DATI A B C Dhev cp(g) cp(l) z,f x,d

Benzene 15.9008 2788.51 -52.36 7352 21.58 32.8 0.35 0.99

Toluene 16.0137 3096.52 -53.67 7830 27.26 40.5 0.65 0.01
kcal/kmol kcal/(kmol*K)

pv (Teb,B) ki (Teb,B) xi*ki pv (Teb,F) ki (Teb,F) xi*ki pv (Teb,D) ki (Teb,D)

Benzene 2.31998735 2.319987 0.0232 1.6261573 1.6261572555 0.569155 1.00619002 1.00619002
Toluene 0.98666679 0.986667 0.9768 0.6628384 0.6628383984 0.430845 0.38718804 0.38718804
1 1

R/Rmin R F (N) N N,real V Qc (kcal/h) Qr

1.05 2.00045369 0.031748 0.634573 29.615363 35.7692040587 52.04869 350823.057 359112.23
1.1 2.09571339 0.061543 0.594685 26.602378 32.0029724635 53.70115 361961.139 370250.312
1.15 2.19097309 0.089559 0.564403 24.683515 29.6043941283 55.35361 373099.221 381388.394
1.2 2.28623279 0.11595 0.537712 23.200662 27.7508271667 57.00608 384237.303 392526.476
1.25 2.38149248 0.140855 0.513675 22.004536 26.2556697508 58.65854 395375.385 403664.558
1.3 2.47675218 0.164394 0.491876 21.017609 25.022010895 60.31101 406513.467 414802.64
1.35 2.57201188 0.186679 0.47201 20.189167 23.9864585235 61.96347 417651.548 425940.722
1.4 2.66727158 0.207805 0.453825 19.483682 23.1046030991 63.61594 428789.63 437078.804
1.45 2.76253128 0.227862 0.437111 18.87544 22.3443003654 65.2684 439927.712 448216.886
1.5 2.85779098 0.246928 0.421688 18.34539 21.6817374089 66.92086 451065.794 459354.967
1.55 2.95305068 0.265075 0.407406 17.87914 21.0989250132 68.57333 462203.876 470493.049
1.6 3.04831038 0.282369 0.394135 17.465629 20.5820357357 70.22579 473341.958 481631.131
1.65 3.14357008 0.298867 0.381768 17.096219 20.1202740184 71.87826 484480.04 492769.213
1.7 3.23882978 0.314624 0.370208 16.764073 19.7050918022 73.53072 495618.122 503907.295
1.75 3.33408948 0.329688 0.359376 16.463707 19.3296337468 75.18318 506756.204 515045.377
1.8 3.42934918 0.344104 0.349201 16.19067 18.9883380701 76.83565 517894.286 526183.459
1.85 3.52460888 0.357913 0.339622 15.941316 18.6766447754 78.48811 529032.368 537321.541
1.9 3.61986858 0.371152 0.330586 15.712623 18.3907792301 80.14058 540170.45 548459.623
1.95 3.71512828 0.383857 0.322045 15.502072 18.1275894472 81.79304 551308.531 559597.705
2 3.81038798 0.396058 0.313957 15.307538 17.8844221994 83.44551 562446.613 570735.787
2.05 3.90564767 0.407786 0.306287 15.127222 17.6590275993 85.09797 573584.695 581873.869
2.1 4.00090737 0.419067 0.299 14.959588 17.4494848089 86.75043 584722.777 593011.95
2.15 4.09616707 0.429926 0.292068 14.803315 17.2541436209 88.4029 595860.859 604150.032
2.2 4.19142677 0.440386 0.285465 14.657262 17.0715780917 90.05536 606998.941 615288.114
2.25 4.28668647 0.45047 0.279165 14.52044 16.9005494225 91.70783 618137.023 626426.196
2.3 4.38194617 0.460196 0.273149 14.391981 16.7399760033 93.36029 629275.105 637564.278
2.35 4.47720587 0.469585 0.267397 14.271127 16.5889090548 95.01275 640413.187 648702.36
2.4 4.57246557 0.478652 0.261891 14.15721 16.4465126841 96.66522 651551.269 659840.442
2.45 4.66772527 0.487414 0.256615 14.049638 16.3120474451 98.31768 662689.351 670978.524
2.5 4.76298497 0.495887 0.251555 13.947885 16.1848567048 99.97015 673827.433 682116.606
2.55 4.85824467 0.504085 0.246697 13.851484 16.0643552696 101.6226 684965.514 693254.688
2.6 4.95350437 0.51202 0.242029 13.760016 15.9500198472 103.2751 696103.596 704392.77
2.65 5.04876407 0.519705 0.237539 13.673105 15.8413810035 104.9275 707241.678 715530.851
2.7 5.14402377 0.527151 0.233218 13.590413 15.7380163499 106.58 718379.76 726668.933
2.75 5.23928347 0.534371 0.229055 13.511636 15.6395447446 108.2325 729517.842 737807.015
2.8 5.33454317 0.541373 0.225043 13.436497 15.5456213355 109.8849 740655.924 748945.097
2.85 5.42980286 0.548167 0.221172 13.364747 15.4559333057 111.5374 751794.006 760083.179
2.9 5.52506256 0.554764 0.217435 13.296157 15.3701962074 113.1899 762932.088 771221.261
2.95 5.62032226 0.56117 0.213826 13.230521 15.2881507906 114.8423 774070.17 782359.343
3 5.71558196 0.567395 0.210337 13.167648 15.2095602504 116.4948 785208.252 793497.425
x,b F 50 kmol/h Teb,B 383.3043 2.351338
0.01 P 1 atm Teb,F 369.9123 2.453324
0.99 E,col 0.8 Teb,D 353.4524 ,i
v,lim 0.3 m/s Trug,D 353.7668 2.595696

xi*ki pv (Trug,D) ki (Trug,D) yi/ki Molto simili perch la miscela praticamente monocomponente
0.996128 1.0159569498 1.01595695 0.974451
0.003872 0.3914005396 0.39140054 0.025549
1 1

DC Costo inst Costo Hex TOTinv Tot,attual (/yr) Cese (/y) CTOT,year
1.334177 52763.5286619 23688.1314 152903.3 15290.332005174 15262.27 30552.6
1.355191 48403.183647 24126.2567 145058.9 14505.888078319 15735.638 30241.53 Minimo
1.375883 45874.3267949 24559.1408 140866.9 14086.693518721 16209.007 30295.7
1.396269 44026.038152 24986.9966 138026.1 13802.606957537 16682.375 30484.98
1.416362 42617.1944427 25410.0229 136054.4 13605.443474248 17155.744 30761.19
1.436173 41527.5405964 25828.4053 134711.9 13471.189171507 17629.112 31100.3
1.455715 40679.1117299 26242.3173 133842.9 13384.285809572 18102.481 31486.77
1.474998 40017.318574 26651.9219 133338.5 13333.848102057 18575.849 31909.7
1.494033 39502.6171757 27057.372 133120 13311.997843538 19049.218 32361.22
1.512827 39105.6986082 27458.8115 133129 13312.902018245 19522.586 32835.49
1.531391 38804.4246166 27856.3758 133321.6 13332.160078224 19995.955 33328.11
1.549733 38581.790926 28250.1928 133664 13366.396738515 20469.323 33835.72
1.56786 38424.5380954 28640.3832 134129.8 13412.984267888 20942.692 34355.68
1.58578 38322.1845126 29027.0615 134698.5 13469.849196079 21416.06 34885.91
1.6035 38266.3410155 29410.3357 135353.4 13535.33533559 21889.429 35424.76
1.621026 38250.2170283 29790.3085 136081.1 13608.105097414 22362.797 35970.9
1.638365 38268.2592106 30167.0773 136870.7 13687.067301015 22836.165 36523.23
1.655522 38315.8832803 30540.7348 137713.2 13771.32361183 23309.534 37080.86
1.672503 38389.272344 30911.369 138601.3 13860.128273809 23782.902 37643.03
1.689313 38485.2233753 31279.064 139528.6 13952.857465616 24256.271 38209.13
1.705958 38601.0290101 31643.8996 140489.9 14048.985715263 24729.639 38778.63
1.722441 38734.3855723 32005.9522 141480.7 14148.067555868 25203.008 39351.08
1.738769 38883.320802 32365.2948 142497.2 14249.723118099 25676.376 39926.1
1.754945 39046.1365486 32721.997 143536.3 14353.626711457 26149.745 40503.37
1.770973 39221.3629401 33076.1255 144595 14459.497697665 26623.113 41082.61
1.786857 39407.7214402 33427.7443 145670.9 14567.093138415 27096.482 41663.57
1.802601 39604.0948474 33776.9143 146762 14676.201828825 27569.85 42246.05
1.818209 39809.5027633 34123.6943 147866.4 14786.639422019 28043.219 42829.86
1.833684 40023.0814 34468.1407 148982.4 14898.244419548 28516.587 43414.83
1.849029 40244.0668605 34810.3074 150108.7 15010.874853901 28989.956 44000.83
1.864248 40471.7812114 35150.2464 151244.1 15124.405528007 29463.324 44587.73
1.879344 40705.6208222 35488.0077 152387.3 15238.725705906 29936.693 45175.42
1.89432 40945.0465491 35823.6393 153537.4 15353.737171087 30410.061 45763.8
1.909178 41189.5754345 36157.1875 154693.5 15469.352586199 30883.43 46352.78
1.923922 41438.7736539 36488.6969 155854.9 15585.494101096 31356.798 46942.29
1.938553 41692.2504978 36818.2103 157020.9 15702.092166609 31830.167 47532.26
1.953075 41949.6532158 37145.7694 158190.8 15819.084519559 32303.535 48122.62
1.967489 42210.6625815 37471.414 159364.2 15936.415310958 32776.904 48713.32
1.981799 42474.9890641 37795.1827 160540.3 16054.034354494 33250.272 49304.31
1.996006 42742.3695107 38117.1129 161719 16171.896476465 33723.641 49895.54
 2.46475993 Hf
x,int 0.35 pari a zf perch q line verticale Hd
y,int 0.57029509 Hb
Rmin/(Rmin+1) 0.65578893 Hd(v)
Rmin 1.90519399 Ricavo Rmin con ric obb (o analiticamente)
-1.9542398E-08 Fzf=Dxd+Bxb B
Nmin 10.1876695 Fenske F=D+B D
Conc,tot(D) 0.03447221
Si dimostra facilmente che seN>13 domina Ctot,D (sempre<Ctot,B)

Ctot,annuo vs R/Rmin
60000

50000

40000

30000

20000

10000

0
05 15 25 35 45 55 65 75 85 95 05 15 25 35 45 55 65 75 85 95
1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2.
20000

10000

0
05 15 25 35 45 55 65 75 85 95 05 15 25 35 45 55 65 75 85 95
1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 2. 2. 2. 2. 2. 2. 2. 2. 2. 2.
2718.645 kcal/kmol
1823.108
3448.255
8563.394

32.65306 kmol/h Sistema 2x2 (bilancio globale e singolo comp)

17.34694 0
DATI A B C Dhev cp(g) cp(l) z,f
Benzene 15.9008 2788.51 -52.36 7352 21.58 32.8 0.35
Toluene 16.0137 3096.52 -53.67 7830 27.26 40.5 0.65
kcal/kmol kcal/(kmol*K)

pv (Teb,B) ki (Teb,B) xi*ki pv (Teb,F) ki (Teb,F) xi*ki pv (Teb,D)

Benzene 2.31998735 2.31998735 0.02319987 1.6261573 1.626157258 0.56915504 1.00619002
Toluene 0.98666679 0.98666679 0.97680013 0.6628384 0.6628383995 0.43084496 0.38718804
1 1
R/Rmin R F (N) N N,real=(N-1)/E V Qc (kcal/h)
1.01 1.9242461 0.00651516 0.75759476 45.152754 55.1909424685 50.726718 341912.612
1.02 1.94329804 0.01294598 0.69307025 35.450261 43.062826089 51.0572109 344140.228
1.03 1.96234998 0.01929408 0.66419185 32.315658 39.1445729814 51.3877037 346367.845
1.04 1.98140192 0.02556105 0.64690775 30.684834 37.1060426199 51.7181966 348595.461
1.05 2.00045386 0.03174843 0.63457335 29.615363 35.7692039105 52.0486894 350823.078
1.06 2.0195058 0.03785773 0.6247058 28.810398 34.7629979513 52.3791823 353050.695
1.07 2.03855775 0.04389042 0.61620887 28.150412 33.9380148197 52.7096752 355278.311
1.08 2.05760969 0.04984794 0.60854324 27.57958 33.2244744888 53.040168 357505.928
1.09 2.07666163 0.05573166 0.60142233 27.068982 32.5862276709 53.3706609 359733.544
1.1 2.09571357 0.06154297 0.59468458 26.602378 32.0029723153 53.7011538 361961.161
1.11 2.11476551 0.06728319 0.58823444 26.169998 31.4624980787 54.0316466 364188.777
1.12 2.13381745 0.07295361 0.58201305 25.765595 30.9569942866 54.3621395 366416.394
1.13 2.15286939 0.0785555 0.5759827 25.384937 30.4811706435 54.6926324 368644.011
1.14 2.17192134 0.0840901 0.57011834 25.024999 30.0312483211 55.0231252 370871.627
1.15 2.19097328 0.08955861 0.56440271 24.683515 29.6043939594 55.3536181 373099.244
1.16 2.21002522 0.0949622 0.55882343 24.358712 29.1983899462 55.6841109 375326.86
1.17 2.22907716 0.10030203 0.55337127 24.049149 28.8114357996 56.0146038 377554.477
1.18 2.2481291 0.10557922 0.54803905 23.75362 28.4420247723 56.3450967 379782.094
1.19 2.26718104 0.11079487 0.54282099 23.471092 28.0888648968 56.6755895 382009.71
1.2 2.28623299 0.11595004 0.53771225 23.200662 27.7508269855 57.0060824 384237.327
uno il ribollitore
x,d x,b F 50 kmol/h T [K]
0.99 0.01 P 1 atm Hp in testa Teb,B 383.304283
0.01 0.99 E,col 0.8 Teb,F 369.912312
v,lim 0.3 m/s (Teb,D) 353.452374
Trug,D 353.766757
ki (Teb,D) xi*ki pv (Trug,D) ki (Trug,D) yi/ki
1.00619002 0.99612812 1.01595696 1.01595696 0.97445073
0.38718804 0.00387188 0.39140055 0.39140055 0.02554927
1 1
Qr DC Costo inst Costo Hex TOTinv Tot,attual (/yr) Cese (/y) CTOT,year
350201.785 1.31712502 79754.2728 23333.7047 206175.955 20617.595510481 14883.57585 35501.1714
352429.401 1.3214087 62552.5379 23422.6465 171950.369 17195.0368862126 14978.24956 32173.2864
354657.018 1.32567853 57155.1892 23511.3637 161333.106 16133.310579722 15072.92326 31206.2338
356884.635 1.32993466 54457.2962 23599.8583 156114.309 15611.4308948945 15167.59697 30779.0279
359112.251 1.33417721 52763.531 23688.1322 152903.326 15290.3326300863 15262.27067 30552.6033
361339.868 1.33840631 51539.5867 23776.1873 150631.548 15063.1548140225 15356.94438 30420.0992
363567.484 1.34262209 50570.29 23864.0256 148868.631 14886.8631265443 15451.61808 30338.4812
365795.101 1.34682467 49755.2338 23951.6488 147413.765 14741.3765233074 15546.29179 30287.6683
368022.717 1.35101418 49042.5326 24039.0589 146163.183 14616.3183088055 15640.96549 30257.2838
370250.334 1.35519074 48403.1858 24126.2576 145058.887 14505.8886732377 15735.6392 30241.5279
372477.951 1.35935447 47819.8822 24213.2467 144066.258 14406.6257780013 15830.3129 30236.9387
374705.567 1.36350548 47281.6645 24300.0279 143163.385 14316.3384852618 15924.9866 30241.3251
376933.184 1.3676439 46781.209 24386.603 142335.624 14233.5623979067 16019.66031 30253.2227
379160.8 1.37176982 46313.3638 24472.9737 141572.675 14157.2675111432 16114.33401 30271.6015
381388.417 1.37588338 45874.3288 24559.1417 140866.941 14086.6940934812 16209.00772 30295.7018
383616.033 1.37998467 45461.1768 24645.1086 140212.571 14021.2570785488 16303.68142 30324.9385
385843.65 1.38407382 45071.5666 24730.876 139604.885 13960.4885258909 16398.35513 30358.8437
388071.267 1.38815091 44703.5642 24816.4456 139040.02 13904.001951972 16493.02883 30397.0308
390298.883 1.39221607 44355.5291 24901.8189 138514.696 13851.4695939687 16587.70254 30439.1721
392526.5 1.39626939 44026.0401 24986.9975 138026.075 13802.607520118 16682.37624 30484.9838
(Ti) Hf 2718.645 kcal/kmol Correnti al contorno
2.351338 x,int 0.35 pari a zf qline verticale Hd 1823.108 kcal/kmol della colonna, tutte
2.453324 y,int 0.5702951 dall'equilibrio Hb 3448.255 kcal/kmol LIQUIDE
2.598711 Rm/(Rm+1) 0.6557889 2.673417E-13 Hd,vap 8563.394 kcal/kmol entrante al cond.
2.595696 Rmin 1.9051942 F 50 kmol/h
2.46476 Nmin 10.18767 Fenske B 32.65306 kmol/h 0
D 17.34694 kmol/h
Testa Conc,tot 0.034472 kmol/m3
Coda (30p) p 120825 Pa
1.19245 atm
Conc,tot 0.041081
Per rispettare la v,max mi serve una concentrazione minima.
Senza perdite carico userei la T,max, cio B. Ma fra testa e
coda cambia anche p per le DeltaP.
Correnti al contorno
della colonna, tutte

entrante al cond.