0.180218 0.175028 0.002881 0.021067 0.028782 0.480474 0.646818 1.013175 38.73702 12.8385 0.98683 0.263422 0.06249 0.011492
0.201624 0.178184 0.003813 0.027145 0.037176 0.502877 0.661285 1.006537 11.67146 0.395356 0.03057 0.028241 0.017016 2.01E-05
0.22334 0.207195 0.004732 0.032805 0.045035 0.522264 0.673814 0.996689 0.659499 5.709283 0.664781 2.62E-05 0.002692 1.86E-08
0.232774 0.222945 0.005637 0.038075 0.052391 0.539042 0.684665 1.007498 16.75361 5.715756 0.359884 0.013032 0.007939 0.001171
0.259794 0.229871 0.006529 0.042981 0.059277 0.553561 0.694061 0.999994 0.804863 0.001645 0.029225 0.041091 0.0041 0.007273
0.270423 0.263203 0.007408 0.04755 0.065722 0.566126 0.702199 0.997631 0.000716 4.255893 0.21469 0.070499 0.020113 0.001746
0.281545 0.275762 0.008274 0.051804 0.071756 0.577 0.709246 0.997295 0.003172 3.210358 0.033978 0.058093 0.037689 0.003186
0.295792 0.298338 0.009127 0.055765 0.077405 0.586411 0.715349 1.002369 5.31454 0.728268 0.003046 0.08084 0.041354 0.000998
0.3113 0.298964 0.009967 0.059453 0.082692 0.594554 0.720634 0.997766 0.148645 49.87058 1.178881 0.097461 0.0348 0.005014
0.326233 0.30961 0.010796 0.062887 0.087642 0.601602 0.725211 0.996219 0.034031 15.55866 0.023702 0.042907 0.025665 0.005234
0.335382 0.330872 0.011612 0.066085 0.092275 0.607701 0.729175 0.99642 0.000293 0.756457 2.399205 0.058902 0.027836 0.001227
0.341387 0.33337 0.012416 0.069062 0.096612 0.612979 0.732608 0.99817 0.813241 0.045185 0.435534 0.022697 0.035158 0.002893
0.361193 0.344606 0.013208 0.071834 0.100672 0.617546 0.735581 0.997093 0.285613 0.043266 3.11134 0.002792 0.008361 0.001674
0.376798 0.352712 0.013989 0.074416 0.104473 0.621499 0.738155 0.998507 1.607089 1.102021 2.076729 0.000654 0.000411 0.001224
0.390566 0.369525 0.014758 0.076819 0.10803 0.62492 0.740385 0.994141 0.310469 0.974868 0.387818 3.06E-05 0.001881 2.52E-06
0.396797 0.384443 0.015516 0.079057 0.111361 0.62788 0.742316 0.995548 0.028639 0.002179 0.021891 0.011251 0.002927 0.001183
0.409253 0.391891 0.016263 0.081141 0.114478 0.630442 0.743988 0.987893 9.69293 0.674578 0.55255 0.024858 0.014041 0.002049

127.6966 148.9397 15.39105 2.397004 1.206209 0.193801

 160.0

140.0
C (mg/L)

120.0 C=156 mg/L

C=78 mg/L
100.0 C=31 mg/L
C=14 mg/l
80.0 C=7,8 mg/l
C=3,1 mg/l
60.0 C=156 mg/L
C=78 mg/L
40.0 C=31 mg/L
C=14 mg/l

20.0 C=7,8 mg/l

C=3,1 mg/l

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 150.0
145.0
C (mg/L)

140.0
135.0
130.0
125.0
C=156
mg/L
120.0
115.0
110.0
105.0
100.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 90.0

80.0
C (mg/L)

70.0

60.0
C=78
mg/L

50.0

40.0

30.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 32.0

31.0
C (mg/L)

30.0

29.0

28.0

27.0 C=31
mg/L

26.0

25.0

24.0

23.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 14.0

12.0
C (mg/L)

10.0

8.0

C=14
6.0 mg/l

4.0

2.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 9.0

8.0

7.0
C (mg/L)

6.0

5.0

4.0 C=7,8
mg/l
3.0

2.0

1.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 3.5

3.0
C (mg/L)

2.5

2.0

1.5 C=3,1
mg/l

1.0

0.5

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 2.196593 0.892008 1.260764 1.408903 0.976385 0.010731
5 0.965379 2.066254 1.351734 1.258161 0.837254 0.004689
10 2.199914 1.756056 1.610305 1.094658 0.709166 -0.29422
15 2.706276 2.382899 1.610305 0.978127 0.630492 -0.30791
20 2.488016 1.999095 1.275302 0.947933 0.537412 -0.32178
25 2.038922 2.160771 1.465574 0.865313 0.433206 -0.45925
30 2.522748 2.109734 1.358405 0.777774 0.384323 -0.54264
35 2.213089 1.703389 1.067768 0.687811 0.229418 -0.58164
40 2.09173 1.965634 0.883631 0.595109 0.161241 -0.79404
45 2.073177 1.874651 1.058869 0.458537 0.084547 -0.88743
50 2.321811 1.266337 0.904672 0.368633 -0.02316 -1.08098
55 2.099059 2.412334 1.238558 0.276341 -0.15532 -1.08693
60 2.011475 2.049014 0.722604 0.075757 -0.30155 -1.19374
65 2.023327 0.98702 -0.64753 -0.0023 -0.403 -1.44879
70 2.120742 1.258693 0.955434 -0.2173 -0.47565 -1.48353
75 2.061884 1.055139 1.275302 -0.47899 -0.76142 -1.65664
80 2.138473 0.597977 1.144517 -0.66094 -1.06338 -1.80324
85 1.880313 0.520754 0.794784 -0.84236 -1.4359 -2.19996
90 1.970956 0.892008 0.293842 -1.33851 -1.6644 -2.76567
95 1.332905 0.401519 -0.42924 -1.82396 -2.38432 -3.24341

Ce 128.6634 73.21056 25.64361 7.907876 4.515446 1.912501

Co 137.8099 82.1954 30.53335 12.78851 7.799609 3.209184
ln(Co-Ce) 2.2134 2.1955 1.5871 1.5853 1.1891 0.2598
k 0.0030 0.0143 0.0132 0.0287 0.0289 0.0288
R -0.2311 -0.6490 -0.6489 -0.9626 -0.9525 -0.9539
R^2 0.0534 0.4212 0.4211 0.9266 0.9073 0.9099
 4
C=156 mg/L
3 Linear
ln(C-Ce)

(C=156 mg/L)
2 C=78 mg/L
Linear (C=78
1 mg/L)
C=31 mg/L
0 Linear (C=31
0 50 100 mg/L)
-1 C=14 mg/l
Linear (C=14
-2 mg/l)
C=7,8 mg/l
-3 Linear (C=7,8
mg/l)
-4 C=3,1 mg/l
t (min)
ln(C-Ce) 3
2.5
2
1.5
1
C=156 mg/L
0.5
0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 3
2.5
2
1.5
1
0.5 C=78 mg/L
0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 2
1.5
1
0.5
0
C=31 mg/L
-0.5
-1
0 10 20 30 40 t 50
(min)
60 70 80 90 100
 2
1.5
ln(C-Ce)

1
0.5
0
-0.5
-1 C=14 mg/l
0 10 20 30 40 50 60 70 80 90 100
-1.5
-2
t (min)
 1.5
1
ln(C-Ce)

0.5
0
-0.5
-1
0 10 20 30 40 50 60 70 80 90 100
-1.5 C=7,8 mg/l
-2
-2.5
-3

t (min)
ln(C-Ce)0.5
0
0 10 20 30 40 50 60 70 80 90100
-0.5
-1
-1.5
-2
-2.5
-3
-3.5

t (min)
 C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 -0.01678 -1.30353 -0.32638 -0.17637 -0.21273 -0.24908
5 -1.248 -0.12928 -0.23541 -0.32711 -0.35186 -0.25512
10 -0.01346 -0.43948 0.023165 -0.49062 -0.47995 -0.55403
15 0.492899 0.187361 0.023165 -0.60715 -0.55862 -0.56772
20 0.274639 -0.19644 -0.31184 -0.63734 -0.6517 -0.58159
25 -0.17445 -0.03477 -0.12157 -0.71996 -0.75591 -0.71906
30 0.309372 -0.0858 -0.22873 -0.8075 -0.80479 -0.80245
35 -0.00029 -0.49215 -0.51937 -0.89746 -0.95969 -0.84145
40 -0.12165 -0.2299 -0.70351 -0.99017 -1.02787 -1.05385
45 -0.1402 -0.32089 -0.52827 -1.12674 -1.10456 -1.14724
50 0.108434 -0.9292 -0.68247 -1.21664 -1.21228 -1.34079
55 -0.11432 0.216796 -0.34858 -1.30893 -1.34443 -1.34674
60 -0.2019 -0.14652 -0.86454 -1.50952 -1.49066 -1.45355
65 -0.19005 -1.20852 -2.23467 -1.58758 -1.59211 -1.7086
70 -0.09263 -0.93684 -0.63171 -1.80257 -1.66476 -1.74333
75 -0.15149 -1.1404 -0.31184 -2.06426 -1.95053 -1.91645
80 -0.0749 -1.59756 -0.44262 -2.24621 -2.25249 -2.06305
85 -0.33306 -1.67478 -0.79236 -2.42763 -2.62501 -2.45977
90 -0.24242 -1.30353 -1.2933 -2.92379 -2.85351 -3.02548
95 -0.88047 -1.79402 -2.01638 -3.40924 -3.57343 -3.50322

Ce 128.6634 73.21056 25.64361 7.907876 4.515446 1.912501

Co 137.8099 82.1954 30.53335 12.78851 7.799609 3.209184
k 0.0030 0.0143 0.0132 0.0287 0.0289 0.0288
 1
ln[(C-Ce)/(Co-Ce)]
0.5 C=156 mg/L

Linear (C=156 mg/L)

0
0 10 20 30 40 50 60 70 80 90 100 C=78 mg/L
-0.5
Linear (C=78 mg/L)

-1 C=31 mg/L

-1.5 Linear (C=31 mg/L)

C=14 mg/l
-2
Linear (C=14 mg/l)
-2.5
C=7,8 mg/l

-3 Linear (C=7,8 mg/l)

C=3,1 mg/l
-3.5
Linear (C=3,1 mg/l)
-4
t (min)
0.6

0.4

0.2

0
0 f(x)10
= - 0.0029586761x
20 30 40 50 60 70 80 90 100
-0.2 R² = 0.1732117695 C=156 mg/L
Linear (C=156 mg/L)
-0.4

-0.6

-0.8

-1

-1.2

-1.4
t (min)
0.5

C=78 mg/L
0 Linear (C=78 mg/L)
0 f(x)10
= - 0.0142731238x
20 30 40 50 60 70 80 90 100
R² = 0.729912321

-0.5

-1

-1.5

-2
t (min)
0.5

C=31 mg/L
0
0 f(x) 10
= - 0.0132075738x
20 30 40 50 60 70 80 90 100 Linear (C=31 mg/L)
R² = 0.7298881771
-0.5

-1

-1.5

-2

-2.5
t (min)
 0
0 f(x) =10
- 0.0287124114x
20 30 40 50 60 70 80 90 100
R² = 0.9791145591
-0.5

-1
C=14 mg/l
Linear (C=14 mg/l)
-1.5

-2

-2.5

-3

-3.5

-4
t (min)
 0
0 f(x) =10
- 0.0289125135x
20 30 40 50 60 70 80 90 100
R² = 0.9732217573 C=7,8 mg/l
-0.5
Linear (C=7,8 mg/l)
-1

-1.5

-2

-2.5

-3

-3.5

-4
t (min)
 0
0 f(x) =10
- 0.0287710976x
20 30 40 50 60 70 80 90 100
R² = 0.9740199092 C=3,1 mg/l
-0.5
Linear (C=3,1 mg/l)

-1

-1.5

-2

-2.5

-3

-3.5

-4
t (min)
 25.0

20.0
T (oC)

T(oC) 1
15.0
T(oC) 2
T(oC) 3
T(oC) 4
T(oC) 5
10.0
T(oC) 6

5.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 9.00

8.00

7.00

6.00
pH
1
pH

5.00 pH
2
pH
4.00 3
pH
4
3.00

2.00

1.00

0.00
0 10 20 30 40 50 60 70 80 90 100
t (min)