Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

Penguard Topcoat - Comp. A with LC

1. Identification of the preparation and of the company

Product name and/or code : Penguard Topcoat - Comp. A with LC
Label No. : 627
Supplier/Manufacturer : Jotun Paints (Europe) Ltd.
Stather Road
Flixborough, Scunthorpe
North Lincolnshire
DN15 8RR
England

Tel: +44 17 24 40 00 00
Fax: +44 17 24 40 01 00
[email protected]

Emergency telephone : Contact National Poison Centre via Hospital or Registered Medical Practitioner
number
Product use : Coatings: Solvent-borne.

2. Hazards identification
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Flammable.
May cause cancer. May cause harm to the unborn child.
Possible risk of impaired fertility. Also harmful by inhalation
and in contact with skin. Irritating to eyes and skin. May cause
sensitisation by skin contact. Danger of cumulative effects. Toxic Dangerous for the
Toxic to aquatic organisms, may cause long-term adverse environment
effects in the aquatic environment.
Additional warning phrases : Contains lead. Should not be used on surfaces liable to be chewed or sucked by
children.

3. Composition/information on ingredients
Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances
Directive 67/548/EEC.
Classification
Product/ingredient Identifiers % 67/548/EEC Regulation (EC) No. Type Notes
name 1272/2008 [CLP]
epoxy resin (MW 700- CAS: 25036-25-3 20-25 Xi; R36/38 Skin Irrit. 2, H315 [1] -
1200) R43 Eye Irrit. 2, H319
Skin Sens. 1, H317
xylene EC: 215-535-7 12,5- R10 Flam. Liq. 3, H226 [1] [2] C
CAS: 1330-20-7 20 Xn; R20/21 Acute Tox. 4, H312
Index: 601-022-00-9 Xi; R38 Acute Tox. 4, H332
Skin Irrit. 2, H315
Solvent naphtha REACH #: 01- 10-20 R10 Flam. Liq. 3, H226 [1] [2] H-P
(petroleum), light 2119455851-35
arom. EC: 265-199-0 Xn; R20, R65 Acute Tox. 4, H332
CAS: 64742-95-6 Xi; R37 STOT SE 3, H335
Index: 649-356-00-4 R66 Asp. Tox. 1, H304
N; R51/53 Aquatic Chronic 2,
H411
lead sulfochromate EC: 215-693-7 5-25 Carc. Cat. 2; R45 Carc. 1B, H350 [1] [2] 1
yellow [This CAS: 1344-37-2 Repr. Cat. 1; R61 Repr. 1A, H360Df
substance is identified Index: 082-009-00-X Repr. Cat. 3; R62 STOT RE 2, H373
in the Colour Index by R33 Aquatic Acute 1,
Colour Index H400
Constitution Number, N; R50/53 Aquatic Chronic 1,
C.I. 77603.] H410

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Penguard Topcoat - Comp. A with LC
butan-1-ol EC: 200-751-6 5-7 R10 Flam. Liq. 3, H226 [1] [2] 6
CAS: 71-36-3 Xn; R22 Acute Tox. 4, H302
Index: 603-004-00-6 Xi; R41, R37/38 Acute Tox. 4, H332
R67 Skin Irrit. 2, H315
Eye Dam. 1, H318
STOT SE 3,
H335 and H336
lead chromate EC: 235-759-9 5-25 Carc. Cat. 2; R45 Carc. 1B, H350 [1] [2] 1
molybdate sulfate red CAS: 12656-85-8 Repr. Cat. 1; R61 Repr. 1A, H360Df
[This substance is Index: 082-010-00-5 Repr. Cat. 3; R62 STOT RE 2, H373
identified in the R33 Aquatic Acute 1,
Colour Index by H400
Colour Index N; R50/53 Aquatic Chronic 1,
Constitution Number, H410
C.I. 77605.]
ethylbenzene EC: 202-849-4 1-3 F; R11 Flam. Liq. 2, H225 [1] [2] -
CAS: 100-41-4 Xn; R20 Acute Tox. 4, H332
Index: 601-023-00-4
urea, polymer with CAS: 68002-19-7 <25 R53 Aquatic Chronic 4, [1] -
formaldehyde, H413
butylated
ethanol EC: 200-578-6 1-5 F; R11 Flam. Liq. 2, H225 [2] -
CAS: 64-17-5
Index: 603-002-00-5
See Section 16 for See Section 16 for
the full text of the the full text of the H
R-phrases declared statements
above. declared above.

Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
Occupational exposure limits, if available, are listed in Section 8.

4. First-aid measures
First-aid measures
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery
position and seek medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do NOT use solvents or thinners.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running water
for at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
Ingestion : If swallowed, seek medical advice immediately and show the container or label.
Keep person warm and at rest. Do not induce vomiting.

5. Fire-fighting measures
Extinguishing media : Recommended: alcohol-resistant foam, CO2, powders, water spray.
Extinguishing media not to : Do not use water jet.
be used
Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may
cause a health hazard. Appropriate breathing apparatus may be required.
Cool closed containers exposed to fire with water. Do not release runoff from fire to
drains or watercourses.

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Penguard Topcoat - Comp. A with LC

6. Accidental release measures

Personal precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.
Refer to protective measures listed in sections 7 and 8.
Spill : Contain and collect spillage with non-combustible, absorbent material e.g. sand,
earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations (see section 13). Preferably clean with a detergent.
Avoid using solvents.
Note: see section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Prevent the creation of flammable or explosive concentrations of vapours in air and
avoid vapour concentrations higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and
other sources of ignition have been excluded. Electrical equipment should be
protected to the appropriate standard.
To dissipate static electricity during transfer, earth drum and connect to receiving
container with bonding strap. Operators should wear antistatic footwear and clothing
and floors should be of the conducting type.
Keep away from heat, sparks and flame. No sparking tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or
mist arising from the application of this preparation. Avoid inhalation of dust from
sanding.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
Put on appropriate personal protective equipment (see Section 8).
Never use pressure to empty. Container is not a pressure vessel.
Always keep in containers made from the same material as the original one.
Comply with the health and safety at work laws.
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors. Vapours may form
explosive mixtures with air.

When operators, whether spraying or not, have to work inside the spray booth,
ventilation is unlikely to be sufficient to control particulates and solvent vapour in all
cases. In such circumstances they should wear a compressed air-fed respirator
during the spraying process and until such time as the particulates and solvent
vapour concentration has fallen below the exposure limits.

Storage : Store in accordance with local regulations.

Notes on joint storage
Keep away from: oxidising agents, strong alkalis, strong acids.
Additional information on storage conditions
Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away
from heat and direct sunlight. Keep away from sources of ignition. No smoking.
Prevent unauthorised access. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage.

8. Exposure controls/personal protection

Engineering measures : Provide adequate ventilation. Where reasonably practicable, this should be achieved
by the use of local exhaust ventilation and good general extraction. If these are not
sufficient to maintain concentrations of particulates and solvent vapours below the
OEL, suitable respiratory protection must be worn.
Ingredient name Occupational exposure limits
xylene EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed
through skin.
STEL: 441 mg/m 15 minute(s).
STEL: 100 ppm 15 minute(s).
TWA: 220 mg/m 8 hour(s).
TWA: 50 ppm 8 hour(s).
Solvent naphtha (petroleum), light EH40-WEL (United Kingdom (UK), 1/2005).
arom. TWA: 125 mg/m 8 hour(s). Form: All forms
TWA: 25 ppm 8 hour(s). Form: All forms
lead sulfochromate yellow [This EH40/2005 WELs (United Kingdom (UK), 8/2007). Skin
substance is identified in the Colour sensitiser.

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Penguard Topcoat - Comp. A with LC
Index by Colour Index Constitution TWA: 0,05 mg/m, (as Cr) 8 hour(s).
Number, C.I. 77603.]
butan-1-ol EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed
through skin.
STEL: 154 mg/m 15 minute(s).
STEL: 50 ppm 15 minute(s).
lead chromate molybdate sulfate red EH40/2005 WELs (United Kingdom (UK), 8/2007). Skin
[This substance is identified in the sensitiser. Notes: as Cr
Colour Index by Colour Index TWA: 0,05 mg/m, (as Cr) 8 hour(s).
Constitution Number, C.I. 77605.]
ethylbenzene EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed
through skin.
STEL: 552 mg/m 15 minute(s).
STEL: 125 ppm 15 minute(s).
TWA: 100 ppm 8 hour(s).
TWA: 441 mg/m 8 hour(s).
ethanol EH40/2005 WELs (United Kingdom (UK), 8/2007).
TWA: 1920 mg/m 8 hour(s).
TWA: 1000 ppm 8 hour(s).

Personal protective equipment

Respiratory system : If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use respiratory mask with charcoal and dust filter
when spraying this product.(as filter combination A2-P2). In confined spaces, use
compressed-air or fresh-air respiratory equipment. When use of roller or brush,
consider use of charcoalfilter.

Skin and body : Personnel should wear antistatic clothing made of natural fibres or of high-
temperature-resistant synthetic fibres.
Hands : For prolonged or repeated handling, use the following type of gloves: gloves:
polyvinyl alcohol or nitrile.

Barrier creams may help to protect the exposed areas of the skin but should not be
applied once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of
penetration, seek advice by the supplier of chemical resistant gloves.
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of
use, as included in the user's risk assessment.
Eyes : Use safety eyewear designed to protect against splash of liquids.

9. Physical and chemical properties

Physical state : Liquid.
Odour : Characteristic.
Colour : Various colours.
Flash point : Closed cup: 25C (77F)
Viscosity : > 7x10-6 m2/s (ISO 3219, 40 C)
Density : 1.37 g/cm3
Explosion limits : 1.1 - 19%
Solubility : Insoluble in the following materials: cold water and hot water.

10. Stability and reactivity

Stable under recommended storage and handling conditions (see section 7).

Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.

Keep away from the following materials to prevent strong exothermic reactions: oxidising agents, strong alkalis, strong
acids.
When welding/cutting/burning on flat finish high concentrations of lead may develop.

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Penguard Topcoat - Comp. A with LC

11. Toxicological information

There are no data available on the preparation itself. The preparation has been assessed following the conventional
method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See
sections 2 and 15 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys,
liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness,
drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the
preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Contains epoxy resin (MW 700-1200). May produce an allergic reaction.

Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.
Reproductive toxicity : Can cause birth defects.
Product name List name Name on list Classification Notes
lead sulfochromate yellow UK Occupational chromium (VI) Carc.
[This substance is identified Exposure Limits EH40 compounds
in the Colour Index by Colour - WEL
Index Constitution Number,
C.I. 77603.]
lead chromate molybdate UK Occupational chromium (VI) Carc.
sulfate red [This substance is Exposure Limits EH40 compounds
identified in the Colour Index - WEL
by Colour Index Constitution
Number, C.I. 77605.]

12. Ecological information

There are no data available on the preparation itself.
Do not allow to enter drains or watercourses.

The preparation has been assessed following the conventional method of the Dangerous Preparations Directive
1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 3 and 15 for details.
Aquatic ecotoxicity
Product/ingredient name Test Result Species Exposure
xylene Mortality Acute LC50 12000 to Fish - Bluegill 96 hours
16114 ug/L Fresh water - Lepomis
macrochirus -
1,1 g
Solvent naphtha (petroleum), light arom. - Acute EC50 <10 mg/L Daphnia 48 hours
- Acute IC50 <10 mg/L Algae 72 hours
- Acute LC50 <10 mg/L Fish 96 hours
lead sulfochromate yellow [This substance - Acute EC50 >100 mg/l Daphnia - 48 hours
is identified in the Colour Index by Colour Daphnia
Index Constitution Number, C.I. 77603.] magna straus
- Acute EC50 >100 mg/l Algae - 72 hours
Scenedesmus
subspicatus
- Acute LC50 2500 mg/l Fish - 96 hours
Leuciscus
idus
ethylbenzene Population Acute EC50 7,2 mg/L Algae 48 hours
Intoxication Acute EC50 2,93 mg/L Daphnia 48 hours
Mortality Acute LC50 4,2 mg/L Fish 96 hours
Ecological information
Biodegradability
Product/ingredient name Aquatic half-life Photolysis Biodegradability

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Penguard Topcoat - Comp. A with LC
xylene - - Readily
Solvent naphtha (petroleum), light - - Not readily
arom.
lead sulfochromate yellow [This - - Not readily
substance is identified in the Colour
Index by Colour Index Constitution
Number, C.I. 77603.]
lead chromate molybdate sulfate red - - Not readily
[This substance is identified in the
Colour Index by Colour Index
Constitution Number, C.I. 77605.]
Bioaccumulative potential
Product/ingredient name LogKow BCF Potential
xylene 3,12 - high
butan-1-ol 0,9 - low
ethanol -0,32 - low

13. Disposal considerations

Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste.
European waste catalogue : 08 01 11* Waste paint and varnish containing organic solvents or other dangerous
(EWC) substances. If this product is mixed with other wastes, this code may no longer apply.
If mixed with other wastes, the appropriate code should be assigned. For further
information, contact your local waste authority.

14. Transport information

Transport within users premises: always transport in closed containers that are upright and secure. Ensure that
persons transporting the product know what to do in the event of an accident or spillage.
International transport regulations
Proper shipping name : Paint.
Marine pollutant : lead chromate molybdate sulfate red this substance is identified in the colour index
substances by colour index constitution number c.i. 77605, lead sulfochromate yellow this
substance is identified in the colour index by colour index constitution number c.i.
77603
UN Number : 1263
Class : 3
Packing group : III
Label :

Marking : The environmental hazardous / marine pollutant mark is only applicable for packages
containing more than 5 litres for liquids and 5 kg for solids.
Additional information
ADR / RID : Tunnel restriction code: (D/E)
Hazard identification number: 30
Special provisions: 640E
IMDG : Emergency schedules (EmS): F-E, S-E
Marine pollutant: Yes.
Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.

15. Regulatory information

EU regulations : The product is classified and labelled for supply in accordance with the Directive
1999/45/EC as follows:
Hazard symbol or symbols :

Toxic Dangerous for the

environment

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Penguard Topcoat - Comp. A with LC
Risk phrases : R10- Flammable.
R45- May cause cancer.
R61- May cause harm to the unborn child.
R62- Possible risk of impaired fertility.
R20/21- Also harmful by inhalation and in contact with skin.
R36/38- Irritating to eyes and skin.
R43- May cause sensitisation by skin contact.
R33- Danger of cumulative effects.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.

Safety phrases : S53- Avoid exposure - obtain special instructions before use.
S23- Do not breathe vapour / spray.
S36/37- Wear suitable protective clothing and gloves.
S38- In case of insufficient ventilation, wear suitable respiratory equipment.
S45- In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
Contains : epoxy resin (MW 700-1200)
xylene
lead sulfochromate yellow [This substance is identified in the Colour Index by Colour
Index Constitution Number, C.I. 77603.]
lead chromate molybdate sulfate red [This substance is identified in the Colour Index
by Colour Index Constitution Number, C.I. 77605.]
Additional warning : Contains lead. Should not be used on surfaces liable to be chewed or sucked by
phrases children.
Restrictions on the : Restricted to professional users.
Marketing and Use
Directive
Industrial use : The information contained in this safety data sheet does not constitute the users
own assessment of workplace risks, as required by other health and safety
legislation. The provisions of the national health and safety at work regulations apply
to the use of this product at work.

16. Other information

CEPE Classification : 1
Full text of abbreviated H : H225 Highly flammable liquid and vapour.
statements H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H335 May cause respiratory irritation. May cause drowsiness or dizziness.
and
H336
H350 May cause cancer.
H360Df May damage the unborn child. Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.

Full text of abbreviated R : R11- Highly flammable.

phrases R10- Flammable.
R45- May cause cancer.
R61- May cause harm to the unborn child.
R62- Possible risk of impaired fertility.
R20- Also harmful by inhalation.
R22- Also harmful if swallowed.
R20/21- Also harmful by inhalation and in contact with skin.
R65- Also harmful: may cause lung damage if swallowed.
R41- Risk of serious damage to eyes.
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Penguard Topcoat - Comp. A with LC
R37- Irritating to respiratory system.
R38- Irritating to skin.
R36/38- Irritating to eyes and skin.
R37/38- Irritating to respiratory system and skin.
R43- May cause sensitisation by skin contact.
R33- Danger of cumulative effects.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapours may cause drowsiness and dizziness.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R53- May cause long-term adverse effects in the aquatic environment.

This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No 1907/2006.

Date of issue : 07.07.2011.

Version : 1.01
Notice to reader
The information in this SDS is based on the present state of our knowledge and on current laws. The product
is not to be used for purposes other than those specified under section 1 without first obtaining written
handling instructions. It is always the responsibility of the user to take all necessary steps to fulfil the
demands set out in the local rules and legislation. The information in this SDS is meant to be a description of
the safety requirements for our product. It is not to be considered a guarantee of the product's properties.

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