Infrared Plastic Solar Cell
Infrared Plastic Solar Cell
CHAPTER 1
INTRODUCTION
It is expected that the global energy demand will double within the next 50 years. Fossil
fuels, however, are running out and are held responsible for the increased concentration of
carbon dioxide in the earths atmosphere. Hence, developing environmentally friendly,
renewable energy is one of the challenges to society in the 21st century. One of the renewable
energy technologies is photovoltaics (PV), the technology that directly converts daylight into
electricity. PV is one of the fastest growing of all the renewable energy technologies, in fact,
it is one of the fastest growing industries at present.
Solar cell manufacturing based on the technology of crystalline, silicon devices is growing
by approximately 40% per year and this growth rate is increasing. This has been realized
mainly by special market implementation programs and other government grants to
encourage a substantial use of the current PV technologies based on silicon. Unfortunately,
financial support by governments is under constant pressure.
At present, the active materials used for the fabrication of solar cells are mainly inorganic
materials, such as silicon (Si), gallium-arsenide (GaAs), cadmium-telluride (CdTe), and
cadmium-indium-selenide (CIS). The power conversion efficiency for these solar cells varies
from 8 to 29% . With regard to the technology used, these solar cells can be divided into two
classes. The crystalline solar cells or silicon solar cells are made of either (mono- or poly-)
crystalline silicon or GaAs. About 85% of the PV market is shared by these crystalline solar
cells. Amorphous silicon, CdTe, and CI (G) S are more recent thin-film technologies.
Current solar power technology has little chance to compete with fossil fuels or large electric
grids. Todays solar cells are simply not efficient enough and are currently too expensive to
manufacture for large-scale electricity generation. However, potential advancements in
nanotechnology may open the door to the production of cheaper and slightly more efficient
solar cells. Scientists have invented a plastic solar cell that can turn the sun's power into
electrical energy, even on a cloudy day. The plastic material uses nanotechnology and
contains the first solar cells able to harness the sun's invisible, infrared rays.
CHAPTER 2
A solar cell (photovoltaic cell or photoelectric cell) is a solid state electrical device that
converts the energy of light directly into electricity by the photovoltaic effect. The energy of
light is electromagnetic fields, which in turn can make a current of electrons flow.
Assemblies of solar cells are used to make solar modules which are used to capture energy
from sunlight. When multiple modules are assembled together (such as prior to installation
on a pole-mounted tracker system), the resulting integrated group of modules all oriented in
one plane is referred as a solar panel. The electrical energy generated from solar modules, is
an example of solar energy. Photovoltaics is the field of technology and research related to
the practical application of photovoltaic cells in producing electricity from light, though it is
often used specifically to refer to the generation of electricity from sunlight. Cells are
described as photovoltaic cells when the light source is not necessarily sunlight. These are
used for detecting light or other electromagnetic radiation near the visible range, for example
infrared detectors, or measurement of light intensity.
The development of solar cell technology began with the 1839 research of French
physicist Antoine-Csar Becquerel. Becquerel observed the photovoltaic effect while
experimenting with a solid electrode in an electrolyte solution when he saw a voltage
develop when light fell upon the electrode. The major events are discussed briefly below,
and other milestones can be accessed by clicking on the image shown below.
Charles Fritts - First Solar Cell: The first genuine solar cell was built around 1883 by
Charles Fritts, who used junctions formed by coating selenium (a semiconductor) with an
extremely thin layer of gold. The device was only about 1 percent efficient.
Albert Einstein - Photoelectric Effect: Albert Einstein explained the photoelectric effect
in 1905 for which he received the Nobel Prize in Physics in 1921.
Russell Ohl - Silicon Solar Cell: Early solar cells, however, had energy conversion
efficiencies of under one percent. In 1941, the silicon solar cell was invented by Russell
Ohl.
Gerald Pearson, Calvin Fuller and Daryl Chapin - Efficient Solar Cells: In 1954, three
American researchers, Gerald Pearson, Calvin Fuller and Daryl Chapin, designed a
silicon solar cell capable of a six percent energy conversion efficiency with direct
sunlight. They created the first solar panels. Bell Laboratories in New York announced
the prototype manufacture of a new solar battery. Bell had funded the research. The first
public service trial of the Bell Solar Battery began with a telephone carrier system
(Americus, Georgia) on October 4 1955.
CHAPTER 3
First generation solar cells are the larger, silicon-based photovoltaic cells. Silicon's ability to
remain a semiconductor at higher temperatures has made it a highly attractive raw material
for solar panels. Silicon's abundance, however, does not ease the challenges of harvesting
and processing it into a usable material for microchips and silicon panels. Solar cells, use
silicon
wafers consisting of Silicon or Germanium that are doped with Phosphorus and Boron in a
pn-junction. Silicon cells have a quite high efficiency, but very pure silicon is needed, and
due to the energy-requiring process, the price is high compared to the power output.
Crystalline Silicon Solar Cells dominate 80-90% of solar cell market due to their high
efficiency, despite their high manufacturing costs
Second generation solar cell, also known as thin-film solar cell (TFSC) or thin-film
photovoltaic cell (TFPV), is made by depositing one or more thin layers (thin films) of
photovoltaic material on a substrate. They are significantly cheaper to produce than first
generation cells but have lower efficiencies. The great advantage of thin-film solar cells,
along with low cost, is their flexibility and versatility to be used in varied environments.
This has led to aesthetically pleasing solar innovations such as solar shingles, solar glass and
solar panels that can be rolled out onto a roof or other surface. The most successful second
generation materials have been cadmium telluride (CdTe), copper indium gallium
selenide(CIGS), amorphous silicon and micro amorphous silicon. The thickness range of
such a layer is wide and varies from a few nanometers to tens of micrometers. These
materials are applied in a thin film to a supporting substrate such as glass or ceramics
reducing material mass and therefore costs. It is predicted that second generation cells will
The electrochemical dye solar cell was invented in 1988 by Professor Graetzel of Lausanne
Polytechnique, in Switzerland. The "Graetzel" dye cell uses dye molecules adsorbed in
nanocrystalline oxide semiconductors, such as TiO2, to collect sunlight. Dye cells employ
relatively inexpensive materials such as glass, Titania powder, and carbon powder. Graetzel's
cell is composed of a porous layer of titanium dioxide nanoparticles, covered with a
molecular dye that absorbs sunlight, like the chlorophyll does in green leaves. Third
generation solar cells are the cutting edge of solar technology. These solar cells can exceed
the theoretical solar conversion efficiency limit for a single energy threshold material.
Current research is targeting conversion efficiencies of 30-60% while retaining low cost
materials and manufacturing techniques.
CHAPTER 4
Solar cells, which largely are made from crystalline silicon work on the principle of
Photoelectric Effect that this semiconductor exhibits. Silicon in its purest form- Intrinsic
Silicon-is doped with a dopant impurity to yield Extrinsic Silicon of desired characteristic
(p-type or n-type Silicon). Working of Solar cells can thus be based on crystalline structure
of Intrinsic and Extrinsic Silicon. When p and n type silicon combine they result in
formation of potential barrier. These and more are discussed below.
Extrinsic silicon in a solar cell has added impurity atoms purposefully mixed in with the
silicon atoms, maybe one for every million silicon atoms. Phosphorous has five electrons in
its outer shell. It bonds with its silicon neighbour atoms having valence of 4, but in a sense,
the phosphorous has one electron that doesn't have anyone to bond with. It doesn't form part
of a bond, but there is a positive proton in the phosphorous nucleus holding it in place. When
energy is added to pure silicon, in the form of heat, it causes a few electrons to break free of
their bonds and leave their atoms. A hole is left behind in each case. These electrons, called
free carriers, then wander randomly around the crystalline lattice looking for another hole to
fall into and carry an electrical current. In Phosphorous-doped Silicon, it takes a lot less
energy to knock loose one of "extra" phosphorous electrons because they aren't tied up in a
bond with any neighbouring atoms. As a result, most of these electrons break free, and
release a lot more free carriers than in pure silicon. The process of adding impurities on
purpose is called doping, and when doped with phosphorous, the resulting silicon is called
N-type ("n" for negative) because of the prevalence of free electrons. N-type doped silicon is
a much better conductor than pure silicon.The other part of a typical solar cell is doped with
the element boron, which has only three electrons in its outer shell instead of four, to become
P-type silicon. Instead of having free electrons, P-type ("p" for positive) has free openings
and carries the opposite (positive) charge
The electric field is formed when the N-type and P-type silicon come into contact. Suddenly,
the free electrons on the N side combine the openings on the P side. Right at the junction,
they combine and form something of a barrier, making it harder and harder for electrons on
the N side to cross over to the P side (called POTENTIAL BARRIER). Eventually,
equilibrium is reached, and an electric field separating the two sides is set up. This electric
field acts as a diode, allowing (and even pushing) electrons to flow from the P side to the N
side, but not the other way around. It's like a hill -- electrons can easily go down the hill (to
the N side), but can't climb it (to the P side).
When light, in the form of photons, hits solar cell, its energy breaks apart electron-hole
pairs(Photoelectric effect). Each photon with enough energy will normally free exactly one
electron, resulting in a free hole as well. If this happens close enough to the electric field, or
if free electron and free hole happen to wander into its range of influence, the field will send
the electron to the N side and the hole to the P side. This causes further disruption of
electrical neutrality, and if an external current path is provided, electrons will flow through
the path to the P side to unite with holes that the electric field sent there, doing work for us
Department of ECE, ATME 9| Page
INFRARED PLASTIC SOLAR CELL
along the way. The electron flow provides the current, and the cell's electric field causes a
voltage.
Silicon is very shiny material, which can send photons bouncing away before energizing the
electrons, so an antireflective coating is applied to reduce those losses. The final step is to
install something that will protect the cell from the external elements- often a glass cover
plate. PV modules are generally made by connecting several individual cells together to
achieve useful levels of voltage and current, and putting them in a sturdy frame complete
with positive and negative terminals.
CHAPTER 5
INFRARED PLASTIC SOLAR CELL
Scientists have invented a plastic solar cell that can turn the suns power into electric energy
even on a cloudy day.
Plastic solar cells are not new .But existing materials are only able to harness the suns
visible light. While half of the suns power lies in the visible spectrum, the other half lies in
the infrared spectrum. The new material is first plastic compound that is able to harness
infrared portion. Every warm body emits heat. This heat is emitted even by man and by
animals, even when it is dark outside.
The plastic material uses nanotechnology and contains the 1 stgeneration solar cells that can
harness the suns invisible infrared rays. This breakthrough made us to believe that plastic
solar cells could one day become more efficient than the current solar cell. The researchers
combined specially designed nano particles called quantum dots with a polymer to make the
plastic that can detect energy in the infrared.
With further advances the new PLASTIC SOLAR CELL could allow up to 30% of suns
radiant energy to be harnessed completely when compared to only 6% in today plastic best
plastic solar cells. A large amount of suns energy could be harnessed through solar farms and
used to power all our energy needs. This could potentially displace other source of electrical
production that produce green house gases like coal. Solar energy reaching the earth is 10000
times than what we consume. If we could cover 0.1% of the earths surface with the solar
farms we could replace all our energy habits with a source of power which is clear and
renewable.The first crude solar cells have achieved efficiencies of todays standard
commercial photovoltaics the best solar cell, which are very expensive semiconductor
laminates convert at most, 35% of the suns energy into electricity.
The solar cell created is actually a hybrid, comprised of tiny nanorods dispersed in an
organic polymer or plastic. A layer only 200 nanometers thick is sandwiched between
electrodes and can produce at present about .7 volts. The electrode layers and nano rods
/polymer layers could be applied in separate coats, making production fairly easy. And
unlike todays semiconductor-based photovoltaic devices, plastic solar cells can be
manufactured in solution in a beaker without the need for clean rooms or vacuum chambers.
Nano rods are manufactured in a beaker containing cadmium selenide, aiming for rods of
diameter-7 nanometers to absorb as much sunlight as possible. The length of the Nano rods
may be approximately 60nanometers.Then the Nano rods are mixed with a plastic
semiconductor called p3ht-poly-(3-hexylthiophene) a transparent electrode is coated with the
mixture. The thickness, 200 nanometers-a thousandth the thickness of a human hair-is a
factor of 10 less than the micron-thickness of semiconductor solar cells. An aluminum
coating acting as the back electrode completed the device. The Nano rods act like wires.
When they absorb light of a specific wavelength, they generate an electron plus an electron
hole-a vacancy in the crystal that moves around just like an electron. The electron travels the
length of the rod until it is collected by aluminum electrode. The hole is transferred to the
plastic, which is known as a hole-carrier, and conveyed to the electrode, creating a current.
CHAPTER 6
(Left) A diagram of a quantum dot structure. (Center) A comparison of solar cells with
different levels of doping. (Right) The 3D potential profile in quantum dot structures
For the past few years, researchers have been using quantum dots to increase the light
absorption and overall efficiency of solar cells. Now, researchers have taken a step further,
demonstrating that quantum dots with a built-in electric charge can increase the efficiency of
InAs/GaAs quantum dot solar cells by 50% or more. The researchers, Kimberly Sablon and
John W. Little (US Army Research Laboratory in Adelphi, Maryland), Vladimir Mitin,
Andrei Sergeev, and Nizami Vagidov (University of Buffalo in Buffalo, New York), and Kitt
Reinhardt (AFOSR/NE in Arlington, Virginia) have published their study on the increased
solar cell efficiency in a recent issue of Nano letters. In their study, the researchers studied
heterostructure solar cells with InAs/GaAs quantum dots. As photovoltaic materials, the
quantum dots allow for harvesting of the infrared radiation to convert it into electric energy.
However, the quantum dots also enhance the recombination of photocarriers and decrease
the photocurrent. For this reason, up to now the improvement of photovoltaic efficiency due
to quantum dots has been limited by several percent. Here, the researchers have proposed to
charge quantum dots by using selective interdot doping.
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INFRARED PLASTIC SOLAR CELL
In addition, the researchers predict that further increasing the doping level will lead to an
even stronger efficiency enhancement, since there was no evidence of saturation. In the
future, the researchers plan to further investigate how these effects influence each other at
higher doping levels. They predict that further increasing the doping level and radiation
intensity will lead to an even stronger efficiency enhancement, since there was no evidence
of saturation.
The methodology and principles developed during this research are applicable to a number
of photovoltaic devices with quantum dots and nanocrystals, such as polymer plastic cells
and dye-sensitized porous metal oxide Gratzel cells, Dr. Sergeev told PhysOrg.com.
Effective harvesting and conversion of infrared radiation due to optimized electron-hole
kinetics in structures with quantum dots and nanocrystals will lead to potential
breakthroughs in the area of solar energy conversion.
CHAPTER 7
Quantum dots grown using colloidal synthesis can be dried into thin films. The application
of the colloidal solution containing the polymer to a metal nano mask consisting of an array
of sub-micron holes allows near-field detection of any quantum dots that lie directly under a
hole. While the distribution of quantum dots in the film is random, variation of the quantum
dot density is easily achieved by dilution, enabling an optimum density for the mask hole
size to be found. If two or more quantum dots lie under a hole in the mask, they will be
detected spectroscopic ally. The use of a metal nano mask for this near-field detection
enables the mask to be charged, which in turn will apply an electric field to the quantum dots
under observation. The application of such an electric field will provide a means of
continuously varying the coupling between quantum dots, which is effectively the J-gate
operation.
The possibility of quantum dots as dye replacements in dye sensitized solar cells has been
theoretically suggested. The size selective growth characteristic of quantum dots allows
absorption tuning. Potentially PbS could span the whole spectrum. Secondly emission at
longer wavelength is observed which could be utilized in a second absorbing layer.
We exploit the photovoltaic properties of quantum dots with plans to use them as dye
replacements in dye sensitized cells such as those designed by Gratzel. An advantage of
QD`s is that they are more stable than dyes of their crystalline nature. Also dyes have low
efficiency due to re-absorption whereas qd emission is red shifted away from absorption.
A photon excites an electron in QD which is swept away by the in-built electric field into the
TiO2/SnO2 electrode and conducted around the circuit. At the Pt/SnO3 electrode the
electron is transferred into the electrolyte which acts as an electron shuttle to the QD.
CHAPTER 8
Konarka's Technologies
Konarka is focused on the development and advancement of nano-enabled polymer
photovoltaic materials that are lightweight, flexible and more versatile than traditional solar
materials.
But Siemenss achievement earlier this year of the highest efficiency to date in plastic solar
cells could change that. The Siemens design combined two of the most important advances in
materials science in the past 30 years: electrically conducting polymers and buckyballs. The
idea of combining these materials to capture solar power first gained credence in the early
1990s, when physicists Sariciftci and Alan Heeger at the University of California, Santa
Barbara, created primitive photovoltaic devices by pouring a solution of conducting plastic
and buckyballs onto a glass plate, spinning the plate to spread the solution into a film, and
sandwiching the film between electrodes. The conducting polymer absorbed photons, kicking
off electrons that were then attracted by the buckyballs and routed to an electrode. In short,
the film acted like a solar cell.Originally, the power output was meager (less than 1 percent of
the energy of incoming sunlight). But the principle of the printable solar cell was proved: you
could layer a photovoltaic material on a surface and make it work without complex
preparations.
CHAPTER 9
IMPROVEMENTS
Some of the obvious improvements include better light collection and concentration, which
already are employed in commercial solar cells. Significant improvements can be made in
the plastic, nanorods mix, too, ideally packing the nanorods closer together, perpendicular to
the electrodes, using minimal polymer, or even none-the nanorods would transfer their
electrons more directly to the electrode. In their first-generation solar cells, the nanorods are
jumbled up in the polymer, leading to losses of current via electron-hole recombination and
thus lower efficiency.
They also hope to tune the nanorods to absorb different colors to span the spectrum of
sunlight. An eventual solar cell has three layers each made of nanorods that absorb at
different wavelength.
CHAPTER 10
APPLICATIONS
2. Like paint the compound can also be sprayed onto other materials and used as
portable electricity.
3. Any chip coated in the material could power cell phone or other wireless devices.
4. A hydrogen powered car painted with the film could potentially convert energy into
electricity to continually recharge the cars battery.
5. One day solar farms of plastic materials could be rolled across deserts to generate
enough clear energy to supply the entire planets power needs.
CHAPTER 11
ADVANTAGES
Plastic solar cells are quite a lot useful in the coming future. This is because of the large
number of advantages it has got. Some of the major advantages are:
1. They are considered to be 30% more efficient when compared to conventional solar
cells.
4. Conventional solar cells are only used for large applications with big budgets. But the
plastic solar cells are feasible as they can be even sewn into fabric- thus having vast
applications.
5. Flexible, roller processed solar cells have the potential to turn the suns power into a
clean, green, consistent source of energy.
CHAPTER 12
DISADVANTAGES
1. The biggest problem with this is cost effectiveness. But that could change with new
material. But chemists have found a way to make cheap plastic solar cells flexible
enough to paint onto any surface and potentially able to provide electricity for
wearable electronics or other low power devices.
CHAPTER 13
CONCLUSION
Plastic solar cells help in exploiting the infrared radiation from the suns rays. They are more
effective when compared to the conventional solar cell. The major advantage they enjoy is
that they can even work on cloudy days, which is not possible in the former. They are more
compact and less bulky. Though at present, cost is a major drawback, it is bound be solved in
the near future as scientists are working in that direction. As explained earlier, if the solar
farms can become a reality, it could possibly solve the planets problem of depending too
much on the fossil fuels, without a chance of even polluting the environment.
REFERENCES
2. The Coming Era of Nanotechnology; 1987. Drexler, K. Eric, Doubleday; New York
7. Thin film solar cells next generation photovoltaic and its application- Y Hamakawa