PC Marine Epoxy Putty

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Safety Data Sheet

Issue Date: 14-Mar-2012 Revision Date: 10-Sep-2015 Version 1

1. IDENTIFICATION

Product Identifier
Product Name PC Marine Epoxy Putty

Other means of identification


SDS # 130606-26R

Recommended use of the chemical and restrictions on use


Recommended Use Adhesives.

Details of the supplier of the safety data sheet


Supplier Address
Protective Coatings Co.
221 S Third St.
Allentown, PA 18102 USA

Emergency Telephone Number


Company Phone Number 610-432-3543 / 800-220-2103
Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International)
1-800-535-5053 (North America)

2. HAZARDS IDENTIFICATION

Appearance Green stick Physical State Solid Odor Pungent

Classification

Skin corrosion/irritation Category 2


Serious eye damage/eye irritation Category 2
Skin sensitization Category 1

Signal Word
Warning

Hazard Statements
Causes skin irritation
Causes serious eye irritation
May cause an allergic skin reaction

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130606-26R - PC Marine Epoxy Putty Revision Date: 10-Sep-2015
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Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing should not be allowed out of the workplace

Precautionary Statements - Response

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN: Wash with plenty of soap and water
Take off contaminated clothing and wash it before reuse
If skin irritation or rash occurs: Get medical advice/attention

Precautionary Statements - Disposal


Dispose of contents/container to an approved waste disposal plant

Other Hazards
Harmful to aquatic life with long lasting effects

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight-%


Non-Fibrous Tale 14807-96-6 30-60
Titanium dioxide 13463-67-7 5-10
Bisphenol A - Epichlorohydrin polymer 25068-38-6 5-10

**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage
of composition has been withheld as a trade secret.**

4. FIRST-AID MEASURES

First Aid Measures

General Advice Provide this SDS to medical personnel for treatment.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get
medical attention.

Skin Contact Wash with soap and water. Remove and wash contaminated clothing before reuse. If skin
irritation or rash occurs: Get medical advice/attention.

Inhalation Remove exposed individual(s) to fresh air for 20 minutes. Consult a physician / poison
center if individual's condition declines or if symptoms persist.

Ingestion Clean mouth with water and drink afterwards plenty of water. Do not induce vomiting. Never
give anything by mouth to an unconscious person. Seek medical advice.

Most important symptoms and effects

Symptoms Causes eye irritation. Causes skin irritation. Direct contact may cause temporary redness
and discomfort. The product contains a small amount of sensitizing substance which may
provoke an allergic reaction among sensitive individuals in contact with skin. Irritating to
mouth, throat and stomach.

Indication of any immediate medical attention and special treatment needed

Notes to Physician Skin and eye conditions may be aggravated by long term exposure.

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5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media


Dry chemical, CO2 or water spray.

Unsuitable Extinguishing Media Not determined.

Specific Hazards Arising from the Chemical


Product is not flammable.

Hazardous Combustion Products Carbon monoxide, Carbon dioxide (CO2), Aldehydes, Acids, Oxides of sulfur and
nitrogen may be formed.

Protective equipment and precautions for firefighters


As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Wear positive pressure self-contained breathing apparatus (SCBA). Do not release runoff from fire control methods
to sewers or waterways. NFPA Class IIIB.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions Wear protective gloves/protective clothing and eye/face protection. Avoid breathing vapors,
mist or gas. Remove any contaminated clothing and wash thoroughly before reuse.

For Emergency Responders Follow applicable OSHA regulations (29 CFR 1910.120).

Environmental Precautions See Section 12 for additional Ecological Information.

Methods and material for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Clean-Up Dispose of contents/container to an approved waste disposal plant.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Wear appropriate
personal protective equipment. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not
eat, drink or smoke when using this product. Wash face, hands, and any exposed skin
thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Store contents under
<90F (32C) . NFPA Class IIIB storage.

Incompatible Materials None known based on information supplied.

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8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines The following information is given as general guidance

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH


Non-Fibrous Tale TWA: 2 mg/m3 particulate matter (vacated) TWA: 2 mg/m3 IDLH: 1000 mg/m3
14807-96-6 containing no asbestos and <1% respirable dust <1% Crystalline TWA: 2 mg/m3 containing no
crystalline silica, respirable silica, containing no Asbestos Asbestos and <1% Quartz
fraction TWA: 20 mppcf if 1% Quartz or respirable dust
more, use Quartz limit
Titanium dioxide TWA: 10 mg/m3 TWA: 15 mg/m3 total dust IDLH: 5000 mg/m3
13463-67-7 (vacated) TWA: 10 mg/m3 total
dust

Other Information If product is sanded, appropriate respirator should be worn to avoid breathing dust.
Pre-existing respiratory disorders may be aggravated by exposure. If sanded, this material
may generate silica / titanium dust. Inhaled silica / titanium has been classified by IARC as
a human carcinogen (see section 11).

Appropriate engineering controls

Engineering Controls Provide general or local exhaust ventilation if product is sanded or ground.

Individual protection measures, such as personal protective equipment

Eye/Face Protection Chemical safety goggles/faceshield. Refer to 29 CFR 1910.133 for eye and face protection
regulations.

Skin and Body Protection Chemical resistant protective gloves. Wear suitable protective clothing. Refer to 29 CFR
1910.138 for appropriate skin and body protection.

Respiratory Protection Follow OSHA respirator regulations (29 CFR 1910.134) and, if necessary, wear a
MSHA/NIOSH-approved respirator.

General Hygiene Considerations Avoid contact with skin, eyes and clothing. After handling this product, wash hands before
eating, drinking, or smoking. If contact occurs, remove contaminated clothing. If needed,
take first aid action shown on section 4 of this SDS. Launder contaminated clothing before
reuse.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical State Solid


Appearance Green stick Odor Pungent
Color Green Odor Threshold Not determined

Property Values Remarks Method


pH Not determined
Melting Point/Freezing Point Not determined
Boiling Point/Boiling Range Not determined
Flash Point > 93.33 C / > 200 F
Evaporation Rate Not determined
Flammability (Solid, Gas) Not determined
Upper Flammability Limits Not determined
Lower Flammability Limit Not determined
Vapor Pressure Not determined
Vapor Density Not determined
Specific Gravity 1.972 (1=Water)
Water Solubility Insoluble in water
Solubility in other solvents Methanol and Acetone
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130606-26R - PC Marine Epoxy Putty Revision Date: 10-Sep-2015
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Partition Coefficient Not determined
Auto-ignition Temperature Not determined
Decomposition Temperature Not determined
Kinematic Viscosity Not determined
Dynamic Viscosity Not determined
Explosive Properties Not determined
Oxidizing Properties Not determined
VOC Content (%) <1%

10. STABILITY AND REACTIVITY

Reactivity
Not reactive under normal conditions.

Chemical Stability
Stable under recommended storage conditions.

Possibility of Hazardous Reactions


None under normal processing.

Hazardous Polymerization Hazardous polymerization does not occur.

Conditions to Avoid
Keep out of reach of children.

Incompatible Materials
None known based on information supplied.

Hazardous Decomposition Products


None known based on information supplied.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Eye Contact Causes serious eye irritation.

Skin Contact Causes skin irritation. May cause an allergic skin reaction.

Inhalation Under normal conditions of intended use, this material is not expected to be an inhalation
hazard.

Ingestion May cause discomfort if swallowed.

Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50


Titanium dioxide > 10000 mg/kg ( Rat ) - -
13463-67-7
Bisphenol A - Epichlorohydrin = 11400 mg/kg ( Rat ) 20000 mg/kg (rabbit) -
polymer
25068-38-6

Information on physical, chemical and toxicological effects

Symptoms Please see section 4 of this SDS for symptoms.

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Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization May cause an allergic skin reaction.

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
However, the product as a whole has not been tested. Titanium dioxide is a possible
carcinogen when it appears as a respirable dust.

Chemical Name ACGIH IARC NTP OSHA


Titanium dioxide Group 2B X
13463-67-7
Legend
IARC (International Agency for Research on Cancer)
Group 2B - Possibly Carcinogenic to Humans
Group 3 IARC components are "not classifiable as human carcinogens"
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present

Numerical measures of toxicity


Not determined

12. ECOLOGICAL INFORMATION

Ecotoxicity
Harmful to aquatic life with long lasting effects.

Component Information

Chemical Name Algae/aquatic plants Fish Toxicity to Crustacea


microorganisms
Non-Fibrous Tale 100: 96 h Brachydanio rerio
14807-96-6 g/L LC50 semi-static

Persistence/Degradability
Not determined.

Bioaccumulation
Not determined.

Mobility
Not determined

Other Adverse Effects


Not determined

13. DISPOSAL CONSIDERATIONS

Waste Treatment Methods

Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.

Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and
regulations.

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130606-26R - PC Marine Epoxy Putty Revision Date: 10-Sep-2015
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14. TRANSPORT INFORMATION

Note Please see current shipping paper for most up to date shipping information, including
exemptions and special circumstances.

DOT Not regulated

IATA Not regulated

IMDG Not regulated

15. REGULATORY INFORMATION

International Inventories

Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS
Non-Fibrous Tale Present X Present Present X Present X X
Titanium dioxide Present X Present Present X Present X X
Bisphenol A - Present X Present X Present X X
Epichlorohydrin polymer

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

US Federal Regulations

CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355).

SARA 311/312 Hazard Categories

Acute Health Hazard Yes


SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

CWA (Clean Water Act)


This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)

US State Regulations

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California Proposition 65
This product contains the following Proposition 65 chemicals.

Chemical Name California Proposition 65


Titanium dioxide - 13463-67-7 Carcinogen

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania


Non-Fibrous Tale X X X
14807-96-6
Titanium dioxide X X X
13463-67-7

16. OTHER INFORMATION

NFPA Health Hazards Flammability Instability Special Hazards


1 1 0 Not determined
HMIS Health Hazards Flammability Physical Hazards Personal Protection
1 1 0 B- Safety Glasses,
Gloves

Issue Date: 14-Mar-2012


Revision Date: 10-Sep-2015
Revision Note: New format

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

End of Safety Data Sheet

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