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S c 40 LMN
PAPER - 1 : PHYSICS, MATHEMATICS & CHEMISTRY Test Booklet Code
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 PART A PHYSICS A
1. Distance of the centre of mass of a solid 1. U
uniform cone from its vertex is z0. If the U z0 U
radius of its base is R and its height is h R h z0
then z0 is equal to : UU ?

5h 5h
(1) (1)
8 8

3h 2 3h 2
(2) (2)
8R 8R

h2 h2
(3) (3)
4R 4R

3h 3h
(4) (4)
4 4

2. A red LED emits light at 0.1 watt uniformly 2. U ..U. ( UU)

around it. The amplitude of the electric 0.1 U U, U
field of the light at a distance of 1 m from UU 1 m U U, l
the diode is :

(1) 5.48 V/m (1) 5.48 V/m

(2) 7.75 V/m (2) 7.75 V/m

(3) 1.73 V/m (3) 1.73 V/m

(4) 2.45 V/m (4) 2.45 V/m

D/Page 2 SPACE FOR ROUGH WORK / U

3. A pendulum made of a uniform wire of 3. U SU
cross sectional area A has time period T. A
When an additional mass M is added to T U M
its bob, the time period changes to TM. If U
the Youngs modulus of the material of the U TM U
1 1
wire is Y then
Y
is equal to : Y Y

(g5gravitational acceleration) (g5L U)

2 2
T A T A
(1) 1 2 M (1) 1 2 M
T Mg T Mg

2 2
T A T A
(2) 1 2 (2) 1 2
TM Mg TM Mg

TM 2 A TM 2 A

(3) 21 (3) 21
T Mg T Mg

TM 2 Mg TM 2 Mg

(4) 21 (4) 2 1
T A T A

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4. For a simple pendulum, a graph is plotted 4. U , S d
between its kinetic energy (KE) and U S d
potential energy (PE) against its S
displacement d. Which one of the () ?
following represents these correctly ? ( S U U S
(graphs are schematic and not drawn to scale) U )

(1) (1)

(2) (2)

(3) (3)

(4) (4)

5. A train is moving on a straight track with 5. U (U) UU U 20 ms21

speed 20 ms21. It is blowing its whistle at U U U
the frequency of 1000 Hz. The percentage 1000 Hz
change in the frequency heard by a person 320 ms21 , UU U
standing near the track as the train passes U U U, mU
him is (speed of sound5320 ms21) close U U
to :
(1) 18% (1) 18%
(2) 24% (2) 24%
(3) 6% (3) 6%
(4) 12% (4) 12%

D/Page 4 SPACE FOR ROUGH WORK / U

6. When 5V potential difference is applied 6. 0.1 m U U 5V UU
across a wire of length 0.1 m, the drift U U U
speed of electrons is 2.531024 ms21. If 2.531024 ms21 U U
the electron density in the wire is 831028 m23 ,
831028 m23, the resistivity of the material U ,
is close to :
(1) 1.631026 Vm (1) 1.631026 Vm
(2) 1.631025 Vm (2) 1.631025 Vm
(3) 1.631028 Vm (3) 1.631028 Vm
(4) 1.631027 Vm (4) 1.631027 Vm

7. 7.

Two long current carrying thin wires, both U I U U

with current I, are held by insulating L lU U
threads of length L and are in equilibrium mU U
as shown in the figure, with threads u S , U S
making an angle u with the vertical. If U U
wires have mass l per unit length then the l g L U , I
value of I is :
(g5gravitational acceleration)

pgL pgL
(1) 2 tan u (1) 2 tan u
m0 m0

plgL plgL
(2) tan u (2) tan u
m0 m0

plgL plgL
(3) sinu (3) sinu
m0 cosu m0 cosu

plgL plgL
(4) 2sinu (4) 2sinu
m0 cosu m0 cosu

D/Page 5 SPACE FOR ROUGH WORK / U

8. 8.

In the circuit shown, the current in the 1V U 1V U U

resistor is :
(1) 0.13 A, from Q to P (1) 0.13 A, Q P
(2) 0.13 A, from P to Q (2) 0.13 A, P Q
(3) 1.3 A, from P to Q (3) 1.3 A, P Q U
(4) 0A (4) 0 () A
9. Assuming human pupil to have a radius 9. 0.25 cm, U
of 0.25 cm and a comfortable viewing ScU U 25 cm ,
distance of 25 cm, the minimum separation 500 nm U , S
between two objects that human eye can U
resolve at 500 nm wavelength is : U ?
(1) 100 mm (1) 100 mm
(2) 300 mm (2) 300 mm
(3) 1 mm (3) 1 mm
(4) 30 mm (4) 30 mm
10. An inductor (L50.03H) and a resistor 10. U , U (L50.03H)
(R50.15 kV) are connected in series to a U (R50.15 kV) 15V l
battery of 15V EMF in a circuit shown (..) UU
below. The key K1 has been kept closed K1 U
for a long time. Then at t50, K1 is opened t50 U, K1 U
and key K 2 is closed simultaneously. , K2 t51ms
At t51ms, the current in the circuit will U, U l U (e5@150)
be : (e5@150)

(1) 6.7 mA (1) 6.7 mA

(2) 0.67 mA (2) 0.67 mA
(3) 100 mA (3) 100 mA
(4) 67 mA (4) 67 mA

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11. An LCR circuit is equivalent to a damped 11. LCR (..U) U
pendulum. In an LCR circuit the capacitor LCR U U
is charged to Q0 and then connected to Q0 , U U U
the L and R as shown below : U L R

If a student plots graphs of the square of l L , , L1 L2

2
maximum charge ( QMax ) on the capacitor (L 1 >L 2 ) , t U U
with time(t) for two different values L1 and QMax 2

L2 (L1>L2) of L then which of the following
?
represents this graph correctly ? (plots are
(U S U S U
schematic and not drawn to scale)
)

(1)
(1)

(2)
(2)

(3)
(3)

(4)
(4)

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12. In the given circuit, charge Q2 on the 2mF 12. U , C 1mF 3mF
capacitor changes as C is varied from 1mF U , 2mF U U Q2
to 3mF. Q2 as a function of C is given U C M Q2
properly by : (figures are drawn schematically ? (
and are not to scale) S U U S U )

(1) (1)

(2) (2)

(3) (3)

(4) (4)

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13. From a solid sphere of mass M and radius 13. U M
R a cube of maximum possible volume is R
cut. Moment of inertia of cube about an () U
axis passing through its center and , , -,
perpendicular to one of its faces is : U $U
U ?

4MR 2 4MR 2
(1) (1)
9 3p 9 3p

4MR 2 4MR 2
(2) (2)
3 3p 3 3p

MR 2 MR 2
(3) (3)
32 2p 32 2p

MR 2 MR 2
(4) (4)
16 2p 16 2p

L
14. The period of oscillation of a simple 14. U , T 5 2p
g

L
pendulum is T 5 2p . Measured value
g L 20.0 cm ,
of L is 20.0 cm known to 1 mm accuracy 1 mm 100
and time for 100 oscillations of the 90 s , 1s ,
pendulum is found to be 90 s using a wrist g U
watch of 1s resolution. The accuracy in
the determination of g is :

(1) 1% (1) 1%

(2) 5% (2) 5%

(3) 2% (3) 2%

(4) 3% (4) 3%

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15. On a hot summer night, the refractive 15. c U , - U,
index of air is smallest near the ground and U -
increases with height from the ground. , -U-
When a light beam is directed horizontally, U , h
the Huygens principle leads us to conclude U ,
that as it travels, the light beam : -U

(1) bends downwards (1) U

(2) bends upwards (2) U U

(3) becomes narrower (3) ()

(4) goes horizontally without any (4) ,

deflection U

16. A signal of 5 kHz frequency is amplitude 16. 5 kHz ()

modulated on a carrier wave of frequency 2 MHz U U U
2 MHz. The frequencies of the resultant , U ()
signal is/are :

(1) 2005 kHz, 2000 kHz and 1995 kHz (1) 2005 kHz, 2000 kHz 1995 kHz

(2) 2000 kHz and 1995 kHz (2) 2000 kHz 1995 kHz

(3) 2 MHz only (3) 2 MHz

(4) 2005 kHz, and 1995 kHz (4) 2005 kHz, 1995 kHz

D/Page 10 SPACE FOR ROUGH WORK / U

17. A solid body of constant heat capacity 17. U U (S) SU c U
1 J/8C is being heated by keeping it in 1 J/8C c (c UU)
contact with reservoirs in two ways : UU U ,
(i) Sequentially keeping in contact with (i) M 2 c
2 reservoirs such that each reservoir U UU c
supplies same amount of heat. c ,
(ii) Sequentially keeping in contact with (ii) M 8 c
8 reservoirs such that each reservoir U UU c
supplies same amount of heat. c ,
In both the cases body is brought from S U U 1008C
initial temperature 1008C to final 2008C , S U
temperature 2008C. Entropy change of the U U ,
body in the two cases respectively is :
(1) ln2, 2ln2 (1) ln2, 2ln2
(2) 2ln2, 8ln2 (2) 2ln2, 8ln2
(3) ln2, 4ln2 (3) ln2, 4ln2
(4) ln2, ln2 (4) ln2, ln2

18. Consider a spherical shell of radius R at 18. () R U

temperature T. The black body radiation T U c U U
inside it can be considered as an ideal gas
of photons with internal energy per unit U
U , u5 ; T4
U V
volume u5 ; T4 and pressure
V 1 U
, p5
3 V
Lc
1 U
p 5 . If the shell now undergoes
3 V U , T R
an adiabatic expansion the relation
between T and R is :
1 1
(1) T; (1) T;
R R
1 1
(2) T; 3 (2) T;
R R3
(3) T ; e2R (3) T ; e2R
(4) T ; e23R (4) T ; e23R

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19. Two stones are thrown up simultaneously 19. 240 m U U ,
from the edge of a cliff 240 m high with U U U ,
initial speed of 10 m/s and 40 m/s U 10 m/s 40 m/s , ,
respectively. Which of the following graph () U
best represents the time variation of U U S U
relative position of the second stone with (U) ?
respect to the first ?

(Assume stones do not rebound after ( , U UU

hitting the ground and neglect air U U U U
resistance, take g510 m/s2) , g510 m/s2)
(The figures are schematic and not drawn to ( S U U S
scale) U )

(1) (1)

(2) (2)

(3) (3)

(4) (4)

D/Page 12 SPACE FOR ROUGH WORK / U

20. A uniformly charged solid sphere of radius 20. R U
R has potential V0 (measured with respect cU V0 (: )
to :) on its surface. For this sphere the 3V0 5V0 3V0 V0
equipotential surfaces with potentials
, , ,
2 4 4 4
3V0 5V0 3V0 V c U ,
, , and 0 have radius R1,
2 4 4 4 R1, R2, R3 R4 ,
R2, R3 and R4 respectively. Then

(1) R150 and R2 < (R42R3) (1) R150 R2 < (R42R3)

(2) 2R < R4 (2) 2R < R4
(3) R150 and R2 > (R42R3) (3) R150 R2 > (R42R3)
(4) R1 0 and (R22R1) > (R42R3) (4) R1 0 (R22R1) > (R42R3)

21. Monochromatic light is incident on a glass 21. A U

prism of angle A. If the refractive index of ,
the material of the prism is m, a ray, m , AB
incident at an angle u, on the face AB U, u U,
would get transmitted through the face AC AC U
of the prism provided :

1 1
(1) u > cos21 m sin A 1 sin21 (1) u > cos21 m sin A 1 sin21
m m

1 1
(2) u < cos21 m sin A 1 sin21 (2) u < cos21 m sin A 1 sin21
m m

1 1
(3) u > sin21 m sin A 2 sin21 (3) u > sin21 m sin A 2 sin21
m m

1 1
(4) u < sin21 m sin A 2 sin21 (4) u < sin21 m sin A 2 sin21
m m

D/Page 13 SPACE FOR ROUGH WORK / U

22. A rectangular loop of sides 10 cm and 22. 10 cm 5 cm U
5 cm carrying a current I of 12 A is placed () l U, I 5 12 A, U
in different orientations as shown in the U U U
figures below : (S) U

(a) (a)

(b) (b)

(c) (c)

(d) (d)

If there is a uniform magnetic field of 0.3 T

0.3 T in the positive z direction, in which , z l ,
orientations the loop would be in (i) stable , () (i) S
equilibrium and (ii) unstable equilibrium ? (ii) S , ?
(1) (b) and (d), respectively (1) (b) (d)
(2) (b) and (c), respectively (2) (b) (c)

(3) (a) and (b), respectively (3) (a) (b)

(4) (a) and (c), respectively (4) (a) (c)

D/Page 14 SPACE FOR ROUGH WORK / U

23. Two coaxial solenoids of different radii 23. U , I U
carry current I in the same direction. Let U , U U
U, U U U
F1 be the magnetic force on the inner
F1 U U U, U U
solenoid due to the outer one and F2 be

the magnetic force on the outer solenoid U F2
due to the inner one. Then :

(1) F1 is radially inwards and F2 50 (1) F1 U U U F2 50

(2) F1 is radially outwards and F2 50 (2) F1 U U U F2 50

(3) F1 5 F25 0 (3) F1 5 F25 0

(4) F1 is radially inwards and F2 is (4) F1 U U U () U

radially outwards F2 U U U

24. A particle of mass m moving in the 24. x- 2v m

x direction with speed 2v is hit by another , y- v 2m
particle of mass 2m moving in the , UU UU (UU)
y direction with speed v. If the collision is S , UU U
perfectly inelastic, the percentage loss in ()
the energy during the collision is close to :

(1) 56% (1) 56%

(2) 62% (2) 62%

(3) 44% (3) 44%

(4) 50% (4) 50%

D/Page 15 SPACE FOR ROUGH WORK / U

25. Consider an ideal gas confined in an 25. ( ),
isolated closed chamber. As the gas () (U)
undergoes an adiabatic expansion, the Lc U U, UU
average time of collision between () Vq U ,
q
molecules increases as V , where V is the V q :
volume of the gas. The value of q is : Cp
Cp g 5
Cv
g 5
Cv

(1) g11 (1) g11

2 2
g21 g21
(2) (2)
2 2
3g 1 5 3g 1 5
(3) (3)
6 6
3g 2 5 3g 2 5
(4) (4)
6 6

26. From a solid sphere of mass M and radius 26. U M R

R R
R, a spherical portion of radius
2
is , U
2
removed, as shown in the figure. Taking U U r5:() U
gravitational potential V50 at r5:, the L V (V50)
potential at the centre of the cavity thus , U UU (U) U,
formed is : L
(G5 gravitational constant) (G5 L SU )

2 2GM 2 2GM
(1) (1)
3R 3R
2 2GM 2 2GM
(2) (2)
R R
2 GM 2 GM
(3) (3)
2R 2R
2 GM 2 GM
(4) (4)
R R

D/Page 16 SPACE FOR ROUGH WORK / U

27. 27.

Given in the figure are two blocks A and B U (U) A U B

of weight 20 N and 100 N, respectively. U 20 N 100 N ,
These are being pressed against a wall by a F mU U U U
force F as shown. If the coefficient of friction , A B 0.1
between the blocks is 0.1 and between block B U U 0.15 , U mU
B and the wall is 0.15, the frictional force B U
applied by the wall on block B is :
(1) 120 N (1) 120 N
(2) 150 N (2) 150 N
(3) 100 N (3) 100 N
(4) 80 N (4) 80 N
28. A long cylindrical shell carries positive 28. U U
surface charge s in the upper half and cU s cU
negative surface charge 2s in the lower 2s (UU) U
half. The electric field lines around the U l -U,
cylinder will look like figure given in : U ?
(figures are schematic and not drawn to scale) ( U S U U S
U )

(1) (1)

(2) (2)

(3) (3)

(4) (4)

D/Page 17 SPACE FOR ROUGH WORK / U

29. As an electron makes a transition from an 29. U, U U /
excited state to the ground state of a S S
hydrogen - like atom/ion : U
(1) kinetic energy decreases, potential (1) , S
energy increases but total energy U U
remains same
(2) kinetic energy and total energy (2)
decrease but potential energy , S
increases
(3) its kinetic energy increases but (3) h S
potential energy and total energy
decrease
(4) kinetic energy, potential energy and (4) , S
total energy decrease

30. Match List - I (Fundamental Experiment) 30. - I ( ) - II ( U)

with List - II (its conclusion) and select () U
the correct option from the choices given
below the list :

List - I List - II - I - II
Franck-Hertz Particle nature
(A) (i) (A) (i)
Experiment. of light
Photo-electric Discrete energy
(B)
experiment.
(ii)
levels of atom
(B) l (ii)
SU
Davison - Germer Wave nature of U U
(C) (iii) (C) U U (iii)
Experiment. electron
Structure of
(iv) (iv) U U
atom

(1) (A) - (ii) (B) - (i) (C) - (iii) (1) (A) - (ii) (B) - (i) (C) - (iii)
(2) (A) -(iv) (B) - (iii) (C) - (ii) (2) (A) -(iv) (B) - (iii) (C)- (ii)
(3) (A) - (i) (B) - (iv) (C) - (iii) (3) (A) - (i) (B) - (iv) (C) - (iii)
(4) (A) - (ii) (B) - (iv) (C) - (iii) (4) (A) - (ii) (B) - (iv) (C) - (iii)

D/Page 18 SPACE FOR ROUGH WORK / U

 PART B MATHEMATICS B

31. Let a , b and c be three non-zero vectors 31. a , b c U
such that no two of them are collinear and U
1 1
( a 3 b )3 c 5 b c a . If u is the ( a 3 b )3 c 5 b c a
3 3

angle between vectors b and c , then a b c u , sin u
value of sin u is :

2 2
(1) (1)
3 3

22 3 22 3
(2) (2)
3 3

2 2 2 2
(3) (3)
3 3

2 2 2 2
(4) (4)
3 3

32. Let O be the vertex and Q be any point on 32. U x258y O U

the parabola, x258y. If the point P divides Q P, U U OQ
the line segment OQ internally in the ratio 1 : 3 U U , P
1 : 3, then the locus of P is :

(1) y 2 52x (1) y 2 52x

(2) x 2 52y (2) x 2 52y

(3) x 2 5y (3) x 2 5y

(4) y 2 5x (4) y 2 5x

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33. If the angles of elevation of the top of a 33. U A, B C, U U
tower from three collinear points A, B and S U ,
C, on a line leading to the foot of the U U
tower, are 308, 458 and 608 respectively, 308, 458 608 , AB : BC
then the ratio, AB : BC, is :
(1) 1: 3 (1) 1: 3
(2) 2:3 (2) 2:3
(3) 3:1 (3) 3:1
(4) 3: 2 (4) 3: 2

34. The number of points, having both 34. , (0, 0), (0, 41) (41, 0) ,
co-ordinates as integers, that lie in the U S
interior of the triangle with vertices (0, 0), Z ,
(0, 41) and (41, 0), is :
(1) 820 (1) 820
(2) 780 (2) 780
(3) 901 (3) 901
(4) 861 (4) 861

35. The equation of the plane containing the 35. U 2x25y1z53, x1y14z55 cU
line 2x25y1z53; x1y14z55, and U , x13y16z51
parallel to the plane, x13y16z51, is : U , U
(1) x13y16z57 (1) x13y16z57
(2) 2x16y112z5213 (2) 2x16y112z5213
(3) 2x16y112z513 (3) 2x16y112z513
(4) x13y16z527 (4) x13y16z527

36. Let A and B be two sets containing four 36. A B U

and two elements respectively. Then the , A3B
number of subsets of the set A3B, each ,
having at least three elements is : ,
(1) 275 (1) 275
(2) 510 (2) 510
(3) 219 (3) 219
(4) 256 (4) 256

D/Page 20 SPACE FOR ROUGH WORK / U

37. Locus of the image of the point (2, 3) in 37. (2, 3) U
the line (2x23y14)1k (x22y13)50, (2x23y14)1k (x22y13)50, k e R
k e R, is a :

(1) circle of radius 2. (1) 2

(2) circle of radius 3. (2) 3

(3) straight line parallel to x-axis. (3) x- U U
(4) straight line parallel to y-axis. (4) y- U U

38. lim ( 1 2 cos 2 x )( 3 1 cos x ) is equal to : 38. lim ( 1 2 cos 2 x )( 3 1 cos x ) UU

x0 x tan 4 x x0 x tan 4 x

(1) 2 (1) 2

1 1
(2) (2)
2 2

(3) 4 (3) 4

(4) 3 (4) 3

x 22 y 11 z 22
39. The distance of the point (1, 0, 2) from the 39. U 5 5
3 4 12
point of intersection of the line x2y1z516 U , (1, 0, 2)
x 22 y 11 z 22
5 5 and the plane U
3 4 12
x2y1z516, is :

(1) 3 21 (1) 3 21

(2) 13 (2) 13

(3) 2 14 (3) 2 14

(4) 8 (4) 8

D/Page 21 SPACE FOR ROUGH WORK / U

 (1 2 2 x )
50
40. The sum of coefficients of integral powers 40. m U x Z
of x in the binomial expansion of
(1 2 2 x )
50
is :

(1)
1 50
2
(
3 21 ) (1)
2
(
1 50
3 21 )
(2)
1 50
2
(
2 11 ) (2)
2
(
1 50
2 11 )
(3)
1 50
2
(
3 11 ) (3)
2
(
1 50
3 11 )
(4)
1 50
2
3 ( ) (4)
2
( )
1 50
3

41. The sum of first 9 terms of the series 41.

13 13 1 2 3 13 1 2 3 1 3 3 13 13 1 2 3 13 1 2 3 1 3 3
1
1
113
1
11 31 5
1 .... is : 1 1 1 ....
1 113 11 31 5
9
(1) 142 (1) 142
(2) 192 (2) 192
(3) 71 (3) 71
(4) 96 (4) 96

42. The area (in sq. units) of the region 42. {(x, y) : y2[ 2x y / 4x 2 1} mU U
described by ( )
{(x, y) : y2 [ 2x and y / 4x 2 1} is :
15 15
(1) (1)
64 64
9 9
(2) (2)
32 32
7 7
(3) (3)
32 32
5 5
(4) (4)
64 64

D/Page 22 SPACE FOR ROUGH WORK / U

43. The set of all values of l for which the 43. l , U
system of linear equations : U
2x 122x21x 35lx 1 2x 122x 21x 35lx 1

2x 123x 212x 35lx 2 2x 123x 212x 35lx 2

2x112x2 5lx3 2x112x2 5lx3

has a non-trivial solution, U ,

(1) contains two elements. (1)
(2) contains more than two elements. (2)
(3) is an empty set. (3) U
(4) is a singleton. (4)

44. A complex number z is said to be 44. z

unimodular if ?z?51. Suppose z1 and z2 ?z?51 z1 z2
z1 2 2 z2 z1 2 2 z2
are complex numbers such that z2
2 2 z1 z2 2 2 z1 z2
is unimodular and z2 is not unimodular. , z1 S
Then the point z1 lies on a :

(1) circle of radius 2. (1) 2 U

(2) circle of radius 2. (2) 2 U
(3) straight line parallel to x-axis. (3) x- U U U
(4) straight line parallel to y-axis. (4) y- U U U

45. The number of common tangents to the 45. x21y224x26y21250

circles x 2 1y 2 24x26y21250 and x21y216x118y12650 cU S
x21y216x118y12650, is : U
(1) 3 (1) 3

(2) 4 (2) 4

(3) 1 (3) 1

(4) 2 (4) 2

D/Page 23 SPACE FOR ROUGH WORK / U

46. The number of integers greater than 6,000 46. 3, 5, 6, 7 8 , U,
that can be formed, using the digits 3, 5, 6, 6,000 Z
7 and 8, without repetition, is :

(1) 120 (1) 120

(2) 72 (2) 72

(3) 216 (3) 216

(4) 192 (4) 192

47. Let y(x) be the solution of the differential 47. U

equation

dy dy
( x log x ) 1 y 5 2 x log x , ( x / 1). ( x log x ) 1 y 5 2 x log x , ( x / 1)
dx dx
Then y(e) is equal to : y(x) , y(e) UU

(1) 2 (1) 2

(2) 2e (2) 2e

(3) e (3) e

(4) 0 (4) 0

1 2 2 1 2 2
A 5 2 1 22
48. If A 5 2 1 22 is a matrix satisfying 48.
a 2 b a 2 b

the equation AA T 59I, where I is 333 U AAT59I, cU U ,

identity matrix, then the ordered pair I, 333 ,
(a, b) is equal to : (a, b)

(1) (2, 1) (1) (2, 1)

(2) (22, 21) (2) (22, 21)

(3) (2, 21) (3) (2, 21)

(4) (22, 1) (4) (22, 1)

D/Page 24 SPACE FOR ROUGH WORK / U

49. If m is the A.M. of two distinct real 49. S l n
numbers l and n (l, n > 1) and G1, G2 and (l, n > 1) U (A.M.) m U l
G3 are three geometric means between l n U (G.M.) G1, G2
and n, then G14 1 2G24 1 G 34 equals. G3 , 4
G1 1 2G2 1 G3
4 4
UU

(1) 4 lmn2 (1) 4 lmn2

(2) 4 l2m2n2 (2) 4 l2m2n2

(3) 4 l2mn (3) 4 l2mn

(4) 4 lm2n (4) 4 lm2n

50. The negation of ~ s (~ r s ) is equivalent 50. ~ s (~ r s )

to :

(1) s (r ~ s) (1) s (r ~ s)

(2) sr (2) sr

(3) s~r (3) s~r

(4) s (r ~ s) (4) s (r ~ s)

dx dx
51. The integral x 2 ( x 4 1 1)3 4 equals : 51. 3
UU
x 2 ( x 4 1 1) 4

1 1
(1) 2( x 4 1 1) 4 1 c (1) 2( x 4 1 1) 4 1 c

1 1
x 41 1 4 x 41 1 4
(2) 2 1c (2) 2 1c
x4 x4

1 1
x4 1 1 4 x4 1 1 4
(3) 1c (3) 1c
x4 x4

1 1
(4) ( x 411) 4 1 c (4) ( x 411) 4 1 c

D/Page 25 SPACE FOR ROUGH WORK / U

52. The normal to the curve, x212xy23y250, 52. x 2 12xy23y 250 (1, 1) U
at (1, 1) :
(1) meets the curve again in the third (1) U Z
quadrant.
(2) meets the curve again in the fourth (2) U Z
quadrant.
(3) does not meet the curve again. (3) U
(4) meets the curve again in the second (4) U m Z
quadrant.

53. Let 53.

2x 2x
tan21 y 5 tan21 x 1 tan21 , tan21 y 5 tan21 x 1 tan21 ,
1 2 x2 1 2 x2
1 1
where ? x ? < . Then a value of y is : ?x? < , y
3 3

3 x 2 x3 3 x 2 x3
(1) (1)
1 1 3 x2 1 1 3 x2

3 x 1 x3 3 x 1 x3
(2) (2)
1 1 3 x2 1 1 3 x2

3 x 2 x3 3 x 2 x3
(3) (3)
1 2 3 x2 1 2 3 x2

3 x 1 x3 3 x 1 x3
(4) (4)
1 2 3 x2 1 2 3 x2

54. If the function. 54.

k x 1 1 , 0 [ x [ 3 k x 1 1 , 0 [ x [ 3
g( x ) 5 g( x ) 5
m x 1 2 , 3 < x [ 5 m x 1 2 , 3 < x [ 5
is differentiable, then the value of k1m is : , k1m
10 10
(1) (1)
3 3
(2) 4 (2) 4
(3) 2 (3) 2
16 16
(4) (4)
5 5

D/Page 26 SPACE FOR ROUGH WORK / U

55. The mean of the data set comprising of 16 55. 16 16
observations is 16. If one of the observation 16 , U U, 3
valued 16 is deleted and three new 3, 4 5 ,
observations valued 3, 4 and 5 are added ,
to the data, then the mean of the resultant
data, is :

(1) 15.8 (1) 15.8

(2) 14.0 (2) 14.0

(3) 16.8 (3) 16.8

(4) 16.0 (4) 16.0

56. The integral 56.

4 4
log x 2 log x 2
log x 2 1 log (36 2 12 x 1 x 2 ) dx log x 2 1 log (36 2 12 x 1 x 2 ) d x
2 2

is equal to : UU
(1) 1 (1) 1

(2) 6 (2) 6

(3) 2 (3) 2

(4) 4 (4) 4

57. Let a and b be the roots of equation 57. a b m U x226x2250

x 2 26x2250. If a n 5a n 2b n , for n/1, n/1 , an5an2bn ,
a 2 2a8 a10 2 2a8
then the value of 10 is equal to :
2a9 2a9

(1) 3 (1) 3

(2) 23 (2) 23

(3) 6 (3) 6

(4) 26 (4) 26

D/Page 27 SPACE FOR ROUGH WORK / U

58. Let f (x) be a polynomial of degree four 58. f (x) 4
having extreme values at x51 and x52. x51 x52 U U
f ( x ) f ( x )
If lim 1 1 5 3 , then f (2) is equal lim 1 1 53 , f (2) UU
x 0 x2 x 0 x2
to :
(1) 0 (1) 0
(2) 4 (2) 4
(3) 28 (3) 28
(4) 24 (4) 24

x2 y2
59. The area (in sq. units) of the quadrilateral 59. 1 51 U U
9 5
formed by the tangents at the end points S U mU
of the latera recta to the ellipse ( )
x2 y2
1 5 1 , is :
9 5
27 27
(1) (1)
2 2
(2) 27 (2) 27
27 27
(3) (3)
4 4
(4) 18 (4) 18

60. If 12 identical balls are to be placed in 3 60. 12 , 3 U

identical boxes, then the probability that , U 3
one of the boxes contains exactly 3 balls
is :
12 12
1 1
(1) 220 (1) 220
3 3
11 11
1 1
(2) 22 (2) 22
3 3

55 2 11 55 2 11
(3) (3)
3 3 3 3
10 10
2 2
(4) 55 (4) 55
3 3

D/Page 28 SPACE FOR ROUGH WORK / U

 PART C CHEMISTRY C U
61. Which compound would give 61. $ U U
5 - keto - 2 - methyl hexanal upon 5 - U - 2 - ?
ozonolysis ?

(1) (1)

(2) (2)

(3) (3)

(4) (4)

62. Which of the vitamins given below is water 62. U

soluble ?
(1) Vitamin E (1) U E
(2) Vitamin K (2) U K
(3) Vitamin C (3) U C
(4) Vitamin D (4) U D

63. Which one of the following alkaline earth 63. U U

metal sulphates has its hydration enthalpy
greater than its lattice enthalpy ? ?
(1) BaSO4 (1) BaSO 4
(2) SrSO 4 (2) SrSO 4
(3) CaSO 4 (3) CaSO 4
(4) BeSO4 (4) BeSO4

D/Page 29 SPACE FOR ROUGH WORK / U

64. In the reaction 64. E

NaNO /HCl CuCN/KCN NaNO /HCl CuCN/KCN

2
D
E 1 N2
2
D E 1 N 2
0258 C D 0258 C D

the product E is :

(1) (1)

(2) (2)

(3) (3)

(4) (4)

65. Sodium metal crystallizes in a body centred 65. U

cubic lattice with a unit cell edge of 4.29. SU U 4.29
The radius of sodium atom is U U
approximately :

(1) 5.72 (1) 5.72

(2) 0.93 (2) 0.93

(3) 1.86 (3) 1.86

(4) 3.22 (4) 3.22

D/Page 30 SPACE FOR ROUGH WORK / U

66. Which of the following compounds is not 66. U
colored yellow ? ?
(1) (NH4)3 [As (Mo3 O10)4] (1) (NH4)3 [As (Mo3 O10)4]

(2) BaCrO 4 (2) BaCrO 4

(3) Zn2[Fe(CN)6] (3) Zn2[Fe(CN)6]

(4) K3[Co(NO2)6] (4) K3[Co(NO2)6]

67. Which of the following is the energy of a 67. U S

possible excited state of hydrogen ? ?
(1) 23.4 eV (1) 23.4 eV

(2) 16.8 eV (2) 16.8 eV

(3) 113.6 eV (3) 113.6 eV

(4) 26.8 eV (4) 26.8 eV

68. Which of the following compounds is not 68. ?

an antacid ?

(1) Phenelzine (1)

(2) Ranitidine (2) UUU
(3) Aluminium hydroxide (3) UU
(4) Cimetidine (4) UU

69. The ionic radii (in ) of N32, O22 and F2 69. N32, O22 F2 ( )
are respectively :
(1) 1.71, 1.40 and 1.36 (1) 1.71, 1.40 1.36

(2) 1.71, 1.36 and 1.40 (2) 1.71, 1.36 1.40

(3) 1.36, 1.40 and 1.71 (3) 1.36, 1.40 1.71

(4) 1.36, 1.71 and 1.40 (4) 1.36, 1.71 1.40

D/Page 31 SPACE FOR ROUGH WORK / U

70. In the context of the Hall - Heroult process 70. -UU c
for the extraction of Al, which of the ?
following statements is false ?
(1) Al31 is reduced at the cathode to (1) U U Al31 U Al
form Al
(2) Na3AlF6 serves as the electrolyte (2) Na3AlF6 l U U

(3) CO and CO2 are produced in this (3) CO CO2
process
(4) Al 2 O 3 is mixed with CaF 2 which (4) CaF2 Al2O3 U
lowers the melting point of the U
mixture and brings conductivity

71. In the following sequence of reactions : 71. C

KMnO SOCl H /Pd KMnO SOCl H /Pd
Toluene
4
A
2
B
2
C, Toluene
4
A
2
B
2
C
BaSO 4 BaSO 4

the product C is :
(1) C6H5CH2OH (1) C6H5CH2OH
(2) C6H5CHO (2) C6H5CHO
(3) C6H5COOH (3) C6H5COOH
(4) C6H5CH3 (4) C6H5CH3

72. Higher order (>3) reactions are rare due 72. U (>3)
to :
(1) shifting of equilibrium towards (1) U UU U U
reactants due to elastic collisions SU
(2) loss of active species on collision (2) UU S$
(3) low probability of simultaneous (3) UU
collision of all the reacting species
(4) increase in entropy and activation (4) U U
energy as more molecules are h
involved

D/Page 32 SPACE FOR ROUGH WORK / U

73. Which of the following compounds will 73.
exhibit geometrical isomerism ? ?
(1) 2 - Phenyl - 1 - butene (1) 2- - 1 - U
(2) 1, 1 - Diphenyl - 1 - propane (2) 1, 1 - U - 1 -
(3) 1 - Phenyl - 2 - butene (3) 1- - 2 - U
(4) 3 - Phenyl - 1 - butene (4) 3- - 1 - U

74. Match the catalysts to the correct 74. U

processes : U
Catalyst Process U
(A) TiCl3 (i) Wacker process (A) TiCl3 (i) U
(B) PdCl2 (ii) Ziegler - Natta (B) PdCl2 (ii) -^
polymerization UU
(C) CuCl2 (iii) Contact process (C) CuCl2 (iii) S
(D) V 2O 5 (iv) Deacons process (D) V 2O 5 (iv) U
(1) (A) - (ii), (B) - (iii), (C) - (iv), (D) - (i) (1) (A) - (ii), (B) - (iii), (C) - (iv), (D) - (i)

(2) (A) - (iii), (B) - (i), (C) - (ii), (D) - (iv) (2) (A) - (iii), (B) - (i), (C) - (ii), (D) - (iv)

(3) (A) - (iii), (B) - (ii), (C) - (iv), (D) - (i) (3) (A) - (iii), (B) - (ii), (C) - (iv), (D) - (i)

(4) (A) - (ii), (B) - (i), (C) - (iv), (D) - (iii) (4) (A) - (ii), (B) - (i), (C) - (iv), (D) - (iii)

75. The intermolecular interaction that is 75. U-

dependent on the inverse cube of distance U U U ,
between the molecules is :

(1) London force (1) U

(2) hydrogen bond (2) U
(3) ion - ion interaction (3) -
(4) ion - dipole interaction (4) - m

D/Page 33 SPACE FOR ROUGH WORK / U

76. The molecular formula of a commercial 76. U$ C8H7SO3Na
resin used for exchanging ions in water ( U = 206) U$ Ca21
softening is C8H7SO3Na (Mol. wt. 206). (
What would be the maximum uptake of U$) ?
Ca21 ions by the resin when expressed in
mole per gram resin ?

2 2
(1) (1)
309 309

1 1
(2) (2)
412 412

1 1
(3) (3)
103 103

1 1
(4) (4)
206 206

77. Two Faraday of electricity is passed 77. CuSO4 , UU l

through a solution of CuSO4. The mass of U U :
copper deposited at the cathode is : (Cu U 563.5 amu)
(at. mass of Cu563.5 amu)

(1) 2g (1) 2g

(2) 127 g (2) 127 g

(3) 0g (3) 0g

(4) 63.5 g (4) 63.5 g

78. The number of geometric isomers that can 78. [Pt (Cl) (py) (NH3) (NH2OH)]1
exist for square planar [Pt (Cl) (py) (NH3) (py 5 pyridine)
(NH2OH)]1 is (py 5 pyridine) :
(1) 4 (1) 4

(2) 6 (2) 6

(3) 2 (3) 2

(4) 3 (4) 3

D/Page 34 SPACE FOR ROUGH WORK / U

79. In Carius method of estimation of 79. U 250 mg
halogens, 250 mg of an organic compound 141 mg AgBr
gave 141 mg of AgBr. The percentage of :
bromine in the compound is : (U Ag5108; Br580)
(at. mass Ag5108; Br580)
(1) 48 (1) 48
(2) 60 (2) 60
(3) 24 (3) 24
(4) 36 (4) 36

80. The color of KMnO4 is due to : 80. KMnO4 U U

(1) L M charge transfer transition (1) L M SU
(2) s 2 s* transition (2) s 2 s*
(3) M L charge transfer transition (3) M L SU
(4) d 2 d transition (4) d 2 d

81. The synthesis of alkyl fluorides is best 81. UU

accomplished by : U
(1) Finkelstein reaction (1) SU
(2) Swarts reaction (2) SU
(3) Free radical fluorination (3) U
(4) Sandmeyers reaction (4) UU

82. 3 g of activated charcoal was added to 82. S 0.06N U 50 mL

50 mL of acetic acid solution (0.06N) in a 3 g cU
flask. After an hour it was filtered and U U U S
the strength of the filtrate was found to be 0.042 N U
0.042 N. The amount of acetic acid (cU- U)
adsorbed (per gram of charcoal) is :
(1) 42 mg (1) 42 mg
(2) 54 mg (2) 54 mg
(3) 18 mg (3) 18 mg
(4) 36 mg (4) 36 mg

D/Page 35 SPACE FOR ROUGH WORK / U

83. The vapour pressure of acetone at 208C is 83. 208C U U c 185 torr
185 torr. When 1.2 g of a non-volatile 208C U, 1.2 g c 100 g
substance was dissolved in 100 g of acetone U , c 183 torr
at 208C, its vapour pressure was 183 torr. U (g mol21 )
The molar mass (g mol21) of the substance
is :

(1) 128 (1) 128

(2) 488 (2) 488

(3) 32 (3) 32

(4) 64 (4) 64

84. Which among the following is the most 84. ?

reactive ?

(1) I2 (1) I2

(2) ICl (2) ICl

(3) Cl2 (3) Cl2

(4) Br2 (4) Br2

85. The standard Gibbs energy change at 85. 300 K U 2A B 1 C

300 K for the reaction 2A B 1 C is $ 2494.2 J
1
2494.2 J. At a given time, the composition U [A] 5
2
,

1 1
of the reaction mixture is [A] 5 , [B]52 [B]52 U [C] 5
2 2
1
and [C] 5
2
. The reaction proceeds in [R58.314 J/K/mol, e52.718]

the : [R58.314 J/K/mol, e52.718]

(1) forward direction because Q < Kc (1) Q < Kc

(2) reverse direction because Q < Kc (2) U Q < Kc
(3) forward direction because Q > Kc (3) Q > Kc
(4) reverse direction because Q > Kc (4) U Q > Kc
D/Page 36 SPACE FOR ROUGH WORK / U
86. Assertion : Nitrogen and Oxygen are the 86. U U U
main components in the U U U
atmosphere but these do not U U
react to form oxides of nitrogen.

Reason : The reaction between nitrogen U U

and oxygen requires high
temperature.
(1) The assertion is incorrect, but the (1) U
reason is correct

(2) Both the assertion and reason are (2)

incorrect

(3) Both assertion and reason are (3) U U

correct, and the reason is the correct ScUU
explanation for the assertion

(4) Both assertion and reason are (4) U U

correct, but the reason is not the ScUU
correct explanation for the assertion

87. Which one has the highest boiling point ? 87. ?

(1) Kr (1) Kr

(2) Xe (2) Xe

(3) He (3) He

(4) Ne (4) Ne

88. Which polymer is used in the manufacture 88. U

of paints and lacquers ? ?
(1) Polypropene (1)
(2) Poly vinyl chloride (2) UU
(3) Bakelite (3) U
(4) Glyptal (4) U

D/Page 37 SPACE FOR ROUGH WORK / U

89. The following reaction is performed at 89. 298 K U
298 K.

2NO(g) 1 O 2 (g) 2NO 2 (g) 2NO(g) 1 O 2 (g) 2NO 2 (g)

The standard free energy of formation of 298 K U NO(g)

NO(g) is 86.6 kJ/mol at 298 K. What is 86.6 kJ/mol 298 K U NO2(g)
the standard free energy of formation of ? (Kp51.631012)
NO2(g) at 298 K? (Kp51.631012)

ln (1.6 3 1012 ) ln (1.6 3 1012 )

(1) 86600 2 (1) 86600 2
R (298) R (298)

(2) 0.5[2386,6002R(298) ln(1.631012)] (2) 0.5[2386,6002R(298) ln(1.631012)]

(3) R(298) ln(1.6310 12)286600 (3) R(298) ln(1.6310 12)286600
(4) 866001R(298) ln(1.6310 12) (4) 866001R(298) ln(1.6310 12)

90. From the following statements regarding 90. H2O2 ,

H2O2, choose the incorrect statement :
(1) It has to be stored in plastic or wax (1) SU U U
lined glass bottles in dark
(2) It has to be kept away from dust (2) U U

(3) It can act only as an oxidizing agent (3) U

(4) It decomposes on exposure to light (4) U

-o0o- -o0o-

SPACE FOR ROUGH WORK / U

D/Page 38 SPACE FOR ROUGH WORK / U

 SPACE FOR ROUGH WORK /

D/Page 39 SPACE FOR ROUGH WORK / U

 Read the following instructions carefully :
1. The candidates should fill in the required particulars 1. U U S U U (D -1) U U
on the Test Booklet and Answer Sheet (Side1) with
Blue/Black Ball Point Pen.
U / U U
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Answer Sheet, use Blue/Black Ball Point Pen only. / U U
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anywhere else (except in the specified space) on the R
Test Booklet/Answer Sheet.
4. Out of the four options given for each question, only 4. U
one option is the correct answer.
5. For each incorrect response, onefourth () of the total 5. U U
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however, will be made if no response is indicated for U U ,
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6. Handle the Test Booklet and Answer Sheet with care, 6. U S U U
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D/Page 40