Thermochemistry and Thermodynamics
Thermochemistry and Thermodynamics
Thermochemistry and Thermodynamics
6. For the following reaction, determine the amount of heat (in kJ) is given off when 1.26 104 g of ammonia
is produced.
9. Rank the following materials in order of increasing entropy (without consulting standard entropy values):
a) KCl(s), KBr(s), SrS(s)
b) CH4(g), C5H12(g), C3H8(g)
c) NaCl(s), NaCl(aq), NaBr(s)
d) Xe(g), Ne(g), Ar(g)
e) NH3(g), Ne(g), CH3CH2OH(g), He(g)
10. For each of the following reactions, calculate the Hrxn and Srxn from the standard enthalpy and entropy
values in your book. Then calculate the Grxn from the Hrxn and Srxn values calculated above at 25C.
a) 2 CH4(g) C2H6(g) + H2(g)
b) 2 NH3(g) N2H4(g) + H2(g)
c) N2(g) + O2(g) 2 NO(g)
d) 2 KClO3(s) 2 KCl(s) + 3 O2(g)
e) 3 H2(g) + Fe2O3(s) 2 Fe(s) + 3 H2O(g)
11. The molar heats of fusion and vaporization of mercury are 23.4 and 59.0 kJ/mole, respectively. Calculate
the molar entropy changes for the solid-liquid and liquid-gas transitions for mercury if it melts at -38.9C and
boils at 357C.
12. Calculate the change in Gibbs free energy for each of following sets of data and indicate whether or not the
reaction will be spontaneous.
a) Hrxn = 125 kJ; Srxn = +253 J/K; T = 298 K
b) Hrxn = +125 kJ; Srxn = 253 J/K; T = 298 K
c) Hrxn = 125 kJ; Srxn = 253 J/K; T = 298 K
d) Hrxn = 125 kJ; Srxn = 253 J/K; T = 555 K
13. Using the Gf values in the table at the back of your book, calculate the Grxn for the following reactions
at 25C, and identify if they are reactant- or product-favored.
a) K(s) + Cl2(g) 2 KCl(s)
b) 4 NH3(g) + 7 O2(g) 4 NO2(g) + 6 H2O(g)
c) 2 CuO(s) 2 Cu(s) + O2(g)
d) SiCl4(l) + 2 Mg(s) 2 MgCl2(s) + Si(s)
14. Find the temperatures at which the following reactions would become spontaneous:
a) H = -126 kJ/mole; S = 84 J/Kmole
b) H = -11.7 kJ/mole; S = -105 J/Kmole
c) H = 10.5 kJ/mole; S = 30 J/Kmole
15. Predict the outcome of the reaction (spontaneous or non-spontaneous) based on the following information:
a) H = +, S = +
b) H = +, S =
c) H = , S = +
d) H = , S =
17. The Ksp for iron (II) hydroxide is 1.6 10-14. Calculate the Gibbs free energy for this reaction.