DATA PENGAMATAN CO2 REMOVAL UNIT

Outlet Natural Gas (3)

Inlet Lean Benfield (2)

Inlet Natural Gas (1)

Rich Benfield (4)

Gambar 1. Unit 201-E (kolom CO2 Absorber)

Tabel 1. Data flow natural gas ( feed gas )masuk - Stream (1)
Tanggal Flow Gas (Nm3/hr)
1-Jun-2017 212.33
5-Jun-2017 212.33
8-Jun-2017 212.33
12-Jun-2017 212.33
15-Jun-2017 212.33
Flow gas NG
Vng= 212.330
ni
Sumber : Log sheet flow fluida Absorber 201-E, 2017

Tabel 2. Komposisi natural gas masuk - Stream (1)

 komposisi Berat Molekul % vol
CO2 44.01 7.0300
N2 28.01 0.2800
CH4 16.04 84.2600
C2 H 6 30.07 5.8800
C3 H 8 44.1 1.4500
i-C4H10 58.1 0.3000
n-C4H10 58.1 0.3300
i-C5H12 72.15 0.1300
n-C5H12 72.15 0.0800
C6H14 86.18 0.2600
Total 100.0000
Sumber : Teknik Proses PUSRI-III, 2017

Tabel 3. Flow lean benfield masuk - Stream (2)

Tanggal Flow Lean Benfield (Nm3/hr)
1-Jun-2017 165.99
5-Jun-2017 165.99
8-Jun-2017 165.98
12-Jun-2017 164.99
15-Jun-2017 164.98
VLb = Flow Lean Benfield
165.586
ni
Sumber : log sheet flow fluida Absorber 201-E, 2017

Tabel 4. Data hasil analisa lean benfield masuk - Stream (2)

Komponen
Tanggal
K2CO3 V2O5 DEA H2O
1-Jun-2017 20.95% 0.89% 1.46% 76.70%
5-Jun-2017 16.55% 0.87% 1.46% 81.12%
8-Jun-2017 15.84% 0.89% 1.49% 81.78%
12-Jun-2017 17.04% 0.86% 1.60% 80.50%
15-Jun-2017 16.15% 0.83% 1.58% 81.44%
Rata-rata 17.31% 0.87% 1.52% 80.31%
Sumber : Laboratorium PT. PUSRI III , 2017

Tabel 5. Data flow natural gas keluar - Stream (4)

Tanggal Flow Gas (Nm3/hr)
 1-Jun-2017 211.772
5-Jun-2017 210.973
8-Jun-2017 211.897
12-Jun-2017 211.774
15-Jun-2017 211.972
Flow gas NG
Vng = 216.57
ni
Sumber : log sheet flow fluida Absorber 201-E, 2017

Tabel 6. Komposisi natural gas (NG) keluar - Stream (3)

komposisi Berat Molekul % vol
CO2 44.01 0.27
N2 28.01 0.30
CH4 16.04 90.39
C2 H 6 30.07 6.31
C3 H 8 44.1 1.56
i-C4H10 58.1 0.32
n-C4H10 58.1 0.35
i-C5H12 72.15 0.14
n-C5H12 72.15 0.09
C6H14 86.18 0.28
Total 100.00
Sumber : Teknik Proses PUSRI III, 2017

Tabel 7. Kondisi Operasi pada CO2 Removal Unit

Tanggal (Juni 2017 )
Parameter
1 5 8 12 15
Suhu input NG (oF) 100 100 100 100 100
Tekanan input NG (Psig) 652 652 652 652 652
Suhu ouput NG (oF) 130 131 133 132 131
Tekanan output NG (Psig) 650 650 650 650 650
Suhu input Benfield atas(oF) 212 212 212 212 212
Suhu input Benfield tengah(oF) 170.6 177.8 177.8 181.4 179.6
Tekanan input Benfield (Psig) 652 652 652 652 652
Suhu output Rich Benfield (oF) 242.6 240.8 242.6 244.4 242.6
P. Operasi Absorber 649.78 649.8 649.81 649.78 649.74
T. Operasi Absorber 121 122 122 121 122
Sumber : Log sheet harian PUSRI III Absorber 201-E, 2017
Suhu input Benfield rata-rata(oF)
Suhu input Benfield rata-rata(K)
Tekanan input Benfield (atm)
 NERACA MASSA CO2 ABSORBER UNIT 201-E

Komposisi NG out :
P = 650 Psig Outlet Natural Gas (4)
T = 131 oF
V = 216.57 Nm3/hr
CO2 0.27 Vol
N2 0.30 Vol
CH4 90.39 Vol
C2 H 6 6.31 Vol Komposisi Benf in:
C3 H 8 1.56 Vol P
i-C4H10 0.32 Vol T (atas)
n-C4H10 0.35 Vol T (tengah)
i-C5H12 0.14 Vol V
n-C5H12 0.08 Vol K2CO3
C6H14 0.28 Vol V2O5
Total 99.99 DEA
H2O
Inlet Natural Gas (1)

Komposisi NG in :
P = 652 Psig Rich Benfield (4)
T = 100 oF
V = 212.33 Nm3/hr
CO2 7.0300 Vol Komposisi Rich Benfield:
N2 0.2800 Vol P
CH4 84.2600 Vol T
C2 H 6 5.8800 Vol V
C3 H 8 1.4500 Vol K2CO3
i-C4H10 0.3000 Vol V2O5
n-C4H10 0.3300 Vol DEA
i-C5H12 0.1300 Vol H2O
n-C5H12 0.0800 Vol
C6H14 0.2600 Vol
Total 100

Gambar 2. Unit 201-E (kolom CO2 Absorber)

 INPUT CO2 ABSORBER
1. Inlet Natural Gas Absorber ( Stream 1 )
Basis = 1 hr operasi

Flow natural gas = 212.330 Nm3/hr

Tekanan NG = 652 Psig =

=

Temperatur Na = 100 oF
= 5 (100 F - 32 F) +273 K
x
9
= 189.444 K

R = 0.08206 atm. m3/kmol. K

Untuk menghitung Laju alir molar digunakan rumus gas ideal,

P . V = n.R.T

Mol Ng = P.V
R.T
Mol Ng = 45.35374 atm
0.08206 atm. m3/kmol. K
Mol Ng = 2.917425 kmol
Nm3/hr

Tabel 1. Massa Input Natural gas (NG) - Stream (1)

Mol komponen
Volume
komponen % vol (Nm3/hr) ( kmol )

CO2 7.0300 14.926799 43.5478

N2 0.2800 0.594524 1.7345
 CH4 84.2600 178.909258 521.9544
C2H6 5.8800 12.485004 36.4241
C3H8 1.4500 3.078785 8.9821
i-C4H10 0.3000 0.63699 1.8584
n-C4H10 0.3300 0.700689 2.0442
i-C5H12 0.1300 0.276029 0.8053
n-C5H12 0.0800 0.169864 0.4956
C6+ 0.2600 0.552058 1.6106
Total 100 212.33 619.4569

2. Inlet Lean Benfield Absorber ( Stream 2 dan 3 )

Basis : 1 hr operasi

Flow lean benfield = 541.9618884 Nm3/hr

Mol lean benfield = P. V

R. T
=

Mencari BM lean benfield

Komposisi BM (kg/kmol)
K2CO3 138
V2O5 181
Rata-Rata
DEA 109
100 H2O 18
652 KHCO3 100
131
650 BM lean benfield = 41.56342 kg/kmol
212
177.44 Mencari Massa lean benfield = mol x BM
652 = 33499.21548 kg
242.6
649.782 mencari dengan menjumlahkan massa tiap komponen
121
Massa K2CO3 = m Benfield
194.72 = 33499.2154812121
363.55 = 5797.374231 kg
44.366
Massa V2O5 = m Benfield
= 33499.2154812121
= 290.7731904 kg

Massa DEA = m Benfield

= 33499.2154812121
= 508.518091 kg

Massa H2O = m Benfield

= 33499.2154812121
= 26902.54997 kg

Maka massa benfield total = 33499.21548 kg

Tabel 2. Massa Input Lean Benfield - Stream (2 dan 3)

komposisi Massa (kg)

K2CO3 5797.3742311786
V2O5 290.7731904
DEA 508.5180910
H2 O 26902.5499687
Total 33499.2155
ORBER UNIT 201-E

Natural Gas (4)

Inlet Lean Benfield (2)

osisi Benf in:

= 652 Psig
= 212 oF
= 177.44 oF
= 165.586 Nm3/hr
= 20.95%
= 0.89%
= 1.46%
= 76.70%

osisi Rich Benfield:

= ..?
= 242.6 oF
= ..?
= ..?
= ..?
= ..?
= ..?

om CO2 Absorber)
SORBER OUTPUT CO2
3. Outlet Natural Gas keluar Absorber ( Stream 3 )
Basis =

Flow natural gas =

( 652 + 14,7 psia ) Tekanan NG =

666.7 psia
1 psia x 14,7 atm
45.3537415 atm

Temperatur Nb =
- 32 F) +273 K =

( Hougen,1943 ) R =

Untuk menghitung Laju alir molar digunakan ru

( Hougen,1943 )

Mol Ng =

1.00 Nm3/hr Mol Ng =

x
189.444444444 K
Mol Ng =

gas (NG) - Stream (1) Tabel 4. Massa output Nat

Massa Natural
BM
Gas

( kg/kmol )
( kg )
44.01 1916.5396
28.01 48.5828
 16.04 8372.1483
30.07 1095.2717
44.10 396.1117
58.10 107.9713
58.10 118.7685
72.15 58.1020
72.15 35.7551
86.18 138.8005
12288.0513

4. Outlet Rich Benfield (Rb) Absorber ( Stream 4 )

Reaksi yang terjadi di dalam CO2 absorber

K2CO3 +
m 42.01
44.366 541.9618884 b 42.01
0.08206 363.55 s 0.0000000
805.97832135 kmol

maka massa komponen Rb :

K2CO3
= K2CO3 sisa reaksi x BM K2C
= 0.00
= 0.00

H2O sisa
= H2O Sisa x BM H2O
= 1452.58
= 26146.37

KHCO3
= KHCO3 bereaksi x BM KHCO
= 84.02
= 8401.99

x %wt K2CO3 Tabel 5. Massa Output Ric

 x 17.31%
komposisi
K2CO3
x %wt V2O5 V2O5
x 0.87% DEA
H2O
KHCO3
x %wt DEA Total
x 1.52%

x %wt H2O
x 80.31%

Tabel 6. Neraca Massa Komponen Total

Input ( kg )
Komponen
S1
nfield - Stream (2 dan 3) CO2 1916.5396
N2 48.5828
ssa (kg) n (kmol)
CH4 8372.1483
742311786 42.0099582 C2 H 6 1095.2717
7731904 1.6064817 C3 H 8 396.1117
5180910 4.6653036 i-C4H10 107.9713
.5499687 1494.5861093696 n-C4H10 118.7685
99.2155 1542.8678529 i-C5H12 58.1020
n-C5H12 35.7551
C6H14 138.8005
H2 O -
K2CO3 -
DEA -
V2O5 -
KHCO3 -
Sub total 12288.0513
Total 45787.2668

Tabel 7. Neraca Massa Total pada Unit 201-E (ko

Komponen
Natural Gas Input
Lean Benfield ( Lb )
Natural Gas Output
Rich Benfield ( Rb )
Total
 OUTPUT CO2 ABSORBER

1 hr operasi

216.57 Nm3/hr

650 Psig = ( 650 + 14,7 psia )

= 664.7 psia
1 psia x 14,7 atm
= 45.2176870748 atm

131 oF
5 (131 F - 32 F) +273 K
x
9
206.667 K

0.08206 atm. m3/kmol. K ( Hougen,1943 )

u alir molar digunakan rumus gas ideal,

P . V = n.R.T ( Hougen,1943 )

P.V
R.T
45.2177 atm x 1.00 Nm3/hr
0.08206 atm. m3/kmol. K 206.66666667 K
2.666283939 kmol

bel 4. Massa output Natural gas (Na) - Stream (3)

Mol
komponen % vol Volume BM
komponen

(Nm3/hr)
( kmol ) (kg/kmol)
CO2 0.2663 0.5768 1.5378617975 44.01
N2 0.3004 0.6505 1.7345000173 28.01
 CH4 90.3900 195.7610 521.954395656 16.04
C2 H 6 6.3078 13.6610 36.4241004242 30.07
C3 H 8 1.5555 3.3688 8.9821000014 44.10
i-C4H10 0.3218 0.6970 1.8584000031 58.10
n-C4H10 0.3540 0.7667 2.0442000036 58.10
i-C5H12 0.1395 0.3020 0.8053000447 72.15
n-C5H12 0.0858 0.1859 0.4956000007 72.15
C6+ 0.2789 0.6041 1.6105999739 86.18
Total 99.734 217 577.4471

CO2 + H2O 2KHCO3

43.55 1494.59 - kmol
42.01 42.01 84.02 kmol
1.54 1452.58 84.02 kmol

sisa reaksi x BM K2CO3

x 138
kg

a x BM H2O
x 18
kg

bereaksi x BM KHCO3
x 100
kg

bel 5. Massa Output Rich Benfield - Stream (F5)

 n (kmol) Massa (kg)
0.0000000 0.00
1.6064817 290.7731904
4.6653036 508.5180910
1452.58 26146.3707219
84.02 8401.99
1458.8479366 26945.6620

Massa Komponen Total pada Unit 201-E (kolom CO2 Absorber)

Input ( kg ) Output ( kg )
S2 S3 S4
- 67.68 -
- 48.58 -
- 8372.15 -
- 1095.27 -
- 396.11 -
- 107.97 -
- 118.77 -
- 58.10 -
- 35.76 -
- 138.80 -
26902.5500 - 26146.3707219
5797.3742 - 0.00
508.5181 - 508.5181
290.7731904 - 290.7731904
- - 8401.99
33,499.215 10,439.199 35347.6536399
45787.2668 45786.8526

tal pada Unit 201-E (kolom CO2 Absorber)

onen Input (kg) Output (kg)
as Input 12288.0513 -
eld ( Lb ) 33499.2155 -
as Output - 10439.1990
eld ( Rb ) - 35347.65
al 45787.2668 45786.8526
 0.4141

Massa Natural
Gas

( kg )
67.6812977066
48.5833454856
8372.1485063165
1095.2726997568
396.110610061
107.973040178
118.7680202099
58.1023982234
35.7575400473
138.8015057476
10439.1990