MD2 Solution
MD2 Solution
MD2 Solution
Nitric acid is made commercially from nitric oxide. Nitric oxide is produced by the gas-phase
oxidation of ammonia.
The feed consists of 15 mol% ammonia in air at 8.2 atm and 227C. Assume ideal gas.
b) Write rate law in terms of conversion. Assume the reaction is first order in both reactants.
Additional information:
R=0.082 atm.dm3/(mol.K),
Solution
Assume ideal gas behavior.
Therefore,
A B + C
follows an elementary rate law and is to be carried out first in a PFR and then in a separate
experiment in a CSTR. When Pure A is fed to a 10 dm 3 PFR at 290 K and a volumetric flow rate
of 5 dm3/s, the conversion is 80%. When a mixture of 50% A and 50% inert (I) is fed to a 10 dm 3
CSTR at 330K and a volumetric flow rate of 5 dm 3/s the conversion is also 80%. What is the
activation energy in cal/mol?
Additional information:
=
Solution