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    Ch7 HM 3 1

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    Najmul Puda Pappadam
    This document provides the details of homework assignment 3 from a chemistry class. It includes 7 problems related to chapter 7 on solutions and electrochemistry. The problems cover topics like calculating ionic atmosphere thickness, limiting molar conductivity, Debye-Huckel-Onsager equation validation, ionic strength calculations, conductivity limits of water, Hittorf cell electrolysis calculations, and transference number determinations. The homework is due on September 20th in class.

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    Ch7 HM 3 1

    Uploaded by

    Najmul Puda Pappadam
    133 views2 pages
    This document provides the details of homework assignment 3 from a chemistry class. It includes 7 problems related to chapter 7 on solutions and electrochemistry. The problems cover topics like calculating ionic atmosphere thickness, limiting molar conductivity, Debye-Huckel-Onsager equation validation, ionic strength calculations, conductivity limits of water, Hittorf cell electrolysis calculations, and transference number determinations. The homework is due on September 20th in class.

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    Ch7-HM-3-1 (1)

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    This document provides the details of homework assignment 3 from a chemistry class. It includes 7 problems related to chapter 7 on solutions and electrochemistry. The problems cover topics like calculating ionic atmosphere thickness, limiting molar conductivity, Debye-Huckel-Onsager equation validation, ionic strength calculations, conductivity limits of water, Hittorf cell electrolysis calculations, and transference number determinations. The homework is due on September 20th in class.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    133 views2 pages

    Ch7 HM 3 1

    Uploaded by

    Najmul Puda Pappadam
    This document provides the details of homework assignment 3 from a chemistry class. It includes 7 problems related to chapter 7 on solutions and electrochemistry. The problems cover topics like calculating ionic atmosphere thickness, limiting molar conductivity, Debye-Huckel-Onsager equation validation, ionic strength calculations, conductivity limits of water, Hittorf cell electrolysis calculations, and transference number determinations. The homework is due on September 20th in class.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 2

    .

    COLLEGE OF ARTS AND SCIENCES


    CHM 331-02
    Homework set 3
    (20 pts)
    Chapter 7
    Due date: Wednesday, September 20th, in class

    1- (2 pts) Estimate the thickness of the ionic atmosphere for solutions of


    0.01 M and 0.1 M KCl in water at 25.0 oC with = 78. Rationalize the
    effect of concentration on this thickness.

    2- (2 pts) Use Table 7.3 to calculate the limiting molar conductivity of all
    salts given in Table 2.

    3- (4 pts) a- Use the following graph to calculate Kohlrauschs constant for


    KCL.
    b- Use equations 7.53, 7.54 and 7.55 to evaluate its value theoretically.
    c- Comment on the validity of Debye-Huckel- Onsager equation

    4- (3 pt) Calculate the ionic strength for 0.2 M solutions of Na2SO4, MgSO4,
    and Ca3(PO4)2
    5- (2 pts) How far can the conductivity of water at 25 C be lowered in
    2 1
    theory by removing impurities? The (in S cm mol ) for KOH, HCl,
    14
    and KCl are, respectively, 274.4, 426.04, and 149.86. Kw = 1.008 10 .
    8 1
    Compare your answer to the experimental value of 5.8 10 S cm .

    6- (4 pts) A solution of KCl was electrolyzed in a Hittorf cell. After a


    current of 0.9 A has been passed for 1.75 h, the mass of KCl in the anode
    compartment decreased by 2.05 g. Calculate:
    a- t+ for potassium ion and t- for chloride ion

    b- If m for the above KCl solution is 111.2 S cm2mol-1, calculate the


    molar ionic conductivity and the ionic mobility for potassium and
    chloride ions at this concentration.

    7- (3 pts) A solution of a strong electrolyte MgS was electrolyzed in a


    Hittorf apparatus. A current of 0.160 amp was passed for 9650 s. the
    electrode reactions are:
    2+
    Mg Mg + 2e
    2+
    and Mg + 2e Mg
    The solution was initially 0.100 molal in MgS. After completion of
    the electrolysis, it was found that the solution in the anode
    compartment contained 100.0 g H2O and 0.0165 mole MgS. Find the
    +2
    transference number of Mg and S-2 in the solution.

    Good Luck

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