1 s2.0 S2212827114012219 Main
1 s2.0 S2212827114012219 Main
1 s2.0 S2212827114012219 Main
com
ScienceDirect
Procedia CIRP 26 (2015) 162 166
Mostafa Ghasemi a,*, Elnaz Halakoo b, Mehdi Sedighi c, Javed Alamd, Majid Sadeqzadehe
a
Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia
b
Advanced Membrane Technology Research Centre (AMTEC), Universiti Technology Malaysia, 81310 Skudai, Johor Malaysia
c
Department of Chemical Engineering, Tarbiat Modares University, Tehran, Iran
d
King Abdullah Institute for Nanotechnology, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
e
Unit de Catalyse et de Chimie du Solide,UMR 8181 CNRS, Universit Lille 1-ENSCL-EC-Lille, Villeneuve dAscq, France
* Corresponding author. Tel.: +60 3 89118588; fax+60 3 8911-8530 E-mail [email protected], [email protected] (Mostafa Ghasemi)
Abstract
Proton exchange membranes (PEMs) have essential role in the performance of microbial fuel cells (MFCs). They act as a separator and
separate anode and cathode compartments and they also transfer protons between anode and cathode. In this study three types of PEMs (Nafion
112, SPEEK and Nafion 117) have been applied to MFC and the amount of produced bioenergy with the feed of a wastewater in 5000 m/l
chemical oxygen demand (COD) have been reported. It has been observed that the MFC working with Nafion 117 as separator produced the
highest power among the other MFCs. Also It was found that the produced power was 179.7 mW/m2 for Nafion 117 while it was 126.1 for
SPEEK and 19.7 for Nafion 112. Moreover it has been concluded that the low power production of Nafion 112 was due to the diffusion of
oxygen from the cathode chamber to the anode chamber that disturb the microorganisms metabolism for degradation of organic compounds.
Generally we have found a new economic PEM for using in MFCs.
2212-8271 2015 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license
(http://creativecommons.org/licenses/by-nc-nd/4.0/).
Peer-review under responsibility of Assembly Technology and Factory Management/Technische Universitt Berlin.
doi:10.1016/j.procir.2014.07.169
Mostafa Ghasemi et al. / Procedia CIRP 26 (2015) 162 166 163
also more durable and also the major piece of the world's 2. Materials and methods:
energy problem which is mostly by fossil fuel is high price.
Prices continue to be far above from the hands of small 2.1. Synthesis of SPEEK
industries[3].
For the preparation of solfunated poly ether ether ketone
Moreover, interests to find out renewable, sustainable and (SPEEK), 20g of polyether ether ketone (PEEK) powder
clean energy source with minimum or zero environmental (Goodfellow Cambridge Limited, UK) was dissolved slowly
pollution has been increased [4].One of the emerging source in 500mL of 95-98% concentrated sulphuric acid (R & M
of renewable energy is fuel cell. Microbial fuel cell (MFC) Chemicals, Essex, UK).
is a type of fuel cell which converts the biochemical energy
stored in organic matter by the aid of microorganism as This solution was stirred vigorously until the entire PEEK was
biocatalysts [5-6]. It means that the chemical oxygen dissolved completely. Next, the homogenous solution was
demand (COD) of wastewater decreased while producing continuously and thoroughly stirred at a controlled
electricity. The limitations of wide spread application of temperature of 80oC for 4 to get the SPEEK with acceptable
MFC as an alternative source of energy is low power output degree of sulfonation. The SPEEK solution was poured into a
and high cost of operation for commercial applications. large excess of ice water to precipitate the SPEEK polymer.
Power generation of MFC depends on many factors The solid was then collected by filtering the solution through
including type of membrane, catalyst, substrate, a Whatman filter paper. Finally, the SPEEK was dried at 70oC
configuration, temperature etc [7]. to remove any remaining water before use [9].
Fig.1. Schematic of a MFC FTIR of PEEK and SPEEK is the broad band of about 3460
In one chamber there is microorganisms that produce cm-1 which shows the O-H vibration of sulfonic group. Due
electrons and protons and in the cathode chamber the
reduction process will be happen and MFC produce to new substitution upon sulfonation the aromatic C-C
electricity.
.
Fig.3. FTIR of the PEEK and SPEEK
4. conclusion
References
degrading bacteria in a microbial fuel cell, Enzyme and anodes, Biochemical Engineering Journal, 62 (2012) 8-16.
Microbial Technology, 51 (2012) 269-273.
[11] R. Huang, P. Shao, C. Burns, X. Feng, Sulfonation of
[8] J.P. Stratford, N.J. Beecroft, R.C.T. Slade, A. Grning, C. poly (ether ether ketone)(PEEK): kinetic study and
Avignone-Rossa, Anodic microbial community diversity as a characterization, Journal of applied polymer science, 82
predictor of the power output of microbial fuel cells, (2001) 2651-2660.
Bioresource Technology, 156 (2014) 84-91.
[12] H. Ilbeygi, M. Ghasemi, D. Emadzadeh, A.F. Ismail,
[9] P. Xing, G.P. Robertson, M.D. Guiver, S.D. Mikhailenko, S.M.J. Zaidi, S A. Aljlil, J. Jaafar, D. Martin, S. keshani,
K. Wang, S. Kaliaguine, Synthesis and characterization of Power generation and wastewater treatment using a novel
sulfonated poly (ether ether ketone) for proton exchange SPEEK nanocomposite membrane in a dual chamber
membranes, Journal of Membrane Science, 229 (2004) 95- microbial fuel cell, International Journal of Hydrogen Energy,
106. xxx (2014) , In press, 1-11
[10] C. Santoro, Y. Lei, B. Li, P. Cristiani, Power generation
from wastewater using single chamber microbial fuel cells
(MFCs) with platinum-free cathodes and pre-colonized