Capacity 5,0 m3 (1) New Crane
Capacity 5,0 m3 (1) New Crane
Capacity 5,0 m3 (1) New Crane
Original edition
Version 1.0 12/2016 EN
Code number of operating manual: 2.3.5000.5300.E.5291.EN
Index
1.0 General information 6
1.1 To the operating staff 6
1.2 Storage of this operating manual 6
1.3 Safety and warning notes 6
Safety and warning notes in this operating manual 6
Requirement and warning signs at the motor grab and in the 7
operating manual
Cross references 7
8.0 Commissioning 21
8.1 Preparation 21
8.2 Electrical connection 22
Motor protection switch 23
8.3 Reeve of the rope sockets 24
9.0 Operation 25
9.1 Safety notes for operation of the motor grab 25
9.2 Grab touch down 25
9.3 Grab closing 25
9.4 Grab opening 26
9.5 End of grab operation 26
11.0 Maintenance 29
11.1 Safety notes for maintenance 29
11.2 Inspection and maintenance plan 31
Tightening torques 31
11.3 Lubrication plan 32
11.4 Inspection and maintenance works 33
Oil level check 33
Replacing of oil filter 34
Replacing of hydraulic oil 35
De-aeration of hydraulic unit 36
Oil tank put under pressure 37
Increase of pressure without compressed air 37
Setting of operating pressure 38
Setting of throttle check valve 39
Replacing the pressure relief valves at the pressure 40
disconnection valve
Checking of suspension chain 41
11.5 Repair 42
11.6 Operating materials 42
Hydraulic oil 42
Grease 43
11.7 Re-commissioning 43
15.0 Annex 55
15.1 Electric circuit diagram 55
15.2 Hydraulic circuit diagram 56
15.3 Control valve 57
15.4 Pressure disconnection valve 58
15.5 Proximity switch 59
15.6 Oil level indicator 60
15.7 Oil temperature switch 61
15.8 Tilt switch 62
15.9 Information on the hydraulic oil 63
Manufacturer / supplier 63
Measures for fire-fighting 63
Measures at unintended release 63
First-aid measures 63
DANGER
Danger
designates a danger with high risk that will lead to death or severe injury if not avoided.
WARNING
Warning
designates a danger with medium risk that may lead to death or severe injury if not
avoided.
CAUTION
Caution
designates a danger with low risk that may lead to minor or moderate injury if not
avoided.
NOTE
Note
This indication refers to supporting information.
Requirement and warning signs at the motor grab and in the operating manual
The safety and warning notes are supplemented by the following symbols in the
operating manual. They are also found at the motor grab.
Cross references
Cross references are indicated in italics.
NOTE
The operation with any other bulk material requires the permission of MRS Greifer- und
Maschinenbau Helmstadt GmbH.
Use of the motor grab is only permitted in ambience temperatures between -10C and
+40C. For the transport and the storage of the motor grab ambience temperatures
between -20C and +50C are permitted.
The motor grab must only be used in connection with a permissible crane system that has
a lifting capacity of at least 12.800 kg.
Intended use also includes
observation of all notices from the operating instructions,
observation of the requirement, prohibition and warning notes,
compliance with the inspection and maintenance intervals and
compliance with the operating instructions of the operator.
Any other or exceeding use shall be deemed non-intended and therefore is expressly
prohibited.
DANGER
During operation with the motor grab bulk material may fall
down!
Dropping material may cause potentially fatal injuries!
The motor grab must only be operated by accordingly trained and
instructed staff.
Standing in the working area of the motor grab is strictly prohibited!
People or pets should not be located in the working area of the
motor grab.
Comply with a safety distance of at least 5 m from the motor grab.
It must be possible to view the working area completely, and it
always has to be sufficiently lit.
A separating protection device must be provided.
DANGER
The motor grab works with an operating voltage of up to 400 V at
accordingly high currents.
Electric shock may cause severe burns and potentially fatal
injuries!
Before starting the work, switch off the main voltage and secure it
against reactivation.
Do not touch any live parts.
Report damaged lines to the maintenance staff without delay.
Never submerse the motor grab in water or other liquids.
Never clean the hydraulic drive unit (electric motor) or the plug
connection with a high-pressure cleaner.
Have work performed by the corresponding specialist staff only.
Wear isolating safety shoes and gloves.
DANGER
When operating the motor grab, ignition sparks may arise that
may cause explosions!
Explosions may cause potentially fatal injuries!
Never operate the motor grab in a potentially explosive
atmosphere!
WARNING
The hydraulic components of the motor grab are pressurised with
a hydraulic pressure of up to 220 bar.
Escaping pressure may cause severe injuries!
Before starting the work, relieve pressure from the hydraulic
system.
Do not open any screws or screw plugs.
Have work performed by the corresponding specialist staff only.
Wear oil-tight safety shoes and gloves as well as safety goggles.
NOTE
CAUTION
The hydraulic components of the motor grab may heat up to
95C.
High temperatures may cause severe burns!
Before working at the motor grab, check the temperature.
Wear isolating gloves.
CAUTION
When operating the motor grab, noise up to 85 dB(A) may arise.
Sound levels in this range may cause irreparable hearing
damage!
Wear hearing protection in direct proximity of the motor grab.
3.1 Construction
1
15
2
14
3
13
4
12
11 5
10 6
9 7
3.2 Function
The motor grab is an electro-hydraulic grab. An electric motor drives the pump, which
then generates pressure in the hydraulic system.
The hydraulic cylinders that are attached to the grab crossbeam and the grab shell are
moved by the hydraulic drive unit; this opens or closes the motor grab.
The movement direction change is achieved by switching the control valve, with the
electrical signals for opening and closing of the motor grab being sent by the crane.
The required electrical control devices are part of the crane control and are not part of
the delivery of the motor grab.
Once the open motor grab is freely hanging on the holding rope, a throttle check valve
prevents that the grab shells accelerate due to their dead weight when closing is
initiated.
Grab opening
The pump conveys the hydraulic oil from the oil tank to the control valve. From the
control valve the hydraulic oil flows across the throttle check valve MK 20 through the
line B to the cylinder ring surface.
The motor grab opens.
The hydraulic oil from the opposite side flows across the control valve back into the oil
tank.
When the pressure in the hydraulic system reaches 220 bar, the hydraulic oil flows
through the pressure disconnection valve back into the oil tank.
Grab closing
The pump conveys the hydraulic oil from the oil tank to the control valve. From the
control valve, the hydraulic oil flows through the line A to the cylinder piston surface.
The motor grab closes.
The hydraulic oil from the opposite side flows across the throttle check valve MK 20 and
through the control valve back into the oil tank.
When the pressure in the hydraulic system reaches 220 bar, the hydraulic oil flows
through the pressure disconnection valve back into the oil tank.
4.1 Transport
The motor grab is delivered standing in opened condition.
4.2 Deposit
Prerequisite: Lifting gear with a minimum lifting capacity of 5.300 kg.
The centre of gravity is centrally in the lower half of the grab crossbeam.
Use the suspension chains to lift the motor grab.
Carefully place the motor grab in opened condition on a horizontal and firm ground.
Observe that no hoses and lines are clamped.
4.3 Storage
Store the motor grab standing in opened position on a horizontal and firm ground.
Apply the blank parts of the piston rods with a grease layer in case of extended
storage to protect them from corrosion.
Wedge the motor grab so that the centre of gravity cannot move.
Protect the motor grab with a tarpaulin from environmental influence.
Denomination Quantity
Motor clamshell grab with hydraulic control 1
Rope sockets with wedge 2+2
Suspension chain, length approx. 847 mm 2
Plug and socket (11 poles + PE, 3 x 125 A, 8 x 25 A, 500 V) 1+1
Hydraulic system and oil tank filled with hydraulic oil 1
Operating manual with spare parts list (2.3.5000.5300.E.5291.EN) 1
2
4
3
6
5
8
7
9
In case of interferences, spare parts orders and if you call our customer service, indicate
the type denomination, serial number and year of construction.
Denomination Value
Grab capacity 5,0 m (at 30 angle of repose)
Dead weight 5.300 kg
Height closed 3.324 mm
Height opened 2.615 mm
Width closed 2.999 mm
Width opened 3.491 mm
Length 2.200 mm
Closing time 13,0 sec.
Opening time 7,0 sec.
Rope diameter required 26 mm
Electrical data
Denomination Value
Supply voltage 400 V
Frequency 50 Hz
Control voltage 230 V
Current consumption 60 A
Motor output 27,5 kW
Duty type S6 - 40%
Degree of protection IP55
Motor rotation speed 1.450 rpm
Hydraulic data
Denomination Value
Flow rate 81,3 l/min.
Operating pressure "closing" 220 bar
Operating pressure "opening" 220 bar
Oil volume 240 litres
Oil type Renolin B 10 VG 32
7.3 Others
ID
Noise emission max. 85 dB (A)
8.0 Commissioning
DANGER
During commissioning, the motor grab may fall over or fall off!
This may cause potentially fatal injuries!
Secure the motor grab against falling over.
Ensure that the motor grab is correct connected to the load lifting
attachment of the crane system.
Have commissioning work performed by the correspondingly
trained specialist staff only.
8.1 Preparation
Connect the rope sockets at the suspension chains of the motor grab to the holding
ropes of the crane system (see chapter 8.3, Reeve of the rope sockets on page 24).
Ensure that the suspension chains are correct assembled at the grab crossbeam.
Slowly lift the motor grab until it is freely hanging about 5 cm above the ground.
NOTE
DANGER
The motor grab works with an operating voltage of up to 400 V at
accordingly high currents.
Electric shock may cause severe burns and potentially fatal
injuries!
Before starting the work, switch off the mains voltage and secure it
against reactivation.
Do not touch any live parts.
Report damaged lines to the maintenance staff without delay.
Never submerse the motor grab in water or other liquids.
Never clean the hydraulic drive unit (electric motor) and the plug
connection with a high-pressure cleaner.
Have work performed by the corresponding specialist staff only.
Wear isolating safety shoes and gloves.
Ensure that power supply by the crane system corresponds to the information on the
identification plate of the electric motor.
The power supply cable of the crane system must have a sufficient cross section in
all phases according to the power data of the electric motor and the length of the
cable.
Connect the socket of the plug connection to the power supply cable of the crane
system (see chapter 15.1, Electric circuit diagram on page 55).
Start the electric motor.
CAUTION
By a wrong rotating direction of the electric motor the hydraulic
pump will be destroyed!
Check the rotating direction of the electric power supply to the
electric motor via a measuring device.
Ensure that the electric motor is connected to a right-hand rotating
field: In view to the ventilation wheel from above the electric motor
has to turn counter-clockwise.
Ensure that the rotating field will be swapped in case the electric
motor is running into the wrong direction.
Check the switches "Grab closing" respect. "Grab opening" to see
that the motor grab performs the movement accordingly.
If not, swap the plug connection.
CAUTION
Improper placement may damage the power supply cable!
Observe that the power supply cable runs in a manner that will not
cause any damage if the motor grab tips over.
Attach the power supply cable to the motor grab with a cable strain
relief. There are two eyelets for this located close to the plug
connection.
5
2
9.0 Operation
DANGER
During operation with the motor grab, bulk material may fall
down!
Dropping material may cause potentially fatal injuries!
The motor grab must only be operated by accordingly trained and
instructed staff.
Standing in the working area of the motor grab is strictly prohibited!
People or pets should not be located in the working area of the
motor grab.
Comply with a safety distance of at least 5 m from the motor grab.
It must be possible to view the working area completely, and it
always has to be sufficiently lit.
A separating protection device must be provided.
CAUTION
Improper operation may damage the motor grab!
Avoid swinging grab movement.
Avoid impact of the motor grab with hopper walls and other
enclosures.
Avoid impact when putting down the motor grab.
Avoid stepping operation when opening and closing the motor
grab.
NOTE
The line from the hydraulic pump to the Contact the customer service.
control valve is faulty or leaking.
The output of the The operating pressure is set too low. Set operating pressure according
hydraulic pump is too to operating instructions.
low. The hydraulic pump and / or the coupling is Contact the customer service.
The motor grab closing faulty.
and opening is too slow.
The oil level is too low. Top up of hydraulic oil according
to operating instructions.
The line from the hydraulic pump to the Contact the customer service.
control valve is faulty or leaking.
The pressure relief valves at the pressure Clean pressure relief valves or
disconnection valve are soiled or faulty. replace them according to
operating instructions.
The motor grab closes The double check valve holds no pressure. Clean double check valve or
self-acting. The valve is soiled or faulty. replace it if necessary.
The seals of the hydraulic cylinder are leaky. Contact the customer service.
The motor grab opens by The double check valve holds no pressure. Clean double check valve or
itself. The valve is soiled or faulty. replace it if necessary.
The seals of the hydraulic cylinder are leaky. Contact the customer service.
The (empty) motor grab The throttle check valve is set incorrectly. Set the throttle check valve
closes by jerks. according to operating
instructions.
The oil temperature is too The oil level is too low. Refill hydraulic oil according to
high. operating instructions.
An unsuitable oil type is used. Perform oil change according to
operating instructions.
The throttle check valve is closed too much. Set the throttle check valve
according to operating
instructions.
11.0 Maintenance
DANGER
During maintenance, the motor grab may fall over or fall off!
This may cause potentially fatal injuries!
Carefully place the motor grab in the open position on a horizontal
and firm place for maintenance work.
Secure the motor grab against falling over.
Let the motor grab cool down to room temperature.
At work heights above 1,8 m use working scaffolding.
Have commissioning work performed by the correspondingly
trained specialist staff only.
Suitable protective equipment must be worn.
DANGER
The motor grab works with an operating voltage of up to 400 V at
accordingly high currents.
Electric shock may cause severe burns and potentially fatal
injuries!
Before starting the work, switch off the mains voltage and secure it
against reactivation.
Do not touch any live parts.
Report damaged lines to the maintenance staff without delay.
Never submerse the motor grab in water or other liquids.
Never clean the hydraulic drive unit (electric motor) and the plug
connection with a high-pressure cleaner.
Have work performed by the corresponding specialist staff only.
Wear isolating safety shoes and gloves.
WARNING
The hydraulic components of the motor grab are pressurised with
a hydraulic pressure of up to 220 bar.
Escaping pressure may cause severe injuries!
Before starting the work, relieve pressure from the hydraulic
system.
Do not open any screws or screw plugs.
Have work performed by the corresponding specialist staff only.
Wear oil-tight safety shoes and gloves as well as goggles.
NOTE
after 500 operating Hydraulic system Replacing hydraulic oil see Replacing of hydraulic
hours oil on page 35
Oil filter Replace see Replacing of oil filter on
page 34
All screw connections For tight fit Tightening torques see table
on page 31
All hydraulic screw For tight fit
connections
every 1.000 Motor grab Visual inspection for
operating hours damage (cracks and
deformation)
Hydraulic system Oil level see Oil level check on
page 33
All screw connections For tight fit Tightening torques see table
on page 31
All hydraulic screw For tight fit
connections
every 4.000 Hydraulic system Replacing hydraulic oil see Replacing of hydraulic
operating hours or oil on page 35
annually
Oil filter Replace see Replacing of oil filter on
page 34
Suspension chain Dimensional check and by an expert; test result must
visual inspection be recorded in chain file
every 3 years Suspension chain Check for absence of by an expert; test result must
cracks be recorded in chain file
Tightening torques
For screws of property class 8.8 and nuts of strength category 8.
NOTE
The lubrication points are marked with red colour on the motor grab.
1
4
2
1
4
2
Fig. 9: Replacing of oil filter Filter element in the filter element housing
CAUTION
Hydraulic oil may cause irreparable environmental damage!
Observe that no hydraulic oil enters the soil or water!
Prerequisite:
The motor grab is opened.
Operationally warm condition.
The hydraulic oil was filtered through a 10 m oil filter (hydraulic oil right from the
barrel is unfiltered and can cause serious damage to the hydraulic pump).
1
4
2
1
4
2
NOTE
During de-aeration of the hydraulic system, the grab must not reach
the end position of the shells opening / closing and must not reach the
operating pressure.
Check the oil tank level with the open motor grab at the oil level control (2).
Close the oil level control (2) and the oil filler opening / vent screw (1).
Fill in 1,5 bar compressed air into the oil tank via the tank valve (4) (see chapter Oil
tank put under pressure on page 37).
Assemble the cover at the grab crossbeam.
NOTE
4 5
4 Tank valve
5 Protection cap
Carefully place the motor grab in the open position on a horizontal and firm ground.
Dismantle the cover from the grab crossbeam.
Close all screw plugs at the oil tank.
Unscrew the protection cap (5) from the tank valve (4).
Fill in 1,5 bar compressed air into the oil tank via the tank valve (4).
Use for that a compressor and a suitable pressure hose with adapter piece (not part
of the scope of delivery).
Screw again the protection cap (5) onto the tank valve (4).
Assemble the cover at the grab crossbeam.
1
4
2
MA
MB
NOTE
When measuring the hydraulic pressure, the hose to the pressure
manometer must be filled with hydraulic oil. If there is air in the
hydraulic hose of the pressure manometer, faulty measurements or
damages at the sealing could occur! Pressure manometers are not
part of the scope of delivery!
Operate the switch "Grab opening".
Loosen the counter nut at the valve A of the pressure disconnection valve and turn
the valve A clockwise as far as it will go (maximum pressure).
Loosen the counter nut at the valve B of the pressure disconnection valve.
Set the valve B of the pressure disconnection valve to a pressure of 250 bar.
Turn screw to the right to increase pressure; turn screw to the left to reduce pressure.
Set the operating pressure of no more than 220 bar at the valve A of the pressure
disconnection valve.
Turn screw to the right to increase pressure; turn screw to the left to reduce pressure.
Release the switch "Grab opening".
Tighten both the counter nuts again.
Assemble the perforated plate covers at the grab crossbeam.
NOTE
The throttle check valve must be set so that the grab shells just close
without jerking.
If the throttle effect is too large, there will be unnecessary dynamic
pressure that will cause early wear of the hydraulic system.
1 2
Fig. 16: Replacing the pressure relief valves at the pressure disconnection valve
Carefully place the motor grab in the open position on a horizontal and firm ground.
Open carefully the oil filler opening / vent screw at the grab crossbeam.
Dismantle the cover from the grab crossbeam.
Connect the pressure manometer to the measuring points MA and MB (see chapter
Setting of operating pressure on page 38).
Ensure that no hydraulic pressure is present in the system.
Turn out the pressure relief valves (1), (2).
Turn in the new pressure relief valves (1), (2) and ensure that the sealing rings are
not damaged.
De-aerate the hydraulic unit (see chapter De-aeration of hydraulic unit on page 36).
Close the oil filler opening / vent screw at the grab crossbeam.
Fill in 1,5 bar compressed air into the oil tank via the tank valve (see chapter Oil tank
put under pressure on page 37).
Set the operating pressure (see chapter Setting of operating pressure on page 38).
Assemble the cover at the grab crossbeam.
11.5 Repair
If repairs are required at the motor grab, contact the company MRS Greifer- und
Maschinenbau Helmstadt GmbH.
HVLP HLP
Bartran HV 32 Energol
BP
Bartran HVX 32 HLP-HM 32
Hyspin AWH 32
Castrol Hyspin AWH 32 Paradene 32AW
TQ-D
NUTO H 32
ESSO UNIVIS N 32
Hydraulic Oil HLP 32
RENOLIN MR 32 MC RENOLIN MR 10 VG 32
FUCHS RENOLIN B 32 HVI RENOLIN B 10 VG 32
RENOLIN ZAF 32 MC RENOLIN ZAF 32 B
Mobil DTE 24
MOBIL Mobil DTE 13 M
Mobil DTE Excel 32
HLP 32
PANOLIN HLP Universal 32
HLP Plus 32
Grease
Grease used: Renolit CA-FN 3 by Fuchs
Brand Marking acc. Colour Product Thickening NLGI- Dripping
to DIN 51502 information Base oil class point
according to (C)
ISO 6743-9
solid lubricant
RENOLIT CA-FN 3 K 2 C-30 light 5-1020 Calcium soap 2 >95
ISO-L-X-CAHA 2 brown mineral oil
NOTE
Manufacturer Type
AGIP Longtime Grease 2
ARAL Aralub HL 2
AVIA Avialub Spezialfett WL
BP Energrease LS 2
Spheerol AP 2 LZV-EP
CASTROL
Spheerol E PL 2
DEA Glissando 20
ESSO Beacon 2
FINA Marson LU
MOBIL OIL Mobilux 2
Alvania G 2
SHELL
Alvania R 2
11.7 Re-commissioning
Check the motor grab for damage, cracks and deformation at re-commissioning.
Check the suspension chains (see Checking of suspension chain on page 41) as well
as the suspension of the motor grab for damage.
Replace all hydraulic hoses for safety reasons.
Replace the hydraulic oil (see Replacing of hydraulic oil on page 35).
Grease all bearing points according to the lubrication plan (see chapter 11.3,
Lubrication plan on page 32).
12.1 Shutdown
Carefully place the motor grab in the open position on a horizontal and firm ground.
Ensure that the motor grab is protected from moisture, extreme temperature
fluctuations, contamination and mechanic damage if it is stored for an extended
period.
Before storage, replace the hydraulic oil (see Replacing of hydraulic oil on page 35).
Grease all bearing points according to the lubrication plan (see chapter 11.3
Lubrication plan on page 32).
If the motor grab is stored lying in closed position the piston rods are visible.
Protect the piston rods against corrosion by greasing and packing in suitable
material.
Wedge the motor grab so that the centre of gravity cannot move.
Protect the motor grab with a tarpaulin from weather influence.
12.2 Disposal
Close the motor grab.
Disconnect the motor grab from the electric power supply.
Drain the hydraulic oil and fill it in suitable containers.
Ensure that no hydraulic oil may enter the soil or water.
Dispose of the drained hydraulic oil in an environmentally compatible manner.
Weld the grab shells together to avoid an unintended opening of the motor grab.
Carefully place the motor grab on a horizontal and firm ground.
Wedge the motor grab so that the centre of gravity cannot move.
Disconnect the motor grab from the load lifting attachment of the crane.
The motor grab contains nearly solely steel materials. Therefore, it can be recycled
entirely.
Have the motor grab disposed of environmentally compatible by an approved
specialist company.
When loading the motor grab, observe that no one is direct present close to the grab.
Overview drawing
10
11
12
23
13
22
14
20
21
30
40
35 60
32 51
52
34
53
50
54
55
35 Hydraulic cylinder
35.10 35.9 35.8 35.7 35.6 35.5 35.4 35.3 35.2 35.1
40.22
40.21
40.20 40.1
40.19
40.18
40.17
40.16
40.2
40.15 40.3
40.14 40.4
40.13 40.5
40.12
40.6
40.11
40.10 40.7
40.8
40.9
Type: 2.3
15.0 Annex
Motor
ON
K1
Motor
OFF
K1 K1
230 V
Cable reel
PE 1 2 3 9 11 10 4 5 6 7 8 Crane part
Socket Grab part
connection
11 poles + PE
3 x 125 A,
8 x 25 A
500 V
U V
PE W
Oil level indicator
Oil temperature
M
Klixon contact
Grab opened
Grab closed
Tilt switch
Valves
Grab
switch
400 V - 50 Hz
Fig. 23: Electric circuit diagram 26-0-26393-4
Grab closing
Grab opening
140 / 100 600
B Throttle
check valve
A MK 20
Control valve
4 WEH 16
Pressure
disconnection
valve NG 3/4"
220 bar
Three-phase motor
P = 22,0 kW
at 100% duty cycle
P = 27,5 kW
at 40% duty cycle
n = 1.450 rpm
DFBN/ HC 240
Pump output
81,3 l/min
7 6
1 Electrical connector
2 Solenoid switch
3 4/3 Directional valve
4 Double check valve
5 Connection plate
6 Connection B (grab opening)
7 Connection A (grab closing)
Features Value
Function Make contact
Connection 20 - 250 V AC/DC
Request Grab opened / Grab closed
1 Electrical connector
2 Oil level inspection switch
3 Float switch
Features Value
Features Value
1 Tilt switch
2 Inductive proximity switch
Features Value
Manufacturer / supplier
FUCHS EUROPE SCHMIERSTOFFE GmbH
Friesenheimerstrae 15
68169 Mannheim / Germany
Phone: +49 621 3701-0 (switchboard)
Fax: +49 621 3701-570
Email: [email protected]
Emergency information: Phone: +49 621 3701-333 or +49 621 3701-0 (switchboard).
First-aid measures
General notes:
- Product-soaked or soiled clothes and shoes must be changed.
- Never put product-containing rags in clothes pockets.
- Do not inhale: provide fresh air.
- After skin contact: Wash off with water and soap immediately and rinse well.
- After eye contact: Rinse eye under running water for several minutes with the eye
held open and seek medical treatment immediately.
- After swallowing: Rinse mouth thoroughly, seek medical treatment immediately.
[email protected]
www.mrs-greifer.de