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    Ap 60e

    Uploaded by

    Costas Aggelidis
    Ap-60e

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    © All Rights Reserved
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    Ap 60e

    Uploaded by

    Costas Aggelidis
    142 views4 pages
    Ap-60e

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    Ap-60e

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    Ap-60e

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    142 views4 pages

    Ap 60e

    Uploaded by

    Costas Aggelidis
    Ap-60e

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 4

    SM

    ANALYTICAL PROCEDURE
    ELIMIN-OX
    DR/2010 Procedure
    N-22130

    AP-60E/2010
    SPECIFICATIONS
    Method: Spectrophotometric (DR/2010)
    Range: 100 to 6000 50 ppb as ELIMIN-OX
    or 22130
    Testing Time: 15 minutes

    DESCRIPTION
    An accurate, simple method of colourimetric
    analysis, the portable DR/2010 spectrophotometer
    is utilised to quickly analyse ELIMIN-OX concen-
    tration for monitoring proper application levels.
    The test is based on iron reduction chemistry and is
    Nalco DR/2010 Spectrophotometer
    simple to perform. The ELIMIN-OX in the sample
    reduces ferric iron to ferrous iron in direct propor-
    tion to the ELIMIN-OX concentration. This solution
    then reacts with Reagent 1 to form a purple colour Description Part No.
    with the ferrous iron.
    Nalco DR/2010 Spectrophotometer P1310A
    Thermometer, lab, 0 to 230F P2028
    ORDERING INFORMATION Pipette, disposable, 1 ml P2107
    Order all replacement parts and reagents by their Sample cells, 25 ml, matched set of two P2502
    part numbers. To be sure this product is compatible Flask, Erlenmeyer, glass, 250 ml P1501
    with your treatment programme, contact your local Cap, plastic (for P1501) P3037
    Nalco representative. Items marked with an * are
    included with the kit or set. Optional Parts and Reagents
    To place your order, please contact your local Description Part No.
    Customer Service Department.
    Pour-Through cell assembly kit P2517
    Sample cells, 25 ml, matched pair P2502
    REPLACEMENT PARTS AND REAGENTS Thermometer, -40 to 450F, digital P2098
    Required Parts and Reagents Thermometer, 50 to 300F, dial P2019
    Thermometer, 0 to 230F, glass P2028
    Description Part No. Pocket pH Meter P1326A
    ELIMIN-OX Reagent Set (100 Tests) P3115 pH (3-colour) test strips (0-14 pH)
    (100/box) P3204
    Includes: pH (3-colour) test strips (510 pH)
    ELIMIN-OX Reagent 1* 100/pkg (2 included) (100/box) P3207
    ELIMIN-OX Reagent 2* 100 ml Sample Cooler, Threaded (Inconel/SS) P4625
    Description Size Part No. Sample Cooler II (316 SS/MS) P4627

    ELIMIN-OX Reagent 1 100/pkg S0195-87


    ELIMIN-OX Reagent 2 100 ml S0196-72

    NALCO APPLIED SERVICES OF EUROPE B . V.


    I R. G. TJALMAW EG 1 2342 BV OEGSTGEEST P.O. BOX 627 2300 AP LEIDEN THE NETHERLANDS

    Registered Trademarks of Nalco Chemical Company 1995,1997 Nalco Chemical Company


    All Rights Reserved Printed in U.S.A. 5-97
    Description Size Part No. SAFETY PRECAUTIONS
    1:1 HCl 50 ml S0726-71 Refer to Material Safety Data Sheet (MSDS) for
    1:1 HCl 100 ml S0726-72 specific reagent personal safety and disposal
    1:1 HCl 500 ml S0726-74 information.
    1:1 HCl 1l S0726-75
    1:1 HCl 4l S0726-08
    Fe-4 50 ml S0734-71 SUPPORT
    Fe-4 500 ml S0734-74 If you have any questions regarding this procedure,
    please contact your local Nalco representative.
    INTERFERENCES
    Substances that reduce ferric iron (such as other SAMPLING
    oxygen scavengers) can interfere. Substances that 1. This is a low level test and is very susceptible to
    strongly complex iron may also interfere. The contamination. Care must be taken to eliminate
    following substances may interfere when present sources of air dissolution and other interfering
    in excess of the stated amount. species. A cooler equipped with a copper cooling
    Ammonia 100 ppm coil should NOT be used. Trace levels of copper
    Borate (as Na2B4O7) 500 ppm catalyse the reaction of ELIMIN-OX and oxygen.
    Cobalt 25 ppb As a result of copper contamination, any
    Copper 50 ppb ELIMIN-OX present in the system may be
    Cyclohexylamine 3 ppm consumed prior to analysis.
    Hardness (as CaCO3) 1000 ppm 2. Reaction glassware should be scrupulously clean.
    Hydrazine 250 ppb For best results, isolate this glassware to be used
    Iron (Ferrous) *See Note only for this test. If glassware is contaminated, it
    Lignosulphonates 50 ppb can be cleaned by rinsing with 1:1 HCl (S0726)
    Manganese 0.8 ppm followed by several iron-free distilled water
    Molybdenum 80 ppm rinses. Commercially available distilled water is
    Morpholine 50 ppm acceptable for use.
    N7200, N7205 25 ppm
    Nickel 0.8 ppm 3. Periodically clean the sample cells with a warm
    Phosphate, phosphonates 10 ppm solution of distilled water containing
    Sulphate 1000 ppm 1.0 ml of Fe-4 (S0734) per 25 ml water. After
    Zinc 50 ppm soaking, rinse the clean cells with a few ml of 1:1
    HCl (S0726) followed by at least 3 rinses
    Light can also interfere with colour development. Keep with iron-free distilled water.
    reacted samples in a dark area during the waiting step.

    Note: Any Ferrous iron will cause a positive interference


    and can be blanked out by performing the procedure on
    the sample omitting Step #6. Subtract this result from
    the samples EOx result to determine the samples true
    ELIMIN-OX concentration. Do not use this iron blanking
    procedure to quantify Fe+2.
    ELIMIN-OX DR/2010 PROCEDURE
    Special Notes: Analyse sample as soon as it is collected. The temperature of the sample should be 22-28 C (72-82 F). Do
    not use a copper-based sample cooler as copper interferes with this reaction. If the temperature of the sample is not in the
    proper range, correct the result as follows:
    EOx [9 X (C*1.8 - 45)] = EOx TC OR EOx [9 X (F - 77)] = EOx TC

    562 nm
    TIMER PROG EDIT

    7 3 2
    READ
    ENTER

    1 2 43 54
    Enter the stored programme Dial the wavelength until the Collect a feedwater sample Fill one of two matched 25 ml
    number for ELIMIN-OX or small display shows after the ELIMIN-OX feed sample cells to the mark with
    NALCO 22130: point. Stopper the flask with sample. Fill the second cell
    562 nm a plastic stopper (P3037). with demineralised or distilled
    Press: 732 ENTER. water. This second cell will
    When the correct wavelength
    The display will show: is dialed in, the display will Notes: Do not use a be the blank.
    quickly show: rubber stopper.
    DIAL nm to 562
    Zero Sample Notes: Matched cells must
    Sampling technique is be used for this procedure.
    then: ppb ELIMIN-OX extremely important. Refer
    to Sampling Section of this The sample temperature
    procedure. should be 22-28 C
    (72-82 F).

    TIMER
    SHIFT
    7

    65 76 87 98
    Add the contents of one (1) Add exactly 0.5 ml ELIMIN- Immediately after the When the timer beeps, the
    ELIMIN-OX Reagent 1 OX Reagent 2 to each cell. addition of the ELIMIN-OX display will show:
    pillows to each sample cell. Mix. Place both cells in the Reagent 2, press SHIFT
    dark. TIMER and a 10 minute ppb ELIMIN-OX
    Swirl the cells to dissolve. reaction period will begin. After wiping any moisture or
    Note: A purple colour fingerprints from the outside
    Note: For accurate results will slowly develop if Notes: Keep both cells in of the cell, place the blank
    use pillows from the same ELIMIN-OX is present. the dark during this into the cell holder and close
    manufacturing lot. period. the light shield.
    Temperature and
    reaction time affect the Note: ppb ELIMIN-OX is
    results. Be sure these equal to ppb 22130.
    factors are controlled as
    described.
    CLEAR READ
    ZERO ENTER

    10
    9 11
    10 12
    11
    Press: ZERO. Immediately remove the Press: READ.
    blank cell and insert the
    The display will show: sample cell. Close the light The display will show:
    ZEROING shield. READING
    then: 0 ppb ELIMIN-OX The result in ppb ELIMIN-OX
    will be displayed.

    Note: ppb ELIMIN-OX is


    equal to ppb 22130.

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