UNIVERSITY OF MINNESOTA DULUTH

DEPARTMENT OF CHEMICAL ENGINEERING

ChE 3211-4211

DRYING CURVES OF A NON-POROUS SOLID

OBJECTIVE

Determine the drying behavior of a non-porous solid and calculate the heat and mass
transfer coefficients during the constant-rate drying period. Determine how your drying curve
plots correspond to the plots shown in Figure 1 below. Determine how the sand temperature
relates to the air temperature and the wet bulb temperature of the air above the sand.

INTRODUCTION

The term "drying" is a relative one, and simply means that there is a further reduction in the
moisture content from some initial level provided by mechanical dewatering to some acceptable
lower level. For example, a moisture content of 10-20% by volume would normally allow
particles to flow freely, yet suppress dust formation. The necessity for drying may be to make a
product suitable for sale (e.g. paint pigments), or for subsequent processing (e.g. in
pyrometallurgical operations).
When a solid dries, two fundamental and simultaneous processes occur: (1) heat is
transferred to evaporate liquid; (2) mass is transferred as a liquid or vapor within the solid and as
a vapor from the surface. These factors governing the rates of these processes determine the
drying rate. Commercial drying operations may utilize heat transfer by convection, conduction,
radiation, or a combination of these. Industrial dryers differ fundamentally by the methods of
heat transfer employed. However, irrespective of the mode of heat transfer, heat must flow to
the outer surface and then into the interior of the solid.
Careful consideration of many factors is necessary in the final selection of the most suitable
type of dryer for a particular application. Some of these factors are:

! Properties of the material being handled

! Drying characteristics of the material
! Flow of the material to and from the dryer
! Product qualities
! Recovery problems
! Facilities available at the site of the proposed installation.

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 When a solid is dried experimentally, data are usually obtained relating moisture content to
time. Consider the drying of a non-porous, insoluble material such as sand in a tray. The
surface of the sand is exposed to a drying medium such as hot dry air passing over the surface.
Figure 1. shows a typical drying curve.

Figure 1. Typical Drying Curve.

Immediately after contact between the wet solid and the drying medium, the solid
temperature adjusts until it reaches a steady state. The solid temperature and the rate of drying
may increase or decrease to reach the steady state condition (AB). At steady state, the
temperature of the wet solid surface is the wet bulb temperature of the drying medium.
Temperatures within the drying solid also tend to equal the wet bulb temperature of the gas, but
the lag in movement of mass and heat result in some deviation. Once the stock temperatures
reach the wet bulb temperature of the gas, they are quite stable and the drying rate also remains
constant. This is the constant rate drying period (BC) which ends when the solid reaches the
critical moisture content. Beyond this point the surface temperature rises and the drying rate
falls off rapidly (CD). Not always distinguishable, there may be another change in drying rate
(DXE1). If this occurs, it is referred to as the second falling rate period. The falling rate periods
can take a far longer time than the constant rate period even though the moisture removal may be
less. The drying rate approaches zero at some equilibrium moisture content (XE1) which is the
lowest moisture content obtainable with the solid under the drying conditions used.

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REFERENCES

Kelly, E.G., and Spottiswood, D.J., "Introduction to Mineral Processing", John Wiley & Sons,
Inc., New York, N.Y., 1982, Chapter 19

Perry, R., Chilton, C.H., Kirkpatrick, S.D., (Editors), "Chemical Engineers' Handbook", 5th
Edition, McGraw-Hill Book Company, Inc., New York, N.Y., 1973, Chapter 15.

McCabe, W.L., Smith, J.C., and Harriot, P., "Unit Operations of Chemical Engineering", 4th
Edition, McGraw-Hill Book Company, Inc., New York, N.Y., 1985, Chapter 25

EQUIPMENT

1. Tray drier
2. Stop watch
3. Humidity meter
4. Velometer
5. Polyethylene bucket
6. Large spatula
7. 500 mL graduated cylinder
8. Digital thermometer

CHEMICALS/MATERIALS

1. Sand.

EXPERIMENTAL PROCEDURE

The temperature of the sand will be recorded using the thermocouple taped to the bottom
pan. Be careful when filling this pan so as not to disturb the thermocouple. The Digital
thermometer should be placed on the top of the balance and connected to the thermocouple
before the balance is turned on so it will zeroed out.
The equipment set up for the laboratory experiment is shown in Figure 2. Distribute about
2800 gms of wet sand between all four trays. The initial moisture content should be $ 10%.
Weigh the dry sand before adding water. The sand should be removed from the container and
drained of excess free water before being loaded evenly and smoothly into the drying trays.
Take care to avoid any spillage. The total weight of the wet sand should be noted before drying
commences. Measure the surface area of the sand exposed to air; that is, the area across which
the water is transferred.

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 At some arbitrary time (t=0), switch on and set the fan speed control to mid-position (5) and
the heater power control to a setting of 9, letting them remain constant throughout the
experiment. Record the total weight of sand in the trays at regular time intervals until drying is
complete. Record the temperature of the sand at the same intervals you record the humidity
measurements. Record relative humidity and temperature measurements of the air stream before
and after the drying trays at appropriate time intervals. Humidity measurements of the air stream
before the drying trays should to be taken every third or fourth time the measurement after the
air stream is taken. Record the air flow rate at appropriate time intervals.

Figure 2. Tray Drier

SAFETY NOTES

1. Personal protective equipment shall include safety glasses with side shields and
thermal mitts. Thermal mitts shall be worn whenever items at temperatures above
ambient are handled. The trays when removed from the drier are at an elevated
temperature.

WASTE DISPOSAL PROCEDURES

There should be no waste from this experiment. The sand will be reused.

07/2012

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 Department of Chemical Engineering
Stockroom Checkout slip

Drying Curves of a Non-porous Solid Experiment ChE 3211

Name: Date:
(print name)

Lab No.: Lab 1 Tuesday 12:00 - 4:50 PM Lab 2: Thursday 12:00 - 4:50 PM

Lab No.: Lab 3 Tuesday and Thursday morning (9:30 - 11:50 AM)
(circle one)

Equipment Out In Equipment Out In

Humidity meter Stopwatch
Velometer Large spatula
Digital thermometer 500 mL graduated cyl.

Name:
(Signature)

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 Instructions for the Fortran Program
PSYCHRO

There is a compiled fortran program on the computers in Engr 270 available for calculating selected
psychrometric parameters from combinations of the input parameters wet and dry-bulb temperatures, dew point,
and relative humidity.
The program PSYCHRO will calculate psychrometric parameters by entering a single set of data (example: dry
bulb (EC) and % relative humidity). It will calculate the other parameters and print them to the screen. It will then
ask whether you want to do another calculation. If you select yes, you will have to enter another set of data.

The program is a compiled fortran program and can be accessed on the computers in Engr 270 by
double clicking on the shortcut PSYCHRO. If the shortcut is not shown on the desktop the fortran
compiled file psychro.exe can be found in C:\lab programs. Answer the questions asked by the
program and input the data when asked. The two data points can be input with a space between
them or you can enter the dry bulb temperature, press <Enter> and then enter the relative humidity
and press <Enter>.

A sample output from this program is shown below.

DATA used in the example

Dry bulb temperature = 30 EC

Percent Relative Humidity = 55 percent.

INSTRUCTIONS

1. Start program. (See instructions above for location of the program.)

2. Select number 3 on the screen (Dry bulb temperature and relative humidity) Press Enter

3. Enter 30,55 Press Enter

4. Example of output

DRY-BULB TEMPERATURE: 30.00 DEGREES C

WET-BULB TEMPERATURE: 22.92 DEGREES C
DEW POINT TEMPERATURE: 19.95 DEGREES C
RELATIVE HUMIDITY: 55.00 PERCENT
ENTHALPY 67.65 J/G
HUMIDITY RATIO: .1467 E-01
DEGREE OF SATURATION .5394
SPECIFIC VOLUME .879 CU. M/KG
VAPOR PARTIAL PRESSURE 2.335 KPA