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From concept

to commercialisation
with DuPont
Engineering Polymers

The DuPont oval and The miracles of science are registered trademarks or trademarks of DuPont or its affiliates.

Table of contents

Start with a partnership that works..................................................................... 1


Your partnership with DuPont ......................................................................... 2
CRASTIN PBT a highly versatile family of thermoplastic polyesters............. 4
DELRIN versatility in design, moulding and performance .............................. 6
HYTREL a thermoplastic and an elastomer all in one ..................................... 8
MINLON the choice for critical components................................................... 10
RYNITE PET takes the heat ............................................................................... 12
ZENITE LCP high heat resistance, and dimensional stability...................... 14
ZYTEL theres always something new ........................................................... 16
ZYTEL ST it starts tough it stays tough.................................................... 18
ZYTEL glass-reinforced dont settle for ordinary glass-reinforced nylon ... 20
ZYTEL HTN the reliable high performance polyamide resin ........................ 22
Properties of CRASTIN PBT ................................................................................... 24
Properties of DELRIN ........................................................................................... 26
Properties of HYTREL .......................................................................................... 28
Properties of MINLON ......................................................................................... 30
Properties of RYNITE PET ..................................................................................... 32
Properties of ZENITE LCP...................................................................................... 34
Properties of ZYTEL ............................................................................................. 36
High temperature performance data of glass-reinforced
ZYTEL HTN compared to ZYTEL PA66.................................................................. 46
Safety, health and the environment.................................................................... 47

Start with DuPont


a partnership that works
Today you need more from your suppliers than just materials. You need
a resource that is willing and able
to join in at the earliest stages of the
product development process. One
that can carry a project from concept
through design, component analysis,
material selection, prototyping, testing, quality control, and even commercialisation. You need a fully fledged partner.
DuPont can be that partner. We believe that true partnership is a dynamic process of teamwork and sharing.
And we recognise that only through
your continued success will our relationship thrive, to bring out the best
in both of us.
If you let our people work with your
people from the initial design concept,
and on through every stage from prototyping to full production, we can
share our unrivalled experience, and
help you choose the optimum engineering polymer for your needs. The
result? A very competitive new product with time-proven success built in.
DuPont engineering polymers offer
you the properties and benefits so
important to giving your products that
extra competitive edge: lightweight
materials for lightweight parts and
components; resistance to corrosion
and abrasion; self-lubrication; reduced
moulding costs; integral colour; reduced finishing time; easier assembly,
and greater customer satisfaction. All
these advantages add up to new
opportunities in design, manufacture
and finished part cost.
We wrote the book on engineering
polymers. Nylon, which we invented
back in the 1930s, led to the development of ZYTEL, the first real engineering thermoplastic.

Our family of high performance


polymers grew rapidly as we added
DELRIN acetal, glass-reinforced ZYTEL,
MINLON mineral reinforced nylon
resin, ZYTEL ST super tough nylon and
RYNITE PET thermoplastic polyester.
More recently, we added a complete
range of PBT polyesters known as
CRASTIN PBT. Today we offer the
broadest range of semi-crystalline
engineering polymers available from
a single supplier, and they all offer
new possibilities for the replacement
of traditional materials such as metal
and wood, as well as better alternatives to many other plastics.
The most recent introductions include
ZENITE LCP liquid crystal polymers and
ZYTEL HTN high performance polyamide resins. In both cases, a standard
range of grades has been commercialised and many new developmental grades are being tested for customer approval.

In today's competitive markets, each


new product launch seems to require
more and more investment. So it pays,
at the earliest stage, to take full advantage of the latest developments in
engineering polymers by starting with
DuPont and calling us in at the initial
concept stage. More than just selling
polymers, we share with you a world
of practical experience and technological know-how that can help you build a
real competitive advantage into everything you design and manufacture.
This brochure contains a great deal
of information, but it is by no means
complete. For more detailed data, contact your local DuPont representative.

Around the world, research in DuPont


technical centres and production plants
never stops. Following the commercialisation of super tough and toughened resins with the DELRIN and
ZYTEL product offerings, our most
recent introduction is DELRIN P, an
acetal with new stabilisation technology, resulting in very good processing performance, even under critical
operating conditions.
Backing this extensive line of plastics
is HYTREL thermoplastic polyester
elastomer. HYTREL combines many
of the most desirable characteristics
of high performance elastomers and
flexible plastics, yet it can be formed
into quality parts by conventional
thermoplastic processing techniques.

registered trademarks or trademarks of DuPont or its affiliates.

Your partnership with DuPont


teamwork from start to finish
When you purchase resins from
DuPont you get much more than
quality thermoplastics. You obtain the
services of a partner who gives you
unrivalled technical support. You open
the door to a world of knowledge that
can provide valuable practical help
at every stage from concept to commercialisation.
We are proud to be able to offer you
assistance from the most experienced
group of technical service experts in
the engineering plastics industry, people who are always up to date with
the very latest developments. Our
engineers have developed vibration
welding methods, runnerless mould
designs for semi-crystalline thermoplastics, and ever more exacting methods of quality control and assurance.
They are people who can find ways
to give your products the extra competitive edge that spells success in
the marketplace.

Partnership
Our idea of partnership means working together, combining the best minds
of our organisations to produce the
best results. DuPont offers you decades of experience, and extensive
resources our people, products, and
considerable technical know-how. And
we have the will to do what is necessary to help you expand your business.

Worldwide
In todays business world, one must
think in much larger terms than ever
before. Everything one designs has
the potential for application internationally. In this kind of competitive
climate, it helps to have a partner that
can speak your language wherever
you or your customers are. With our
truly global operation, we can work
with you in virtually any country, and
we can help you expand your business
into those countries.

Concept

Our people working


with yours
From your first phone call to the time
your new product is ready for shipment, our people are there with solutions that work. And if we dont have
an answer readily available, well be
the first to tell you.

Computer Aided
Technical Services
Our worldwide Computer Aided Technical Service facilities (CATS) can provide you with full computer aided engineering (CAE) and computer aided
design (CAD) services, including finite
element analysis and 3D modelling.
Three core computer systems are
linked within the Asia/Pacific, European and American regions. Within
each region, CAD servers and Personal Designer Systems are networked
with the core systems. The most up
to date graphic programmes and data
exchange make it possible to exchange
drawings with customers using other
design systems.

Right from the start, you can call upon


the expertise of our technical consultants for a thorough analysis of your
design concept. Well take a close
look, and ask tough questions; but
in the end our wide experience with
engineering polymers can save you
considerable time and money.
Well work with your designers to
arrive at a solution that is both creative
and practical. We can suggest the best
material for your needs, whether it has
been proved around the world or its
a new technology in development.
Our technical advisors will even tell
you if an alternative material not available from us would be better for your
application.

Design
Once your concept has been analysed,
fine-tuned and proved feasible, our
DuPont Design professionals bring
their expertise to the table. They can
help you determine the specific
design engineering details that will
optimise product performance and
production economy. And they can
often reduce costs by consolidating
several parts into a single component.

Prototype testing
We know that a customer cant always
stop a production line to do a test
run. So we have created a polymers
industry in microcosm at each of our
worldwide Technical Centres. Here,
under controlled conditions, you can
test a prototype tool, and modify it if
necessary, with a full computer printout monitoring every factor. Our experts will examine your moulds and
machines, as well as the way youre
using them. And theyll ensure that
the rough tooling you need to produce
test parts for various analyses is properly designed.
Our expertise in prototype testing and
microstructural analysis ensures that
any potential process problems are
corrected and that your final materials
are properly selected. When we have
your prototypes in hand, we can help
your laboratories analyse performance
with mechanical, chemical exposure,
heat-ageing, accelerated wear, and
environmental exposure testing
again, utilising our own in-house
facilities to complement yours.

Commercialisation
Production
At DuPont we can provide you with
the help you need to make your production start-up as trouble-free as
possible, including utilisation of our
Advanced Technical Centres moulding machines. Here, close monitoring
of trial production runs helps anticipate
and eliminate any potential trouble with
final production, and ensures that materials grades are best tailored to meet
your requirements.
The same equipment can also help
you perfect new production methods,
or even create new processes. In
addition, our experience in Statistical
Process Control can aid you in pinpointing parameters needing close
monitoring to maximise productivity
and eliminate rejects. As a final bonus,
well put the industrys most experienced technical field force at your disposal where you need it most right
in your own production facilities.

With DuPont you get more than broad


industry experience and important
contacts within it. As your partner in
the development of a new product,
we're prepared to complement your
efforts and help assure its success
in the marketplace. This could include
access to our national and international
marketing, legal and financial expertise for ideas, guidance and direction
in the successful commercialisation
of your product.
Your current project may simply be an
improvement to an existing product
or process. Or you may want to do
something that has never been done
before. Either way, we can be of great
help to you. Our people are ready to
work with your moulder, your mould
maker, and your quality control people right through from prototype test
to full production.
Remember, the sooner you start with
DuPont, the bigger the contribution
we can make.

CRASTIN PBT a highly versatile family


of thermoplastic polyesters with a wide
variety of applications

DuPont CRASTIN PBT thermoplastic polyesters are based on polybutylene terephthalate.


By making physical and technical modifications, a very wide range
of products is available that are ideally suited to an enormous variety of industrial applications, including electronics, electrical, automotive, mechanical engineering, chemical and apparatus engineering, domestic and medical appliances and sporting goods. In fact,
this growing family is currently available in over 30 different grades,
approximately half of which are flame retardant.
Among the many features of various CRASTIN PBT grades are mechanical and physical properties of stiffness and toughness, heat
resistance, friction and wear resistance, excellent surface finishes
and good colourability. They have excellent electrical insulation
characteristics and high arc-resistant grades are available.
Processing is simple, with good flow properties leading to short
cycle times using standard injection moulding machines. Postmoulding operations such as welding, fastening and glueing are
also easy, as are printing, painting, hot stamping and laser marking.
All-in-all, the DuPont CRASTIN PBT range spells versatility, processing ease and good economics.

1. The inner and outer housing of this


device are moulded of CRASTIN, all
4 parts are assembled with snap-fits.
For this consumer product, DuPont
PBT combines the following: good
mechanical properties, stiffness, resistance to usual bathroom chemicals
and temperature resistance. It has
good mould flow-characteristics, an
important consideration for a highprecision moulding on which sensitive electronic components are
mounted.

2. CRASTIN PBT with high tracking resistance, replaced epoxy in automotive ignition distributor caps because
of its excellent moulding properties.
Such high-voltage applications require
optimal dielectric performance as well
as excellent thermal resistance and
dimensional stability.
3. CRASTIN is used for door handles
for automotive applications. It is a 30%
glass fibre reinforced PBT that provides excellent mechanical properties
and UV resistance.
4. Dimensional stability, chemical
and temperature resistance facilitated
KATKO in Finland to opt for CRASTIN
SK645FR for this load break switch. It
is a 30% glass-reinforced PBT meeting UL94 V0 requirements. Compared
to the traditionally used thermoset,
CRASTIN offers higher productivity, an
integrated design and significant cost
reductions.
5. CRASTIN FR grade that meets
UL94 V0 requirements was used for
these modular terminals. Providing
outstanding dielectric and precision
moulding properties, it permits highspeed data exchange with a reduce
number of terminal connections.
CRASTIN is resistant to chemicals and
humidity, it is an excellent electrical
insulator, has high arc resistance and
a high comparative tracking index.

6. Eurometers Ltd. uses CRASTIN PBT


for the main housing and the top cover for their E6 gas meter. DuPont PBT
is a good electrical insulator, withstands extremes of temperature,
resists to domestic chemicals and
has excellent dimensional stability. It
also gives an attractive surface finish,
which does not deteriorate with time.
Flow-tube assembly (foreground) is
made from DELRIN.
5

DELRINversatility in design,
moulding and performance

DELRIN acetal resin is a highly versatile engineering plastic with


metal-like properties. It offers outstanding strength, stiffness and
hardness, dimensional stability, fatigue, abrasion and solvent
resistance, is self-lubricating, and available in a variety of colours
and specialty grades.
Its superior mechanical properties compared with acetal copolymer help improve productivity and increase profitability. Its ability
to meet European regulations on food contact considerably
increases its potential, and because it can be moulded easily into
complex shapes with fast cycle times and rapid assembly techniques, production costs are lowered.
The product range includes UV resistant grades, resins for low
friction and wear, the DELRIN P series for optimum processing
for highly demanding operating conditions, as well as tough and
super tough grades.
DELRIN 100ST super tough is seven times tougher in notched Izod
and falling weight (Gardner type) testing than standard DELRIN at
23C. In impact fatigue tests, it is more resistant than toughened
polyester and polycarbonate.
With these new generations of versatile DELRIN acetals, you gain
new flexibility and freedom in designing all types of products for
all types of applications.

1. By making different parts from


various types of DELRIN, including
tough, lubricated and general purpose
grades, Brauns Spanish operation
has produced an efficient meat grinding accessory for the companys Minipimer hand mixer, which already
relies on DuPont polymers for other
components.
High mechanical strength, low coefficient of friction, food approval, and
special assembly techniques with
parts in DELRIN, have all contributed
to giving this appliance high performance at a reasonable price.
2. Excellent fuel resistance and its
ability to be moulded into complex
shapes make DELRIN an ideal material for this fuel swirl pot found in automotive petrol tanks.

3. DELRIN provides the right combination of stiffness, toughness, fatigue


and impact resistance needed for reliable gears in literally hundreds of different types of applications.
4. Car makers increasingly adopt
DELRIN to replace metal for loud
speakers. It brings good acoustic,
colourability, aesthetic, impact resistance. It is also easier to assemble,
does not need surface finishing as
plating and painting.

5. Ski and snow board bindings of


DELRIN look better because of the integral, moulded-in colours; they benefit from its low-temperature (40C)
impact resistance and low coefficient
of friction, and last longer because
they wont corrode.
6. DELRIN 100 is ideal for automotive
door locks as it allows for extensive
functional integration due to its unmatched combination of stiffness and
toughness.

7. DELRIN-KEVLAR eliminates metal


machining, tooling and lubrication processes. It provides dimensional stability, toughness, abrasion resistance
and a smooth, aesthetic surface for
applications such as conveyor belt
systems.

If you need even more versatility,


look to HYTREL a thermoplastic
and an elastomer all in one

HYTREL thermoplastic polyester elastomers provide a winning


combination for many parts and components. They give the flexibility of rubbers, the strength of plastics, and the processibility of
thermoplastics. They can be processed easily on conventional
injection, blow and rotational moulding equipment, and can also
be extruded and melt-cast.
HYTREL is ideal for parts requiring low flex fatigue and high loadbearing capacity. It is strongly resistant to tearing, flex-cut growth,
creep and abrasion. Its mechanical properties provide the strength
and stiffness you need, in addition to outstanding toughness. Its
chemical properties make it highly resistant to hydrocarbons and
many other fluids.
HYTREL retains these properties at temperatures from 40C to
+110C, and even up to +150C with additional heat stabilisers.
HYTREL standard grades are available in a full range of Shore D
hardnesses from 35 to 82, as well as high performance grades
with hardnesses of 30D and 72D. Special grades include heat
stabilised, flame retardant, food approved, glass-reinforced, blow
moulding and extrusion grades. Concentrates offered include black
pigments, UV protection additives, hydrolysis resistant additives,
heat stabilisers, and flame retardants.
If you have multi-part or multi-material components that could be
made simpler or operate more efficiently with HYTREL we invite
you to learn more about this unique thermoplastic elastomer.

1. HYTREL in Airbag Deployment Door


application offers a unique consistency of physical properties over a wide
range of temperature, it can be used
in extreme low temperature environments and withstands the automotive
interior requirements including UV,
aestetics.
2. Flexibility in design, increased stiffness without adding weight or thickness, and an impeccable performance
at all temperatures was reason enough
for the people at Salomon to choose
HYTREL for the energy spring of their
in-line skate.
3. HYTREL proved to be the answer
for the interior door handle in the restyled SEAT Toledo. Besides a nice,
soft touch and matt surface, SEAT
was looking for very specific mechanical and chemical properties. The possibility of moulding the DuPont elastomer in a tool that was designed for
the previously used acetal copolymer
meant a significant cost saving, as
HYTREL has similar mould shrinkage.
4. The Suehiro Industry Co. Ltd knows
all about zapping. Their change to
HYTREL, from the traditional silicone
rubber for keypads of remote controls
resulted in shorter production cycles,
increased design flexibility and an ideal
feel. An altogether superior class
of product is how Suehiros development manager describes HYTREL.
5. Using HYTREL, Paguag developed
a range of flexible coupling with longer service life, greater reliability and
better performance. HYTREL has very
good resistance to synthetic oil, water,
grease, ozone and many other chemicals. It also has excellent resistance
to flex fatigue and crack propagation
and maintains these properties over
a wide range of temperatures.
6. The HYTREL HTR8105 BK in CVJ
boots put an end to a very costly and
complicated repair in case of failure
during the life of the car. These CVJ
boots for the Ford Mondeo moulded
by ContiTech in Germany, are extremely cost-effective compared to their
rubber counterparts, and offer superior
toughness and resistance to greases.

7. Another HYTREL application in


automotive components is the blowmoulded air-duct made of HYTREL
HTR4275 BK. VW has adopted this
innovative technology and benefits
for noise reduction, light weight and
an overall reduction of the number of
parts in the engine compartment, due
to its multi-functionality.
By using these parts, engine performance can be improved by as much as 2%.

Impact resistance, dimensional stability


and outstanding functional flexibility make
MINLON the choice for critical components

The MINLON range of mineral and mineral/glass-reinforced nylons


offers a unique balance of properties that allows designers to
maintain the optimum balance of strength and rigidity, while minimising the effects of warpage.
A major benefit of MINLON is its dimensional stability low warpage
and distorsion. This is due to the fact that its shrinkage is isotropic
even over varying wall thicknesses within the same application.
DuPonts experience in the area of mineral-reinforced nylons has
led to the development of a wide range of compositions tailored
for a variety of demanding applications. Mineral-reinforced resins
for automotive wheel covers feature an excellent surface for
painting, together with easy flow, fast cycle times, fatigue resistance and resistance to repeated high impacts.
For under-bonnet applications such as engine styling covers,
where a combination of low warpage and excellent surface finish
is required, a range of mineral or mineral/glass-reinforced resins,
based on PA6 and PA66, have been developed.
Even for the most demanding under-bonnet applications, MINLON
grades featuring a specially-developed glass and mineral combination and a nylon 66 matrix provide the ultimate combination of
strength, stiffness and creep resistance at elevated temperatures.
Resistance to hot oil and hot air ageing, combined with precision
moulding and low warpage are additional benefits.

10

1. MINLON has established itself as


the leading material for automotive
wheel covers. Mineral-reinforced,
impact-modified products such as
MINLON 13MM and EFE6096 are
optimised to provide the needed balance of properties for the application.
VW, Peugeot, Citron, Renault, Volvo,
Audi and Honda are among the many
car manufacturers around the world
who use DuPont MINLON resins for
wheel covers.
2. MINLON is used for automotive
rocker covers because it provide high
stiffness, heat stability, oil and chemical resistance, while weighing less
than the metal it replaces. BMWs
rocker cover of MINLON helps reduce
engine noise still further and cuts production costs.

3. MINLON was chosen for car interior door handles for its mechanical
properties and dimensional stability.
The very smooth surface of MINLON
allows chrome-plating with very high
blemish free quality.
4. The worlds first plastic throttle
body is part of an air intake manifold
from Rover and is made from MINLON.
High stiffness and heat resistance,
outstanding dimensional stability and
uniform mould shrinkage was needed
for accurate dimensional control of the
throttle body bore.
5. The combination of toughness
and stiffness enables gears of high
dimensional precision to be moulded.
MINLON 11C140B is being successfully used in the automotive industry.

5
4

6. Easier assembly and lower costs


made MINLON 11C140 the material
of choice for motor brackets from
Switzerlands Maxon. Multi-functional
integration becomes a practical reality
thanks to the flexibility of design that
is made possible with MINLON.

7
6

7. If any application has to rely on


resistance to weather conditions and
temperature variations, it must be
street lighting. MINLON is used for the
housing of street lighting reflectors
by Gewiss in Italy. Easily processable,
MINLON 13T2, a toughened PA66,
30% mineral reinforced nylon, provides the housing with high stiffness,
low warpage and a perfect surface
aspect.
11

RYNITE

PET

takes the heat

When youre looking for the ultimate combination of stiffness,


temperature performance, maximum dimensional stability, and
a high gloss finish, RYNITE PET is the most cost-effective answer.
It unites the best properties of reinforced polyethylene terephthalate (PET) with easier processability to produce high performance
parts that can be moulded conventionally.
RYNITE is the only PET-based polyester system with the virtue of
rapid crystallization. It also has a 20C heat deflection advantage
over PBT. It can be processed over a broad temperature range.
And, because of its low water absorption, parts in RYNITE PET
maintain their properties and dimensional stability. This makes it
a prime candidate for the replacement of die-cast metals and thermosets in many demanding applications where stiffness, critical
tolerances and exterior finish are key requirements. The outstanding flow characteristics of RYNITE PET allow it to fill complex, thinwalled moulds with less injection pressure than is needed with
other resins. This is a particularly important advantage with miniature parts.
RYNITE FR530L, widely used in the electrical and electronic component industries, has a UL temperature index of +155C, among
the highest of all thermoplastic polyesters.

12

1. This induction hob from BSH Balay


is made of RYNITE, which was chosen
for its dimensional stability, stiffness
and good mouldability. The RYNITE
FR531 NC used by Balay was specially developed to support temperatures
of up to 200C.
2. RYNITE 545 was chosen for the
connector housing of this Bosch alternator because of the good combination of mechanical properties it offers.
In addition it has good thermal and
chemical resistance. It also permits
high productivity in multi-cavity moulds.
3. This encapsulated oscillating pump
for carpet cleaners employs two different grades of RYNITE: FR530 and
HP415. The Class F homologation of
these grades permit the use of this
pump for export to the USA. The possibility to laser print RYNITE avoids the
utilisation of more polluting solventbased marking systems.

4. The recent range of irons launched


by Braun is using a custom coloured,
heat stabilised RYNITE PET for the iron
skirt. RYNITE gives higher productivity
at lower total cost compared to the
thermoset which was used previously.
5. An earlier die-cast metal motor with
fan (left), and the re-designed unit in
RYNITE (right). The switch from metal
to plastics meant simpler manufacturing, weight reduction, fewer components and lower assembly costs, reduced stock inventory and improved
performance for a range of vacuum
cleaners from Electrolux.

5
4

6. Rear windshield wiper arms for


cars like the Fiat Punto are made
out of a RYNITE grade which is specifically developed for severe weathering conditions. Mechanical properties
like creep resistance, as well as superior surface appearance, are of major
importance in this application.
6

13

ZENITE LCP high heat resistance, and


dimensional stability for precision moulding

ZENITE LCP liquid crystal polymer resins are easily melt processible
and have a number of highly desirable properties that make them
especially suitable for precision electrical and electronic parts in
lighting, telecommunications, aerospace, automotive, fibre optics
and other advanced uses. Typical applications include connectors,
bobbins, relays, motor components, sockets, imaging and sensor
devices, ignition systems, etc.
The ZENITE LCP family features excellent dimensional stability and
creep resistance, especially at very high temperatures. When in a
molten state its molecules tend to align with the flow, providing
even greater strength in the flow direction; this also contributes
to its superior wide-temperature range.
The physical advantage of low thermal expansion and low mould
shrinkage-properties is further enhanced in thin-wall sections due
to even more pronounced molecular alignment. In addition these
resins are highly resistant to many chemicals, including concentrated acids, bases and hydrocarbons. They also display outstanding fatigue resistance and high dielectric strength performance
over a very wide temperature range.

14

1. Because of its toughness and mechanical strength over a broad temperature range, ZENITE 6130 liquid
crystal polymers as found in compact
coil forms, offer United Technical Products Inc. board assembly advantages
and result in excellent pin retention.
Its suitability for precision moulding
in thin sections allows board space
saving at equal winding space. The
material is UL94 V0 recognized.

2. Injection moulded microminiature


surface-mount Conan connectors,
used in portable phones and computers, are a classic case for ZENITE. High
thermal stability, precision surfaces and
strength in thin walls are crucial factors
in the field of micro-electronics.
3. The qualities of ZENITE permit these
bobbin assemblies to obtain increased
winding space, excellent pin positioning and to withstand SMT soldering
processes.

4. In the miniature world of Littelfuse


Inc., ZENITE LCP is welcomed for use
in holders for ceramic fuses and for
the encapsulation of glass fuses. It
allows assembly by infrared and other
soldering processes. The strength of
the material is put to the test every
time a fuse has to be replaced; a test
successfully passed with ZENITE.
5. ZENITE can also be perfectly and
easily metallised. For this reason, this
lamp socket, made by VLM, is moulded in ZENITE, with a very high temperature resistance as a result. Extra
high thermal resistance LCP replaces
other high temperature polymers,
which sometimes melt under these
extreme conditions.

6. The market trend is to design smaller antifog lamps with more powerful
bulbs, hence the temperature reached inside the housing has dramatically increased. ZENITE 6330 BK was
selected for its excellent heat resistance, no out-gassing, and good surface appearance.

15

Theres always something new


in todays ZYTEL

Since DuPont introduced the first nylon materials nearly 70 years


ago, ZYTEL has become the worlds largest selling nylon resin.
Today we offer a wide range of unreinforced nylons, providing the
right choice for every market need; designers can choose just the
right balance of properties to do the job in the most cost-effective
way.
ZYTEL resists hostile environments. It can withstand high temperatures and can be modified to meet tough impact conditions.
Its electrical insulation characteristics, UL flammability rating, and
ability to be coloured are among the other important benefits
it offers.
ZYTEL resins are designed for high productivity. They provide excellent flow properties, reduced moulding cycles, and fast mould
release. This can mean appreciable gains in productivity, resulting
in more saleable parts per hour.

16

1. These cable straps moulded in


unreinforced ZYTEL have good flex
strength and creep resistance, and
a UL94 V2 rating. ZYTEL allows easy
filling of complex mould cavities,
resulting in fast moulding cycles.
2. The Rover 25 Diesel fuel swirl pot
is manufactured from an unreinforced
heat stabilised ZYTEL variant. The
product was chosen due to the ability
of the grade to resist contact with
Diesel fuel and elevated temperatures.

3. The body and actuators of these


switches are moulded in an unreinforced ZYTEL resin. The grade withstands the soldering temperatures,
meets the relevant flammability
requirements and also enables snap
fit features to be incorporated. The
moulding characteristics lead to fast
cycling and general ease of processing.
4. These aerosol valves moulded in
ZYTEL 135F allow fast cycling and
economical manufacturing. They
show excellent chemical resistance
and dimensional stability with a very
tight tolerance band. This make possible the continuous production of
high precision components.
5. Changing from die-cast zinc to
impact-modified ZYTEL 408 enabled
Global to improve their design, and
produce the only nylon castors with
the required combination of impact
and creep resistance to meet British
Standards for furniture.

6. ZYTEL 101F is used in this refrigerator lamp housing for its good elongation, UL94 V2 rating and excellent
surface glossiness. It is also unaffected by cleaning materials.
7. Cupboard hinges moulded in ZYTEL
135F allow fast cycling and economical manufacturing. They show excellent stiffness and toughness, as well
as resistance to creep and fatigue.

17

It starts tough it stays tough


its for your toughest jobs ZYTEL ST

Unlike most other engineering thermoplastics, super-tough


ZYTEL ST is insensitive to notching, meaning that it can take a lot
of punishment and stay in one piece. Scratches dont concentrate
stress and become weak points, parts keep their toughness, and
they dont become brittle at low temperatures. In fact, at 20C,
ZYTEL ST is tougher than most thermoplastics at room temperature.
ZYTEL ST is a nylon, so it has outstanding resistance to chemicals,
solvents, oils and greases.
Designers working with ZYTEL ST can specify intricate shapes,
varying thicknesses and tricky corners and know that moulders
can produce these parts easily and quickly.
And for an even broader range of application possibilities, talk to
us about some of the new ZYTEL ST resins. They include Super
Tough glass-reinforced compositions for extra strength, consistent
performance and low cost special, soft resins for longer endurance and repeated flexing in complicated shapes and extra low
temperature resins for winter sport and automotive applications.

18

1. What takes more abuse than a


skateboard? A snakeboard, a new
double-jointed skateboard development that enables riders to perform
even more spectacular jumps and
spine-jarring manoeuvres. Plastic was
an obvious choice because of its fromthe-mould finish and colourability. But
finding one thats light, resilient and
very, very tough was less easy, and for
Clausen Plastics (Pty) Ltd, the choice
narrowed down to just one that met
all their requirements ZYTEL ST801
Super Tough nylon.

2. ZYTEL ST overcame production


problems posed by this Jaguar cooling fans aerodynamic and structural
requirements. Using ZYTEL ST cut
one third of the original steel fans
weight, and eliminated costly spot
welding.
3. High stiffness and impact resistance were the key criteria that led
Hilti AG of Liechtenstein to choose
DuPont ZYTEL resin for their unique
stand-off curtain-wall fasteners. This
DuPont nylon is suitable for use
between 40 C and 80 C, resists
weathering, has low humidity absorbtion plus excellent creep and stresscrack resistance.

4. Italian sport manufacturer MGM


chose ZYTEL for the plate system of
its new In-line roller/Ice skating shoe.
The excellent impact and abrasion
resistance of DuPont ST nylon easily
withstands all the knocks and scrapes
to which ice-skates and in-line rollers
are subjected.
5. ZYTEL ST replaced expensive
fabricated metal for a range of Gas
Cylinder Valve Guards produced by
Norton Plastics in the UK.
The guard protects the gas cylinder
valve from damage, which can occur
particularly when the cylinders are
accidentally dropped during transportation. The low temperature impact
resistance of ZYTEL ST is a key reason for using the product in this application, combined with the materials
ability to be easily injection moulded
and coloured.

6. Carbon canisters are devices incorporated into modern vehicles, which


help to minimise fuel emission levels.
They are often located low down in
the engine compartment, being exposed to flying road surface debris,
high temperatures, oil and fuel vapour.
Tennex (UK) have chosen to produce
a canister housing and lid in ZYTEL ST
which readily resists this highly demanding environment and provides
an excellent barrier to fuel vapour.

19

Dont settle for ordinary glass-reinforced


nylon move up to the extra performance
of glass-reinforced ZYTEL

For designers who need high strength, stiffness, and the highest
deflection temperatures, ordinary glass-reinforced thermoplastics
are not enough; for the really tough jobs, they need glass-reinforced ZYTEL the worlds top selling glass-reinforced nylon.
During formulation, we upgrade the base resins rigidity, tensile
strength, creep resistance, heat distortion temperature, low temperature impact strength, and dimensional stability by combining
it with selected glass fibres. The result is a range of products that
finds increasing use especially in car engine compartments,
where it is replacing metals and other plastics.
Fan wheels for freezer rooms, dishwasher pump housings and
typewriter daisy wheels are other applications proving the ability
of glass-reinforced ZYTEL to measure up to any challenge. The
possibilities of this material are virtually endless. Thats why it is
finding such a broad range of uses not only in the automotive
industry but also throughout the electrical, appliance and furniture industries.

20

1. Dolmar reduced the weight of its


former grinder-cutter by about 25%
by using ZYTEL for the housing and
the double-bottomed fuel tank. In this
application, DuPont nylons excellent
mechanical strength, balance of stiffness and toughness, high heat distortion temperature, good abrasion resistance and chemical resistance play
important roles.
2. Reducing complexity and improving cost-effectiveness are always high
on the agenda at Audi. Together with
DuPont and the system supplier
Mann+Hummel an air intake manifold,
using ZYTEL 70G35, ensured rigidity
and mechanical strength that the
manifold needs under extreme vibration loads at high temperatures.

3. The ability to resist fatigue in the


presence of pressurised antifreeze at
120C makes glassreinforced ZYTEL
the ideal material for radiator end
tanks.
4. Glass-reinforced, flame-retardant
ZYTEL has helped Braun design a
multifunctional coffee grinder motor
bracket with far fewer components
than the aluminium bracket it replaced.
ZYTEL complies with the arc tracking
and flammability requirements of
European and American specifications,
and provides all the stiffness and heat
resistance demanded by this application.
5. Glass-reinforced ZYTEL was chosen
for this circuit breaker made by Medex,
Spain. Its flame retardant properties
(GW960 at 3 mm), good surface
appearance, low warpage and high
tensile modulus are the main reasons
for selecting this flame retardant nylon.

3
4

6. ZYTEL is often used for automotive


rocker covers because it provides the
high stiffness, heat stability, oil and
chemical resistance required, while
weighing less than the metal it replaces.
7. A special glass reinforced, heatstabilized, hydrolysis resistant grade
of DuPont ZYTEL helped Grundfos
to develop new domestic circulator
pumps that are lighter than cast iron
pumps. ZYTEL also resists cleaning
fluids and other aggressive substances
found in domestic heating systems.

21

ZYTEL HTN the reliable high performance


polyamide resin for critical applications

ZYTEL HTN (high performance polyamide resin) features excellent


physical and electrical properties at the shorter-term elevated
temperatures encountered with SMT Surface Mount Technology
components, connectors, fuse holders and coil forms, etc. For
the automotive industry, ZYTEL HTNs resistance to lubricants, fuels,
salt, anti-freeze, transmission fluids, etc. makes it ideal for a broad
range of under-bonnet applications. The ZYTEL HTN range retains
its excellent physical and mechanical properties even in conditions
of high humidity and heat.
ZYTEL HTN displays outstanding high-temperature stability, strength,
toughness and low moisture absorption, making it the ideal material where performance reliability in tough conditions is paramount.
For long-term heat ageing applications, ZYTEL HTN glass-reinforced
outperforms PA66 products. It offers a unique combination of
high-temperature performance with improved dimensional stability, low creep, lower moisture absorption and higher chemical
resistance than conventional nylons.

22

1. Schupa-Elektro uses ZYTEL HTN in


its UP-PI protection switch because
this material resists deformation at
temperatures of up to 260 C, has
a maximum operating temperature
of 300 C for short periods and also
meets UL94 V0 flammability specifications.
2. Cooper Power Systems looked
at the performance of ZYTEL HTN in a
hot and humid environment for their
secondary bushings for pad-mounted
distribution transformers. In test, it
proved to have a higher heat deflection
temperature, better high-temperature
electrical strength and higher tensile
strength than the polymers commonly used in such electrical applications.

3. To prevent these spiders, or multifunctional armature insulators in windshield wiper motors, from burning or
melting in case of an overload (e.g.
frozen wipers), ITT Automotive chose
ZYTEL HTN to do the job. Injection
moulded, ZYTEL HTN insulators are
of a uniformly high quality that resists
extremely high temperatures. In the
production process, the material allows
a very high throughput and very low
scrap rates.
3

4. ZYTEL HTN was selected by WOCO


for the Mercedes Class A resonator
because of its high peak temperature
resistance and good heat ageing.
5. AMP chose ZYTEL HTN because it
is suitable for IR reflow soldering and
had good flow properties during the
moulding process.
6. The use of ZYTEL HTN has enabled
a fan to be designed with excellent
air circulation and extremely low
noise by taking advantage of ZYTEL
HTN low warpage, dimensional stability and property retention at high
temperatures.

23

Properties of non-flame retardant CRASTIN


thermoplastic polyester resins

PBT

Unreinforced
Property

Test conditions

MECHANICAL

Yield stress
Yield strain
Stress at break (tensile)
Strain at break (tensile)
Tensile modulus
Flexural strength
Charpy impact strength (notched)
Charpy impact strength (unnotched)
Izod impact strength (notched)

TEMPERAT. INDEX

THERMAL

Izod impact strength (unnotched)


Melting temperature, by DSC
Temperature of deflection under load

10C/min
0,45 MPa
1,8 MPa
5 MPa, 4 100 100 mm plate
Coefficient of linear
Parallel (in flow direction) 23C to 55C
thermal expansion Normal (perpendicular to flow) 23C to 55C
Relative temperature index
Electrical
Mechanical with impact
Mechanical without impact
Tensile strength
(for stress and break)

3 mm
3 mm
3 mm
5000 h
20000 h

ELECTRICAL

Dissipation factor 1)
Surface resistivity
Volume resistivity
Electric strength (Dielectric strength)
Comparative tracking index (CTI)

FLAMMABILITY

CTI M

OTHERS

23C
23C
23C
23C, 50 mm/min
23C, 5 mm/min
23C, 1 mm/min
23C
23C
30C
23C
30C
23C
30C
23C
30C

Flammability classification

0,75 mm
1,5 mm
1,6 mm
3 mm

Burning rate
Glow wire flammability index
Oxygen index
Density
Water absorption

23C, 1 mm, 102 Hz


23C, 1 mm, 106 Hz
23C, 1 mm
23C, 1 mm
23C, 1 mm
23C, plate 2 mm, 20 s
23C, 1 mm
23C, 3 mm
Plate 4 mm

23C, saturation, immersed


23C, equilibrium, 50% R.H.

Properties are not applicable for this material.


1) Specimen of 80 80 1 mm, measured with silver paint.

All the above information is subject to the disclaimer printed on the back page of this document.

24

General
purpose
S600F20

Super
tough
ST820

Test
method

Units

ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2

MPa
%
MPa
%

58
3,8

ISO 527-1/-2
ISO 178
ISO 179/1eA

MPa
MPa
kJ/m2

2500

ISO 179/1eU

kJ/m2

NB

ISO 180/1A

kJ/m2

ISO 180/1U

kJ/m2

ISO 11357-1/-3
ISO 75 -1/-2

C
C

225
150
50

225
105
48

ISO 11359-2

104/C

1,3
1,3

1,9
1,9

UL 746B

130
115
120

IEC 60216

IEC 60250
IEC 60093
IEC 60093
IEC 60243-1

104
104
ohm
ohm m
kV/mm

IEC 60112

5,5

20
200
>1014
>1013
26
600
250

38
7,1

>50

1700
67
87
12,5
NB
NB
58
10
NB
215

1015
>1013

600
>600 M

UL 94/IEC 60695

HB
HB

ASTM D 635
IEC 60695-2-12
ISO 4589-1/-2

cm/min
C
%

ISO 1183
Similar to ISO 62

kg/m3
%

22

HB
4,6
700
19

1310
0,50
0,20

1220
0,31
0,12

Properties of flame retardant


CRASTIN PBT thermoplastic
polyester resins
Reinforced

Filled

Unreinforced

Reinforced

General
purpose
SK605

Glass
beads
SO655

General
purpose
S660FR

General
purpose
SK655FR1

140

Low
warp
LW9330

135

Tough
T805

145

50

2,8
9700
210
12,4
11,1
68
82
11
9
56
55

2,3
9800

4,2
7400
160
14
12,5
77
89
12
10
50
50

2,5
11000
220
11

3,6
4000
95
3,5
3,5
34
50
4
3
26
25

225
220
205
179
0,3
0,9

220

213
205
186
152
0,3
1,2

225-250

130
130
130
165
145

130
130
130

9
55
7
65

185

25
180
>1015
>1013
31
17
450
400
200 M

113

PBT/PET
SK9230

HB
HB

1530
0,37
0,13

1420

10

205

225
212
99

135

Low
warp
LW9330FR

120

120
120
120
150
135

440

HB
HB
3,5
750
19

HB
HB

1510
0,35
0,14

1550
0,55
0,2

Tough
T845FR

105

2
11000

3,7
4,3
67
67
4
4
57

3
10500
210
10
10
60
57
10
10
50

3,6
8200
170
11,5
10
60
65
11
9
44
44

225
165
55

225
222
213

220

130
130
140

140
130
140

2800

9
45

185

1
1

140
130
140
155
140
95
218
1015
>1013
29
17
500
450
200 M

HB
HB
3
750
19

45

54
3,2

Super
tough
ST830FR

140
120
140

136
190
1015
>1013
25
17
250
250
200 M

130
130
130

146
1014
>1013

375
600

250

V0

V0

V0
V0

210
205
185
165
0,3
1,2
140
140
140
160
145
130
170
1015
>1013
27
16
275
300
175 M

HB
HB
2,7
750
22

V0
V0
960
30

960
32

960

960
30

1530
0,35
0,12

1470

1680

1550

1670
0,27
0,10

V0

* = property not applicable for this material.


NB = no break.

All the above information is subject to the disclaimer printed on the back page of this document.

25

Properties of DELRIN acetal resins

Test
Test conditions method

Property

PROCESSING

OTHERS

FLAMMAB. RHEOLOGY

THERMAL

MECHANICAL

Yield stress 1)

23C, 5 mm/min
70C, 5 mm/min
100C, 5 mm/min
120C, 5 mm/min
Yield strain 1)
23C, 5 mm/min
70C, 5 mm/min
100C, 5 mm/min
120C, 5 mm/min
Strain at break 1)
23C, 5 mm/min
23C, 50 mm/min
Nominal strain at break
23C
Tensile modulus 2)
23C, 1 mm/min
70C, 1 mm/min
100C, 1 mm/min
120C, 1 mm/min
Charpy impact strength (notched)
23C
30C
Charpy impact strength (unnotched)
23C
30C
Izod impact strength (notched)
23C
40C

ISO 527-1/-2

MPa

ISO 527-1/-2

ISO 527-1/-2

High
viscosity

High
viscosity

Medium
viscosity

100/
107

100P/
127UV

111P

500/
507

73/72
50
36
22
21/25
18
14
9

70
50
36
22
22/23
18
14
9

72

19

72
50
36
23
15
14
11
8

45/50
3100
1500
900
600
14
11
NB
NB/350
14/12
12/8

45
3000
1300
900
700
15
11
NB/400
350
14/13
12/11

40
3200

12
8
210
200
11
11

45
30
3200
1500
1000
600
9
8
340
300
9/8
9/6

178
165
100
115
174
160

178
160/165
95
110
174
160

178
165
100
115
174
160

178
165
100
115
174
160

104/C
1,1/1,2
1,1/1,2

1,1/1,2
1,11/1,2

1,1
1,1

1/1,2
1/1,2

g/10 min

2,3/2,2

2,4

2,3

14

HB

HB

HB

HB

kg/m3
%

1420
0,27/0,25
0,2/0,22
0,9
92
120

1420
0,4
0,28
1,4/1,2
92
120

1420
0,3
0,22
1
92
120

1420
0,31/0,25
0,22
0,9
92
120

2,1
1,9

2,1
1,9

2
1,9

2,1/1,9
2/1,8

ISO 527-1/-2
ISO 527-1/-2

%
MPa

ISO 179/1eA

kJ/m2

ISO 179/1eU

kJ/m2

ISO 180/1A

kJ/m2

Melting temperature, by DSC


10C/min ISO 11357-1/-3
Temperature of deflection under load 0,45 MPa ISO 75-1/-2
1,8 MPa
Annealed, 1,8 MPa
Vicat softening temperature
10 N ISO 306
50 N
Coefficient of linear thermal expansion
ISO 11359-2
Parallel (in flow direction) 23C to 55C
Normal (perpendicular to flow) 23C to 55C

C
C

Melt mass-flow rate


190C/2,16 kg ISO 1133

Flammability classification
Density
Water absorption

1,5 mm UL94/IEC 60695

ISO 1183
24 hours immersion Similar to ISO 62
50% R.H., equilibrium
Saturation, immersed
Scale M ISO 2039/2
Scale R

Hardness, Rockwell
Mould shrinkage

Parallel (in flow direction) 2 mm ISO 294-4


Normal (perpendicular to flow) 2 mm
Chemical resistance

1) Testing speed 5 mm/min.

All resins have outstanding resistance to neutral chemicals,


including a wide variety of solvents

2) Testing speed 1 mm/min.

All the above information is subject to the disclaimer printed on the back page of this document.

26

Units

High
viscosity

Medium
viscosity

Medium
viscosity

Low
viscosity

Low
viscosity

Low friction
and wear

Toughened

Toughened

Toughened

500P/
527UV

511P

900P/
927UV

911P

500CL

100ST

100T

500T

71/70
50
36
23
14/15
14
11
9

40
30
3200
1400
1000
600
9
8
300/270
300/260
9/8
9/8

73

12

71
50
35
22
12/14
12
10
8

74

70
50
36
22
14
13
11
11

43

52

58

30

26

16

>100
>50
1400

75
>50
1900

8
6
180
180
8
7

>100
23
3100
1500
1000
600
8
7
350
290
9
9

100
20
NB
NB
90
20

25
14
NB
NB
20
13

15
12
NB
NB
14
8

8
7
260
260
8
8

27
25/18
3200/3300
1400
900
600
7/8
6
200
200
7/6
7

178
160/165
95
110
174
157/160

178
165
105
115
174
160

178
165/159
95
110
174
160

178
165
110
115
174
160

178
160
90
105
174
159

178
100
60
70
168
116

178
160
80
85
170
140

178
155
80
90
171
139

1,13/1,21
1,09/1,2

1,2
1,17

1,23
1,23

1,17
1,17

1,12
1,14

1,26
1,36

1,2

1,26
1,18

15

14

25

25

14

12

HB

HB

HB

HB

HB

HB

HB

HB

1420
0,4
0,3
1,4/1,2
92
120

1420
0,3
0,2
0,9
92
120

1420
0,43
0,3
1,4
92
120

1420
0,28
0,2
1
92
120

1420
0,27
0,24
1
92
120

1340
0,44
0,35
0,9
58
105

1370
0,3
0,9
59,3
112,6

1390
0,41
0,2
0,8
79
117

2,1/1,9
2/1,8

1,9
1,8

2,1
2

1,9
1,8

1,9
1,9

1,3
1,4

2,1
1,9

1,8
1,7

25
3400

20
3400

55
30
2500

All resins have outstanding resistance to neutral chemicals,


including a wide variety of solvents
* = property not applicable for this material.

All the above information is subject to the disclaimer printed on the back page of this document.

27

Properties of HYTREL thermoplastic polyester elastomer resins


General purpose grades

RHEOLOGY

THERMAL

MECHANICAL

Property

1)

Test
Test conditions method

Stress at break (tensile)


Strain at break (tensile)
Stress at 5% strain
Stress at 10% strain
Tensile modulus
Flexural modulus

23C, 50 mm/min
23C, 50 mm/min
23C, 50 mm/min
23C, 50 mm/min
23C, 1 mm/min
40C
23C
100C
Izod impact strength (notched) 2)
40C
23C
Charpy impact strength (notched) 2)
23C
Melting temperature, by DSC
Temperature of deflection under load
Vicat softening temperature
Melt mass-flow rate

ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2
ISO 178

MPa
%
MPa
MPa
MPa
MPa

ISO 180/1A

kJ/m2

ISO 179/1eA

kJ/m2

10C/min ISO 11357-1/-3


0,45 MPa ISO 75-1/-2
1,8 MPa
10 N, 50C/h ISO 306
190C, 2,16 kg ISO 1133
220C, 2,16 kg
230C, 2,16 kg
240C, 2,16 kg

OTHERS

Density
Water absorption

ISO 1183
23C, equilibrium 50% R.H. ISO 62
23C, immersion 24 h
23C, saturation, immersed
Shore hardness, Durometer D
23C, maximum ISO 868
15 s
Resistance to flex cut growth, Ross (pierced) 23C ASTM D 1052

Taber abrasion resistance


ASTM D 1044
23C, CS-17 wheel, 1 kg, 1000 cycles modified
23C, H-18 wheel, 1 kg, 1000 cycles
Initial tear resistance, die C
ISO 34-1
Normal (perpendicular to flow) 23C
Parallel (in flow direction) 23C
1) All properties were measured on injection-moulded specimens at 23C, unless specified otherwise.
2) Specimens 6,35 mm thick.

All the above information is subject to the disclaimer printed on the back page of this document.

28

Units

G3548L

G4074

G4078W G4774

G5544

6358

9,7
240
1,7
2,5
23
50
32
7
NB
NB
NB

17
250
2,5
4,4
55
200
65
30
NB
NB
NB

17
250
2,5
4,4
55
170
65
16
NB
NB
NB

17
200
3,8
6,8
105
260
117
60
NB
NB
NB

23
300
6
11
185
810
183
100
27
64
90

46
490
12
15
280
1850
296

C
C

154

170
50

170
50

75

115

115

208
60
45
168

215
77
45
190

213
85
45
195

g/10 min

10

5,3

5,3
11

10

1180

1220
0,4
1,6
2,2
55
50

1220
0.2
0,5
0,6
63
58

kg/m3
%

points

1150

5
35
26

Cycles to
5 cut
>106
growth
mg
30
310
kN/m
58

1180
0,4
2,1
3,7
40
35

1180
0,4
2,1
3,7
40
35

2,5
4,1
47
43

>106

>106

>106

9
193

20
260

13
168

9
116

96
86

88

94

140
123

19
81
120

0,8 106

145
158

High-performance grades

Specialty grades

7248

8238

3046

4056

4068

4556

5526

5556

6356

7246

HTR
5555HS

46
350
14
20
525
2390
544

50
400
28
33
1180
2600
1116
260
5,5
11,2
15

20
900

30
424
2,4
4,2
53
155
62
27
NB
NB
NB

22
620
2,4
3,5
30
172
45
28

34
550
4,1
5,7

44
500
6,9
11
188
760
200
100
115

46
490
12
15
280
1800
296
150
19
81
125

53
450
14
23
525
2350
550
200
7
40
120

42
520
6,9
10,3
184
760
195
110
110
60
84

30
300
7,5
10,8
150
750
170
60
130
NB
NB

36
450
5,5
8,9
74
470
115
45
114
NB
NB

14
400
3,9
5,2
140
650
145
50

NB

42
500
6,9
11
180
760
180
100
NB
NB
NB

150
50

193
55

110

135

193
50
35
155

203
65
45
180

203
70
45
180

211
85
45
195

218
95
45
205

203
60
40
177

196
50
45
170

198
60
40
155

170
48
45
109

8,5

8,5

18

8,1

0,5

2,6

4,7

1160
0,2
0,5
0,5
55
52

1170
0,2

1420

219
95
45
205

221
105
45
210

24

NB
NB
NB
172

11

NB

210
87
44
NB
NB
NB

12,5

1250

1280
0,2
0,3
0,6
82
74

0,3
0,6
72
68

HTR
5612

HTR
8068

5,6
8,5
9

13

HTR
4275 BK

12,5
1070

30
25

1150
0,2
0,6
0,7
40
39

1100
0,3
0,7
0,7
40
33

1140
0,2
0,6
0,6
45
40

1190
0,2
0,6
0,6
55
51

1190
0,2
0,6
0,6
55
52

1220
0,2
0,5
0,6
63
58

1260
0,2
0,3
0,6
72
68

1190
0,2
0,7
0,6
55
52

>10 6

>10 6

0,5 10 6 0,5 10 6 0,5 10 6 0,03 10 6 0,1 10 6

0,05 10 6 0,6 10 6

1,9
0,6
50
48

44

>10 6

9
20

3
100

15
80

3
72

7
70

6
64

7
77

13
47

20
227

38
186

25

112

212
228

98
101

95

123
122

133
133

137
137

145
158

167
200

124
134

98
171

106
129

64
68

* = property not applicable for this material.


NB = no break.

All the above information is subject to the disclaimer printed on the back page of this document.

29

Properties of MINLON mineral reinforced nylon resins


Mineral reinforced grades

MECHANICAL

Stress at break (tensile)


Strain at break (tensile)
Tensile modulus
Charpy impact strength (notched)
Charpy impact strength (unnotched)
Izod impact strength (notched)

THERMAL

Melting temperature, by DSC


Temperature of deflection under load 1)
Vicat softening temperature
Coefficient of linear thermal
expansion

Parallel
Normal 3)
2)

ELECTRICAL

Comparative tracking index (CTI)


Electric strength (dielectric strength)
Surface resistivity
Volume resistivity
Relative permittivity

FLAMMAB.

Dissipation factor

Flammability classification 4)

OTHERS

Density
Water absorption
Rockwell hardness

PROCESSING

Ball indentation hardness

1)
2)
3)
4)

23C, 5 mm/min
23C, 5 mm/min
23C, 1 mm/min
23C
30C
23C
30C
23C
30C

Mould shrinkage

PA66/6 blend

PA66

MINLON

MINLON

MINLON 13T2
DAM
50% RH

Units

DAM

10B140
50% RH

ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2
ISO 179/1eA

MPa
%
MPa
kJ/m2

ISO 179/1eU

kJ/m2

ISO 180/1A

kJ/m2

82
3,5
6600
3,5
3,5
35
25
3,5
2,5

54
9
3900
4,5
2
60
25
4
2,5

Test
Test conditions method

Property

PA66

10C/min
0,45 MPa
1,8 MPa
50 N
23C to 55C
23C to 55C

ISO 11357-1/-3 C
ISO 75-1/-2
C
ISO 306
ISO 11359-2

C
104/C

23C, 1 mm
23C, 1 mm
23C, 1 mm
23C, 1 mm
102 Hz, 1 mm
106 Hz, 1 mm
102 Hz, 1 mm
106 Hz, 1 mm

IEC 60112
IEC 60243-1
IEC 60093
IEC 60093
IEC 60250

V
kV/mm
ohm
ohm m

IEC 60250

104

1,5 mm UL 94/
IEC 60695
ISO 1183
23C, equilibrium 50% RH Similar
23C, saturation, immersed to ISO 62
ISO 2039-2
Scale M
Scale R
ISO 2039-1

Parallel (in flow direction) 2 mm ISO 294-4


Normal (perpendicular to flow) 2 mm

kg/m3
%

MPa
%

DAM
89
10
5800
6,5
5
130
80
6
4

263
240
200
245
0,67
0,88

256
220
140
235
0,86
0,86

575
40

550
36
>10
1010
9,4
4,5
2100
550
15

4,5
3,9
110
230

4,3
3,6
120
240

11C140
50% RH
60
24
2500
9
4
NB
80
9
4

72
16
4300
9,5
6
NB
115
9
5,5
263
225
89
230
0,94
0,85

27
1014
109
12,6
4,5
4400
750

37

4,2
4,1
110
200

HB

HB

HB

1500
1,6
5

1460
1,8
5,7

1360
1,5
6

95
121
250

86
120
255

80
118
200

1,2
1,2

169

1,4
1,4

55
34
2200
11
5
NB
115
11
4

127

9,3
4,1
3600
550

115

1,4
1,6

Values are obtained by first annealing test bars for 30 min. in oil at 50C below melting point of the resin.
In flow direction.
Perpendicular to flow.
Numerical flame test ratings are not intended to present behaviour of moulded parts in real life fire conditions; each end-user must determine whether any potential flammability hazards exist with parts moulded from MINLON
enginnering thermoplastic resins. UL yellow cards available upon request.

All the above information is subject to the disclaimer printed on the back page of this document.

30

Mineral reinforced grades Mineral glass reinforced grades


PA66

PA6

PA66

PA6

MINLON 13MM
DAM
50% RH

MINLON 73M30
DAM
50% RH

MINLON EFE6053
DAM
50% RH

MINLON 73GM30HSL MINLON EFE6091 BK


DAM
50% RH DAM
50% RH

74
19
3800
7,5
5,5
NB
110
7
5

82
14
4900
6,5
3,5
125
85
6
4

157
2,3
10400
4,5
4
45
40

110
3
7000
6
6
45
45
4,5
4,5

263
220
80
244
0,85
0,85

51
55
1800
13
4,5
NB
110
12
4,5

223
196
111
210
0,88
1,02

56
46
1800
13
3,5
NB
85
12

95
4,6
7200
6,5
4
50
40

263
256
245
250
0,28
0,87

223
214
190, 195
210
0,47
0,79

PA66

60
4
4000
8
6
55
40
6,5
4

132
2,4
8200
4,5

79
4
5600
6

40

45

3,5

3,5

263
243

28

4,9
4,8
140
130

13,9
5
5400
700

HB

HB

HB

HB

1240
2,1
7,7

1350
2,1
6,3

1470
1,5
5

1350
1,8
6,3

254
1,8
1,4

0,9
0,9

1470
1,6
5

149

0,4
1,1

0,4

NB = no break.

All the above information is subject to the disclaimer printed on the back page of this document.

31

Properties of RYNITE

PET

thermoplastic polyester resins


Glass reinforced

THERMAL

MECHANICAL

General purpose
Property

Test conditions

Test method

Units

Stress at break (tensile)

23C, 5 mm/min

ISO 527-1/-2

Strain at break (tensile)

23C, 5 mm/min

ISO 527-1/-2

Tensile modulus

23C, 1 mm/min
23C
30C
23C
30C

Charpy impact strength (notched)


Charpy impact strength (unnotched)

TEMPERATURE INDEX
ELECTRICAL
FLAMMABILITY
OTHERS

530

545

MPa

120

158

182

2,7

2,5

ISO 527-1/-2

MPa

7200

11000

15500

ISO 179/1eA

kJ/m2

9
8
33
27

11
11
60
45

11
11
60
40

ISO 180/1A

kJ/m2

9
7,7

10
10

11

ISO 179/1eU

Izod impact strength (notched)

23C
30C

Melting temperature, by DSC

10C/min

ISO 11357-1/-3

252

252

252

Temperature of deflection under load

0,45 MPa
1,8 MPa

ISO 75-1/-2

245
220

245
224

250
230

Coefficient of linear thermal expansion


Parallel (in flow direction) 40 to 23C
23 to 55C
55 to 160C
Normal (perpendicular to flow) 40 to 23C
23 to 55C
55 to 160C

ISO 11359-2

104/C
0,31
0,25
0,11
0,72
0,93
0,90

0,22
0,10
0,04
0,67
0,81
1,07

0,18
0,13
0,05
0,54
0,71
0,95

140
140
140
140
140
140
140
140
140

140

140

140
140
140
140
140
140
140
140
140

Relative temperature index:


Electrical

PROCESSING

520

0,75 mm
1,5 mm
3 mm
0,75 mm
1,5 mm
3 mm
0,75 mm
1,5 mm
3 mm

Mechanical with impact

Mechanical without impact

UL 746B

140
140
140
140

Comparative tracking index (CTI)

23C, 1 mm

IEC 60112

250

250

250

Electric strength (Dielectric strength)

23C, 1 mm

33,5

IEC 60243-1

kV/mm

35

32

Surface resistivity

23C

IEC 60093

Ohm

1014

1014

Volume resistivity

23C

IEC 60093

Ohm m

1013

1013

HB
HB
HB

HB
HB

HB
HB
HB

650
750

800

750
850

20

20

Flammability classification 1), 2)

0,75 mm
1,5 mm
3 mm

Glow wire flammability index

2 mm
3 mm

UL 94

IEC 60695-2-12

Oxygen index

ISO 4589-1/-2

Density

ISO 1183

kg/m3

1460

1560

1690

Similar to ISO 62

0,2
1,1

0,2
0,7

0,14
0,62

ISO 294-4

%
0,25
0,85

0,2
0,8

0,25
0,85

Humidity absorption

23C, equilibrium 50% RH


23C, saturation, immersed

Mould shrinkage, plates 60 60 2 mm


Parallel (in flow direction) 2 mm
Normal (perpendicular to flow) 2 mm

1) Flame-retarded resins are subject to specific UL processing and handling regulations for applications where an official UL rating is required. For more detailed information, please contact your DuPont representative.
2) Numerical flame test ratings are not intended to represent behaviour of moulded parts in real life fire conditions; each enduser must determine whether any potential flammability hazards exist with parts
moulded from RYNITE. UL yellow card available upon request.
All the above information is subject to the disclaimer printed on the back page of this document.

32

Glass reinforced
Tough

Colour stable

Flame retardant

Mineral
reinforced

GW520CS

GW525CS

935

415HP

408

530CS

936CS

FR515

FR530L

79

125

180

120

107

135

170

140

165

85

3,3

2,3

2,6

1,8

2,3

4700

9500

11000

11200

6800

11500

17000

9000

11000

10200

11
8
55
25

12
12
70
86

11

10
10
43
30

10

20

8,5
8,5
40
33

10

50

8
7
40
35

35

40

6
4
25
20

13
7,7

13

9,5

7,7
6

8
9,5

7,5

5,9
4

250

252

245

247

254

252

254

252

250

252

238
207

220

245
225

205

240
200

243
222

240
224

220

235

230
200

0,40
0,20
0,32
0,98
1,17
1,09

0,24
0,14
0,08
0,85
0,85
0,92

0,33
0,18
0,12
0,70
0,88
1,05

0,22
0,19
0,1
0,68
0,92
0,98

0,16
0,11
0,07
0,55
0,79
0,96

140
140
140
120
120
120
140
140
140

140
140
140
140
140
140
140
140
140

140
140
140
140
140
140
140
140
140

140
140
140
140
140
140
140
140
140

155
155
155
155
155
155
155
155
155

155
155
155
155
155
155
155
155
155

140
140
140
140
140
140
140
140
140

250

250

225

250

250

200

250

FR543

Colour stable glow wire


(flame retardant)

0,26
0,16
0,14
0,53
0,52
0,81
140
140
140
140
140
140
140
140
140

140
140
140
140
140
140
140
140
140
300

34

33

1013

1013

1014

1015

1014

1011

1013

1013

>1013

1013

V0
V0

V0
V0
V0

V0
V0

HB
HB
HB

960

960
960

960

32

33

35

1530

1675

1790

0,17
0,77

0,11
0,62

0,13
0,83

0,25
0,9

0,2
0,75

0,3
0,7

HB
HB
HB

HB
HB
HB

HB
HB
HB

750
19

22

22

1390

1490

1590

1630

0,25
2,5

0,35
0,85

0,15
0,6

0,2
0,4

0,35
0,85

39

HB
HB

HB
HB
HB
825
21

1580

1650

1580

All the above information is subject to the disclaimer printed on the back page of this document.

33

Properties of ZENITE

LCP

liquid crystal polymer resins

Test
Test conditions method

Property 1)

Units

ZENITE
3130L

ZENITE
6130L

ZENITE
6140L

ZENITE
6330

ZENITE
7130

ZENITE
7145L

ASTM

mm

3,2

3,2

3,2

3,2

3,2

3,2

ISO

mm

143

130

123

127

150

120

110
35
19

130
50
35

135

125
48

150
60
56

119
40

1,8

1,8

1,1

1,5

0,9

1,7

2,6

1,3

1,7

1,1

17200

13000

18700

8800

17000

18000

12,5
4,5
2,8

11,7
5,5
4,8

10,5
4,8

18
9
9

18,6
9

46

51

130
20
11

170
50
33

183

125
42

174
64
48

158
58
43

10,0
3,1
2

12
5,5
4,8

15,6

9,6
3,3

13,1
8
6,5

13,8
8,3
8,6

25
25

30
35

12

8
9

20

12
10

25
35

25
35

20

40
60

33

13
18

46
72

110
125

80

160

185
225

60

327
415

440
655

555
740

316

330

335

335

335

353

355

225

275
265

280

275
245 3)

295

295

0,06
0,45

0,13
0,37

0,08
0,22

0,14
0,36

0,75 mm

130 6)

240

240 6)

130

240 6)

240

0,75 mm

130 6)

220 7)

130 7)

130

210

210

0,75 mm

130 6)

240

240 6)

130

240 6)

240

Thickness

Stress at break (tensile)


ISO 527-1/-2
23C, 5 mm/min, 4 mm

MPa

Tensile strength at break

MPa

23C, 3,2 mm ASTM D638


150C, 3,2 mm
200C, 3,2 mm

Strain at break (tensile)


ISO 527-1/-2
23C, 5 mm/min, 4 mm

Elongation at break

ASTM D638

ISO 527-1/-2

MPa

23C, 3,2 mm
Tensile modulus
23C, 1 mm/min, 4 mm
ASTM D638

GPa

MECHANICAL

23C, 3,2 mm
150C, 3,2 mm
200C, 3,2 mm
Shear strength

23C, 3,2 mm ASTM D732

MPa

ASTM D790

MPa

Flexural strength
23C, 3,2 mm
150C, 3,2 mm
200C, 3,2 mm
Flexural modulus

ASTM D790

GPa

23C, 3,2 mm
150C, 3,2 mm
200C, 3,2 mm
Charpy impact strength
(notched)

ISO 179/1eA

Izod impact strength 2)


(notched)
Izod impact strength
(unnotched)

ISO 179/1eU

THERMAL
TEMPERAT. INDEX

kJ/m2

30C, 4 mm
23C, 4 mm
ASTM D256

J/m

40C, 3,2 mm
23C, 3,2 mm
ASTM D4812 J/m
40C, 3,2 mm
23C, 3,2 mm

Melting temperature, by DSC

10C/min ISO 11357-1/-3 C

Temperature of deflection under load


ISO 75-1/-2
0,45 MPa, 4 mm
1,8 MPa, 4 mm
4)

Coefficient of linear thermal expansion


ASTM E228
Parallel (in flow direction) 23-150C, 3,2 mm
Normal (perpend. to flow) 23-150C, 3,2 mm

10 /C

Relative temperature index 5)


Electrical
Mechanical
with impact
Mechanical
without impact

UL 746B

All the above information is subject to the disclaimer printed on the back page of this document.

34

kJ/m2

30C, 4 mm
23C, 4 mm

Charpy impact strength


(unnotched)

58

Properties of ZENITE

LCP

liquid crystal polymer resins (continued)

Test
Test condition method

Property 1)
Thickness

Dielectric constant

Units

ZENITE
3130L

ZENITE
6130L

ZENITE
6140L

ZENITE
6330

ZENITE
7130

ZENITE
7145L

ASTM

mm

3,2

3,2

3,2

3,2

3,2

3,2

ISO

mm

ASTM D 2520 B
23C, 1E3 Hz, 3,2 mm
150C, 1E3 Hz, 3,2 mm
200C, 1E3 Hz, 3,2 mm
23C, 1E09 Hz, 3,2 mm
120C, 1E09 Hz, 3,2 mm
150C, 1E09 Hz, 3,2 mm
200C, 1E09 Hz, 3,2 mm
250C, 1E09 Hz, 3,2 mm

Dissipation factor

ELECTRICAL
FLAMMABILITY

4,4
5
5
4,3
4,4
4,4
4,5
4,8

3,6

0,02
0,013
0,012
0,004
0,015
0,024
0,045

0,013
0,007
0,014
0,004
0,016
0,023
0,032
0,034

0,013

3,9
4
4
4,1
4,2

4,3
5
5
4,3
4,4
4,4
4,7
0,033

4,6
5,4
5,5

0,013
0,006
0,012
0,004
0,016
0,022
0,030
0,033

0,013
0,009
0,015

ASTM D 2520 B
23C, 1E3 Hz, 3,2 mm
150C, 1E3 Hz, 3,2 mm
200C, 1E3 Hz, 3,2 mm
23C, 1E09 Hz, 3,2 mm
120C, 1E09 Hz, 3,2 mm
150C, 1E09 Hz, 3,2 mm
200C, 1E09 Hz, 3,2 mm
250C, 1E09 Hz, 3,2 mm

0,002
0,014
0,020
0,029
0,026

Surface resistivity

23C IEC 60093

ohm

>1015

>1015

>1015

>1015

>1013

Volume resistivity

23C IEC 60093

ohmm

>1013

>1013

>1013

>1013

>1013

22
21

29
28
27

26

>28 9)
>28 9)
>26 9)
>27 9)

21
20
20
20

217

175-249

175-249

167

<100

V0
V0

V0
V0
V0

V0
V0

Electric strength (Dielectric strength)


ASTM D149
Short Time 8)
23C, 3,2 mm
120C, 3,2 mm
150C, 3,2 mm
200C, 3,2 mm

kV/mm

Comparative tracking index (CTI)

UL 746B
23C

OTHERS

4
5,5
6,2
4,3
4,3
4,4
4,6

Flammability classification

Glow wire flammability index

0,75 mm UL 94
1,5 mm
3 mm
3 mm IEC 60695-2-12

V0
V0
V0
C

960

960

42

41

1620
1620

1620
1680

Oxygen index

ISO 4589-1/-2

Density

ISO 1183

Kg/m3

Black
White
Natural

1) Changes to the colours shown by using other colourants and additives may alter some or all of these properties. The data listed here will fall within the normal range of product properties but they should not be
used to establish specification limits nor be used as the basis of design. Please note that property values
are generally better at lower thicknesses. More data is available in the ZENITE Product guide and properties L-10147.
2) Determined on 127 12,7 mm end-gated specimens impacted in the transverse direction.
3) Natural colour; 239C for black.
4) Determined by Quartz Dilatometer method on 76,2 127 3,18 mm specimens.

V0
V0
V0

960

1710
1760

47

45

45

1630

1620
1660

1740
1810

1630
5) Complete UL listing available on request.
6) at 0,75 mm Provisional value.
7) at 3 mm black.
8) Determined with surrounding medium of a high temperature oil. Use of other mediums including air may
alter some or all properties.
9) Arcing around occurred on 65 per cent of test specimens.

All the above information is subject to the disclaimer printed on the back page of this document.

35

Properties of ZYTEL nylon resins


Unreinforced

Property

Test conditions

MECHANICAL

Yield stress
Yield strain
Stress at break (tensile)
Strain at break (tensile)
Nominal strain at break
Tensile modulus
Charpy impact strength (notched)
Charpy impact strength (unnotched)

THERMAL

Izod impact strength (notched)

Melting temperature, by DSC


Temperature of deflection under load
Vicat softening temperature
Coefficient of linear
Parallel (in flow direction)
thermal expansion
Normal (perpendicular to flow)

FLAMMAB.

ELECTRICAL

Relative permittivity
Dissipation factor
Surface resistivity
Volume resistivity
Electric strength (Dielectric strength)
Comparative tracking index (CTI)

OTHERS

10C/min
0,45 MPa
1,8 MPa
50 N, 50C/h
23C to 50C
23C to 50C

102 Hz, 1 mm, 23C


106 Hz, 1 mm, 23C
102 Hz, 1 mm, 23C
106 Hz, 1 mm, 23C
23C
23C
1 mm, 23C
1 mm, 23C

Flammability classification1)
Glow wire flammability index
Oxygen index
Density
Water absorption

1,5 mm
1,5 mm
1,5 mm

Equilibrium, 50% RH, 23C


Saturation, immersed, 23C

Rockwell hardness

Ball indentation hardness


PROC.

23C, 50 mm/min
23C, 50 mm/min
23C, 5 mm/min
23C, 5 mm/min
23C, 50 mm/min
23C, 50 mm/min
23C, 1 mm/min
23C
30C
23C
30C
23C
30C

Mould shrinkage

Test
method

Units

ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2

MPa
%
MPa
%

ISO 527-1/-2
ISO 527-1/-2
ISO 179/1eA

%
MPa
kJ/m2

ISO 179/1eU

kJ/m2

ISO 180/1A

kJ/m2

ISO 11357-1/-3 C
ISO 75-1/-2
C
ISO 306
ISO 11359-2

ISO IEC 60250


IEC 60250

104

IEC 60093
IEC 60093
IEC 60243-1
IEC 60112

ohm
ohm m
kV/mm
V

UL 94/IEC 60695
IEC 60695-2-1 C
ISO 4586
%
ISO 1183
Similar
to ISO 62
ISO 2039-2

Scale M
Scale R
H 358/30 ISO 2039-1
H 961/30
Parallel (in flow direction) 2 mm
Normal (perpendicular to flow) 2 mm

C
104/C

ISO 294-4

kg/m3
%

PA66

PA66

ZYTEL 101L
DAM
50% RH

ZYTEL 103HSL
DAM
50% RH

83
4,5

85
4,4

40
22
3100
5
4
NB
NB
5
5

53
25

>50
>100
1200
15
4
NB
NB
13
4

263
200
70
238
1
1,1
3,8
3,5
80
180
1012
1012
31
600

40
20
3100
5
4
NB
NB
5
6

10,9
4
2100
750
>1015
1011
28

3,8
3,5
75
165
1012
1013
31
600
V2
950
28

1140
2,7
8,5

1140
2,7
8,5

MPa

>50
>100
1250
14
4
NB
NB
14
5

263
200
70
238
1
1,1

V2
850
28

79
121

54
25

12,8
4
5800
700
1012
1011
28

59
108
85

160
%

1,3
1,3

1,3
1,3

1) Numerical flame test ratings are not intended to present behaviour of moulded parts in real life fire conditions; each end-user must determine whether any potential flammability hazards exist with parts moulded from ZYTEL
nylon resins. UL yellow cards available upon request.

All the above information is subject to the disclaimer printed on the back page of this document.

36

Unreinforced
PA66

PA6

PA612

ZYTEL 135F
DAM
50% RH

ZYTEL 7335F
DAM
50% RH

ZYTEL 151L
DAM
50% RH

98
4,5

18
13
3600
4
3
NB
NB
3
2,3

69
18

>50
>50
2100
9
3
NB
NB
6,5
2

263
210
88
243
1,21
1,21

90
4

30
8
4000
4
2
40
110
3
2

55
24

>50
>50
1400
18
3
NB
60
1,5
1,5

62
4,5

100
17
2400
3,5
3,5
NB
NB
4
4,5

223
185
70
200
0,76
0,92

218
135
62
180
1,1
1,2

4,2

>1013

3,6
3,2
135
160
1012
1013

600

600

>600

V2
850

HB

V2

3,9
3,8
70
200

8,7
3,9
2400
600

300

54
18

>100
>50
1700
4
3
NB
40
4,5
3

6
4
1000
1012

27
1140
2,7
8,5
87
123

0,8
1,3

1130
3
9
64
116

1060
1,3
3

114

0,5
0,5

103

1,2
1,2

NB = no break.

All the above information is subject to the disclaimer printed on the back page of this document.

37

Properties of ZYTEL nylon resins


Toughened

Property

Test conditions

MECHANICAL

Yield stress
Yield strain
Stress at break (tensile)
Strain at break (tensile)
Nominal strain at break
Tensile modulus
Charpy impact strength (notched)
Charpy impact strength (unnotched)

THERMAL

Izod impact strength (notched)

Melting temperature, by DSC


Temperature of deflection under load
Vicat softening temperature
Coefficient of linear
Parallel (in flow direction)
thermal expansion
Normal (perpendicular to flow)

FLAMMAB.

ELECTRICAL

Relative permittivity
Dissipation factor
Surface resistivity
Volume resistivity
Electric strength (Dielectric strength)
Comparative tracking index (CTI)

OTHERS

10C/min
0,45 MPa
1,8 MPa
50 N, 50C/h
23C to 50C
23C to 50C

102 Hz, 1 mm, 23C


106 Hz, 1 mm, 23C
102 Hz, 1 mm, 23C
106 Hz, 1 mm, 23C
23C
23C
1 mm, 23C
1 mm, 23C

Flammability classification1)
Glow wire flammability index
Oxygen index
Density
Water absorption

1,5 mm
1,5 mm
1,5 mm

Equilibrium, 50% RH, 23C


Saturation, immersed, 23C

Rockwell hardness

Ball indentation hardness


PROCESS.

23C, 50 mm/min
23C, 50 mm/min
23C, 5 mm/min
23C, 5 mm/min
23C, 50 mm/min
23C, 50 mm/min
23C, 1 mm/min
23C
30C
23C
30C
23C
30C

Mould shrinkage

Test
method

Units

ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2

MPa
%
MPa
%

ISO 527-1/-2
ISO 527-1/-2
ISO 179/1eA

%
MPa
kJ/m2

ISO 179/1eU

kJ/m2

ISO 180/1A

kJ/m2

ISO 11357-1/-3 C
ISO 75-1/-2
C
ISO 306
ISO 11359-2

PA66

ZYTEL 114L BK097


DAM
50% RH

ZYTEL 408
DAM
50% RH

75
7

61
6

30
20
3000
12
8
NB
NB
10
7

52
33

>100
>50
1400
15
5
NB
NB
15
5

263
149
75
225
1,21
1,21

IEC 60250

104

IEC 60093
IEC 60093
IEC 60243-1
IEC 60112

ohm
ohm m
kV/mm
V

UL 94/IEC 60695
IEC 60695-2-1 C
ISO 4586
%
ISO 1183
Similar
to ISO 62
ISO 2039-2

ISO 294-4

kg/m3
%

55
35
2200
18
15
NB
NB
19
11

3,2

3,6

200

600

1012

1011

575

3,2
2,9
200
200
1015
1013
33,5
600

HB

HB
675
19

1120
2,5
7,9

1090
2,2
7

76
118

71
115

MPa

43
26

>100
>50
2200
25
6
NB
NB
20
4

263
155
65
210
1,32
1,32

IEC 60250

Scale M
Scale R
H 358/30 ISO 2039-1
H 961/30
Parallel (in flow direction) 2 mm
Normal (perpendicular to flow) 2 mm

C
104/C

PA66

7
3,7
1500
500
>1015
1011

50
102

85
123

1,1
1,2

1,2
0,9

1) Numerical flame test ratings are not intended to present behaviour of moulded parts in real life fire conditions; each end-user must determine whether any potential flammability hazards exist with parts moulded from ZYTEL
nylon resins. UL yellow cards available upon request.

All the above information is subject to the disclaimer printed on the back page of this document.

38

Toughened

Supertough

PA66

PA66

PA6

PA66

ZYTEL 450
DAM
50% RH

ZYTEL 490
DAM
50% RH

ZYTEL 7300T
DAM
50% RH

ZYTEL ST801
DAM
50% RH

55
5,5

68
4

50
5,7

55
5,4

50
28
2200
22
10
NB
NB
25
10

40
29

>100
>50
1000
67
9
NB
NB
70
8

263
92
65
195
1,61
1,61

>1013

50
33
2100
67
20
NB
NB
66
17
263
85
68
220
1,52
1,52

50
29

>100
>50
950
104
15
NB
NB
83
16

40
15
2750
14
9
NB
NB
11
13
223
55
195
1,04
1,22

40
30

>100
>50
890
110
5
NB
NB
90
6

60
32,4
2000
80
18
NB
NB
80
20

600

600

HB

HB

HB

HB
675
19

1080
2,2
7

1080
2,3
7,1

1100
2,6
9

1080
2,2
6,7

112

1,7
1,3

1,6
1,1

0,6
0,7

>100
>50
900
115
17
NB
NB
94
20

263
132
65
205
1,2
0,9
3,2
2,9
80
140
1015
1012
31
600

1010

43
37

8
3,6
1800
550
1015
1011
39

89

1,6
1

NB = no break.

All the above information is subject to the disclaimer printed on the back page of this document.

39

Properties of ZYTEL nylon resins


Glass reinforced

Property

Test conditions

MECHANICAL

Yield stress
Yield strain
Stress at break (tensile)
Strain at break (tensile)
Nominal strain at break
Tensile modulus
Charpy impact strength (notched)
Charpy impact strength (unnotched)

THERMAL

Izod impact strength (notched)

Melting temperature, by DSC


Temperature of deflection under load
Vicat softening temperature
Coefficient of linear
Parallel (in flow direction)
thermal expansion
Normal (perpendicular to flow)

FLAMMAB.

ELECTRICAL

Relative permittivity
Dissipation factor
Surface resistivity
Volume resistivity
Electric strength (Dielectric strength)
Comparative tracking index (CTI)

OTHERS

10C/min
0,45 MPa
1,8 MPa
50 N, 50C/h
23C to 50C
23C to 50C

102 Hz, 1 mm, 23C


106 Hz, 1 mm, 23C
102 Hz, 1 mm, 23C
106 Hz, 1 mm, 23C
23C
23C
1 mm, 23C
1 mm, 23C

Flammability classification1)
Glow wire flammability index
Oxygen index
Density
Water absorption

1,5 mm
1,5 mm
1,5 mm

Equilibrium, 50% RH, 23C


Saturation, immersed, 23C

Rockwell hardness

Ball indentation hardness

PROC.

23C, 50 mm/min
23C, 50 mm/min
23C, 5 mm/min
23C, 5 mm/min
23C, 50 mm/min
23C, 50 mm/min
23C, 1 mm/min
23C
30C
23C
30C
23C
30C

Mould shrinkage

Test
method

Units

ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2

MPa
%
MPa
%

ISO 527-1/-2
ISO 527-1/-2
ISO 179/1eA

%
MPa
kJ/m2

ISO 179/1eU

kJ/m2

ISO 180/1A

kJ/m2

ISO 11357-1/-3 C
ISO 75-1/-2
C
ISO 306
ISO 11359-2

IEC 60250
IEC 60250

104

IEC 60093
IEC 60093
IEC 60243-1
IEC 60112

ohm
ohm m
kV/mm
V

UL 94/IEC 60695
IEC 60695-2-1 C
ISO 4586
%
ISO 1183
Similar
to ISO 62
ISO 2039-2

Scale M
Scale R
H 358/30 ISO 2039-1
H 961/30
Parallel (in flow direction) 2 mm
Normal (perpendicular to flow) 2 mm

C
104/C

ISO 294-4

kg/m3
%

PA66

PA6

ZYTEL 70G30HSL
DAM
50% RH

ZYTEL 73G30HSL
DAM
50% RH

195
3,4
3

125
5
5

180
3,5

10000
12
10
82
70
13
12

7200
16
10
93
73
17
10

9500
12
10
95
80
14
10

263
260
255
250
0,22
1,07
4,4
4,1
70
150
>1015
>1013
38
400

115
5,5

6200
20
20
95
85
19
11

223
220
210
215
0,22
1,02
10,8
4,6
4600
650
1013
109
32

4,4
4,1

1014
1013

HB

HB

1370
1,9
6

1360
1,9
6,3

104
124

88
117

275

187

1013
108

MPa

0,3
1,1

0,2
0,7

1) Numerical flame test ratings are not intended to present behaviour of moulded parts in real life fire conditions; each end-user must determine whether any potential flammability hazards exist with parts moulded from ZYTEL
nylon resins. UL yellow cards available upon request.

All the above information is subject to the disclaimer printed on the back page of this document.

40

Glass reinforced (Speciality)

Toughened glass reinforced

PA66

PA612

PA66

PA66

PA6

ZYTEL 70G30HSLR
DAM
50% RH

ZYTEL 77G33L
DAM
50% RH

ZYTEL 79G13L
DAM
50% RH

ZYTEL 80G33HS1L
DAM
50% RH

ZYTEL 73G30T
DAM
50% RH

195
3,3

130
5

165
3

135
3

118
4

67
10

135
3,5

95
5

165
3

102
5

10000
12
10
82
70
13
12

7200
16
10
92
72
17
10

9500
12
10
70
60
12
10

7900
12
10
65
40
12
10

5100
8
6
67
59
8
6

3700
14
6
59
54
9
4

8500
20
16
90
100
20
15

5800
22
14
80
75
20
10

9600
19
19
106
94
15
10

6200
25
25
98
94
20
11

263
261
255
250
0,22
1,07
4,3
4,1
70
150
1015
1013
38

218
215
200

263
260
242
240
0,5
1,3

0,17
1,13
10,8
4,6
4600
650
1013
109
32

4,1
3,8
135
150
1012
1013
27
600

200

3,9
3,7
65
130

37
475

263
260
245
245
0,15
1,19
9,8
4,5
2500
660

223
221
210
215
0,28
1,2

4
3,6

9,3
4,3

130
1012

600
1010
109

35

4,1
3,8

1015
1013
35

HB

HB
673
23

HB

HB

HB

1370
1,9
6

1320
0,7
2

1210
2,2
6,5

1330
1,5
4,5

1340
1,8
6,2

0,3
1,1

0,3
1

90
120

74
110

180

100

0,5
0,8

1015
109
39

70
110

0,3
0,8

0,2
0,4

All the above information is subject to the disclaimer printed on the back page of this document.

41

Properties of ZYTEL nylon resins


Flame retardant

Property

Test conditions

MECHANICAL

Yield stress
Yield strain
Stress at break (tensile)
Strain at break (tensile)
Nominal strain at break
Tensile modulus
Charpy impact strength (notched)
Charpy impact strength (unnotched)

THERMAL

Izod impact strength (notched)

Melting temperature, by DSC


Temperature of deflection under load
Vicat softening temperature
Coefficient of linear
Parallel (in flow direction)
thermal expansion
Normal (perpendicular to flow)

FLAMMAB.

ELECTRICAL

Relative permittivity
Dissipation factor
Surface resistivity
Volume resistivity
Electric strength (Dielectric strength)
Comparative tracking index (CTI)

OTHERS

10C/min
0,45 MPa
1,8 MPa
50 N, 50C/h
23C to 50C
23C to 50C

102 Hz, 1 mm, 23C


106 Hz, 1 mm, 23C
102 Hz, 1 mm, 23C
106 Hz, 1 mm, 23C
23C
23C
1 mm, 23C
1 mm, 23C

Flammability classification1)
Glow wire flammability index
Oxygen index
Density
Water absorption

1,5 mm
1,5 mm
1,5 mm

Equilibrium, 50% RH, 23C


Saturation, immersed, 23C

Rockwell hardness

Ball indentation hardness

PROC.

23C, 50 mm/min
23C, 50 mm/min
23C, 5 mm/min
23C, 5 mm/min
23C, 50 mm/min
23C, 50 mm/min
23C, 1 mm/min
23C
30C
23C
30C
23C
30C

Mould shrinkage

PA66/6 Copolymer
FR72G25V0
DAM
50% RH

Test
method

Units

ZYTEL FR70G25V0
DAM
50% RH

ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2

MPa
%
MPa
%

125
2

110
2,6

135
2,5

100
3,5

ISO 527-1/-2
ISO 527-1/-2
ISO 179/1eA

%
MPa
kJ/m2

ISO 179/1eU

kJ/m2

ISO 180/1A

kJ/m2

9000
10
9
43
45
6,5
6

7500
10
6,5
45
10
6,5
6

9200
12
11
55
70
9
8

6500
14
9
60
60
13
8

0,26
0,83

242
241
215
220
0,2
1,06

ISO 11357-1/-3 C
ISO 75-1/-2
C
ISO 306
ISO 11359-2

C
104/C

IEC 60250
104

IEC 60093
IEC 60093
IEC 60243-1
IEC 60112

ohm
ohm m
kV/mm
V

UL 94/IEC 60695
IEC 60695-2-1 C
ISO 4586
%
ISO 1183
Similar
to ISO 62
ISO 2039-2

ISO 294-4

263
243
235
0,26
0,83
4,3

IEC 60250

Scale M
Scale R
H 358/30 ISO 2039-1
H 961/30
Parallel (in flow direction) 2 mm
Normal (perpendicular to flow) 2 mm

PA66

kg/m3
%

42
4,4
180

160
120
1013
37
325

26
325

1013
35
325

V0
960

V0
960

1490
0,9
3,4

1490
1,1
4,1

130

25

MPa
227
%

0,3
0,8

133

213

1406

0.3
0,8

1) Numerical flame test ratings are not intended to present behaviour of moulded parts in real life fire conditions; each end-user must determine whether any potential flammability hazards exist with parts moulded from ZYTEL
nylon resins. UL yellow cards available upon request.

All the above information is subject to the disclaimer printed on the back page of this document.

42

High viscosity/Extrusion
PA66

PA66

PA66

PA66

PA612

ZYTEL FR70M30V0
DAM
50% RH

ZYTEL E40
DAM
50% RH

ZYTEL E42A
DAM
50% RH

ZYTEL E51HSB
DAM
50% RH

ZYTEL 158
DAM
50% RH

85
4,4
73
2

54
6

8600
2,5
2
21
21
2,1
2,1

4500
3
2
24
19
2,57
1,9

263
240
200
235
0,64
0,81
4,1
3,7
140
140
>1015
>1013
40
325

50
3000
6
4
NB
NB
5,5
3
263
205
72
242
1
1

9,1
4,2
4100
500
109
33

3,9
100

1013
600

V0
960
38
1620
1,3
4

55
28

86
5

52
27

85
4,4

55
29

>50
1200
20
3
NB
NB
12,5
2

>50
3100
6
5
NB
NB
5,5
4,5

>50
1200
20
4
NB
NB
12
4

>50
3000
7

>50
1200
22

NB

NB

19

1
1

263
205
72

223
205
70

1
1

1
1

4,3
3,6
150
240
1013
30,5
600

10,3
4,2
2000
750
1012
1011

1
1

3,.9

1013
600

HB

35
2400
4
4
NB
NB
4
5

>50
1500
8
4
NB
NB
6
4,5

6
4
1000
1011

600
HB
25

1140
2,7
8,5

1140
2,7
8,5

1140
2,6
8,5

1060
1,3
3
114

1
1

52
19

218
135
62
180
1,2
1,2
3,6
3,2
140
165
1012
1013

100

600

62
4,3

1,4
1,4

1,4
1,4

1,5
1,5

108

1,2
1,2

NB = no break.

All the above information is subject to the disclaimer printed on the back page of this document.

43

Properties of ZYTEL nylon resins


Specialities

Property

Test conditions

MECHANICAL

Yield stress
Yield strain
Stress at break (tensile)
Strain at break (tensile)
Nominal strain at break
Tensile modulus
Charpy impact strength (notched)
Charpy impact strength (unnotched)

THERMAL

Izod impact strength (notched)

Melting temperature, by DSC


Temperature of deflection under load
Vicat softening temperature
Coefficient of linear
Parallel (in flow direction)
thermal expansion
Normal (perpendicular to flow)

FLAMMAB.

ELECTRICAL

Relative permittivity
Dissipation factor
Surface resistivity
Volume resistivity
Electric strength (Dielectric strength)
Comparative tracking index (CTI)

OTHERS

10C/min
0,45 MPa
1,8 MPa
50 N, 50C/h
23C to 50C
23C to 50C

102 Hz, 1 mm, 23C


106 Hz, 1 mm, 23C
102 Hz, 1 mm, 23C
106 Hz, 1 mm, 23C
23C
23C
1 mm, 23C
1 mm, 23C

Flammability classification1)
Glow wire flammability index
Oxygen index
Density
Water absorption

1,5 mm
1,5 mm
1,5 mm

Equilibrium, 50% RH, 23C


Saturation, immersed, 23C

Rockwell hardness

Ball indentation hardness


PROC.

23C, 50 mm/min
23C, 50 mm/min
23C, 5 mm/min
23C, 5 mm/min
23C, 50 mm/min
23C, 50 mm/min
23C, 1 mm/min
23C
30C
23C
30C
23C
30C

Mould shrinkage

PA6

FN718
DAM
50% RH

ZYTEL FN727
DAM
50% RH
23
44
>50

Test
method

Units

ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2
ISO 527-1/-2

MPa
%
MPa
%

30
50
>50

ISO 527-1/-2
ISO 527-1/-2
ISO 179/1eA

%
MPa
kJ/m2

>50
960
123
35

ISO 179/1eU

kJ/m2

ISO 180/1A

kJ/m2

ZYTEL

ISO 11357-1/-3 C
ISO 75-1/-2
C
ISO 306
ISO 11359-2

C
104/C

NB
NB

>50
>50

420

NB
NB

>50
770
131
65
NB
NB
NB

263

223

50
220
1,2

45
180
1,2

1040

1020

25
>50
>50

350

NB
NB
NB

1,2

IEC 60250
IEC 60250

104

IEC 60093
IEC 60093
IEC 60243-1
IEC 60112

ohm
ohm m
kV/mm
V

UL 94/IEC 60695
IEC 60695-2-1 C
ISO 4586
%
ISO 1183
Similar
to ISO 62
ISO 2039-2

Scale M
Scale R
H 358/30 ISO 2039-1
H 961/30
Parallel (in flow direction) 2 mm
Normal (perpendicular to flow) 2 mm

PA66

ISO 294-4

kg/m3
%

MPa

14
1,3

1) Numerical flame test ratings are not intended to present behaviour of moulded parts in real life fire conditions; each end-user must determine whether any potential flammability hazards exist with parts moulded from ZYTEL
nylon resins. UL yellow cards available upon request.

All the above information is subject to the disclaimer printed on the back page of this document.

44

High Performance Polyamide, glass reinforced


PA6T/XT

PA6T/XT

PA6T/XT

HTN51G35HSL
DAM
50% RH

ZYTEL

ZYTEL HTN51G45HSL
DAM
50% RH

ZYTEL

HTN51G35HSLR
DAM
50% RH

220
2,4

210
2,1

220
2,4

210
2,1

240
2,4

230
2,1

12 500
12
11
65
56
11
11

12 500
11

12 500
12

12 500
11

15 000
11

55

65

44

11

11

10

15 000
11
12
85
61
12,5
12

300
275
265
0,15
0,49

0,18

300
275
265

300
275
265

0,18

0,15
0,45

4,5

120
1014
>1013
36
600

180
1014
>1013
35
600

HB
725
23

13

10
36
600

75
12

0,15

1013
1013
34
600

HB
23

24

1470

1470
0,4
1,5

1580

0,2
0,7

0,2
0,7

0,2
0,6

NB = no break.

All the above information is subject to the disclaimer printed on the back page of this document.

45

High temperature performance data of glass-reinforced ZYTEL


compared to ZYTEL PA66 resins
Property

Test method

Units

Melting temperature, by DSC


Glass transition temperature 1)
DAM
50% RH
Accelerated creep at 427,5 MPa, 100C 2)
Flexural creep modulus estimated after 10 years
% total strain estimated at 10 years
Flexural modulus 3)
DAM at 100C
Compressive strength 3)
DAM at 100C
Electric strength 4) (Dielectric strength)
DAM at 23C
DAM at 100C

ISO 3146 C
ISO 11357-3

C
C

ZYTEL HTN
51G35HSL

ZYTEL PA66
70G33HS1L

300

263

125
90

50
15

4520
0,6

2190
1,2

9520

4300

220

130

36
26,1

N/A
N/A

ISO 178

ISO 178

MPa
%
MPa
MPa

IEC 60243-1

1) The glass transition temperatures are based on the onset of loss in modulus as measured by the Dynamic
Mechanical Analysis (DMA) Method.
2) The Accelerated Creep was based on DMA to measure short-therm creep conducted at constant load and
at various elevated temperatures. These data were then superimposed to form a Master Curve, from
which the long-term creep behaviour is estimated. Annealed sample were used for the test specimens.

All the above information is subject to the disclaimer printed on the back page of this document.

46

HTN

kV/mm

3) Dry as Moulded (DAM) ISO properties.


4) ASTM D 149 Short-Term Method. Test Specimens: 1,6 mm thick, DAM.
N/A = not applicable

Safety, health and the environment

DuPont also cares for you, your employees, your communities


and our future generations. A company commitment has been
made, and significant programs are under way to continuously
improve our products and processes so that :
Injuries, Illnesses and Incidents are avoided;
Waste and Emissions are minimised or eliminated;
Energy and natural resources are conserved.
This will assure that we remain your strong partner also under
more and more stringent future regulations. And we will provide
you with the right products, so that you too can meet the increasing regulatory requirements. In addition, many things we learn
and develop can be used in our customers workshops. We are
more than willing to share this experience with you.
Already today, our Engineering Polymers are designed to enable
the design of reusable parts and to recycle any material waste.

The information in this brochure applies only to the specific compositions described. Colourants or other additives may alter some or all of the
properties of these compositions. This applies both to natural resins with the NC010 suffix and to coloured resins with other suffixes. The data
listed in this brochure fall within the normal range of product properties but they should not be used to establish specification limits nor used
as the basis of design.

47

For further information on Engineering Polymers contact:


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Chemical Terminals (1985) Ltd.
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IL-633 43 Tel Aviv
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ACENYL
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Telefax (212) 211 66 38

H-11737 11.03 Printed in Switzerland 2003 E.I. du Pont de Nemours and Company.

Ukraine
Du Pont de Nemours International S.A.
Representative Office
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Kyiv 252042
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United Kingdom
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Telefax (01442) 24 94 63
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(1884) Berazategui-Bs.As.
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Brasil
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Asia Pacific
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South Africa
Plastamid (Pty) Ltd.
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Cape Town
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P.O. Box 80022
Wilmington, Delaware 19880
Tel. (302) 999 45 92
Telefax (302) 892 07 37

Requests for further information from countries


not listed above should be sent to:
Du Pont de Nemours International S.A.
2, chemin du Pavillon
CH-1218 Le Grand-Saconnex/Geneva
Tel. (022) 717 51 11
Telefax (022) 717 52 00
The information provided in this documentation corresponds to our knowledge on the subject at the date of its
publication. This information may be subject to revision as
new knowledge and experience becomes available. The
data provided fall within the normal range of product properties and relate only to the specific material designated;
these data may not be valid for such material used in combination with any other materials or additives or in any
process, unless expressly indicated otherwise. The data provided should not be used to establish specification limits nor
used alone as the basis of design; they are not intended
to substitute for any testing you may need to conduct to
determine for yourself the suitability of a specific material for
your particular purposes. Since DuPont cannot anticipate all
variations in actual end-use conditions DuPont makes no
warranties and assumes no liability in connection with any
use of this information. Nothing in this publication is to be
considered as a license to operate under or a recommendation to infringe any patent rights.
Caution: Do not use this product in medical applications
involving permanent implantation in the human body. For
other medical applications see DuPont Medical Caution
Statement.

The DuPont oval and The miracles of science are registered trademarks or trademarks of DuPont or its affiliates.

Hellas
Ravago Plastics Hellas ABEE
8, Zakythou Str.
GR-15232 Halandri
Tel. (01) 681 93 60
Telefax (01) 681 06 36

sterreich
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P.O. Box 19
AT-1051 Wien
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Fax (01) 512 35 71-31
e-mail: [email protected]
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