w

w
w
.X
tr
me
eP
ap
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS

er
International General Certificate of Secondary Education

s.c
om
*6145201818*

CHEMISTRY 0620/31
Paper 3 (Extended) May/June 2011
1 hour 15 minutes
Candidates answer on the Question Paper.
No Additional Materials are required.

READ THESE INSTRUCTIONS FIRST

Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use a pencil for any diagrams, graphs or rough working.
Do not use staples, paper clips, highlighters, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.

Answer all questions.

For Examiners Use
A copy of the Periodic Table is printed on page 12.
1
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part
question. 2

Total

This document consists of 11 printed pages and 1 blank page.

IB11 06_0620_31/4RP
UCLES 2011 [Turn over
 2
For
1 The following techniques are used to separate mixtures. Examiners
Use
A simple distillation B fractional distillation C evaporation

D chromatography E filtration F diffusion

From this list, choose the most suitable technique to separate the following.

(a) methane from a mixture of the gases, methane and ethane .................. [1]

(b) water from aqueous magnesium sulfate .................. [1]

(c) glycine from a mixture of the amino acids, glycine and lysine ................... [1]

(d) iron filings from a mixture of iron filings and water .................. [1]

(e) zinc sulfate crystals from aqueous zinc sulfate .................. [1]

(f) hexane from a mixture of the liquids, hexane and octane .................. [1]

[Total: 6]

2 Selenium and sulfur are in Group VI. They have similar properties.

(a) One of the main uses of selenium is in photoelectric cells. These cells can change light
into electrical energy.

(i) Name a process which can change light into chemical energy.

....................................................................................................................................

(ii) Name a device which can change chemical energy into electrical energy.

.............................................................................................................................. [2]

(b) The electron distribution of a selenium atom is 2 + 8 + 18 + 6.

(i) Selenium forms an ionic compound with potassium. Draw a diagram which shows
the formula of this ionic compound, the charges on the ions and the arrangement of
the valency electrons around the negative ion.
Use o to represent an electron from an atom of potassium.
Use x to represent an electron from an atom of selenium.

[3]

UCLES 2011 0620/31/M/J/11

 3
For
(ii) Draw a diagram showing the arrangement of the valency electrons in one molecule Examiners
of the covalent compound selenium chloride. Use
Use x to represent an electron from an atom of selenium.
Use o to represent an electron from an atom of chlorine.

[3]

(iii) Predict two differences in the physical properties of these two compounds.

....................................................................................................................................

.............................................................................................................................. [2]

(c) The selenide ion reacts with water.

Se2 + H2O HSe + OH

What type of reagent is the selenide ion in this reaction? Give a reason for your choice.

...........................................................................................................................................

..................................................................................................................................... [3]

[Total: 13]

3 Iron from the blast furnace is impure. It contains about 4 % carbon and 0.5 % silicon. Most
of this impure iron is used to make mild steel, an alloy of iron containing less then 0.25 %
carbon.

(a) A jet of oxygen is blown through the molten iron in the presence of a base, usually
calcium oxide. Explain how the percentage of carbon is reduced and how the silicon is
removed.

...........................................................................................................................................

...........................................................................................................................................

...........................................................................................................................................

..................................................................................................................................... [4]

UCLES 2011 0620/31/M/J/11 [Turn over

 4
For
(b) (i) Why are steel alloys used in preference to iron? Examiners
Use
.............................................................................................................................. [1]

(ii) State a use of the following alloys.

mild steel ...................................................................................................................

stainless steel ...................................................................................................... [2]

(c) Both iron and steel have typical metallic structures - a lattice of positive ions and a sea
of electrons.

(i) Suggest an explanation for why they have high melting points.

....................................................................................................................................

....................................................................................................................................

.............................................................................................................................. [2]

(ii) Explain why, when a force is applied to a piece of steel, it does not break but just
changes its shape.

....................................................................................................................................

.............................................................................................................................. [2]

[Total: 11]

4 A major ore of zinc is zinc blende, ZnS. A by-product of the extraction of zinc from this ore is
sulfur dioxide which is used to make sulfuric acid.

(a) (i) Zinc blende is heated in air. Zinc oxide and sulfur dioxide are formed. Write the
balanced equation for this reaction.

.............................................................................................................................. [2]

(ii) Zinc oxide is reduced to zinc by heating with carbon. Name two other reagents
which could reduce zinc oxide.

.............................................................................................................................. [2]

(iii) The zinc obtained is impure. It is a mixture of metals. Explain how fractional distillation
could separate this mixture.
zinc bp = 908 C, cadmium bp = 765 C, lead bp = 1751 C

....................................................................................................................................

.............................................................................................................................. [2]

UCLES 2011 0620/31/M/J/11

 5
For
(b) Sulfur dioxide is used to make sulfur trioxide in the Contact Process. Examiners
Use
2SO2(g) + O2(g) 2SO3(g)

The forward reaction is exothermic. The conditions used are:

temperature: 450 C
pressure: 2 atmospheres
catalyst: vanadium(V) oxide

Explain, mentioning both position of equilibrium and rate, why these conditions give the
most economic yield.

...........................................................................................................................................

...........................................................................................................................................

...........................................................................................................................................

..................................................................................................................................... [4]

[Total: 10]

5 Hydriodic acid, HI(aq), is a strong acid. Its salts are iodides.

(a) It has the reactions of a typical strong acid. Complete the following equations.

(i) ............Li + ............HI ........................ + ................... [1]

(ii) zinc hydriodic .......................... ..........................

+ + + .........................
carbonate acid .......................... ..........................
[1]

(iii) MgO + ............HI ................... + ................... [1]

(b) Two of the reactions in (a) are acid / base and one is redox. Which one is redox? Explain
your choice.

...........................................................................................................................................

...........................................................................................................................................

..................................................................................................................................... [2]

(c) Describe how you could distinguish between hydriodic, HI(aq), and hydrobromic, HBr(aq)
acids, by bubbling chlorine through these two acids.

result with hydriodic acid ..................................................................................................

result with hydrobromic acid ....................................................................................... [2]

UCLES 2011 0620/31/M/J/11 [Turn over

 6
For
(d) 20.0 cm3 of aqueous sodium hydroxide, 2.00 mol / dm3, was placed in a beaker. The Examiners
temperature of the alkali was measured and 1.0 cm3 portions of hydriodic acid were Use
added. After each addition, the temperature of the mixture was measured. Typical results
are shown on the graph.

temperature

18.0 cm3 volume of

acid added

NaOH(aq) + HI(aq) NaI(aq) + H2O(l)

(i) Explain why the temperature increases rapidly at first then stops increasing.

....................................................................................................................................

.............................................................................................................................. [2]

(ii) Suggest why the temperature drops after the addition of 18.0 cm3 of acid.

.............................................................................................................................. [1]

(iii) In another experiment, it was shown that 15.0 cm3 of the acid neutralised 20.0 cm3 of
aqueous sodium hydroxide, 1.00 mol / dm3. Calculate the concentration of the acid.

....................................................................................................................................

.............................................................................................................................. [2]

[Total: 12]

6 The structural formula of a butanol is given below.

CH3 CH2 CH2 CH2 OH

(a) Butanol can be made from petroleum and also by fermentation.

(i) Describe the chemistry of making butanol from petroleum by the following route.

petroleum butene butanol

....................................................................................................................................

....................................................................................................................................

.............................................................................................................................. [3]

UCLES 2011 0620/31/M/J/11

 7
For
(ii) Explain, in general terms, what is meant by fermentation. Examiners
Use
....................................................................................................................................

....................................................................................................................................

....................................................................................................................................

.............................................................................................................................. [3]

(b) Butanol can be oxidised to a carboxylic acid by heating with acidified potassium
manganate(VII). Give the name and structural formula of the carboxylic acid.

name ........................................................................................................................... [1]

structural formula

[1]

(c) Butanol reacts with ethanoic acid to form a liquid, X, which has the sweet smell of
bananas. Its empirical formula is C3H6O and its Mr is 116.

(i) What type of compound is liquid X?

.............................................................................................................................. [1]

(ii) Give the molecular formula of liquid X.

.............................................................................................................................. [1]

(iii) Draw the structural formula of X. Show all the individual bonds.

[2]

[Total: 12]

UCLES 2011 0620/31/M/J/11 [Turn over

 8
For
7 Excess hydrochloric acid was added to powdered zinc. The hydrogen evolved was collected Examiners
and its volume measured every 20 seconds. Use

The experiments were repeated at the same temperature using the same number of moles
of powdered magnesium and aluminium.

metal B

metal A
volume of
hydrogen
metal C

time

(a) Identify metals A, B and C by choosing from zinc, magnesium and aluminium. Give a
reason for each choice.

metal A .............................................................................................................................

...........................................................................................................................................

metal B .............................................................................................................................

...........................................................................................................................................

metal C .............................................................................................................................

..................................................................................................................................... [5]

(b) Using moles, explain why two of the metals form the same volume of hydrogen but the
third metal forms a larger volume.

...........................................................................................................................................

...........................................................................................................................................

..................................................................................................................................... [3]

[Total: 8]

UCLES 2011 0620/31/M/J/11

 9
For
8 There are two types of polymerisation - addition and condensation. Examiners
Use
(a) Explain the difference between them.

...........................................................................................................................................

...........................................................................................................................................

..................................................................................................................................... [2]

(b) Poly(dichloroethene) is used to package food. Draw its structure. The structural formula
of dichloroethene is shown below.

H Cl

C C

H Cl

[2]

(c) The polymer known as PVA is used in paints and adhesives. Its structural formula is
shown below.

CH2 CH CH2 CH

OOCCH3 OOCCH3

Deduce the structural formula of its monomer.

[1]

UCLES 2011 0620/31/M/J/11 [Turn over

 10
For
(d) A condensation polymer can be made from the following monomers. Examiners
Use
HOOC(CH2)4COOH and H2N(CH2)6NH2

Draw the structural formula of this polymer.

[3]

[Total: 8]

UCLES 2011 0620/31/M/J/11

 11

BLANK PAGE

UCLES 2011 0620/31/M/J/11

 UCLES 2011
DATA SHEET
The Periodic Table of the Elements
Group
I II III IV V VI VII 0
1 4
H He
Hydrogen Helium
1 2

7 9 11 12 14 16 19 20
Li Be B C N O F Ne
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
3 4 5 6 7 8 9 10

23 24 27 28 31 32 35.5 40
Na Mg Al Si P S Cl Ar
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
11 12 13 14 15 16 17 18

39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84

K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

publisher will be pleased to make amends at the earliest possible opportunity.

Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
12

85 88 89 91 93 96 101 103 106 108 112 115 119 122 128 127 131

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe

0620/31/M/J/11
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

133 137 139 178 181 184 186 190 192 195 197 201 204 207 209

Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Caesium Barium Lanthanum Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
55 56 57 * 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86

226 227
Fr Ra Ac

Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
Francium Radium Actinium
87 88 89

140 141 144 150 152 157 159 162 165 167 169 173 175
*58-71 Lanthanoid series
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
90-103 Actinoid series Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium
58 59 60 61 62 63 64 65 66 67 68 69 70 71
a a = relative atomic mass 232 238
Key X X = atomic symbol Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium
b b = proton (atomic) number 90 91 92 93 94 95 96 97 98 99 100 101 102 103

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).

University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included the
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every