Swami Ramanand Teerth Marathwada

University, Nanded

SYLLABUS
B. SC. THIRD YEAR (CHEMISTRY)
SEMESTER PATTERN

IN FORCE FROM JUNE - 2011

1
 B. Sc. First Year (Semester-I)
Chemistry

Paper Total
Course No. Course Periods/week Marks
No. Periods
I CH-101 Inorganic Chemistry 2 30 32
II CH-102 Organic Chemistry 2 30 34
III CH-103 Physical Chemistry 2 30 34

B. Sc. First Year (Semester-II)

Chemistry

Paper Course No. Total

Course Periods/week Marks
No. Periods
IV CH-104 Inorganic Chemistry 2 30 32
V CH-105 Organic Chemistry 2 30 34
VI CH-106 Physical Chemistry 2 30 34
VII CH-107 Laboratory Course-I 4 120 100

B. SC. Second Year (Semester-III)

Chemistry

Paper Periods /
Course No. Course Total Periods Marks
No. week
VIII CH-201 Inorganic Chemistry 2 30 32
IX CH-202 Organic Chemistry 2 30 34
X CH-203 Physical Chemistry 2 30 34

B. SC. Second Year (Semester-IV)

Chemistry

Paper Periods /
Course No. Course Total Periods Marks
No. week
XI CH-204 Inorganic Chemistry 2 30 32
XII CH-205 Organic Chemistry 2 30 34
XIII CH-206 Physical Chemistry 2 30 34
XIV CH-207 Laboratory Course-II 4 120 50
XV CH-208 Laboratory Course-III 4 120 50

2
 B. SC. Third Year (Semester-V)
Chemistry

Paper Periods /
Course No. Course Total Periods Marks
No. week
XVI CH-301 Inorganic Chemistry 2 30 32
XVII CH-302 Organic Chemistry 2 30 34
XVIII CH-303 Physical Chemistry 2 30 34

B. Sc. Third Year (Semester-VI)

Chemistry

Paper Periods /
Course No. Course Total Periods Marks
No. week
XIX CH-304 Inorganic Chemistry 2 30 32
XX CH-305 Organic Chemistry 2 30 34
XXI CH-306 Physical Chemistry 2 30 34
XXII CH-307 Laboratory Course-IV 4 120 50
XXIII CH-308 Laboratory Course-V 4 120 50

B. Sc. Chemistry Degree Marks

Class Theory Marks Practical Marks Total Marks

B. Sc. F. Y. 200 100 300
B. Sc. S. Y. 200 100 300
B. Sc. T. Y. 200 100 300
Total 600 300 900

3
 B. Sc. Third Year, Semester-V
Paper XVI [CH-301]
Inorganic Chemistry
Periods: 30 Marks: 32

Unit:-I
1.1 Coordination chemistry (Part-I) 10
a) Introduction: addition or molecular compound, double salt, coordination
compound. Comparison of double salt and coordination compound.
b) Terminology: complex ion, central metal atom, ligand, types of ligand,
coordination number and coordination sphere.
c) Nomenclature: Rules of nomenclature of coordination compound, and its
applications to nomenclature of simple and bridging complex compounds.
d) Werners theory of coordination compound, postulates, applications with
reference to CoCl3.6NH3, CoCl3.5NH3, CoCl3.4NH3, CoCl3.3NH3.
e) Chelating agents and its classification, difference between metal complex and
metal chelate complex.
f) Isomerism: Structural isomerism, ionization, hydrate, linkage, coordination
isomerism, geometrical isomerism, optical isomerism in 4 and 6 coordination
complex.
g) E. A. N. of metal complexes.
Unit-II
2.1 Chemistry of inner transition elements (Part-I) 08
a) Introduction; definition of inner transition elements,
Lanthanides: Position in periodic table.
b ) Electronic configuration of lanthanides; oxidation state; magnetic moment;
color.
c) Separation of lanthanides by ion exchange method.
d) Lanthanide contraction, cause and consequences.
e) Absorption spectra of lanthanides. Lanthanides act as shift reagents.
Unit-III
3.1 Theory of gravimetric analysis 06
a ) Introduction; definition of gravimetric analysis.
b) Steps involved in gravimetric analysis;
c) Precipitation, types of precipitates, factors affecting the precipitation such as
temperature, pH and complex.
d) Purity of the precipitate: Post precipitation, co precipitation and fractional
precipitation.
e) Condition for the completion of precipitation.
f) Digestion of precipitate, filtration, washing, drying, ignition, and weighing
along with conversion factor.
Unit-IV
4.1 Metal carbonyls 06
a) Definition, types 1) Mononuclear carbonyl, characteristics and examples; 2)
Polynuclear carbonyl, characteristics and examples.
b) Preparation properties and structure of Nickel tetra carbonyl.
c) Nature of metal carbon bond in metal carbonyl and their evidences.
d) Structure of Fe2(CO)9, Fe3(CO)12, Ir4(CO)12, Co2(CO)8.

4
 B. Sc. III Year
Paper XVII [CH-302] Semester-V
Organic Chemistry
Periods: 30 Marks: 34

UNIT-I
1.1 Synthetic Drugs and Dyes: 08P
A] Synthetic Drugs:
a) Introduction.
b) Definition: i) Pharmacy ii) Pharmacology iii) Chemotherapy iv) Metabolites
and anti-metabolites v) Bacteria vi) Gram positive and Gram negative.
c) Classification on the basis of:
(1) Chemotherapeutics: (Antimalerials, Antiseptic, Antibacterial, Antibiotics,
Antifungal.)
(2) Functional: (Analgesics, Antipyretics, Sedatives, Anaesthetics)
d) Synthesis and Uses:
i) Sulphanilamide from acetanilide.
ii) Sulphadiazine from 2-aminopyrimidine.
iii) Chloroquine from 4,7-dichloroquinoline and N,N-diethyl,1,4-
pentanediamine.
iv) Aspirin from Salicylic acid.
v) Paracetamol from phenol.
B] Synthetic Dyes:
a) Introduction, Theories of colour and chemical constitution [Witts and
Armstromg(Quinonoid) Theories]
b) Classification of dyes on the basis of structure.
c) Synthesis of dyes and their applications:
i) Methyl Orange.
ii) Phenolphthalein.
iii) Fluoroscein.
iv) Cangored.
UNIT:-II
2.1 Alkaloids: 05P
a) Introduction, Occurrences, general properties.
b) General methods for determination of structure of alkaloids.
c) Constitution of Ephedrine.
d) Synthesis of i) Nicotine from nicotinonitrile, ii) Papaverine from 1, 2-diacetyl
benzene iii) Piperonal from catechol.
2.2 Vitamins: 04P
a) Introduction.
b) Classification.
c) Occurrence, structure, and deficiency diseases of Fat soluble vitamins. A, D, E
K and Water soluble vitamins B1, B2, B6, B12.
Unit-III
3.1 Amino Acids and Proteins 08P
A] Amino Acids:
a) Introduction, Classification (acidic, basic, neutral).
b) Acid-base behavior, Zwitter-ion formation.
c) Preparation of -amino acids, i) -halogenated acids, ii) Gabriel phthalimide
synthesis iii) Streckers synthesis.

5
 d) Reactions due to i) NH2 ii) COOH iii) NH2 and COOH group.
B] Proteins
a) Introduction, Classification, Structure of proteins (primary and secondary)
b) Properties of proteins.
c) Importance of proteins.
3.2 Organic Reagents: 05P
Synthetic applications of following reagents
a) Selenium dioxide (SeO2).
b) Lead tetraacetate (CH3COO)4Pb.
c) Osmium tetraoxide (OsO4)
d) Lithium alluminiumhydride (LiAlH4)
e) Sodium borohydride (NaBH4)

6
 B. Sc. Third Year, Semester-V
Paper-XVIII (CH-303)
Physical chemistry
Periods: 30 Marks: 34

Unit -I
1.1 Spectroscopy: 14P
a) Introduction, Electromagnetic radiation and characteristics, Region of the spectrum.
Width and intensity of spectral lines. Factors affecting width and intensity of spectral
lines. Brief introduction to molecular spectra.
b) Rotational Spectra:
Classification of molecules, Rotational spectra of diatomic molecules: Rigid rotator
model; moment of inertia; energy levels of rigid rotator, selection rules; spacing
between spectral lines of diatomic rigid rotator, isotope effect, qualitative description
of non rigid rotator. Numericals on bond length.
c) Vibrational Spectra:
Infrared spectrum, Simple Harmonic oscillator model, Energy levels of simple
harmonic oscillator, selection rules, pure vibrational spectrum, intensity,
determination of force constant and qualitative relation of force constant and bond
energies. Numericals on force constant.
d) Raman Spectra:
Concept of polarizability. Classical and quantum theory of Raman scattering.
Rotational Raman spectrum of a diatomic molecule, Rotation-vibration Raman
spectrum, selection rules. Experimental Raman spectroscopy.
e) Electromagnetic spectra:
Concept of potential energy curve, Frank-Condon principle, types of electronic
transitions.
Unit-II
2.1 Chemical kinetics 08P
a) Introduction, Third order reaction with equal concentration of all reactants, their
characteristics.
b) Kinetics of complex reactions: i) Opposing reaction ii ) Consecutive reaction iii)
Chain reaction.
c) Kinetics of photochemical reactions: 1. Hydrogen-chlorine reaction.
2. Decomposition of HI. 3. Dimerization of Anthracene
Unit III:
3.1 Distribution Law 08P
a) Introduction, Nernst distribution law, solubility and distribution law, Limitation of
distribution law.
b) Association and dissociation of solute in solvent.
c) Henrys law.
d) Determination of equilibrium constant from distribution coefficient.
e) Extraction with solvent.
f) Liquid-liquid chromatography.
g) Applications of distribution law.
i) Numerical on Nernst distribution law.

7
 B. Sc. Third Year, Semester-VI
Paper XIX [CH-304]
Inorganic Chemistry
Periods: 30 Marks: 32

Unit-I
1.1 Coordination theory (Part-II) 10
a) Valence bond theory of coordination compounds: Postulates, inner orbital and
outer orbital complexes of coordination number 4 and 6. Limitations of VBT.
b) Crystal field theory: Shape of d-orbitals, postulates, splitting of d-orbital in
octahedral complexes, tetrahedral complexes, tetragonal and square planar
complex.
Definition of CFSE, calculations of CFSE for octahedral and tetrahedral
complexes.
c) Factors affecting 10 Dq or magnitude of crystal field splitting : Nature of
ligand, oxidation state of metal ion, size of d orbital, geometry of complexes.
d ) Applications of CFT.
e) John teller effect in octahedral complexes of Cu++.
f) Limitations of CFT.
Unit-II
2.1 Chemistry of inner transition elements (Part-II) 04
a) Actinides: Position in periodic table.
b) Electronic configuration and oxidation state of actinides.
c) Chemistry of uranium: occurrence; extraction from pitchblend by acid
digestion process, properties and uses.
d) Compounds of Uranium: i) Uranyl nitrate, ii) Uranyl acetate
Preparation, properties and uses.
Unit-III
3.1 Non-Aqueous Solvents 08
Introduction
Water as a universal solvent
Classification of solvents
General properties of solvents such as dipole moments, dielectric constant,
Troutons constant, electrical conductance, viscosity, autoionisation.
Liquid Ammonia as a non-aqueous solvent:
Physical data of liquid ammonia.
Chemical reactions in liquid ammonia: Autoionisation, Acid-base,
Precipitation, Complex formation, Ammonolysis, Redox, Ammonation,
Solubility effect in liquid ammonia.
Advantages and disadvantages of liquid ammonia as a solvent.
Solution of alkali metals in liquid ammonia.
Unit-IV
4.1 Corrosion and Passivity 08
A) Corrosion: Introduction.
Types of corrosion. Theories of corrosion: Electrochemical theory
Method of preventation of corrosion
B) Passivity: Introduction
Theories of passivity: a) Gaseous film b) Physical theories, c) Oxide layer
theory. Applications of passivity
Electrochemical passivity. Mechanical Passivity.

8
Reference books:-
1. Principles of Inorganic Chemistry by Puri, Sharma and Kalia.
2. Inorganic Chemistry by Gurudeep Raj Chatwal.
3. Advanced inorganic chemistry vol. II by Satyaprakash, Tuli, Basu and Madan.
4. Inorganic Chemistry by Huheey, Keiter and Keiter.
5. Concise Inorganic Chemistry by J. D. Lee.
6. A text book of Practical Chemistry for B. Sc. By V. V. Nadkarny, A. N. Kothare and
Y. V. Lawande.
7. Advanced practical inorganic Chemistry by O. P. Agarwal.

9
 B. Sc. III Year
Paper XX CH-305 Semester-VI
Organic Chemistry
Periods: 30 Marks: 34

UNIT:-I
1.1 Ultra-Violet Spectroscopy: 04P
a) Introduction.
b) Electromagnetic radiation.
c) Units used in spectroscopy: a) Wave length b) Wave number c) Frequency.
d) Beer-Lambert law and Molar absorption.
e) Types of electronic transitions.
f) Concept of chromophore and auxochrome, Bathochromic, Hypsochromic,
Hyperchromic, Hypochromic shift.
g) Differentiate spectral characteristics between conjugated dienes and enones
and calculate max (maximum absoption) for it.
1.2 Infra-Red spectroscopy: 04P
a) Molecular Vibration, Hooks law.
b) Measurement of IR Spectrum, Finger print region, Functional group region.
c) Interpretation of IR spectra of simple organic compounds.
(a) Ethane (b) Ethene (c) Ethyne (d) Benzene (e)1-Propanol (f) 2-Propanol
(g) t-Butyl alcohol (h) Phenol. (i) Acetone (j) Acetophenone (k) Acetaldehyde
(l) Benzaldehyde (m) Benzoic acid (n) Methyl benzoate (o) Phenyl cyanide
1.3 PMR Spectroscopy: 04P
a) Introduction.
b) Principles of NMR Spectroscopy.
c) Orientation of hydrogen nucleus.
d) Pressional motion of nucleus.
e) Shielded proton in acetylene.
f) Deshielded protons in benzene.
g) Number of signals (equivalent and non-equivalent protons) in following
compounds: a) Acetone (b) Cyclobutane (c) Methanol (d) Ethyl benzene (e)
Ethyl amine (f) Mesitylene (g) Diethyl ether.
h) Chemical Shift.
i) Spin-spin coupling, coupling constant.
j) Interpretation of PMR spectra of simple organic molecules such as
Ethyl bromide, ethanol, acetaldehyde, 1,1,2-tribromoethane, ethyl acetate,
Toluene, acetophenone, ethylamine, acetic acid, benzoic acid.
1.4 Problems based on UV, IR, and PMR simple organic compounds using
spectroscopic technique. 05P
Unit-II
2.1. Aromatic Carboxylic Acids: 06P
Introduction and Classification of aromatic carboxylic acids.
A) Benzoic Acid.
i) Preparations from: a) phenyl cyanide; b) toluene.
ii) Reactions of benzoic acids.
a) Acyl-halide formation, b) Reduction, c) Decarboxylation, d) Nitration.
B) Anthranilic Acid:
i) Preparations from: a) from phthalimide, b) from O-nitro toluene.
ii) Reactions of anthranilic acid.

10
 a) Action of heat, b) Nitrous acid, c) Acetic anhydride, d) Acetylation
C) Salicylic Acid:
i) Preparations by: a) Kolbes method, b) Reimer-Tieman reaction.
ii) Reactions of Salicylic acid.
a) bromination, b) nitration, c) decarboxylation, d) Reaction with Zn-dust.
D) Phthalic Acid:
i) Preparations from: a) From O-Xylene, b) From Naphthalene.
ii) Reactions of Phthalic acid.
a) Action of heat, b) Action of PCl5, c) Action of ethanol.
2.2 Aromatic Sulphonic acid: 04P
A) Introduction and Nomenclature.
B) Preparation of Sulphonic acid from Benzene with mechanism.
C) Chemical properties: a) Salt formation, b) Formation of sulphonyl chloride, c)
Formation of Sulphonic esters and amides, d) Replacement of sulphonic group by
phenolic group, e) Replacement of sulphonic group by cyano, f) Replacement of
sulphonic group by Hydrogen, g) Replacement of sulphonic group by NH2
group.
2.3 Pesticides: 03P
a) Introduction, Classification.
b) Synthesis and Uses of i) DDT, ii) BHC, iii) Methoxychlor, iv) 2,4-D, v)
Baygon (from 2-isopropyl phenol)

Reference books:
1. Synthetic drugs by Gurudeep and Chatwal.
2. Synthetic dyes by Gurudeep and Chatwal.
3. Organic Chemistry by S. M. Kapoor. vol. II and III.
4. Organic Chemistry by Morrison and Boyd.
5. T. B. of organic chemistry by Arun Bahl and B. S. Bahl.
6. Synthetic organic chemistry by O. P. Agrawal.
7. T. B. Organic chemistry by P. L. Soni and H. M. Chawla.
8. Organic chemistry by M. K. Jain.
9. Organic chemistry by Tewari Mehrotra.
10. Organic chemistry by Soloman.
11. Organic chemistry by Carey.

11
 B. Sc. Third Year, Semester-VI
Paper-XXI (CH-306)
Physical chemistry
Periods: 30 Marks: 34

Unit-I
1.1 Electrochemistry 12P
a) Introduction to electrochemistry, concept of electrode potential, single electrode
potential and standard electrode potential, oxidation and reduction potential.
b) Electrochemical cells: Electrolytic and Galvanic cells-reversible and irreversible cells,
conventional representation of electrochemical cells.
c) EMF of cell, measurement of EMF.
d) Reference electrodes, indicator electrodes, calomel electrode.
e) Relation between EMF and G, H and S.
f) Nernst equation, application of Nernst equation to oxidation half cell and reduction
half cell.
g) Electrolyte concentration cell: Concentration cell with transport and Concentration
cell without transport.
h) Application of EMF measurement in determination of pH by using a) Quinhydrone
electrode and b) glass electrode.
i) Potentiometric titrations.
j) Numerical on Nernst equation, concentration cell, G, H and S.
Unit-II:
2.1. Thermodynamics: 12P
a) Introduction
b) Work Function and Free Energy Function: Helmholtz function (A) or work function,
change of A at constant temperature, Gibbs free energy (G) or free energy function,
relation between G and A, change of G at constant temperature, variation of work
function with temperature and volume, variation of free energy function with
temperature and pressure. The Gibbs-Helmholtz equation.
c) The Nernst heat theorem. Third law of thermodynamics.
d) Thermodynamics of open system: partial molar properties; concept of chemical
potential, partial molar free energy. Gibbs-Duhem equation. Variation of chemical
potential with temperature and pressure. Chemical potential in case of a system of
ideal gases.
e) Vant-Hoffs isotherm. Vant-Hoffs reaction isochore. Integrated form of Vant-Hoffs
equation.
f) Clapeyron equation. Clausius- Clapeyron equation and its applications.
g) Thermodynamic derivation of law of mass action. Relation between G and Kp.
h) Numericals on Vant-Hoffs isotherm and Integrated form of Vant-Hoffs equation.

Unit-III
3.1 Surface Chemistry 06P
a) Introduction: Adsorption, mechanism of adsorption, factors affecting adsorption,
difference between adsorption and absorption.
b) Types of adsorption: Physical adsorption and chemical adsorption.
c) Adsorption of gas by solid.
d) Types of adsorption isotherm: i) Freundlich adsorption isotherm, ii) Langmuir
adsorption isotherm, (Derivation).

12
Reference Books:
1. Physical Chemistry by G. M. Barrow (Tata Mc-Graw Hill publishing Co., Ltd.)
2. Elements of Physical Chemistry by S. Glasstone & D. Lewis (D.van nostrand co. inc.)
3. Physical Chemistry by W. J. Moore (Orient Longman).
4. Principles of Physical Chemistry by S. H. Maron and C. F. Prutton.
5. University General Chemistry by C. N. R. Rao (Mc-Millan).
6. Elements of Physical Chemistry by P. W. Atkins. (Oxford University Press).
7. Physical Chemistry by R. A. Alberty (Wiley Eastern Ltd.).
8. Physical Chemistry through problems by S. K. Dogra, D. Dogra(Wiley Eastern Ltd)
9. Principles of Physical Chemistry by Puri, Sharma and Pathania (Vishal Publication Jallandher, Delhi)
10. Physical Chemistry by A. J. Mee. ELBS & Heinemann Educational Books Ltd.
11. Essentials of Physical Chemistry by Arun Bhal, B. S. Bahl and G. D. Tuli. (S. Chand )
12. Chemical Kinetics by K. J. Laidler (Tata Mc-Graw Hill Publishing Co. Ltd).
13. Text Book of Physical Chemistry by Soni-Dharmarha.
14. A Text Book Physical Chemistry by S. Glasstone, (Mac Millan.)
15. Advanced Physical Chemistry by D.N.Bajpai. (S.Chand)
16. Advanced Physical Chemistry by Gurdeep Raj. (Goel publishing house, Meerut).

13
 B. Sc. Third Year
Paper-XXII (CH-307)
Organic and Inorganic Chemistry
Periods: 120 Marks: 50

Note: At least sixteen experiments should be taken.

1. Only demonstration.
i) Column Chromatography.
a. Seperation of fluoroscein methylene blue.
b. Seperation of leaf pigment from spinachleaves.
2. Qualitative analysis :(any seven)
Separation of organic binary mixture and analysis of each compound with preparation
of one derivative.
Acids: Salicylic acid, cinnamic acid, phthalic acid, benzoic acid.
Phenols: -Naphthol. naphthol.
Base:- p-nitroaniline, m-nitroaniline, p-toludine.
Neutral: Urea, glucose, m-dinitrobenzene, Anthracene, Naphthalene.
3. Synthesis of organic compounds, with determining its physical constant and %
yield. (Reactions to be carried out in molar quantities and suggest its possible
mechanism) (Any five)
1) Preparation of 2,4,6-tribromoaniline from aniline.
2) Preparation of p-nitroacetanilide from acetanilide.
3) Preparation of benzoate from phenol / -Naphthol.
4) Preparation of p-nitroaniline from p-nitroacetanilide.
5) Preparation of m-nitroaniline from m-dinitrobenzene.
6) Preparation of fluoroscein from phthalic anhydride.
7) Preparation of phenolphthalein from phthalic anhydride.
8) Preparation of benzoic acid from toluene.
9) Preparation of pyrimidone from ethyl acetoacetate and urea.
10) Preparation of pyrazolone from ethyl acetoacetate and Phenylhydrazine.
Inorganic Section
1. Gravimetric estimation of Iron as Fe2O3.
2. Gravimetric estimation of Sulphate as BaSO4.
3. Gravimetric estimation of Nickel as Ni (DMG)2.
4. Gravimetric estimation of Aluminium as Al (Oxinate)3.

14
 B. Sc. Third Year
Paper-XXIII, [CH-308]
Laboratory Course-V
Physical and Inorganic Chemistry

Periods: 120 Marks: 50

Note: At least sixteen experiments should be taken.
Instrumental
1. Determine the normality and strength of oxalic acid conductometrically using standard solution of
strong base (NaOH / KOH).
2. Determine the concentration of KCl solution by titrating it with standard solution of AgNO3
conductometrically.
3. Determine the equivalent conductance of a strong electrolyte at several concentration and hence verify
the Onsagers equation.
4. Determine the normality and strength of acids in mixture [strong acid (HCl / HNO3) and weak acid
(CH3COOH / HCOOH)] potentiometrically using standard solution of strong base (NaOH / KOH).
5. Determine the dissociation constant a weak acid (CH3COOH / HCOOH) potentiometrically using
standard solution of strong base (NaOH / KOH).
6. Determination of empirical formula of a complex between Fe3+ and 5-sulphosalicylic acid by Jobs
method colorimetrically.
7. Determination of dissociation constant of an organic acid (CH3COOH) using various buffers
(CH3COOH + CH3COONa) pH metrically.
8. To study inversion of cane sugar by polarimetrically.
Non-Instrumental
1. Determine the rate constant of the reaction between potassium per sulphate and potassium iodide
having equal concentrations of reacting species (a = b).
2. Determine energy of activation of hydrolysis of an ester by acid / base.
3. Investigate the reaction between bromic acid and hydroiodic acid.
4. Determine molecular weight of non volatile solute by Rast method / Beckmanns freezing point
method.
5. Determine enthalpy change of neutralization of a strong acid by a strong base.
6. Determine interfacial tension between immiscible liquids, benzene and water by stalagmometer.
7. Determine molecular weight of a polymer by viscosity measurement.
8. Separation of mixture of o- & p-nitro anilines on an alumina column.
Inorganic Section:
1. Preparation of complexes and estimation of metal ion.
a) [Cu(NH3)4]SO4
b) [Ni(NH3)6]SO4
c) CoCl3. 4NH3
d) Sodium trioxalato ferrate.
e) Co[Hg(SCN)4].
Reference Books:
1. Experimental Physical Chemistry by A. Findlay. Longman.
2. Advanced Practical Physical Chemistry by J.B. Yadav.
3. Experiments in Physical Chemistry by R. C. Das and B. Behra. Tata Mc Graw Hill.
4. Advanced experimental Chemistry Vol. I. Physical by J. N. Gurtu and R. Kapoor. S. Chand & Co.
5. Experiments in Physical Chemistry by J. C. Ghosh, Bharati Bhavan.
6. Practical book of Physical Chemistry by Nadkarni Kothari & Lawande. Bombay Popular Prakashan.
7. Systematic Experimental Physical Chemistry by S. W. Rajbhoj, Chondhekar. Anjali Publication.
8. Practical Physical Chemisty by B. D. Khosala & V. C. Garg. R. Chand & Sons.
9. Experiments in Chemistry by D. V. Jagirdar.
10. Practical Chemistry, Physical Inorganic Organic and Viva voce by Balwant Rai Satija. Allied
Publishers Pvt. Ltd.
11. College Practical Chemistry by H. N. Patel, S. R. Jakali, H. P. Subhedar, Miss. S. P. Turakhia,
Himalaya Publishing House, Mumbai.
12. College Practical Chemistry by Patel, Jakali, Mohandas, Israney, Turakhia, Himalaya Publishing
Housing, Mumbai.

15
 FACULTY OF SCIENCE
PRACTICAL EXAMINATION
B. Sc. (Third Year) CH-307
(Organic & Inorganic Chemistry) Paper-XXII

Time: 6 Hr CHEMISTRY Marks: 50

N. B.:
(i) Use of logarithmic table and Non-programmable calculator is allowed.
(ii) No candidate is allowed to appear for practical examination without certified
record book.
(iii) Obtain the signature of examiner on your observations and readings.

Q. 1 Viva-voce & Certified Laboratory Journal 05

Q. 2 a) Determine the type of given binary mixture and Separation of organic 05
binary mixture.
b) Analyze the one organic compound qualitatively and find out the nature, 15
detection of elements, functional group, physical constant and derivative.
Q. 3 a) Starting from __________________________ prepare the pure sample 10
of______________________ and mention yield and physical constant of
prepared sample.
b) Procedure and mechanism. 03
c) Calculate Percentage (%) Yield. 02
Q. 4 a) Estimate the amount of ______________________ as __________ by 12
gravimetrically.
b) Procedure 03

16
 FACULTY OF SCIENCE
PRACTICAL EXAMINATION
B. Sc. (Third Year) CH-308
(Physical & Inorganic Chemistry) Paper-XXIII

Time: 6 Hr CHEMISTRY Marks: 50

N. B.:
(i) Use of logarithmic table and Non-programmable calculator is allowed.
(ii) No candidate is allowed to appear for practical examination without certified
record book.
(iii) Obtain the signature of examiner on your observations and readings.

Q. 1 Viva-voce & Certified Laboratory Journal 05

Q. 2 Determine the normality and strength of oxalic acid conductometrically 15
using standard solution of strong base (NaOH / KOH).
OR
Determine the concentration of KCl solution by titrating it with standard
solution of AgNO3 conductometrically.
OR
Determine the equivalent conductance of a strong electrolyte at several
concentration and hence verify the Onsagers equation.
OR
Determine the normality and strength of acids in mixture [strong acid
(HCl / HNO3) and weak acid (CH3COOH / HCOOH)] potentiometrically
using standard solution of strong base (NaOH / KOH).
OR
Determine the dissociation constant a weak acid (CH3COOH / HCOOH)
potentiometrically using standard solution of strong base (NaOH / KOH).
OR
Determination of empirical formula of a complex between Fe3+ and 5-
sulphosalicylic acid by Jobs method colorimetrically.
OR
Determination of dissociation constant of an organic acid (CH3COOH)
using various buffers (CH3COOH + CH3COONa) pH metrically.
OR
To study inversion of cane sugar by polarimetrically.
Q. 3 Determine the rate constant of the reaction between potassium per 15
sulphate and potassium iodide having equal concentrations of reacting
species (a = b).
OR
Determine energy of activation of hydrolysis of an ester by acid / base.
OR
Investigate the reaction between bromic acid and hydroiodic acid.
OR
Determine molecular weight of non volatile solute by Rast method /
Beckmanns freezing point method.
OR
Determine enthalpy change of neutralization of a strong acid by a strong
base.

17
 OR
Determine interfacial tension between immiscible liquids, benzene and
water by stalagmometer.
OR
Determine molecular weight of a polymer by viscosity measurement.
OR
Separation of mixture of o- & p-nitro anilines on an alumina column.
Q. 4 Preparation of ............complex. Estimate the amount of metal
ion . volumetrically.
a) Procedure 03
b) Preparation 04
c) Estimation 08

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