Experiment n6
Experiment n6
Experiment n6
6
METALS AND SOME ASPECTS OF CORROSION
1.OBJECTIVES
Familiarize with the properties of metals;
Ascertain the relative activities of metal;
Demonstrate the concepts of corrosion; and
Investigate the methods of corrosion prevention.
2. THEORY
Metals possess certain characteristics properties; malleability (ability to be
flattened into thin sheets). Ductility (ability to be drawn out into wires, surface luster
(“shininess”), and electrical conductivity. Others “bulk” properties, reflect of the wats
atoms are arranged an particular samples.
Metals are characterized by loosely held valence electrons occupying only a few
of the possible orbital of the outermost principal energy levels. In condensed phases
( liquid or solids), metallic atoms are packed closely together. The valence electrons of
one atom may spend a portion of their time in vacant valence orbital of neighboring
atoms. The close spacing of various possible electronic levels ( sublevels ) permits
valence electrons in metal considerable freedom of distribution. In metallic crystals and
to a lesser extent, in liquid metals, the valence electrons are quite mobile and are not
closely associated with any particular ions in a “cloud” of fluid electron cloud. The ease
of the electron flow, malleability, and ductility of metals and the high surface luster of
pure metals are explained in terms of this model for the metallic bond.
Rusting of metals is a special case of metal oxidation. Iron will oxidize to form
rust. Water will cause metals to rust; this reaction can be accelerated by adding salts. In
the corrosion process, metals get oxidized. For example in mild steel (which is greater
than 99%) the metal corrodes according to the following equation: