/

HAL.L.IBURTON

MATERIAL SAFETY DATA SHEET

Product Trade Name: ALDACIDE G ANTIMICROBIAL
Relllslon Date: 14-May-2008
1. IOENTIF ICATION OF THE SUBSTANCE/PREPARATION ANO OF THE
1 COMPANY/UNOERTAKING
--- -

Slatement of Hazardous Natura Hazardous according to criteria or WorkSafe

ManufacturerlSuppller Halliburton Australia Pty Ud .

53-55 Bannis1er Road
Canning Vale
WA6155
Australia

ACN Number: 009 000 775

Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300

Product Emergency Telephone

Australia : 08-64244950
Papua New Guinea: 051281 5755000
NewZealand: 06-7559274

Fire, Pollee & Ambulance - Emergency Telephone

Australia : 000
Papua New Guinea: 000
New Zealand: 111

Idcntification of Substances or Preparatlon

Product Trade Name: ALDACIDE , ~' G ANTIMICROBIAL

Synonyms: None
Chcmlcal Famlly: Aldehyde
UN Number: None
Dangerous Goods Class; None
Subsldlary Risk : None
Hazchem Code : None
Polsons Schedule: S6
Appllcation: Biocide

Prepared By Chem ical Compliance

Telephone : 1-580-251-4335
e-mail : rdunexchem@halliburton .com

[2. COIYIPQSITIO~IINFORMAT I ON ON INGREDIENTS

SUBSTANCE CAS Numbcr PERCENT Australia NOHSC ACGIH TLVTWA

p lul araldehyde - ----r11~11 .jO~ 8 = '---l TIF 30% - . .1 ppm n. - - A..9~ PLCPmC---_.__ _
ALDACIDE G ANTIMICROBIAL
Pago 1 016
 Total to 100%

. HAZARDS IDENTIFICATION
Huard Overvllw Keep out o, reach of chlldren. May cause eye buma. May cause Irreversible eye
damage. May cause severe ski n Irritaton. May be hannful If 8wallowed. May be
harmfullf Inhaled. May cause allertlic skln reacllon.
Hazard Rltlngs
Flammablllty: o
Toxlclty: 2
lody Contact: 3
Rctlvlty: O
Chronlc: 2

Seal.: MlnJNII=O Low-1 Moderate-2 Hlgh=3 Extrem.=4

k. FIRST AIO MEASURES

Inhalltlon If inhaled, remove from area to fresh alr. Get medical attenlion If resptratory Irritatlon
develops or If brealhing becomes dlfftcult.
Skln In case of contaet, Immediately f1ush skln wlth plenty of soap and water for at least 15
minutes. Gel medlcal aHenlion,
Ey.. Immedlately f1ush eyes wlth large amounts of water for al least 30 minutes. Seek
prompt medlcal aHentlon.
In9..tlon Do NOT induce vomiling. Give nOlhlng by mouth. Oblain Immedlate medicar
attention.
Notla to Physlclan Probable mucosal damage may contralndlcate the use of gastrlc lavage.

15. FIRE FIGHTING MEASURES

Sultable Extlngulahlng Media Water fog, carbon dloxlde, foam, dry chemlcal.
Unsullabla Extlngulshlng Media None known.
Spaclal Exposure Haz.rds Decomposltlon In ftre may produce toxie gases.
Speclal Protectlvl Equlpment lar Full protective do1hing and approved self-containad brealhlng apparatus required for
FlreFlght.rs tire f1ghllng personnel.

16. ACCIDENTAL REL.EASE MEASURES

Peraonal Precautlonary M.asures Use approprlate protecllve equlpmant. Use only competent persons for eleanup.
Envlronmental Praeaullonary Prevent from enlerfng sewers, walerways, or low areas.
Mealures
Procedura for Claanlng I Isolate spill Bnd stop laak whare safe. Contain spill wtth aand or other n8rt materals.
Absorptlon Scoop up and remove.

W. HANDLING ANO STORAGE

Handling Precautlons Avold contael wlth eyes, skln, or clothlng. Avold breathlng vapors. Do not swallow.
Wash hands after use. Launder contaminated clolhlng befare reuse.
AL.DACIDES G ANTIMICROSIAL
PIge 2 0111
Storage Informatlon Stora away from aeids. Slore 8Way from alkalls. Keep container closed when nol In
use. Product has a ahelf lite of 12 months.
\8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Englneerlng Control. Use in a well ventllated area. Local exhausl ventlJatlon should be used In ereas
wilhout good cross venlilatlon. If vapora are strong enough lo be irrltating to the
nose or eyes, the TLV la probably belng exceeded and speclal ventllation or
resplratory protecUon maybe requlred.
R.splratory Protectlon Full Faceplece Respirator wlth Organic vapor cartridge with partlculate prefilter.
Hand Protecllon Nltrile gloves. Butyl rubber gloves.
Skln Protactlon ButyI costad apron or clothlng.

EYI Protectlon Splashproof chemical monogoggles or safety glasses wllh slde shlelds In conjuncllon
with a faca shleld. Do NOT wear contact tenses.
Other Precaut!ons Eyewash fountalns and safety showel'S mus! be easlly accessible.

j. PHYSICAL ANO CHEMICAL PROPERTIES

Physleal Stata: Llquld

Color: Transparent
Odor: Sharp
pH: 3.1-4.5
SpeclfJc Gravlty@ 20 C (Wat.,.1): 1.064
e
Denllty 11 20 (kg/l): 1.064
Bulk Dln.lty @ 20 C (kQlm'): Not Determinad
Bolllng Polnl/Rangl (C): 100.5
Freezlng Polnl/Ranga (C): -10
Pour PolntIRange (e): Not Determinad
Flash Poi nI/Ranga (e): Not Determined
Flash Polnt Mathod: Not Oetermlned
Autolgnltlon Temperature (C) : Not Oeterminad
Flammablllty LImita In Alr Lower (g/m'): Not Determined
Flammablllty LImita In Alr - Lower (%): Not Determined
FlammabJlIty Llmlt. In Alr Upper (glm'): Not Determlned
Fllmmablllty LImita In Alr Upper ('lo): Not Determlned
Vapor Preasure @ 20 C (mmHg): 0.2
Vapor Oenllty (AIr=1): 0.8
Pereent Vol.tll..: 100
Evaporatlon Rate (Butyl Acetata=1): 0.9
Solublllty In Watar (g/100ml): Soluble
Solublllty In Solventa (g/100ml): No! Determlned
VOCa(g/I}: Not Determlned
Vlscoalty, Dynamlc O 20 C (elntlpolse): Not Determlned
e
Vlscos!ty, Klnemallc @ 20 (eentlatrokes): Not Determined
Partltlon CoefflcJenl/n-OctanoJlWatar: -0.333
Molecular Welght (g/mol.): Not Determinad
O.composlllon Temperatura (C): Not Determlned

110. STABILlTY ANO REACTIVITY

Stablllty Data: Stable
Hazardoul Polymertzatlon: Will Not Occur

ALDACIDE~ o AHTIMICROBIAL
'1IIe:l orl
Condltlon. to Avold Avold temperaturas greater than 100 F (38 C).
Incompltlbltlty (Mltarlal. to Strong aclds. Strong alkalls.
Avold)
Hazardous Decompo.ltlon Carbon monolCide and calbon dioxide.
Products
Addlllonal GuldelJne. Not Appllcable

111. TOXICOLOGICAL INFORMATION

Principie Route of Expo.ura Eye or skin contact, Inhalatlon.
Inhalltlon Harmfullf Inhalad. Causes severa resplratory IrrI1alion. Vapors glvan off by healad
product may ba harmful. May cause allarglc respiratory reaotion. Inhalallon of vapors
may result In skln senaHlzallon.
Skln Contact May cause skln IrtitaUon. May cause skin bums on prolongad contacto Harmfullf
absorbed Ihrough Ihe skln. Prolongad or widespread contact may result in the
absorption of polentlally harmful amounts of malertal. Thls product containa
Ingredlents whlch may produce en allerglc skln reaction. It should be treated as e
skln sensHizer.
Eye Contact May cause eye bums. May cause parmanent eya damage. Hlgh vapor concenlrallon
wlll cause IrrHallon.
Ingeltlon Causes bums of the mouth, Ihroel and stomach. Harmful if swallowad. Asplratlon
Into Ihe lungs may cause chamlcal pneumonltls Includlng coughlng, difflculty
brealhlng, wheezlng, coughlng up blood and pneumonla. whlch can be fatal.
Aggrlvlted Medlcal Condltlon. Skin disorder&. Lung dlsorders. Uver dlsorders.
Chronlc EffectllCarclnogenlclty No data availabla lo Indlcate product or components present al greater !han 1% are
chronic health hazards.
Other In'ormatlon None known.
Toxlclly Tests

Oral Toxlclty: LOSO: 1639-1990 mgJkg (Rat)

Dermll Toxlclty: L050: > 2000 mg/kg (Rabblt)
Inh.l.tlon Toxlclty: LCSO: 480 mg/m3 (5000 ppm) 4hour (ral)
Prlmary Irritatlon Effect: Not determinad
Carclnogenlclty Not detennlned
Ganotoxlclty: Not determinad
Reproductiva I Not determlned
Dlvelopmlntal Toxlclty:

112. ECOLOGICAL INFORMATION

Moblllly (Water/Soll'AIr) No! detarmlned
Perslstence/Degradablllty ReadHy blodegradable

ALDACIDE~ o ANnMICROlIlAL
'111'" 0'8
Blo-accumulaUon Not Determine<!

Ecotoxicologlcallnformatlon
Acute Flsh Toxlclty: May be highly toxlc to aquello tlfe.
Acute Cru.tacean. Toxlclty:TLM48: 0.11 mgll (Acartla tonsa)
Acute A1g Toxlelty: EC50: 8.1 mgJI (Skeletonema costatum)
Chemleal Fatt Inform.tlon Not determined
Other Informatlon Not appllcable

H3. DISPOSAL CONSIDERATIONS

DI.posal Method Disposal should be mada In Bcconlance wlth federal, state, and local regulatlons.
Contamlnatld Packaglng Followall appllcable natlonal or local regulallons.

114. TRANSPORT INFORMATION

Land Transportation
AOR Not restricted by surface modes.

Alr Transportation
ICAOnATA Not restricted by 8urface modes.
UN3334. Aviation Regulated Uquld, N.O.S (Contains Glutaraldehyde), 9

Saa Transportation
1M DO Not restrlcted by surface modes.

Othlr Shlpplng Information

EPG: Not determlned
IERO: Not determlned
Lab.la: None

115. REGULATORY INFORMATION

Chemlcallnventorles

Australlan AICS Inventory Not Delennined

US TSCA Invlntory AII components IIsted on Inventory.
EINECS Inventory Thls product, and 811 ils components, compiles wlth EINECS

CI lfleatlon C Corroslve.

Rlsk Phrase. R34 Causes bums.

R20/22 Hannful by Inhalation and ir swaUowed.
R42J43 May cause sensltlzallon by inhalation and skin contad

ALDACIDEe G ANTIMICROIlIAL
Page. ofll
Safety Phra S23 00 nol breathe gas, fumes, vapour or spray.
S26 In case of conlact with ayas, rlnaa immedlately with plenty of water and seek
medlcal advice.
545 In case of accidenl or If you feel unwell, seek medica! advice Immedlately.
S1/2 Keep klcked up and out of reach of children.
S36/37/39 Wear sultable protectlve clolhlng, gloves end eyefface protectlon.

116. OTHER INFORMATION

The followlng .aetlon. hava be.n revlsed Ilnca the l.,. IlIua of thl. MSDS
Not IppUcable

Contact
Australlan Pollons Informatlon Centre
24 Hour Servlee: - 13 11 26
Pollee or Fire Brigada: - 000 (exchange): 1100

Naw Zelland Polaons Infonnatlon System

Deunedln: -(03) 4791200 (Normal Hours)
-(03) 474 0999 (Emergency)

Addltlonallnformatlon For addltional informaUon on the use of thls product, contact your local Halliburton
representatlve.

For questlons about the Material Safety Data Sheet for thls or other Halllburlon
products, contact Chemlcal Compllance al 1-580251-4335.

Dllclalmer Statement Thls Informal/on is fumlshed wlthout warranty, expressed or Implied, as to accuracy
or complaleness. The Infonnation Is obtalned from vartous sourees Including the
manufacturar and olher Ihlrd party aources. The Informal/on may nol be valld under
all conditions nor If Ihls material Is used in comblnatlon wllh olher meleriars or In sny
process. FInal determlnatlon of sultabillty of sny matertalls the sole responslblllty of
the user.
--END OF MSDS-

ALDACIDES ca ANTIMICROIIIAL
Pace lofl
 z

H A LLISURTON

MATERIAL SAFETY DATA SHEET

Product Trade Name: AQUAGEl GOlO SEAL
Revlsion Date: 02-Jan-2007
~ IDENTIFICATION OF THE SUBSTANCEIPRE PARATION ANO OF THE
[ -COMPANY/U
- - NOERTAKING ._- --
Statement of Hazardous Nature Hazardous according lo critera of WorkSafe

ManufacturerlSupplier Halliburlon/Baroid Australia Pty . Ud.

53-55 Bannister Road
Canning Vale
WA6155
Austra lia

ACN Number: 009 000 775

Telephane Number: 61 (08) 9455 8300
Fax Number: 61 (08) 94555300

Product Emergeney Telephone

Australia: 08-64244950
Papua New Guinea : 05 1 281 5755000
New Zealand: 06-7559274

Fire, Pollee & Ambulanee - Emergeney Telephone

Australia : 000
Papua New Guinea: 000
New Zealand : 111

Idenllflcation of Substances or Preparatlon

Produet Trade Name: AQUAGEL;. GOlD SEAL

Synonyms: None
Chemlcal Family: Mineral
UN Number: None
Dangerous Goods Class: None
Subsldlary Risk: Nane
Hazchem Code: None
Poisons Schedule: Nane
Application: Viscosifter

Prepared By Chemical Camplianee

Telephone : 1-580-251 -4335

PERCENT Australl NQHSC ACGIH TLV-TWA

_JQ ~
iyu ~ 1 ~J1/rn' !O.025 .!!!9/rri ~

AQUAGEL GOL O SEAL

Pago 1 of 7
2. COMPOSITION/INFORMATION ON INGREDIENTS
prystaHlne allles, tridymlte 15468-32-3 0-1% 0.1 mglm3 ~ .05mg/m)

Cryatalllne a!lles, quar1z 14808-6()'7 1 - 5% 0.1 mg/m3 :0.025 mg/m3

Benlonlle 1302-78-9 60 -100% 1II0t determinad !Not aDPlicable

Tolallo 100%

13. HAZA ROS IOENTIFICATION

Hazard Overvlew CAUTIONI - ACUrE HEALTH HAZARD

May cause eye and resplratory imlallon.

OANGERI CHRONIC HEALTH HAZARD

Breathlng crystaUlne slnca can cause Iung dlseasa, Includlng silicosis and lung
caneer. Crystalllne slllea has also been aasociated with sclerod8rma and kidnay
dlsease.

Thls product contalns quartz, cristobali!e, andlor trlclymlte whlch may become
alrbome wlthout a visible cloud. Avold breathlng dusl Avo/eI Cfeating dusty
condltlons. Use only wlth adequate ventUatlon to keep exposurea below
recommended expolure IImlts. Wear a NIOSH eertlfied, European Standard EN
149, or equivalen! resplrator when using Ihls producl. Revlew the Malerlal Safety
Data Sheet (MSDS) for thla product, whlch has been provlded to your employer.
Hazard Ratlngs
Flammablllty: o
Toxlelty: O
Body ContaGt: O
Reacllvlty: O
Chronlc: 4

Scale: MlnlNllaO Low a 1 Moderal8 m2 Hlgh=3 Extrame=4

k. FIRST AIO MEASURES

Inhalatlon If Inhaled, remove fmm area to fresh alr. Gel medlcal sltention If resplratory irritation
develops or If breathlng becomes difficult.
Sk'n Wash wlth soap and water. Get medlcal attentlon H Imtation persists.
Eye. In case ot contact, immedlately flush eyes with plenty of water for at leasl15 minutes
and get medlcal altentlon if Irrltation perslsts.
Ingtlon Under normal condltlons, flrat ald procedures are not required.
Note. lo PhYllclan Tres! symptomatlcally.

. FIRE FIGHTING MEASURES

Sultable Extlngulshlng Media AlI standard flre IIghtlng media

UnluJlable Extlngullhlng Media None known.
Spee'al Expo.ure Hazard. Nol appllcable.
Spee'.1 Protectlv8 Equlpment for Nol appllcable.
Flre-Flghtara

AQUAGELe GOL.D SEAL

Palla 2 ot7
i. ACCIDENTAL RELEASE MEASURES

Personal Pracaullonlry Mlllur... Use approprlale prolecllve equlpmlnt. Avold creallng and brealhlng dust.
Envlronmental Precautlonary None known.
Mealurel
Procedur. for Claanlngl Collect uslng dusUeas melhod and ho/d for appropriate disposal. Conslder posslble
Abaorptlon tolde or flre hazards associated with contamlnatfng substancea and use appropriate
melhods for col/eellon. storage and d/sposal.

17. HANDLING ANO STORAGE

Handling Prlclutlona Thls product contalns quartz, erisloballte. and/or lridymlte whlch may become
a/rbome wfthout a visible cloud. Avo/d brealhlng dusl. Avold creatlng dusty
conditions. Use only wilh adequate venUlalion lo keep exposure below
recommended exposure IImlls. Wear a NIOSH cartinad, European Slandard En 149.
or equlvalent resp/ralor when us/ng th/s preducl. Materia//s s/ippery when wet.
Storage Informallon Use goOO housekeeplng /n atorage and work areas to prevent acaJmu/ation of dusl.
Close container when not in use. 00 not reuse .mpty container. Product has a she/f
IIfe of 24 months.

lB. EXPOSURE CONTROLS/PERSONAL PROTECTION

Eng/neerlng Controla Use approved industrial venlilatlon and local exhaust as requ/red lo ma/ntaln
exposures below appllcable exposur. IImlts IIsted in Section 2.
R.aplratory Prot.elIon Wear a NIOSH certlfled, European Standard EN 149, or equivalent respirator when
uslng thls produe!.

Hand Prolactlon Normal work glovas.

Skln Protactlon Wear clothlng appropriate for the work envlronmenl. Dusty clelhing should be
laundered befere reuse. Use precautlonary measures te avo/d creating dust when
removlng or launderlng clolhlng.
Eye Prol.ctlon Wear safety glaases er goggles to proteel agalnst Qxposure.
Olher Precaullons None known.

19. PHYSICAL ANO CHEMICAL PROPERTIES

Phy.IClI Stat.: Powder

Color: Tan
Odor: Mlld earthy
pH: 8-10
Speclflc Gravlty@20C (Watar=1): 2.6
Oanllty @ 20 C (kgll): Not Determlned
Bulk D.nelty O 20 C (ka/mi): Not Determinad
Solllng PolntlRang. (C): Not Determlned
Freazlng PolntlRange (C): Not Determlned
Pour POlntlRanga (C): Not Determlned
Flash PolntlRanga (e): Not Determinad
Flash Polnt Mathod: Not Determlned
Autolgnltlon Temperalur. (e): Not Determined
Flammlblllty L/mi'" In Alr Lower (g/mI): Not Delermlned
AQUAGELGI GOLD SEAI.
Page 3017
j. PHYSICAL ANO CHEMICAL PROPERT1ES
Fllmmlblllty Limita In Alr - Low.r (%): Not Detenninad
Flammlblllty Limita In Alr - Upp.r (g1m J ): Not Detennined
Flammablllty Llmlts In Alr - Upper (%): Not Determinad
Vapor Prallura 020 C (mmHg): Not Determinad
Vapor Denslty (AIr-1): Not Determined
Parc.nt Volatll.. : Not Datermlned
EVlporatlon Rat. (Butyl Acetate=1): Not Detennln.d
Solublllty In Water (g/100ml): Insoluble
Solublllty In Solventa (g/100ml): Not Determinad
vaCa (gIl): No! Determinad
VIICOllty, Dynlmle @ 20 C (c.nUpols.): Not Determlned
V1scoalty, Klnematlc G 20 C (centlstrokes): Not Delennlned
Partltlon COlfflclentlnoOctanol/Water: Not Determinad
Molecular WIlght (gImo le): Not Determined
DlcampOlltlon Tamp.,.ture (e): Nol Determlned

110. STABILITY ANO REACTIVITY

Stab/llty Data: Stable

Hazardous POlymerlzatlon: WIU Not Occur

Condltlanl lo Avold None antlclpated

Incompatlblllty (Materlala to Hvdrofluoric aeid.

Avold)

Hazardoul O.composlllon Amorphous silica may transform at elevated temperaturas to tridymlte (870 C) or
Products cristoballta (1470 C).

Addltlanal Guldelln'l NOI Appllcable

111. TOXICOLOGICAL INFORMATION

Principie Rauta of Expalure Eye or skln contact, Inhalatlon.

Inhalatlon Inhaled crystallina slllca In the form of quartz or cristobalite from occupaOonal
sourcea la carclnogenlc lo humans (IARC. Group 1). There iB sufficient evldence In
experimental anlmals for tha carclnogenlclty of tridymlte (IARC. Group 2A).

Brealhlng sllles dusl may cause IrritaUon of Ihe nose, Ihroal, and resplratory
passeges. Breathlng slliea dusl may not cause nollceable InJury or IIIness aven
o,
though permanent lung damaga may be occurring. Inhalatlon dust may 8160 have
sarlous chronic heallh effecls (See "Chronlc EffectslCarclnogenlclty- aubsectlon
below).

Skln Contaet May cause mechanlcal skln Irritatlon.

Eye Conblct May cause eye irritallon.

Ing Uon None known

Aggravatad M.dle.1 Condlllons Individuals with resplralory dlsease, including but notlimlted lo asthma and
bronchitla, or subJect to aye IrrltaUon, should not be exposed to quara dusl.

AQUAGELe GOLD SEAL

PIDI40fT
Chronlc Effects/Clrclnogenlclty Silicosis: Excesslve Inhalation of respirable crystalllne slllea dust may cause a
progresslve, dlsabling, and somelimesfatallung distase called silicosIs. $ymptoms
In elude cough. shortness o, brealh. wheezlng. nonspecific chest IlIness. and
redueed pulmonary runctJon . Thls dlsesse la exacerbated by smoking. Indlvlduals
wllh silicosis are predlsposed lo develop tuberculosis.

Cancer Status: The Inlernatlonal Ageney for Research on Caneer (IARC) has
determlned \hat cryslalllne slllca inhaled In Ihe form 01 quartz or Cllsloballte ftom
occ:upatlonal sources can cause lung caneer In humans (GtoUP 1 carclnogenlc lo
human s) and has determinad Ihat there Is sufflelenl evldence In experimental
anlmals for Ihe carclnogenlclty of trldymlte (Group 2A posslble eare/nogen to
humans). Refer lo !ABC Monogtapb 68 SIIICI, Soma SlIIcales and Organlc Fibras
(June 1997) in conjunetlon wi1h Ihe use of !hese minerals. lhe National Toxlcology
Ptogram cJassifies respirable crystalllne sUlea as -Known lo be a human carclnogen".
Refer to Ihe 9th Repon on Csrelnogens (2000). The American Conferenee of
Govemmentallndus!"el Hyglenlsls (ACGIH) classlnes crystalllne sltlca. quartz. as a
suspected human esrclnogen (A2).

lhere Is some evldence that brea\hlng respirable crystalllne slSca or !he disease
silicosis la assoclaled wI!h an Incteasad Incldence of slgnlficant disease endpolnts
auch as scleroderma (an immune system disorder manlfested by scamng of Ihe
lungs, skln. and olher Intemal organa) and kIdney dlsease.

Other In'ormltlon For further Informallon consult "Adversa Effects of CrystalJine SlIIca Exposure"
publlshed by the American Thoraclc Soclety Medlcal Section of Ibe American Lung
Associalion, American Joumal of Resplratory and Critlcal Care Medicine. Volume
155, pages 761768 (1997).
Toxlclty Tests

Ora' Toxlclty: Not determinad

Oannal Toxlclty: Not delermlned
Inhllallon Toxlclty: Not determinad
Prlmary Irrltatlon Effect: Nol determInad
Carclnouenlclty Refer to IARC MonQgraph 68, SlI!ca. Sorne SIIiCites Bnd Organlc Fibres (June
1997).
Ganotoxlclty: Not determInad
Reproductlve I Nol determinad
Developmental Toxlclty:

112, ECOLOGICAL INFORMATION

Moblllty (Water/SoIUAlr) No! determined

PerslstenceJDegradabll1ty Not determlned

Blo..ccumulatlon Not Determlned

Ecotoxicologicallnformatlon
Acute Flsh Toxlclty: Not determined
Acute Cruatlcaans Toxlclty:Not determlned
Acuta Alu.a Toxlclty: Not determlned
AQUAGELGD GOLO lEAl.
Pla' 50f7
Ch,mleal Fati Informatlon Not determlned
Other Informatlon Not appllcable

\13. DISPOSAL CONSIDERATIONS

DI.posll Mathod Bury In a l\censad landflll accordlng to federal, atete, and local regulatlons.
Contamlnated Paeklglng Follow all applicable nallonal or local regulations.

"4. TRANSPORT INFORMATION

Land Transportatlon
ADR Not restrlcted

Alr Transportation
ICAOIlATA Not reslticled

Saa Transportatlon
IMDG NoI restricted

Other Shipping 'nformation

EPG: Not determinad
IERG: . Not determlned
Labela: None

ijs. REGULATORY INFORMATION

Chemleallnvantorta.

Auttrallan AICS Invantory Not Oe1ermlned

US TSCA Inventory A11 components IIsled on Inventory.
ElNECS Inventory This producto and alllts componenls. compiles wlth EINECS

Cla..meatlon Crystalllne .lIIea la nol claaslfled as a carcinogen In EU Councll Directivas

67/5481EEC and 88/379/EEC.

RI.k Phr None

Safaty Phra.e. None

h6. OTHER INFORMATION

The followlng cllona haV8 baen revisad slnca the Isat ISSUB of Ihls MSDS
Not appllcabl.

AQUAOI!L. GOLD lEAL

Pille. o, 7
Contact
AUltrlllan Pollons Infonnatlon Centre
24 Haur Sarvlce: - 13 11 26
Pollee or Flre Brigade: - 000 (exchange): - 1100

Nlw Z.aland Pollonl Infarmatlan Syatem

Oeunldln: -(03) 4791200 (Normal Hours)
-(03) 474 0999 (Emergency)

AddlUonallnfonnatlon For addltlonallnformalion on tIle use of thls product, contact your local Halllburton
representativa.

For quesUons about the Material Safety Dala Sheet for thls or otller Halliburton
products, contact Chemlcal CompUance at 1-580-251-4335.

Dllclllmer Statement This informatlon is fumished wlthout warranty, eICpressed or Irnplled, as lo accuracy
or completeness. The informellon is obtalned from various sources Includlng tIle
manufacturer and other Ihlrd party sourees. The Infarmallan may nol be valld under
aH condtlons nor if this materialls used In combinatJon wllh olher materlals or In any
process. Final determlnation o, suitability o, any material is the sole responslbility of
tha user.
-END OF MSDS'"

AQUAOELGD OOLD SEAL

Pall. 7 ar7
 3

HALLIBURTON

MATERIAL SAFETY DATA SHEET

Product Trade Name: BARAZAN o PLUS
Revlsion Date: 03-Jan-2008
1. IDENTIFicATION OF THE SUBSTANCE/PREPARATION ANO OF THE
1 ~Q~PANY'UNOERTAK I N G . . _ .

Statement of Hazardous Natura Not classified as hazardous according lo criteria of WorkSafe

ManufacturerlSuppller HalliburtonlBaroid Australia Ply. Ud

53-55 Bannisler Road
Canning Vale
WA 6155
Australia

ACN Number: 009 000 775

Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300

Product Emergency Telephono

Australia: 08-64244950
Papua New Guinea: 05 1 281 5755000
New Zealand : 06-7559274

Fire, Police & Ambulance Emorgency Telephone

Auslralia 000
Papua New Guinea : 000
New Zealand: 111

Identfication of Substances or Preparation

Product Trade Name: BARAZAN , ~ D PLUS

Synonyms: None
Chcmlcal Famlly: Polysaccharide
UN Number: None
Dangerous Goods Class: None
Subsldlary Risk: None
Hazchem Code: None
Polsons Schedule: None
Appllcatlon: Viscosifier

Prepared By Chemical Compliance

Telephone : 1-580-251-4335
e-mail: fdunexchem@hallibur1on com

~. C~POS-ITIO-N!fNFRJIJ!ATION Qt'! lliGREDIENTS

SUBSTANCE CAS Numbcr Australia NOHSC ACGIH TLV-TWA
Jx,lI1lh;n 9"m !11138 -66 -2 'Nut aJ1pIi GlUI~ 110 rll9'tn . ---

BARAZANoX O PLUS
Pago 1 016
 Total to 100%

13. HAZARDS IDENTIFICATION

Hazard Overvlew May cause aya Irritallon. Alrbome dust may be explosiva.
Hazard Ratlngs
Flammablllty: 1
Toxlclty: O
Body Contaet: 1
Rctlvlty: O
Chronlc: O

Seala: Mln/NII=O Low"1 Modarate=2 Hlgh=3 Extrem.=4

&. FIRST AIO MEASURES

Inhalltlon IIlnhaled, remove from araa to fresh airo Gel medical attenllon if respiralory Irritatlon
develops or If brealhing becomes diffiC\.lIt.
Skln Wash wlth soap and water. Get medlcal attention If irritaton perslsts.
Eyes In case of contact, Immedlately flush ayas wlth plenty of water far al least 15 minutes
and gel medical attenton if Irrltatlon perslsts.
Ingestlon Under normal condltions, first ald procedures are not requlred.
Not to Phyllclan Not Applicabla

IS. FIRE FIGHTING MEASURES

Sultable Extlngullhlng Media Water fog, carbon dioxide, foam, dry chamical.
Unlultabla ExtIngulshlng Madla None known.
Speelal Expolure Hazards Decomposition in nre may produce toxle gases. Organie dust In lhe presence of an
IgnlUon souree can ba explosiva In hlgh concenlratlons. Good housekeeping
pracUces are requlred to mlnlmlze thls potenUal.
Speel.1 Prot.etlve Equlpmant for FuI! protective clothlng and approved self-contalned breathlng apparatus requlred for
Flr.-Flghtars lire fightlng personnel.

~. ACCIDENTAL RELEASE MEASURES

Personal Pracautlonlry Me.sures Use approprlate protectlve equlpment. Avoid creatlng and braalhlng dusl.
Envlronmental Precautlonary None known.
Mealuras
Procedure for Cleanlng I Scoop up and remove.
Ablorpllon

W. HANDLING AND STORAGE

Handling Preclutlonl Slippery whan wet. Avold craaling or inhallng dusl.

Storage Infarmallon Store away from oxidlzers. Slore in a cool, dry locatlon. Producl has a shelf life of 6
months.
BARAZAN. D PLUS
P.... 20f.
lB. EXPOSURE CONTROLSIPERSONAL PROTECTION

Englnaarlng Control. Use In a well ventUated area.

Resplratory Protectlon Not nonnally needad. But If slgnlficant axposurea are posslble then the following
resplrator is recommended:
Dustlmlst resplrator. (95%)
Hand Proteetlon Nonnal wor1< gloves.

Skln Prolectlon Nonnal work caveralls.

Eye Prolectlon Wear safety glasses ar gOggl8S lo proleet against exposure.
Other Precaudon. None known.

19. PHYSICAL ANO CHEMICAL PROPERTIES

Phyalcal State: Powder

Color: White lo yellow

Odor: Slighl
pH: 5.5-8.5 (1%)
Speclflc Gravlly@ 20 e (Water=1): 1.6
e
Denllty O 20 (kgll): Not Determlned
Bulk Oln,ley @ 20 C (kg/m'): Not Determinad
BoUlng PolntlRanga (e): Not Determlned
Freezlng PolntlRange (e): Not Determinad
Pour PolntlRanga (C): Not Determinad
Fla.h PolntlRanga (e): Not Detarmlnad
Fla,h Polnt Mlthod: No! Determlned
Au!olgnltlon Temperatura (C): 204
Flammablllly Llmlt. In Alr Lower (g/m'): No! Determinad
Flammablllly Limita In Alr Lower ('''): Not Determlned
Flammablllly Limita In Alr Upper (g/m'): Not Determined
Flammablllty Llmlts In Alr Upper (%): Not Determined
Vapor Pressure @ 20 e (mmHg): No! Determined
Vapor Denally (AIr-1): Not Determinad
Parcent Volatlle.: Not Determined
Evaporatlon Rate (Butyl Acetate=1): Not Determinad
So'ublllly In Water (g/100m'): Soluble
Solublllly In Solventl (g/100ml): No! Determinad
VOCa (gil): No! Determlned
e
Vlscoslly, Dynamlc G 20 (centlpolse): Not Oetermlned
Vlscoslty, Klnematlc @20 C (cantlstrokes): Not Determinad
Partltlon eoafftclentln.(JclanollWater: Not Determlned
Molecular Welght (g/mole): 1,000.000
Decompolltlon Temperature (e): No! Determined

110. STABILITY ANO REACTIVITY

Stablllty Data: Stable
Huardoul Polyrnerlzatlon: Will No! Oceur

Condltlon. to Avold Keep away from heat, sparks and Oame.

Incompatiblllty (Materlals to Strong oxidlzers.
Avold)
Hazardou8 Deeomposltlon Camon monoxlde and carbon dloxide.
Products
Addltlonal Guldellnes Not Applicable

111. TOXICOLOGICAL INFORMATION

Principie Route of Expoaure Eye or skln contact, inhalation.
Inhalatlon May impede respiration.
Skln Conteet None known.
Eye Contact May causa ml/d eye Irrltallon.
Ingntlon None known
Aggravated Medlcal Condlllona None known.
Chronlc Effecta/Cerclnogenlclty No data avallable lo indicale product or components presenl al greater than 1% are
chronlc health hazards.
Other Informltlon None known.
Toxlclty Tta

Oral Toxlclty: LOSO: > 5000 mglkg (Rat)

Darmel Toxlclty: Not determlned
Inhalatlon Toxlclty: Not determinad
Prlmery Irrlladon Effect: Nol determlned
Carclnogenlclty Nol determlned
Genotoxlclty: Not determlned
Reproductlve I Nol determinad
Developmentel Toxlclty:

\12. ECOLOGICAL INFORMATION

Moblllty (Water/So lIJAIr) Not determinad

Perslat.nce/Degrldablllty 800(5 Day): 200 mg/g COO: 1600 mglg

Blo-Iccumulltlon Not Determined

Ecotoxicologfcaf Informatlon
Acute Flah Toxlclty: TLM96: 320-560 ppm (Oncorhynchus myklss)
Acute Crustlce.na Toxlclty:TLM96: > 75000 ppm (Mysidopsis bahla)
Acut. Alga. Toxlclty: Not determinad
ehemlca' Fate Intonnatlon Not determined
Olher Informallon Not appllcable

IARAZANa D PLUS
P.ge 40'6
113. DISPOSAL CONSIDERATIONS
Dlspol.1 Method 8ury In a llcensed landflll eccordlng 10 federal, state. and local regulallons.
Contamlnated Packaglng Follow all appllcable natlonal or local regulations.

114. TRANSPORT INFORMATION

Land Transportatlon
ADR Not raslrlelad

Air Transportatlon
ICAOI/ATA Not restrlctad

Sea Transportation
IMDG Not restrleted

Other Shlpplng Informatlon

EPG: Nol detarmlned
IERG: Not determlned
Llb.'a: None

115. REGULATORY INFORMATION

ChemlcallnYlntorles

Austranan AICS Inyentory Not Datermlned

US TSCA Inventory AlI eomponents IIsted on inventory.
EINECS Invlntory This produet, and alllts components, complies wlth EINECS

Cla&slflcatlo n Not Classlfied

Rlsk Phrases None

Salaty Phra188 None

116. OTHER INFORMATION

The followlng secllons hay. been revisad slnca the last Issua of thls MSDS
Not appllcable

Contact
Australlan Polsons Inlonnatlon Centra
24 Hour Sarvice: - 13 11 26
Pollee or Are Brigada: - 000 (exchange): - 1100

New Zealand Polsons Informatlon Systam

Deunedin: -(03) 4791200 (Normal Hours)
-(03) 4740999 (Emergency)

BARAZANIID D PLUS
Pille 50,e
Addltlonallnformatlon For addllionallnformatlon on the use of thls product, conlact your local Halllburton
representative.

For questlons about tha Material Safety Data Sheet for thls or other Hllllburton
products. contact Chemlcal CompHance al 1-580-251-4335.

Dlsel.lmer Statement This Information 16 fumlshed wlthout warranty, expressed or Implied, as to accuracy
or completeness. The nformallon Is obtalned (rom various sourees Including the
manufacturer and olher third party sourees. The informatlon may nol be valld under
all conditlons nor Ir lhls material la used In oomblnation wlth other malerlals or in any
proceas. Final delermlnatlon of sultablllty o, any materlalls Ihe sole responsiblllty of
the user.
-END OF MSOS....

BARAZANGP D PLUS
P."., ."a
'

: -~ .

BA~\OI
.' -< .

,1," ,

MATERIAL SAFETY DATA SHEET

BAROID

Revlslon Date: 06/06/2000

11. CHEMICAL PRODUCT ANO COMPANY IDENTIFICATION

Product Trada Neme: BAROIO

Synonyms: None
Chmlcal Famlly: Mlnaral
Appllcatlon: Welghl Addltlve

ManufacturerlSuppll.r
Barold Drflllng Flulds
Product Servfca Lina of Halllburton Energy Servlces, Inc.
P.O. Box 1615
) Houston, TX n251

Telephone: (281) 871-4000

Emargancy Telephone: (800) 668-9260 or (713) 678-3000
CHEMTREC: (800) 424-9300

Preparad By
Prodlrot Stewardshlp
T.lepllon.: 1-680-251-4335

12. COMPOSITIONnNFORMATION ON INGREOIENTS

ACGIH TLV-TWA CSHA PELTWA
Sub.lance Walghl
p.rcent ('/o)

Barium sulfate 60100% 10 mglm3 15 mglM3

7727-43-7
Cryslalllne alllcs, quertz 1 - 5% 0.05 mglm3 0.1 mgJM3
14808-60-7

13. HAZA ROS IDENTlFICATION

Hazard Ovarvlew
)May cause-delayed injury lo lungs, PolenliBI carclnogen.

BAROIOIi)
Page 1 of7
 1:4=.~F~IR~S~TZA~ID=M~E~A~S:U~R~E~S:====:::=:=:======:======:=====::====:~~.I.)
Inhaladon
l' Inhalad, remove from area to Ireah alr. Get medk:al aHenllo" Ir raaplrafcry irritaDo" develops or Ir brealhlng becomes
dimcull.

Skln
Wash wflh aoap and wa1er. Gel medlcal attenUon If Imtatlon persista.

Eyas
In case of contad, Immedlately nush eyes wlth plenty of water far allelal 15 minutes and gel medica! aHendon If Irritadon
perslsls.

Ing.stlon
00 nol Induce vomltlng. SIoWIy dllute wlth 1-2 glasees o, water or mili< and aaak medlcal attanHon. Naver glva anythlng by
mouth lo an unconsclous persono

Notes lo Phyalclan
Not Appllcabla

15. FIRE FIGHTING MEASURES

Flash PorntJRanga (F): Nol Determinad
Flash PolntJRange (C): Not Determinad
Flaah pornl Method: Not Detennlned
AutolgnlUon Temparatura (F): Not DetermInad
Autolgnlllon Temperatura (e): Not Determlned
Ftammablllty Llmlts In Alr Lowar (%): Nol DetermInad )
Flammablllly Limita In Alr Upper ('.4): NoI Determlned

Flr. Extlngul.hlng MedIa

Al! standard tiretighUng media.

Speelal Expolure HUlrd.

Not appllcable.

Spaclal Protactlva Equlpment for Flre-Flghtar.

Nol appllcable.

NFPA ~tlng.: Haallh 1, FlammabllJty 0, ReacUvlty O

HMIS Retlngs: Flammabllily O, RaacUvlty 0, Haalth 1

16. ACCIDENTAL RELEASE MEASURES

Personal Pracautlonary Measura.

Use approprlale protacve equipment. Avold creaUng and braalhlng dual.

Envlronmental Pr.cautlonary Measur.a

Noneknown.

Proc.dure for Claanlng/Absorptlon

Scoop up and remove.
)
BAROIDrD
Page 20f7
 17. HANDLINGANOSTORAGE
)
Handling Precautlons
Avold oreaUng or Inllaling dust.

Storage Informatlon
Slore In a cooI, dry IocaUon.

Is, EXPOSURE CONTROLS/PERSONAL PROTECTION

Engln rlng Controla

Use In a wall v.ntilated area.

Ra.plratory ProtecUon
Not nonnally needed. Bul if slgnlflcant exposures are posalbla then (he following resplratcr is recommended. Duatlmlat
respJl1Itor.

Hand Prot.ctJon
Normal work g/oves.

Skln Protecllon
Normal wark coveralls.

Eye Protectlon
Wear saf.ty olasses or gaggl.s lo protect agalnsl exposure.

Olher Precaullons
Noneknown.
9. PHYSICAL ANO CHEMICAL PROPERTIES

Phy.lcal Stat.: Salid

Color: Plnk lo tan lo gray
Odor: Odorteaa
pH: Nol Catennlnad
Spaclnc Gravlty@20 e (Wat....1): 4.23
O.nally @ 20 e (Ib /gallon): Nol Detennlned
Bulk Dan.1ty @ 20 C (lbe/ft3): 150
80lllng PolnURanga (F): Not Detennlned
90lllna PolntlRang. (C): Nol Determlned
Fraazrng PolntlRanga (F): Nat Detenn~ed
Freezlng POlntIRanga (e): Not Catarrnk'led
Vapor p,. ur. @ 20 e (mmHg); Nol Detennfned
Vapor O.nally (41,.1); Not Determlned
Perclnt VolatUe.: Not Detennlned
EVllporatlon Rata (Butyl Aeata"-1): Not Detennlned
SolubJlfty In Watar (g/100ml): Insoluble
Solublllty In Solvanta (g/100ml): Not Detennlned
Solublllty In s Water (g/100ml): Not Determinad
VOC. (lbaJgallon): Not Determined
Vlscoslty, Dynamlc @ 20 e
(eantlpol.a): Not Delermlnad
Vlscoslly, Klnamatlc @ 20 e
(cantJB!roka.): Not Determinad
Partltlon Caeff1cl.nUn-octanollWa~er: Not Determinad
)
BAROID
Page 3 of7
 Molacular Walght (,,'mol.): 233.4

110. STABILITY ANO REACTIVITY )

StabllJly Data: Stabla

Hazardous Polymerfzatlon: Will Not Occur

CondltJons to Avold
None antlclpatad

Incompatlbmty (Mat.r'lI. to Avold)

Nona known.

Hezardoua Oecomposlllon Product.

Nona knO'M1.

Addltlonal QuldaUn
Not Appllcabla

111. TOXICOLOGICAL INFORMATION

PrincIpIa Routa of Expolure
Eye or skin contact, Inharallen.

Inhal.tlon
May cause resplratory Irrttatlon. May cause silicosis, whlch reduce. fung function. Tha lung damaga can lead to haart
problema. .
)
Skln Contact
None known.

Eye Contact
May cause mlld aya Irritatlon.

In$l Oon
May produce n,/Vous system atreel! auch as feallng of weakn888. unsteady walk, and dllatlon of blood ves.el May affact
tha ha.rt and cardlovalClllar system.

Aggravatad Medlcal Condltlona

Lung dlaorders.

Chronlc EffactsfCarclnoganlclty
Containa crystalllne sfllca whlcn may cause a delayed, progreasive lung dlsease (silicosis). The IARe and NTP haya
determinad lIlera Is sufflelant avldence In humana 01 tha carclnogenlclty of c:ryslalline aillca.

Other Informatfon
Nona known.

Toxlclty Te.ts

Or.' Toxlclty: Not determinad.

Dermal Toxlclty: Not determinad

.'

BAROIO
Page4of7
 Inhalatlon Toxlclty: Not determinad

Prlmary Irrltltlon EfflCt: Not dalannlned

Carclnoganlclty
Nol determinad

O.notoxlclty: Nol detennined

Reprod~ctlvelD.valopm.ntal
Toxlclty: Not detennlned

112. ECOLOGICAL INFORMATION

MobJllty (Watar/SoIl/Alr)
Not detennlned

P.,..latanceID.graclablllty
Not appncabla

Blo-accumulatlon
Not Oalennlnad

Ecotoxlcologlcallnfonnatlon
Acule Flsh Toxicity: No( detannlnad
Acula Crustaca8M Toxlclty: Not datennlnad
Acuta Algae Toxlclty: Not de18nnlned

) eh.mlcal Fata InformaUon

Not determinad

oth,r Infonnation
Not appllclbla

113. DISPOSAL CONSIDERATIONS

DI.posal M.thod
Bury In a llcensed landflll accordlng to fedaral, state, and local ragulatlona.

Contamlnat.d Packaglng
Follow all appllcable naUonal or local regulatlons.

114. TRANSPORT INFORMATION

Land Transportatlon
DOT

Not rastricted

Canadlan TDG

)
BAROICI)
Page 50f7
 Not reslrfcled

ADR
Nol restrictad

Alr Transportatlon
ICAO/IATA

Not restrfcted

Sea Transportation
IMDG

Nat ,a.lncted

Other Shlpplng Informatlon

Labels: None

115. REGULATORY INFORMATION

US Regulatlons
US TSCA Inventary )
AlI componants listad on Inventory.

EPA SARA ntla 111 Extremely Hazardous Substance.

Not appllcable

EPA SARA (311,312) Hazard CI...

Acule Heallh Hazard
Chronlc Heallh Haurd

EPA SARA (313) Chemlcal.

Thls product does nol conlaln a toxlc chemlcal for rouUne annual "Tax/e Chemlcal Release Reportlng" under Sectlon 313 (40
CFR372).

EPA CERCLAlSuperfund Reportable Splll Quantlty For Thl. Product

Nol applicable.

EPA RCRA Hazardous Wasle Cla lfte.tlon

Ir product be comes a waBle, 11 do8s NOT me.l th critena of a hazardoua wasta as deflned by \he US EPA.

CalifornIa Propoaltlon 65
The Callfomla ProposiUon 65 regulatlons apply lo thls product

MA Rlght.to-Know Law
One or more componants lisiad.
)
BAROro
Page 60f7
 NJ Rlghtto.Know Llw
) One or more components listed.

PA Rlghtto.Know u.w
One or more components listad.

Canadlan Regulatlons
Canadlan DSL Inventory
AlI componenla listed en Inventory.

WHMIS Hazard C
D2A Ver Toxfc Materials

116. OTHER INFORMATrON

The followlng aactlon. hay. besn revisad slnca 'he last I u. of Chia MSOS
Not appUcable

Addltlonallnformatlon
Far addlUona' infonnaticn on the use of Ihls product. contact your local Hal/iburton representa Uve.

For quaslions about Ihe Malarial Safety Data Sheet for Ihls DI' olhar Halllburton products, contact Product Slewardshlp at 1
580-251-4335.

DI.elalmer Slatement
Thla Informallon /a fumished wllhout w8rranty, expressed or Implled, 88 to accuracy or complateness. The Informal/on le
) obtalned rrom various aoulC.s Incfudlng the manufacturer and olher lhlrd perty aources. Ths InformaUon may not ba valld
undar aD condltlona nor If Ihle mat.1181ls used In comblnaUon wlth olher malerfals or in sny procesa. Final detennlnaUon 01
lultablllty of sny maleriells lhe IIcle responalblllly of lhe us.r.

-END OF MSOS-

)
BAROIC
Page 70f7