Safety Data Sheet: Hardening Bath 1719-2000

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Renfert GmbH

Safety Data Sheet

according to Regulation (EU) No. 1907/2006

Hardening Bath 1719-2000


Print date : 26.02.2009 Product code : 1719-2000 Page 1 of 5

1. Identification of the substance/preparation and of the company/undertaking

Identification of the substance or preparation


Hardening Bath 1719-2000
Use of the substance/preparation
Self-hardening plastic solution for plaster models, dies etc.
Company/undertaking identification
Company name : Renfert GmbH
Street : Untere Giesswiesen 2
Place : D-78247 Hilzingen
Telephone : +49 7731 8208-0 Telefax : +49 7731 8208-70
Contact person : Frau Andris Telephone : +49 7731 8208-927
e-mail : [email protected]
Internet : www.renfert.com
Emergency telephone : Vergiftungs-Zentrale Freiburg
+49 761 19 240

2. Hazards identification

Classification
Indications of danger : Highly flammable, Irritant
R-phrases :
Highly flammable.
Irritating to eyes.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.

3. Composition/information on ingredients

Chemical characterization ( preparation )


Surface hardener (resin solution)

Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification

200-662-2 67-64-1 acetone, propan-2-one, propanone > 70 % F, Xi R11-36-66-67

Full text of each relevant R phrase can be found in heading 16.

4. First aid measures

General information
Change contaminated clothing.
After inhalation
Provide fresh air.
After contact with skin
After contact with skin, wash immediately with plenty of Water and soap. In case of skin irritation, seek
medical treatment.
After contact with eyes
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After ingestion
Rinse mouth immediately and drink large quantities of water. Do not induce vomiting. Immediately get
medical attention.

Revision no. : 1,00 GB - EN Revision date : 11.12.2008


Renfert GmbH
Safety Data Sheet

according to Regulation (EU) No. 1907/2006

Hardening Bath 1719-2000


Print date : 26.02.2009 Product code : 1719-2000 Page 2 of 5

5. Fire-fighting measures

Suitable extinguishing media


Extinguishing powder. Carbon dioxide (CO2). alcohol resistant foam. Water fog.
Extinguishing media which must not be used for safety reasons
High power water jet.
Special exposure hazards arising from substance or preparation itself, combustion products, resulting
gases
Vapours may form explosive mixtures with air.
Special protective equipment for fire-fighters
In case of fire and/or explosion do not breathe fumes.
In case of fire: Wear self-contained breathing apparatus.

6. Accidental release measures

Personal precautions
Provide adequate ventilation.
Wear personal protection equipment.
Remove all sources of ignition.
Environmental precautions
Do not empty into drains or the aquatic environment.
Methods for cleaning up/taking up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Collect in closed containers for disposal.

7. Handling and storage

Handling
Advice on safe handling
Use only in well-ventilated areas.
Avoid contact with skin and eyes.
Advice on protection against fire and explosion
Vapours may form explosive mixtures with air. Keep away from sources of ignition. No smoking.
Further information on handling
In case of open handling, use devices with built-in suction where possible.
Storage
Requirements for storage rooms and vessels
Keep container tightly closed in a cool, well-ventilated place.
Further information on storage conditions
Protect against: heating.

8. Exposure controls/personal protection

Exposure limit values

Exposure limits (EH40)


CAS-No. Chemical name ml/m mg/m F/ml Category Origin

67-64-1 Acetone 500 1210 TWA (8 h) WEL


1500 3620 STEL (15 min) WEL

Revision no. : 1,00 GB - EN Revision date : 11.12.2008


Renfert GmbH
Safety Data Sheet

according to Regulation (EU) No. 1907/2006

Hardening Bath 1719-2000


Print date : 26.02.2009 Product code : 1719-2000 Page 3 of 5

Exposure controls
Occupational exposure controls
See chapter 7. No further action is necessary.
Protective and hygiene measures
Do not breathe vapour.
Avoid contact with skin, eye and clothing.
"Wash hands when done working with material; at breaks, lunch, shift changes, etc."
Respiratory protection
Respiratory protection required in case of: Insufficient ventilation.
Hand protection
Tested protective gloves are to be worn: Suitable material: NBR (Nitrile rubber). PVC (Polyvinyl
chloride).
In the cases of special applications, it is recommended to check the chemical resistance with the
manufacturer of the gloves.
Eye protection
Tightly sealed safety glasses.
Environmental exposure controls
Do not empty into drains or the aquatic environment.

9. Physical and chemical properties

General information
Physical state : liquid
Colour : colourless
Odour : characteristic
Important health, safety and environmental information
Test method
pH-Value : not applicable
Changes in the physical state
Boiling point : 54 C
Flash point : - 16 C DIN 51755
Lower explosion limits : 2,1 * vol. %
Upper explosion limits : 13,0 * vol. %
Density (at 20 C) : 0,84 - 0,86 g/cm
Water solubility : miscible.
Viscosity / dynamic : product has not been tested.
Other information
* Data apply to the principal component.

10. Stability and reactivity

Conditions to avoid
Keep away from sources of ignition. No smoking.
Vapours may form explosive mixtures with air.
Materials to avoid
Reacts with : Oxidizing agents, strong.

11. Toxicological information

Acute toxicity

Revision no. : 1,00 GB - EN Revision date : 11.12.2008


Renfert GmbH
Safety Data Sheet

according to Regulation (EU) No. 1907/2006

Hardening Bath 1719-2000


Print date : 26.02.2009 Product code : 1719-2000 Page 4 of 5

Acute toxicity, oral


LD50: > 2.000 mg/kg
species: rat.
Corrosive and irritant effects
Irritant effect on the skin: Not an irritant.
Irritant effect on the eye: irritant.
Sensitising effects
no danger of sensitization.
Empirical data on effects on humans
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Has de-greasing effect on the skin.
Further information
product has not been tested. The statement is derived form the properties of the components.

12. Ecological information

Persistence and degradability


Some of the components are biodegradable.
Further information
product has not been tested. The statement is derived form the properties of the components.

13. Disposal considerations

Advice on disposal
Carry out a burning of harzardous waste according to official regulations.
Waste disposal number of waste from residues/unused products
080111 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF
COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND
PRINTING INKS; wastes from MFSU and removal of paint and varnish; waste paint and varnish
containing organic solvents or other dangerous substances
Classified as hazardous waste.
Contaminated packaging
Handle contaminated packaging in the same way as the substance itself.

14. Transport information

Land transport (ADR/RID)


UN number : 1866
ADR/RID class : 3
Warning plate
ADR/RID packing group : II
Description of the goods
HARZLSUNG, entzndbar
Marine transport
UN number : 1866
IMDG code : 3
Marine pollutant : no
IMDG packing group : II
Description of the goods
RESIN SOLUTION flammable

Revision no. : 1,00 GB - EN Revision date : 11.12.2008


Renfert GmbH
Safety Data Sheet

according to Regulation (EU) No. 1907/2006

Hardening Bath 1719-2000


Print date : 26.02.2009 Product code : 1719-2000 Page 5 of 5

Air transport
UN/ID number : 1866
ICAO/IATA-DGR : 3
ICAO packing group : II
Description of the goods
RESIN SOLUTION flammable

15. Regulatory information

Labelling
Danger symbols : F - Highly flammable; Xi - Irritant
R phrases
11 Highly flammable.
36 Irritating to eyes.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
S phrases
07/09 Keep container tightly closed and in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
24 Avoid contact with skin.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
51 Use only in well-ventilated areas.
Additional advice on labelling
The R and S phrases can be omitted if the pack contains no more than 0,125 litres.
EU regulatory information
1999/13/EC (VOC) : 79,88 % (679 g/l)
National regulatory information
Water contaminating class : 1 - slightly water contaminating
Additional information
M 017 Lsemittel (BGI 621)
M 004 Reizende Stoffe / tzende Stoffe (BGI 595)

16. Other information

Full text of R-phrases referred to under sections 2 and 3


11 Highly flammable.
36 Irritating to eyes.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
Further Information
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights. The receiver of our product is singulary
responsible for adhering to existing laws and regulations. Reserved for industrial and professional use.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

Revision no. : 1,00 GB - EN Revision date : 11.12.2008

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