General Manufacturing Steps
General Manufacturing Steps
Flint was
first formed as a metamorphic rock. While many sedimentary rocks contain significant
proportions of flint that was weathered and transported, the material of interest in ceramics is
what has remained as the pure mineral.
4. The first ceramics were simply dried outside and then burned in an open fire. Today, there are
many varieties of dryers such as band, batch and tunnel dryers which are used, together with
electrical, microwave assisted and bottle kilns. Removing the water or other binders from the
formed material is known as drying. The formed materials hold water and binder in its mix
that can in turn cause shrinkage, warping or distortion of the product. convection drying is
the most commonly used method in which heated air is circulated around the ceramic piece
that alleviates the risk of such imperfections in the final product. Air drying often is performed
in tunnel kilns, which typically use heat recovered from the cooling zone of the kiln. Drying
must be carefully controlled to strike a balance between minimizing drying time and avoiding
differential shrinkage, warping, and distortion.
Ceramic glaze, a vitreous coating to a ceramic material whose primary purposes are
decoration or protection
Molded brick wall facing
The tile industry uses the largest volumes of engobe by far, these are employed as opaque
barriers between less-than-white bodies and their glazes.
6. Firing of Traditional CeramicsHeat treatment process that sinters the ceramic material
Performed in a furnace called a kiln Bonds are developed between the ceramic grains, and
this is accompanied by densification and reduction of porosity Therefore, additional
shrinkage occurs in the polycrystalline material in addition to that which has already occurred
in drying In the firing of traditional ceramics, a glassy phase forms among the crystals which
acts as a binder
Vitrification is the solidification of a melt into a glass rather than a crystalline structure
(crystallization). Glass, clay bodies and glazes vitrify, but in ceramics use of the term focuses
most on clay bodies. Vitrification is a process. As clay is fired hotter and hotter, it reaches a
point where, if cooled from there, it will produce ware of sufficient density and strength as to
be useful for the intended purpose. A clay that has been fired sufficiently dense and strong for
the purpose intended is said to be 'mature'.
Vitrification (noun) is the process of melting that clays and glazes go through as they are fired to
maturity. In a fully matured clay body, the spaces between refractory particles are completely
filled up with glass, fusing the particles together and making the clay body impervious to water.
Vitreous (adjective) is the state of either being or becoming vitrified.
Vitrify (verb) is the activity of becoming vitreous
Vitrification is how "solid", non porous or glass like a piece becomes in firing. A fully vitrified
piece will hold water without glaze. Different types of clay get there at different
temperatures.
Vitrification (from Latin vitreum, "glass" via French vitrifier) is the transformation of a
substance into a glass,[1] that is to say a non-crystalline amorphous solid. In the production
of ceramics, vitrification is responsible for its impermeability to water
Firing is a key process in the manufacture of ceramic products, as it controls many important
properties of the finished ware. This need a very accurate temperature gradient during firing to
make sure that the products obtain the correct treatment. These include mechanical strength,
abrasion resistance, dimensional stability, resistance to water and chemicals, and fire
resistance. Afterwards controlled cooling is necessary, so that the products release their heat
gradually and preserve their ceramic structure. When clay-based ceramic products are fired in a
kiln, any residual moisture is driven off at temperatures of between 100 and 200 C. The most
important changes relating to the development of ceramic properties involve the breakdown of
the lattice structure of the original clay minerals, followed by the formation of new crystalline
compounds and glassy phases. Although clay products never become absolutely vitrified or
glasslike, it is necessary that the clay become hard (or almost vitrified) at a reasonable
temperature. Any substance will melt at some temperature. The strength of fired clay is
increased by the formation of new crystalline growth within the clay body, particularly the
growth of mullite crystals.
Early Stage to Firing
Drying and water-smoking first change completion in drying. This must be done slowly of formation
of 100oC steam will occur within the body and may cause it to burst.
The next change is at 350oC. Chemically combined water begins to be driven off. (This is part of the
molecular structure of clay and is unaffected under 350 oC.) This release of sudden steam must
be done slowly or object will crack.
At 500oC, the clay is completely dehydrated, no longer slake or disintegrate in water, has lost all
plasticity. It may not be reclaimed and used again. An irreversible change has taken place -
dehydration - this is not accompanied by any shrinkage. At 500 oC, the clay is more fragile now
than it was when put into the kiln.
As temperature increases beyond red heat, vitrification occurs. Hardening, tightening and finally,
partial glassification of clay. Vitrification gives the fired clay its characteristic hard, dense,
durable and rocklike properties. It is accompanied by shrinkage in the clay. Vitrification proceeds
gradually as temperature increases and becomes increasingly hard, up to a point of melting and
deformation. Hardening results from the melting of some of the components in the clay, in part,
those components we consider impurities, iron oxide, etc.(clay has numerous oxides) it tends to
fuse gradually, impurities (as temp) melt in small beads of glass, soaks into surrounding areas,
binding particles like a glue and act as a solvent in promoting further fusion. If firing is carried
on clay would reach a liquid state and when cooled, be glass. We don't do this.
A short firing time results in a product that is porous and has a low density; a short to intermediate
firing time results in fine-grained (i. e., having particles not larger than 0.2 millimeters), high-
strength products; and long firing times result in a coarse-grained products that are more creep
resistant. Applying pressure decreases firing time and makes it possible to fire materials that are
difficult to fire using conventional methods.
dried parts pass through a controlled heating process, and the oxides are chemically changed to
cause bonding and densification. The fired part will be smaller than the dried part. is done at a
temperature below the melting point of the ceramic.
The temperature at which vitrification (glass formation) takes place, varies according to the
mineralogy of the clay.
Sintering is the process of compacting and forming a solid mass of material by heat [1] or
pressure[2] without melting it to the point of liquefaction. Because the sintering temperature
does not have to reach the melting point of the material, sintering is often chosen as the
shaping process for materials with extremely high melting points such
as tungsten and molybdenum. Sintering in practice is the control of both densification and grain
growth. Densification is the act of reducing porosity in a sample thereby making it more dense.
Grain growth is the process of grain boundary motion and Ostwald ripening to increase the
average grain size. Many properties (mechanical strength, electrical breakdown strength, etc.)
benefit from both a high relative density and a small grain size. Therefore, being able to control
these properties during processing is of high technical importance. Since densification of
powders requires high temperatures, grain growth naturally occurs during sintering. Reduction
of this process is key for many engineering ceramics. The sintering of liquid-phase materials
involves a fine-grained solid phase to create the needed capillary pressures proportional to its
diameter and the liquid concentration must also create the required capillary pressure within
range, else the process ceases. The vitrification rate is dependent upon the pore size, the
viscosity and amount of liquid phase present leading to the viscosity of the overall composition,
and the surface tension. Temperature dependence for densification controls the process because
at higher temperatures viscosity decreases and increases liquid content. Therefore, when
changes to the composition and processing are made, it will affect the vitrification process. [3]
7. Following firing, some ceramic products are processed further to enhance their characteristics
or to meet dimensional tolerances. Annealing at high temperature, followed by gradual cooling
can relieve internal stresses within the ceramic and surface stresses due to machining. Surface
coatings are applied to traditional clay ceramics to create a stronger, impermeable surface and
for decoration. Coatings also may be applied to improve strength, and resistance to abrasion
and corrosion. Coatings can be applied dry, as slurries, by spraying, or by vapor deposition.
What we call the annealing point is the temperature just below the freezing point, which is just
under 1000F for most soda-lime soft glass. At this temperature, the glass is cool enough that
it no longer moves or slumps with gravity, and hot enough that it cannot begin to build up stress
in the glass. If glass is held at this temperature long enough (about 1 hour per in. of
thickness), it will relieve any stress, and cooling can begin from there.
ID taper grinding, OD taper grin Chemical Mechanical Polishing (CMP) is a technique which
utilizes both a mechanical abrasive with a chemical surface reactant with the material
surface. ding with diamond wheels, radius grinding, non-round grinding, thread grinding etc for
ceramic parts.
In some cases, particularly involving porcelain tiles, the fired surface is polished to achieve a
shiny, unglazed homogenous tile.
8. Ceramic tiles are individually somewhat fragile, but when tightly packed in cardboard
boxes, prove remarkably robust during handling and transportation. Storage of heavy clay goods
made on a large scale is often outdoors, but products which are bagged or boxed require
warehouse storage, as do certain moisture sensitive refractory products. Regularly shaped
ceramic units such as bricks, blocks, pipes and refractory units are normally strapped into
standard sized packs, which are often subsequently polyethylene-wrapped and may be
palletised. Ceramic products at the top end of the value range, such as table- and
ornamentalware, demandrigorous inspection and sorting followed by sophisticated protective
packaging. In contrast, unshaped refractory products are usually simply weighed into bags and
then palletised.
Risks & Opportunities
The production of glass and ceramics is very energy-intensive.
Energy is used primarily to melt and refine raw materials. In addition, further downstream
processing to form and finish
glass or ceramics also requires a significant amount of energy.
High temperatures, toxic dust, moving machines and falls from heights are the
main health and safety issues.
Heavy machinery is involved in glass and ceramic manufacturing. Production processes
expose workers to high
temperatures and solvents. Risks to the health and lives of workers may be mitigated by
training, protective equipment
and technical measures.
Large amounts of water are used for cooling and production purposes.
Water is used to cool the molten raw material and the tools used in the glass product
manufacturing process.
The gaseous emissions from kilns and furnaces may contain toxic substances.
Emissions to air depend on the choice of fuel used for the kilns and furnaces. Emissions
normally include substances as
NOx, SOx, CO, hydrocarbons and fluorides. Fluorides, in particular, can pose a risk to human
health.
Wastewater may be contaminated with heavy metals.
There are several wastewater
Ceramics are often displayed vertically on walls with spring- loaded mounting brackets. These brackets
may exert too much pressure on ceramic plates and often cause cracks and damage. Other vertical
plate racks are made that do not exert undue pressure and are much safer for your prized objects.
Separate prongs can also be used in place of either type of mounting device. It helps to pad the part of
the mount with a synthetic felt to prevent any scratching onto the surface of the object.
Another common problem in the display of ceramic and glass pieces involves the gradual, incremental
movement of objects on surfaces due to underground vibrations. The movement can be caused by any
constant, transmitted vibration source like subways, trains, underground equipment, and normal
building vibration. Objects in museums are often carefully secured to their display surfaces with very
small dots of soft wax to prevent them from walking off their display vitrines. Caution should be used,
however, when using wax. One must take into consideration whether the wax may be safely removed
from the object. There are expert conservators who have researched and studied ways to reduce
earthquake-related damages to displayed objects. If you live in earthquake area and display important
objects, you can get information about these experts and their methods by contacting a local objects
conservator.
A major source of damage to ceramics and glass can be improper handling and carelessness. A
thoughtless tap of a glass goblet on the storage shelf can result in a chip or complete breakage.
Careless handling can also lead to the formation of internal cracks that weaken the ceramic or glass
structure. It is always best to overestimate the brittleness and underestimate the strength of an
artifact. Of course, anyone who has poured hot water into a cold glass or mug and heard a delicate
chink sound will recall the heartache of breaking a favorite piece.
When moving ceramic and glass objects, always carry one object or one part of an object at a time. It is
best to place your hands around the body of the object rather than using an existing handle, rim, or
spout for support. Be sure you have a level space of adequate size available to place the object, and a
clear path to move, before removing the piece from its original location. Carry objects from room to
room or up and down stairs in a padded basket or box rather than in your hands. If you were to trip or
fall with your hands full, you would crush the object and most likely injure yourself as well. Use soft
padding to prevent ceramic and glass objects from clinking against each other during transport or in
overcrowded conditions.
Glass is a frozen liquid, and acquires its solid appearance because its viscosity increases with cooling
Float glass is a sheet of glass made by floating molten glass on a bed of molten metal, typically tin,
although lead and various low melting point alloys were used in the past. This method gives the sheet
uniform thickness and very flat surfaces. Modern windows are made from float glass. Most float glass
is soda-lime glass, but relatively minor quantities of specialty borosilicate[8] and flat panel display glass
are also produced using the float glass process. [9] The float glass process is also known as
the Pilkington process,[10] named after the British glass manufacturer Pilkington, who pioneered the
technique (invented by Sir Alastair Pilkington) in the 1950s.
Glassblowing is a glassforming technique that involves inflating molten glass into a bubble (or
parison), with the aid of a blowpipe (or blow tube). A person who blows glass is called
a glassblower, glassmith, or gaffer. A lampworker (often also called a glassblower or glassworker)
manipulates glass with the use of a torch on a smaller scale, such as in producing precision laboratory
glassware out of borosilicate glass.
2. Soda ash plays a vital role by reducing the furnace temperature necessary to melt the silica used,
thus reducing the energy required to produce glass. (1) Sand (SiO2 silica) (main composition) in
its pure form it exists as a polymer, (SiO2)n; (2) Soda ash (sodium carbonate Na2CO3) - normally
SiO2 softens up to 2000C, where it starts to degrade (at 1713C most of the molecules can
already move freely); (3) Limestone (calcium carbonate or CaCo3) or dolomite (MgCO3) - also
known as lime, calcium carbonate is found naturally as limestone, marble, or chalk. Lime increases
the hardness and chemical durability and providing insolubility of the materials.
3. fine grained ingredients closely controlled for quality, are mixed to make a batch, which flows into
the furnace, which is heated up to 1500 degree Celsius. The above raw materials primarily mixed in
batch helps to make clear glass. If certain metal oxides are mixed to this batch they impart colors
to the glass giving it a body tint. The above raw materials primarily mixed in batch helps to make
clear glass. If certain metal oxides are mixed to this batch they impart colors to the glass giving it a
body tint. Apart from the above basic raw material, broken glass aka cullet, is added to the mixture
to the tune of nearly 25% ~ 30% which acts primarily as flux. The flux in a batch helps in reducing
the melting point of the batch thus reducing the energy consumed to carry out the process.
Chem rxn takes place and results in a liquid state glass. Impurities, glass gal rise to the surface and
are removed. At this stage,
4. The fused mass obtained will be allowed to coll but still in a liquid state. Liquid glass is then poured
into moulds of required shape. Viscosity, a measure of liquid fluidity, varies inversely with
temperature. As the temperature decreases, viscosity increases. As glass cools, it gets "stiffer" or
more viscous.
Glass from the furnace gently flows over the refractory spout on to the mirror-like surface of molten
tin, starting at 1100 deg Celsius and leaving the float bath as solid ribbon at 600 deg Celsius.
Float Method- Molten glass is floated over a bath of molten tin before it is solidified in a separate
chamber.
5. Glass obtained by rapid cooling is brittle, as glass cools, it shrinks and solidifies.
Heat then cools in an long narrow chamber by a conveyor belt where it cools slowly giving transparent
glass. Annealing strengthens the glass
6. to ensure the highest quality inspection takes place at every stage. Occasionally a bubble that is
not removed during refining, a sand grain that refuses to melt or a tremor in the tin puts ripples in
the glass ribbon. Automated online inspection does two things. It reveals process faults upstream
that can be corrected. And it enables computers downstream to steer round the flaws. Inspection
technology now allows 100 million inspections per second to be made across the ribbon, locating
flaws the unaided eye would be unable to see.