Engineering Plastics and

Plastic Composites in
Automotive Applications

Kalyan Sehanobish

Warrendale, Pa.

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Library of Congress Cataloging-in-Publication Data

Sehanobish, Kalyan.
Engineering plastics and plastic composites in automotive
applications/Kalyan Sehanobish.
p. cm.
Includes bibliographical references.
ISBN 978-0-7680-1933-9
1.Plastics in automobiles. 2.Automobiles--Design and
construction. I.Society of Automotive Engineers. II.Title.
TL154.S383 2009
2008053079
629.232--dc22

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ISBN 978-0-7680-1933-9
Copyright 2009 SAE International
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do not necessarily represent those of the organizations to which the authors are
affiliated or SAE. The authors are solely responsible for the content of this book.
SAE Order No. T-122
Printed in the United States of America.

Introduction

efore the 1970s, plastics were considered primarily as non-engineering

materials and were used in applications such as belts, hoses, gaskets,
carpet backing, sealing, adhesives, tires, and so forth as a part of an
engineering solution. Those individuals who are not materials scientists
presumably wont classify elastomers (i.e.,natural and synthetic rubbers) and
adhesives used in these applications as engineering plastics, although those
materials have enabled the engineering function since their inception. It
wasnt until plastics started to replace metals that they began to be considered
as engineering materials.
Today, plastics have penetrated into engineering applications within the
automotive industry, replacing traditional materials at a significant rate
in only the past 30years. By themselves, plastics are poor choices for
engineering applications because of their poor strength-to-density ratio.1 The
introduction of plastics containing inorganic fillers and of plastic composite
systems with cross-linkable resins as binders advanced the growth of plastics
as structural materials in engineering applications. This book will not only
cover some of the current applications of plastics and their advantages but
also will address what may be foreseen in terms of new applications for
plastics in automotive engineering.
However, before going any further, lets share some actual data (Table1)
compiled from various sources on the penetration of plastics and plastic
composites into passenger vehicles.2,3 From Table1, it is evident that the use
of plastics in engineering applications has crept upward from approximately
4.6% of the overall vehicle body weight in 1977 to approximately 7.6% in 2003.
At first glance, this may not seem impressive, until you consider the increases
in the variety of equipment and accessories added to vehicles during the past
30years. In fact, these lightweight materials have allowed the industry to
maintain the overall weight of vehicles at the same level as a basic new car in
1977. Today, plastics comprise almost 50% of the material volume in most new
cars. Studies show that each 100pounds of plastics can replace approximately
200 to 300pounds of mass from traditional material.2,3

TABLE 1
PLASTICS IN A TYPICAL PASSENGER VEHICLE*

Year

Weight of
Plastics and
Plastic Composites
(lb)

2003

255.0

3358.5

7.6

2002

255.0

3339.5, 3357.53

7.6

2001

253.0

3309.0

7.6

2000

248.5

3286.0

7.6

1999

245.0

3274.0

7.5

1998

243.5

3261.5

7.5

1997

242.0

3248.0

7.5

1992

243.0

3135.5

7.7

Total Vehicle Weight

(lb)

Percentage of
Plastics and
Plastic Composites
(%)

1991

238.0

3059.0

7.8

1990

222.0, 2293

2896.0, 3140.53

7.7, 7.33

1989

224.5

3140.0

7.1

1988

219.5

3010.0

7.3

1987

221.5

3178.0

7.0

1986

216.0

3118.0

6.9

1985

211.5

3187.5

6.6

1984

206.5

3141.5

6.6

1983

200.0

3192.0

6.3

1982

202.5

3101.5

6.5

1980

196.5

1978

176.0, 180

1977

168.0

3309.0
3

5.9
3

3494.0, 3569.5

5.0, 5.03

3665.5

4.6

*This table is taken from publicly available data in Reference 2, with some exceptions in Reference 3 as noted.

Lets start by classifying the plastics found in various segments of an

automobile. (The use of plastics as foams and fabrics for noise absorption
and comfort will not be addressed here.) To begin, we find examples of
plastics primarily in decorative, safety, noise, vibration, and harshness
applications for the interior parts of the vehicle. These applications include
the cockpit systems (e.g.,instrument panels [IPs], structural portions of IPs,
and dashmats), headliners, seat systems (e.g.,seat backs and seat bases),
soft and hard trim (e.g.,door trim and pillars), interior door handles,
gloveboxes, and packaging trays. Steering wheels, door handles, and
mirror housings are other interior items that are built from plastics. Plastics

vi

have even entered critical safety-oriented applications such as airbags and

airbag covers.
Plastics are making modest advances in all horizontal and vertical body panel
parts in the exterior of the vehicle or behind the cockpit, thereby replacing
metals. These applications include door panels, roofs, floors, fenders, back
panels, hoods, and mud plates often used as part of the firewall. Greater
penetration of plastics into these parts is expected to occur in the future.
Other panels that will be considered here as exterior parts include the bumper
fascia, quarter panels, underbody shields, drag panels, exterior door handles,
and mirror housings. Improved performance and lightness of weight will
drive more plastics in these applications.
The powertrain segment is the most complicated and challenging application
of plastics. As modern plastics meet these challenges, the presence of
plastics will continue to grow. Plastics have already found their way into air
induction systems (e.g.,intake manifolds, ducts, air cleaners, air filters, and
snorkels), cooling systems (e.g.,hoses), side and front engine covers, engine
fans, turbo systems (e.g.,turbo impellers and housings), valve covers, oil
pans, oil filters, and belly pans.
Fuel systems have already experienced an invasion by plastics. The use of
plastics can be seen in fuel tanks, fuel rails, fuel pump parts, connectors,
hoses, and fuel filters. Furthermore, external and internal lighting systems
have already gone primarily to plastics. Wheel systems have adopted plastics
much earlier in the construction of tires, wheel covers, and wheel house
liners, although wheel systems remain primarily the domain of metals.
In spite of such frequent use of plastics, the automobile remains largely a
metal play with sheet metal, cast iron, aluminum, magnesium, and so forth.
According to the Society of the Plastics Industrys 1998 edition of Facts and
Figures, the land transportation industry consumes only approximately 5% of
the total plastics consumed in millions of pounds and remained unchanged
between 1993 and 2008. The packaging industry consumes approximately
25% of all plastics made today. Although more new applications for plastics
will be introduced in the transportation industry, a similar increase in the
use of plastics in other industries will tend to maintain the ratio of plastics
consumed as fairly constant. A dramatic change in this ratio can occur only
if regulatory mandates for lowering the weight of vehicles pushes plastics
vii

further into the horizontal and vertical body parts of vehicles, coupled with
innovation in plastic composites that addresses both the temperature-related
expansion issues and the high-temperature baking issues of plastics. The use
of plastics as structural beams and rails remains far from reality and only a
dream for the plastics industry and fabricators within that industry.
Although the field of plastics and plastic composites in the transportation
industry is vast, this book will focus on plastics that have already made entry
into the automotive segments mentioned in the preceding paragraphs. It will
conclude by projecting the future of plastics in the automotive industry in
light of predicted global trends.

viii

Contents
Introduction ............................................................................................................... v
Executive Summary ................................................................................................. ix
Chapter One ................................................................................................................1
Why Choose Plastics for Automotive Applications?
Chapter Two ................................................................................................................3
Plastics in the Interior of the Vehicle
Chapter Three ...........................................................................................................15
Plastics in Horizontal and Vertical Body Panels
Chapter Four .............................................................................................................19
Plastics in the Exterior of the Vehicle
Chapter Five ..............................................................................................................23
Plastics in the Powertrain
Chapter Six ................................................................................................................25
Plastics in Fuel Systems
Chapter Seven ...........................................................................................................29
Plastics in Lighting and Wheel Systems
Chapter Eight ............................................................................................................31
The Future of Plastics in Automotive Applications
References..................................................................................................................37
List of Acronyms ......................................................................................................41
About the Author .....................................................................................................45

iii

Chapter One

Why Choose Plastics for

Automotive Applications?
lastics is a broad term utilized primarily by the end users of
these materials. In technical terms, the scientific nomenclature
that more commonly defines plastics is that they are polymers
composed of long covalent-bonded molecules.

Plastics often are classified into three groups:

1. Thermoplastics
2. Rubbers
3. Thermosets
Thermoplastics can be melted or softened and then reformed, and they
demonstrate very little elastic recovery below their glass transition
temperature. By comparison, rubbers exhibit large extensions and will spring
back easily upon release. Thermosets are heavily cross-linked polymers
that normally are rigid and intractable. The use of both thermosets and
thermoplastics in passenger vehicles has grown to the point where a wide
variety of plastics now are used in vehicles. Figure1 shows the top ten types
of plastics used in automotive applications in North America.4

Figure 1 The use of

plastics in automotive
applications in North
America.

Plastics offer several advantages in terms of their performance characteristics

when used individually, as highly formulated filled plastic blends, and as
reinforced plastic composites. For example, plastics are durable, strong,
and lightweight, and they can be made transparent, translucent, or opaque.
Likewise, plastics can be soft, flexible, or hard, and they can be formed
into almost any shape, size, or color. Plastics can provide resistance to
heat, chemicals, and corrosion, depending on how they are formulated.
Furthermore, plastics are excellent thermal and electrical insulators and can
be formulated to impart both thermal and electrical conductivity to a certain
extent. In most cases, plastics are cost effective while providing automakers
with the design freedom to incorporate safety, styling, and comfort into
vehicles. Over the past decade, significant progress has been made in the
recovery and recycling capabilities for automotive plastics, but much more
remains to be done.
Thus, there are many good reasons that automotive engineers find plastics to
be an attractive and beneficial material for use in the design of vehicles. As
concerns about safety and lightness of weight unfold, plastics will continue to
be a key player in the automotive industry.

Chapter Two

Plastics in the Interior

of the Vehicle

oday, interior components account for the largest share of plastics

in vehicles. This fact is not expected to change dramatically as
plastics continue to gain acceptance for use elsewhere in vehicles.
Traditionally, instrument panels (IPs) were made from several metal
components that had to be painted and were held together by a steel
supporting structure. Plastics initially entered the IP market to improve
aesthetics on top of the steel structure. With the progression of time,
thermoplastics have been expanding further into this application segment,
facilitating complex designs and a reduction in both cost and weight. These
thermoplastics include the following:

Acrylonitrile-butadiene-styrene (ABS)
High-heat ABS (HHABS)
Blends of polycarbonate (PC) and ABS
Modified polyphenylene ether (PPE)
Modified polypropylene (thermoplastic polyolefin [TPO])
Long-glass-filled polypropylene (LGF PP) and ABS
Styrene maleic anhydride (SMA)

Designs that utilize thermoplastics could enable the integration of airbag

housings, instrument housings, and so forth with structural needs
(i.e.,structural portions of IPs), allowing for the elimination of steel beams.
However, the cost advantages remain debatable.
Lets take a closer look at some of the plastics in interior applications and
their performance characteristics. Figure2 shows some of the typical interior
applications for which plastics are predominantly the material of choice.
Because of their useful combination of toughness, stiffness, solvent resistance,
and processability, ABS polymers began to appear in interior applications
3

(a)

(c)

(b)

Figure 2 Various interior parts made from plastics: (a) instrument panel retainer,
(b) door trim, and (c) A-pillar hard trim. (Courtesy of LyondellBasell Advanced
Polyolefins)

during the 1980s. These materials are created by the polymerization of

acrylonitrile, butadiene, and styrene. The quantity of each of these three
monomers plays an important role in the ultimate properties of the resulting
copolymer. Resin suppliers can tailor resins for particular applications and
markets by varying the ratios of these three monomers and the morphologies
of the dispersed phases in subsequent processing. In 2008, the worldwide
capacity of ABS had been estimated to be 8million metric tons per year
(18billion pounds per year). In North America and Europe, the major
suppliers of ABS are BASF, BayerAG, and The Dow Chemical Company.
The recent introduction of thermoplastic polyolefin (TPO) into the same
application space has offered a considerable challenge to ABS suppliers in
terms of improving gloss. Although ABS has better mechanical properties
than most compounded TPOs, the lower gloss of TPO offers the benefit of
4

molded-in-color parts for use by the fabricators and ultimately the original
equipment manufacturers (OEMs). Recently, some manufacturers claim to
have reduced the gloss of ABS to that of the level of TPOs by adjusting the
morphology, but commercial acceptance of such materials is only in an early
stage.5 Figure3 displays one example of a part that typically is made from
TPO. The 60 gloss measurements shown at all locations in Figure3 are
plotted as a graph in Figure4.

Figure 3 60 gloss
measurement locations in an
injection-molded glovebox.

Figure 4 60 gloss
measurements at all
locations presented in
Figure3.

At all locations on Figure3, the gloss numbers of the new ABS grade as
molded undoubtedly are lower and even better than a competitive TPO
considered for the specific application.
The need to balance superior stiffness and toughness over that of existing
ABS led to the introduction of PC/ABS blends in the automotive industry.
Polymer blends have always played an important role in automotive
applications by providing additional properties that cannot be achieved with
only a single material. Based on its versatility, PC/ABS blends are considered
a mainstay engineering material for applications such as automotive IPs and
body panels.
Although ABS and PC are extremely useful amorphous resins (see the
discussion of PCs in Chapter7 on car lighting systems), they have some
limitations that can be resolved only by using them as blends. For example,
PC offers exceptional clarity, toughness, and heat resistance. Likewise, it is
notch sensitive and is more difficult to process than ABS resins. Similarly,
ABS is a tough material, is readily processed, and adheres well to paint and
foams. Because of the exceptional compatibility between these phases, an
alloy of these two resins results in a resin with a unique combination of their
properties. Blends of PC and ABS are noted for offering high heat resistance,
stiffness, toughness with less notch sensitivity, improved processability, and
versatile surface characteristics.
Figure 5 shows the notched Izod impact-resistance response as a function
of weight percentage of PC in the blend, measured in a typical part both
perpendicular and parallel to the flow direction to the mold. (The notched
Izod impact resistance is a standardized measure of practical fracture
toughness of material, ASTM D256, ISO 180.) Clearly, the notched Izod
impact is optimum near 70% weight of PC in the blend composition (or 65%
PC and 35% ABS by weight). Most PC/ABS blends sold in the market today
are formulated from the optimum blend composition. These PC/ABS blends
are available in four grades, based on performance needs:
1.
2.
3.
4.

General purpose
High flow
Blow molding
Low gloss

Figure 5 Impact
resistance versus blend
composition in a PC/
ABS blend.

All four grades are formulated by incorporating mineral fillers, glass

fibers, carbon fibers, and so forth to meet the performance need for rigid
applications with very little sacrifice of toughness.
Modified polyphenylene ether (PPE), more accurately named poly(2,6-dimethyl-p-phenylene ether), is made by the oxidation of substituted
phenols. It is characterized by regular, closely spaced groups of phenyls.6
(Phenol is an aromatic chemical compound derived from benzene.) General
Electric Plastics (now SABIC) made this polymer available commercially as
polyphenylene oxide (PPO). It often is modified by blending with a second
polymer that usually is a polystyrene (PS). This high-performance polymer
offers high heat-deflection temperatures and good flame resistance, and it
provides good flow and impact resistance only when combined with highimpact polystyrene. It is sold by SABIC in the automotive market under the
commercial name of Noryl PPO. However, a lack of chemical resistance,
ultraviolet (UV) resistance, and color stability mean that items made of this
polymer must be painted frequently when used in some demanding interior
applications. For IPs, UV resistance and color stability are critical and
often are preferred over high heat resistance (e.g.,heat resistance values of
approximately 208C for PPE, compared to approximately 145C for PC and
even lower for general-purpose ABS).
7

This polymer is also blended with nylon and is commercialized under the
name of Noryl. Nylons are one type of the early polymers developed by
Carothers in the 1930s. Most nylons are synthesized by repeatedly adding
two molecules of a diamine and two molecules of an acid. Depending on the
type of molecule, nylon can have wide range of properties.
Thermoplastic polyolefin is a useful polymer blend of polypropylene (PP),
filler, additives (e.g.,slip agents and anti-oxidants), and a thermoplastic
elastomer. In general, TPO can be classified into two broad categories:
1. High stiffness
2. High toughness
Today, TPOs are used increasingly in special automotive applications because
of their lower specific gravity, injection moldability, economics, recyclability,
and noise performance. Some variations of these essential ingredients
either are compounded in extruders (other mixers) or are prepared in some
combination of reactors (often referred to as reactor TPO) that can make both
PP and the rubber followed by some post-reactor addition of other chemicals.
Toyota Super Olefin Polymer (TSOP) is a special type of TPO offered
primarily in Japan.7 It is highly differentiated in its flow characteristics,
modulus, and balance of low-temperature properties due to some unusual
shared continuous morphology achieved through a unique fabrication route
of PP and elastomer blend. The ratio of elastomer to PP in this blend can be
adjusted to control the modulus and elastic recovery of a TPO.8
As already stated, typical TPO formulations can be classified for highstiffness and high-toughness (low-modulus) applications.7 High-toughness
formulations are designed for low ductile-to-brittle transition temperature
(DBTT) of 40C as measured by a notched Izod impact test (test method
ASTMD265), whereas the high-stiffness formulations are in the range of
20CDBTT.
Recently, a Grupo Antolin door module made from TPO for the Dodge
Caliber and Jeep Compass and Patriot received a Society of Plastics Engineers
body interior award in 2006 (Figure6). The door trim module combines all
door hardware components plus the trim panel. It was injection molded by
The Dow Chemical Company using a specific grade of TPO.

Figure 6 Door
module made of TPO.

Long-glass-filled (LGF) PP and ABS are glass-reinforced blends of PP and

ABS. Estimates are that approximately 30% of the 2million metric tons
of e-glass fiber consumed globally for polymer reinforcement is used in
thermoplastic composites. (E-glass is a type of alkali-free glass originally
used in electrical applications.) These composites have been growing at a
healthy pace of 15 to 20% per year, largely fueled by automotive applications.
Two key reasons that glass-reinforced thermoplastics are becoming so
important are their recyclability and their fit with the injection-molding
process. The incorporation of LGF reinforcement in PP has facilitated the
use of a lower-cost polymer in semi-structural engineered applications in
the automotive industry. Furthermore, LGF PP is especially interesting
because the enhanced reinforcing abilities of the glass fiber and the cost and
performance of PP make it an economical engineering material. This material
is quickly gaining importance, as evidenced by its annual growth rate of
more than 35% over the last four years. Although less versatile than LGF PP,
LGF ABS was introduced recently and promises a better balance in impact
performance. Figure7 shows an IP retainer made from LGF ABS.
Another plastic called styrene maleic anhydride (SMA) was first introduced
commercially under the trade name DYLARK and currently is sold
by NOVA Chemicals for the IP market segment as well. Styrene maleic
anhydride copolymers were developed during the late 1960s. In the early

Figure 7 Instrument panel retainer made with LGF ABS.

1970s, elastomer-modified reactor and fiberglass-reinforced DYLARK grades

offered enhanced heat resistance, impact resistance, tensile and flexural
strength, and flexural modulus properties. These performance characteristics
were adapted into a new and growing automotive applicationinjectionmolded substrates for softIPs.
In late 1970s, vehicle designs increased the slope of the windshield, which
in turn increased the temperature on the top surface of the exposed IPs.
Due to the thermal expansion of the cross-car beam, IPs using competitive
substrates buckled and warped along the windshield edge. The thermal
stability of DYLARK glass-reinforced resins demonstrated the physical
properties required to withstand thermal expansion in the new designs.
Glass-reinforced DYLARK also met U.S.government regulations for
improved safety and head impact through greater energy management over
a range of temperatures and speeds. Soft IPs progressed beyond carriers for
polyurethane foam to include more intricate designs for one- and two-piece
IP constructions. The new designs were more functional, had improved
cross-car structure, and contained additional packaging compartments for
the radio, heater, and speedometer openings. Variations of formulated
thermoplastics discussed so far can be used in any soft or hard trim
applications, gloveboxes, and packaging trays.
Dashmats are panels that are placed between the engine and the instrument
panel to prevent engine noise and other airborne noises from reaching the

10

ears of the occupants in an automobile. In the past few years, filled TPO has
been formulated to function as a sound barrier with various porous sound
absorbers. Rigid polyurethane (PU) thermosets also can be used as dashmat
solutions. Headliners, another component of the interior segment, consist
of many functional parts below the roof, and rigid PU is used most often as
a backing for the underlying foams and fabrics. Thermoplastic solutions are
found less frequently in this application.
Plastics recently have been used in seat backs through considerable design
engineering modification. A push toward weight reduction made this change
possible, and increasing numbers of OEMs are recognizing the advantage
of plastics in this application. Seat backs are a highly regulated safety item,
and plastics were first introduced by The Dow Chemical Company in 2000
for use in rear seat backs. Traditionally, steel has been the material of choice.
However, the introduction of PC/ABS as a double-shell blow-molded structure
led to a 20 to 25% weight savings.9 This blend was first introduced successfully
in the 2006 Audi TT in Europe (Figure8). Subsequently, other North American
OEMs adopted similar seat back designs made from PC/ABS for large vehicles,
but TPO or reinforced TPO also could be used in this application.

Figure 8 Blow-molded seat back made for

the 2006 Audi TT.

11

Seat bases are more demanding than seat backs. They must provide longterm creep resistance and must withstand low-speed crashes. They also must
be able to accommodate various comfort features (e.g.,reclining system,
heating, and massaging). For high-end cars, the performance need often
drives the choice of polymer composite (i.e.,thermoplastic or thermoset).
For low-end cars, LGF thermoplastic types of solutions may be adequate.
Fabricators recently have been trying to introduce a one-piece seat with
optional reclining features that would be suitable for low-cost cars. Engineers
are trying to make seats thinner and lighter to improve fuel efficiency, but
plastics have not yet appeared as the prime candidate.10
Interior door handles are less demanding than exterior door handles in terms
of chemical resistance. Clearly, PC/ABS is a winner in this application.
Steering wheels are made either from molded and pigmented vinyl ester
resins or from reaction-injection-molded1114 (RIM) pigmented urethane
when a ductile material is required. Low-friction acetyl often is used for the
switches, levers, and bearings of steering columns. It also is used in a variety
of automotive applications due to its ability to withstand high mechanical
and thermal stresses.
There are two types of vinyl ester resins:
1. Epoxy-based resins
2. Non-epoxy-based resins
A non-epoxy-based vinyl ester is simply a methacrylate terminated polyester.
It has a reduced resistance to caustic and acids and can be used as a plastic
composite binding resin in applications where high chemical resistance is not
critical. Epoxy vinyl ester resins have not penetrated the automotive market
because relatively inexpensive polyesters can meet most of the performance
needs except chemical resistance. However, it is possible to imagine the
introduction of epoxy vinyl ester resins into more corrosive or severe
applications near the engine, batteries, external body parts, and so forth.
Reaction-injection-molded PU offers a solution for the rapid production
of complex plastic parts directly from low-viscosity monomers (single
chemical unit) and oligomers (chain of multiple chemical units).1114 These
liquids are combined by impingement mixing as they enter the mold.
12

Reaction-injection-molded PU chemistry specifically involves the mixing

of polyoles (oligomers of alcohol units) and isocyanates (carbon-nitrogen
compounds). Thorough mixing is required in the mixing phase to achieve
uniform physical properties in the final manufactured part. For commercial
applications, most RIM chemical reactions in the mold must take place in less
than a minute. Non-reinforced RIMPU systems are soft and stretchy and can
have a modulus close to 1000MPa, a strength of approximately 30MPa, and
an average elongation to break that is close to 150%. The thermal expansion
of non-reinforced PU systems can be reduced approximately tenfold in
RIMPU composites by using appropriate fillers.
Nylon6,6 is the primary polymer for airbag fabric today. It is a mature
solution in which the airbag is coated with silicone to meet the requirements
for permeability. Polychloroprene was the polymer of choice as a coating
in the early development of airbags, but its inherent flaws made silicone
the coating of choice. Airbags are sewn mainly with nylon6,6 yarn. With
consideration of alternative deployment approaches to the current azidebased pyrotechnique and the introduction of more airbags or inflated air
curtains in vehicles, new material approaches will become more feasible.
Styrene-ethylene block (SEB) copolymers are the primary incumbent for
airbag covers. They often are referred to as r-TPV (made by a reactive
extrusion process with ethylene propylene diene monomer [EPDM], a
cross-linker, and PP). The total global demand for SEBS is approximately
30million pounds, divided almost equally among Japan, North America, and
Europe.6 Because of the fear of safety-related litigation, SEBS compounds
associated with airbags are designed to have superior elongation, tensile,
and tear strength over many other thermoplastic elastomers. SEBs are part
of the styrene block copolymer (SBC) family. In a crude sense, SBCs possess
strength properties that are equivalent to those of vulcanized elastomer
systems without vulcanization.
Thus, the interior of vehicles is a key application for the use of plastics. These
interior applications include IPs, body panels and door panels, dashmats, seat
backs, seat bases, steering wheels, and airbag covers. The materials in use
today can be individual polymers or blends that offer a variety of properties,
including high impact resistance, high stiffness, injection moldability, and
heat resistance. As materials science moves forward, plastics are expected to
play an important role in the interior of vehicles.
13

Chapter Three

Plastics in Horizontal and

Vertical Body Panels

he exterior body panels of vehicles include the door panels, roof, floor,
fenders, hood, and back panels. These highly demanding applications
require very strict and low coefficients of linear thermal expansion
(CLTEs) comparable to those of metals, with high-temperature sag resistance to
survive the high heat of the electrocoating bake ovens in the assembly lines of
large car platforms. (High temperatures in the bake ovens are needed primarily
to impart corrosion resistance to the rest of the steel structure.) This makes the
entry of plastics difficult because plastics are always introduced with existing
metals and therefore must match the specifications of the metal body panels.
For example, a certain amount of surface conductivity is essential to allow
painting side by side with metals in a single streamlined process.
The first major industrial use of thermoplastics (a filled blend of
polycarbonate [PC] and acrylonitrile-butadiene-styrene [ABS]) in an
automotive exterior door panel, rocker panel, and rear panel was introduced
by The Dow Chemical Company in a special process developed for the
General Motors Saturn line of vehicles. A formulated blend of nylon6,6
and polyphenylene oxide (PPO), known as NorylGTX, also was introduced
at the same time in those same Saturn vehicles by General Electric Plastics
(now SABIC) using a special assembly line procedure (Figures9 and10).
Some European OEMs also lowered the temperature of the bake ovens
to accommodate Noryl GTX to make exterior body panels. Most of the
applications are found in vehicle fenders. The absorption of moisture by
nylon remains a critical issue to be resolved in order to meet the performance
need. Some of the special requirements to accommodate plastics often have
driven the OEMs back to metal as a solution.
Apart from thermoplastics, two other materials labeled as SMC (sheet
molding compound) and reaction-injection-molded (RIM) were utilized as
body panels (Figure11). This type of body panel has higher material costs

15

Figure 9 Door panel made

of filled PC/ABS; fenders
and quarter panels made of
NorylGTX.

Figure 10 Rear panel made of

filled PC/ABS.

Figure 11 RIM fenders in the C6 GMX245 Corvette.

16

than steel but lower tooling costs and is used primarily when build volumes
are less than 200,000vehicles per year.
Of the total market for body panels, such composite vertical body panels
enjoyed a share of 6%, aluminum encompassed 3%, and steel encompassed
91% until 1998.14 Of that, SMC enjoys the largest portion. A fiberglassreinforced thermosetting compound, SMC usually is available in sheet form
that is rolled into coils interleaved with plastic film to prevent adhesion. It is
made by dispensing mixed resin (generally a polyester), fillers, maturation
agent, catalyst, and mold release agent onto two moving sheets of polyethylene
(PE) film. The lower film also contains chopped glass roving or glass mat. In
this way, SMC can be molded into complex shapes with little scrap.
Apart from the disadvantage of the build volume, recyclability had been
an Achilles heel for thermosets and often prevented them from entering
this relatively large market segment. It is interesting to note that the
paint systems used on thermoplastics limit their true recyclability as well.
Recently, for some offline and at-line fender applications, both PP-talc and
thermoplastic polyolefin (TPO)-based solutions have been attempted. These
had been essentially proven in very small car platforms.
Floor and roof panels have not been penetrated yet by plastics due to
various engineering shortcomings. However, many efforts to change this
are underway in concept cars such as the Toyota Sienna, which featured a
sliding roof system that uses the SABIC Lexan GLXPC resin and is coated
with Exatec900vt plasma. On the other hand, plastic composites have
been considered for application in hoods for a long time with only selective
penetration into the market. These include both glass fiber and carbon fiber
composite with a thermosetting matrix, but they are far from competing in cost
with metal solutions. Mud plates are a small panel often designed into the IP
to allow cockpit devices to be installed. These are made mostly of SMC to meet
the requirements for stiffness.
In summary, the entry of plastics into the exterior body panels of vehicles
has been difficult, but plastics are found in the panels, fenders, and hoods
of certain vehicles. Some panels, such as floor and roof panels, have yet to
utilize plastics, but concept cars are incorporating plastics into these areas.

17

Chapter Four

Plastics in the Exterior

of the Vehicle

n 1925, front and rear bumpers became standard equipment on all

cars. What were simple metal beams at that time evolved into complex
engineering components that are integral to the protection of vehicles
in low-speed collisions. Plastics entered these applications in the 1980s
because of advantages such as their aesthetically pleasing appearance,
corrosion resistance, lightness of weight, and ease of design. The expansion
rate of plastics is delimited by metals, but the designers can work around
that shortcoming. Bumpers do not have to be included in the assembly line
with metals and thus can be painted separately and then assembled onto the
vehicle later. Molded-in-color bumpers also have been considered in the past
but were difficult to match to the color of the rest of the exterior body panels.
Highly filled reformulated versions of thermoplastic polyolefin (TPO),
acrylonitrile-butadiene-styrene (ABS), and polycarbonate (PC)/ABS blends
are found in bumper applications around the world. Today, TPO dominates
this market worldwide. Other than these polymers and blends, thermosets
often enter into this market as reaction-injection-molded (RIM) products.
In fact, RIM was the first plastic to be approved for bumper fascia in North
America to meet the low-temperature crashworthiness demanded by
some OEMs. Unfortunately, due to process complexity, RIM could not be
fabricated at a high enough rate to meet the demands of large car platforms.
Faster cycle time for part production is delimited by the speed of curing
chemistry and the ability of the resin to flow into molds. Furthermore, the
automotive industry wanted to move away from the use of thermoset polymer
systems that cannot be remelted. This attribute of thermosets was labeled
by the industry as non-recyclable, and the industry made room for other
thermoplastics such as TPO that can be remelted. Reaction-injection-molded
parts are made from urethane epoxies, polyesters, and polyamides. A study
of cost versus performance reported that RIM gives the best costperformance
characteristic for composite materials and is competitive with steel.13

19

The future of the front-end systems of vehicles will depend on how

innovative and plastics-friendly OEM engineers are willing to become. An
example of such an innovative step is the design of a hybrid front-end carrier
(FEC) system (Figure12). The design and performance of such a hybrid
system, in which long-glass-filled polyphenylene (LGFPP) specifically
designed for the application was bonded with electrocoated metal, compared
successfully with a traditional FEC built from steel and bolted or welded to
the body-in-white.15

Figure 12 Bonded FEC made

from LGF PP.

Figure13 displays the assembled prototype in which a newly invented

acrylic-based adhesive was used for bonding plastics with plastics and
metals. Subsequently, Volkswagen of Mexico has introduced other
thermoplastic composite solutions for its FECsystems in the Golf, Jetta, and
Bora, using different methods to join to the body-in-white.16
Quarter panels have seen some plastics solutions but have been a difficult
application for PC-based materials due to the need for the environmental
stress crack resistance associated with fuel exposure. Nylon-based solutions
have been implemented in a few cars but suffer from dimensional stability
issues caused by fuel vapor absorption. Plastics also have been introduced
20

Figure 13 Assembled
prototype for testing at
Volkswagen.

as underbody shields to protect metals from corrosion. Due to the nature of

the application, this part must have strong resistance to cracking from stone
chips and similar abuses. However, with new technology to protect metal
parts, this application has reached a plateau in some geographical areas.
Here in the United States, LGF PP and ABS are the two predominant plastics
in use. New designs with multifunctional capabilities will make some of the
present solutions obsolete in the future. However, plastics will always play a
significant role under the car body.
Exterior door handles are another application that has turned to plastics
to balance chemical resistance and mechanical properties. Many filled
thermoplastics such as blends of PC and polybutylene terephthalate (PBT),
polyethylene terephthalate (PET), and nylon have been tried or used in
this application, with nylon as the clear winner. Exterior mirror housings
likewise use many thermoplastic solutions such as ABS, PC/ABS, blends of
polyphenylene oxide (PPO) and polystyrene (PS), nylon, blends of PP and
ethylene propylene diene monomer (EPDM), and weatherable ABS. Again,
nylon clearly dominates this application in terms of volume. Many other
exterior parts continue to adopt thermoplastic solutions. Figure14 shows an
impingement shield constructed from LGFPP.
As explained in this chapter, plastics have made their way into the exterior of
vehicles, particularly in bumper applications but also as underbody shields
and exterior door handles. However, environmental conditions and stresses
have limited the use of plastics in some exterior parts of vehicles. New
automotive applications for plastics continue to be found, and their future
will depend on the innovation of designers and OEMs.

21

Figure 14 This impingement

shield illustrates an underbody
application made from LGF PP.

22

Chapter Five

Plastics in the Powertrain

he initial rate of market penetration of plastics under the hood of

vehicles had been slowed by the fact that as recently as a decade or
two ago, engineers felt that only metallic materials could meet the
demanding conditions found near engines. After a long period of plastics
proving themselves in designs optimized for metals, the automotive
community finally started designing parts with plastic properties in mind
from the onset. As a result, under-the-hood connectors, radiator grilles, and
end caps are a relatively new application segment for plastics. Nylon (PA12,
PA6) and polybutylene terephthalate (PBT) are the polymers predominant in
this segment.
Polybutylene terephthalate is used primarily under the hood or close to
the electrical and electronic connectors of the engine and in smart network
interface devices, power plugs and electrical components, switches and
controls, circuit breaker enclosures, and various housings, especially under
the hood.

SABIC, DuPont, and Ticona are the biggest manufacturers of PBT, with
products sold under the brand names of Valox (SABIC), Crastin,
(DuPont), and Celanex and Vander (Ticona). These products usually
range from 100% unmodified PBT resins to combinations of glass-fiberreinforced, mineral-filled, mineral-/glass-reinforced, and flame-resistant
grades.
In the automotive industry, there is no known application of unmodified PBT.
However, PBT and modified resins offer chemical resistance, outstanding
dielectric strength, electrical properties, low-temperature performance down
to 40C, strength and modulus at elevated temperatures, good processability
(long flow in thin sections), and, last but not least, flame resistance.
Heating and air conditioning ducts and consoles now provide temperature
regulation to both the rear and front passenger seats. The consoles typically

23

are manufactured from acrylonitrile-butadiene-styrene (ABS) resins, as well as

polypropylene (PP) and styrene maleic anhydride (SMA) resins. The driving
force for plastic intake manifolds is not only weight and cost reduction but
also to provide improved air flow, corrosion resistance, packaging flexibility,
noise reduction, and charge densities.17 Air intake manifolds also allow
more runners to the cylinders for improved performance. Nylon had been a
fairly common material of choice for air intake manifolds (Figure15). Plastics
enabled improved air flow in ways that have been unobtainable with cast
metal, such as exceptionally smooth interior walls with all runners directed
toward the incoming air. Stylists also like the uniform matte finish and the
coordinated under-the-hood theme of plastics. Figure15 shows a prototype
air intake manifold constructed from a nylon blend.

Figure 15 An example of a plastic

air intake manifold.

Although plastics initially were viewed as unsuitable for the extreme

environments found near engines in vehicles, they now are appearing in more
areas under the hood as replacements for metals. Many plastics can meet
the requirements for strength, high temperatures, and even flame resistance
needed for powertrain applications while offering the advantages of low
weight, low cost, improved air flow, and corrosion resistance.
24

Chapter Six

Plastics in Fuel Systems

n vehicle fuel systems, the fuel tank is the largest plastic component.
For nonpolar fuels, high-density polyethylene (HDPE) is the most costeffective material of choice. High molecular weight of HDPE with proper
long-chain-branched architecture for high melt strength allowed companies
such as Kautex (currently Kautex Textron) and Inergy L.P. to introduce blowmolded HDPE fuel tanks into the market more than a decade ago (Figure16).

Figure 16 Typical example of a modern multilayer plastics fuel tank.

As the fuel mixture formulation changed in polarity and emissions

regulations evolved, multilayer tank technology evolved as well, with HDPE
as the primary layer and an ethylene vinyl alcohol (EVOH) copolymer layer
for barrier properties. As even more stringent emissions regulations loom
on the horizon, multilayer tanks are being fabricated with improved joints
and pinch-off designs. These changes also have incorporated changes in
the molecular architecture of the base HDPE resin. Some producers are

25

responding to the challenge with material solutions based on nylon (also

referred to as polyamide [PA], PA6, PA12, fluoroamides, and so forth).
Typical applications of nylon-based plastics also include fasteners for interior
and exterior components, a host of connectors, holding fixtures (Figure17),
and radiator end caps. These applications rely on the ductility and toughness
of impact-modified nylon6,6 as a mechanism to connect assemblies or to
attach components together.

Figure 17 Typical injectionmolded impact-modified

nylon6,6 components:
(A)afuel line connector,
(B)aChristmas tree fastener,
and (C)aTufflock fastener.

Fuel vapor canisters represent a relatively new automotive application

of molded impact-modified nylon6,6 that is experiencing rapid growth
(Figure18). The material is an excellent choice for this application because of
its inherent toughness and resistance to the combined effects of temperature

26

Figure 18 Two types of fuel vapor canisters molded from impactmodified nylon6,6.

and gasoline vapor. The Clean Air Act of 1990 mandated that beginning
with the 1998 model year, all new cars were required to make provisions to
trap hydrocarbon (HC) fumes emitted from the fuel tank or dealing with the
refueling process. DuPont leads the market in impact-modified nylon6,6
with products that exhibit a range of impact and mechanical performance.
The market is segmented into three performance categories:
1. Super toughness
2. Moderate toughness
3. Low toughness
The introduction of plastics into fuel rail applications in North America was
driven by the need to accommodate alternative fuels. Now that this use of
plastics has been accepted, engineers have started to consider plastics for
all kinds of fuel rails to take advantage of the associated weight and cost
benefits. This is a challenging application because of the need to balance

27

flammability, dimensional stability, and mechanical properties. Methanolcontaining fluids remain a challenge because they tend to soften the plastics
and lower its mechanical properties.
Thus, the use of plastics in fuel systems has grown in recent years. While the
largest application of plastics is fuel tanks, many other current applications
include fasteners, connectors, radiator end caps, fuel vapor canisters, and fuel
rails.

28

Chapter Seven

Plastics in Lighting
and Wheel Systems

lass headlight lenses have been replaced almost completely by

transparent polycarbonate (PC) plastics. These PC plastics are
designed to resist high levels of heat and shattering, and they can be
molded into almost any shape. Another choice for this market is the use of
acrylic plastics.
The first reported synthesis of aromatic polycarbonates from bisphenol-A can
be traced back to Einhorn18 in 1898. However, no additional investigations
into this polymer were made for the next 50years. Despite numerous
investigations into PCs derived from other aromatic diols (a type of alcohol
compund), the foundation of the PCindustry lies on bisphenol-A (a type of
alcohol compound). Today, it is estimated that the global PC manufacturing
capacity is approximately 2.6million metric tons. The major producers are
General Electric Plastics (now SABIC) and BayerAG, with a combined global
capacity of 60%. Capacities are relatively balanced between Western Europe
and the United States. Japans share of the global capacity is approximately
half that of the western regions. Between 2000 and 2010, global capacity
growth is projected to be greater than 50%.19 However, the regional shares
should remain the same, except for some relative increase in capacity in
Western Europe.
Polycarbonate was the first amorphous engineering polymer to be
commercialized, and it possesses an enviable combination of performance
attributes. Clearly, PC has the most advanced combination of properties such
as impact resistance, ductility, clarity, dimensional stability, inherent ignition
resistance, high-temperature resistance, rigidity, and creep resistance. On
the other hand, the weaknesses of PC lie in its solvent resistance (organics),
abrasion resistance, ultraviolet (UV) resistance (limited), notch sensitivity,
and hydrolytic stability (limited).

29

Polycarbonate offers good resistance to UV light but displays yellowing.

Ultraviolet stability can be extended with absorbers, coatings, and cap layers.
Typical automotive exterior lighting applications rely on UV protection via
proprietary coatings. Solvent resistance is an issue for some automotive
applications that otherwise would use PC. For example, the use of PC and its
blends in parts that can come into contact with gasoline is discouraged due
to the potential stress cracking that might result in the part after exposure to
gasoline.
The wheelbase is still considered a challenge for plastics, although plastics
can make a significant improvement to the rotational mass in the car. No
major OEM has introduced wheels made entirely of plastics yet. Vinyl esterbased composites had been attempted but with no commercial success.
On the other hand, plastics have served well in the decorative segment
of the wheel. Wheel covers, also known as hubcaps, are decorative parts
attached to the steel wheel that covers the lug nuts. Generally, painted
acrylonitrile-butadiene-styrene (ABS) and thermoplastic polyolefin (TPO) are
used most often in making hubcaps. Chrome-plated emulsion ABS also is
used in this application for customers who prefer the appearance of chrome.
Chrome plating is a finishing treatment utilizing the electrolytic deposition
of chromium. Many other plastics such as mass ABS and TPO have been
attempted in this application with limited success.
In summary, headlight lenses are one of the most common automotive
applications for plastics, and polycarbonate was the first commercialized
polymer to offer many beneficial performance characteristics for automotive
lighting. Wheel systems remain within the domain of metals, except for
decorative uses such as those found on hubcaps.

30

Chapter Eight

The Future of Plastics in

Automotive Applications

lastics will continue to follow a steady growth path in automotive

applications, but that will not dramatically improve the total weight
percentage of plastics consumed by the automotive industy. This
scenario is likely to change only if fuel costs continue to rise and alternative
fuels are not bringing any relief to the general public.
Market penetration by plastics either will be enabled by acceptance of
more thermoset-based composite solutions or by part integration leveraged
by advanced adhesive systems. Certainly many hybrid polymermetal
technologies are being considered and will surface in the market by the year
2025. Developing countries will look for lightweight and environmentally
friendly cars, and in most cases, this will make plastics and plastic composites
as well as bioplastic solutions attractive.
If a breakthrough occurs in the electrocoating process, there also is a good
possibility that more plastics and plastic composites will find their way onto
the car assembly line in body panels for large car platforms. This must be
supported by significant technical innovation in fiber, resin, and fabrication
technology of plastic composites to make their economic competitiveness
comparable to that of metals.
Plastics had been struggling to get into the body panel segment since first
introduced, with a few companies such as Renault maintaining interest
with measured acceptance. Recently, it has been reported that plastic roof
and liftgate modules will become mainstream in the next five to ten years.
Plastic Omnium claims that its thermoset (composite) liftgate for the Buick
Rendezvous weighs 10to20% less than its steel-based design.20

31

However, consideration of fuel costs is not significant enough to spark

increased replacement of metal in vehicles. The Peoples Car, which was
introduced by Tata Motors in 2007 as the least-expensive car in the world and
has a high projected volume, is still made primarily of metals (Figure19).

Figure 19 The
$2,000 Peoples Car
introduced by Tata
Motors in 2007.
(Courtesy Tata Motors)

Plastics solutions today still cannot meet the demands of frugal car designers
such as Tata Motors. The need for fuel economy has driven expensive carbon
fiber composite technology onto the automotive scene; however, questions
remain regarding the need in the automotive segment and the average
consumers ability to pay for this technology. All composite bodies in some
race cars have given OEMs a higher level of confidence in the approach. But
the pocketbook rather than technology will drive the future.
As safety standards become more stringent, airbags will be considered
elsewhere in vehicles, beyond the driver and passenger sides. This
transformation is already in progress, with the need for thorax airbags,
inflatable curtains, knee bags, and pedestrian safety front-end airbags. Plastics
solutions probably are the only way to meet this need. However, intelligent
electronic detector and interactive response systems will play a major role in all

32

of these safety devices, dictating the need for more or fewer airbags. Innovative
and smart polymer foams also will find a niche in this area.
Application areas such as exhaust systems, powertrain assemblies, and
turbo impellers are only beginning to be explored and will be receptive
to innovative plastics solutions.21 The need for fuel efficiency also will
drive the need for innovation of lightweight second-stage turbo impellers.
Making such parts from plastic is largely a pipe dream today because of the
requirement for 300C or greater exposure over extended periods. Plastic
gear systems are already being considered and will begin to appear in the
market as better ways to deal with parts in friction are determined and as
new lubrication technologies are brought to the market. Plastic composite
wheels may be offered in the future as part of the drive to improve fuel
efficiency and certainly will have a big impact in the reduction of rotational
mass. The technology is feasible as long as the drive is there.
As seen in recent years, massive worldwide awareness to be free of the
dependence on petroleum as an energy source also will impact alternative
sources of plastics. If we learn from our past mistakes, multiple routes for
making plastics will be found, rather than only one. Environmental concerns
also will bring innovative recycled plastics solutions to market.22 SABIC
was able to convert polyethylene terephthalate (PET) from recycled bottles to
polybutylene terephthalate (PBT) with virgin material properties for use in
the automotive applications discussed in earlier chapters of this book. Other
examples with recycled nylon and polyphenylene ether (PPE) demonstrated
that plastic bumpers can be made from recycled parts simply by clever
reformulation, without reclaiming the virgin material properties.23 Recycling
technology for all thermoplastics used in the automotive industry is being
advanced continuously and refined.24,25 Thermosets are a bigger challenge,
and a fully formulated thermoset part at best can be burned for fuel value.
The challenges associated with thermoplastics are not easy because many of
our solutions involve thermosets used as paints or components of solutions.
Separation techniques are neither easy nor affordable.
In a recent publication, a vision was presented by Tier1 automotive solution
providers. It stated, Light weight, high-strength materials (including
polymer-matrix composites) will be the focus for material development in
the automotive industry for the next several years The use of bio-based

33

materials, such as poly(lactic acid), soybean oil derived materials, and the
like are being investigated to cut our dependence on petroleum-based
materials.26
High-performance polymer composites are not ready for mass-produced cars,
regardless of whether they are made using glass fiber or carbon fiber, because
fabrication techniques are limited to small car build volumes. Carbon fiber
composites (CFCs) pose an additional problem because the purity needed for
performance will drive the cost upward. Pundits predict that with adequate
research funding, they could lower the cost to an affordable level within five
to ten years. This is plausible if the purity level of these fibers is sacrificed to
a certain extent or if the use of mixed glass and carbon fibers is considered.
Furthermore, the development of a higher-throughput composite part
production line will be necessary to enter the high-volume mass-produced
car segment. Mid-luxury cars have started to use high-performance CFCs
in selected body parts for lightness of weight, styling, and improved crash
performance. For example, Figure 20 shows how BMW adopted a CFC roof
segment in one of its car platforms. High-performance cars and race cars
have already adopted the CFC route, as shown in Figure21.
Thus, the future of plastics in the automotive industry depends largely
on technological and manufacturing innovation, as well as economic and
environmental factors and new ways to manufacture the plastics.

Figure 20 Roof
segment made of CFC
in the BMW MS CSL.

34

Figure 21 Front structure made completely of CFC in the

Mercedes SLRMcLaren.

35

About the Author

Dr. Kalyan Sehanobish is a leading expert in
materials science, with particular emphasis
on fracture behavior. He completed his
undergraduate and graduate education in
Chemical Engineering in India. He then came
to the United States to attend Case Western
Reserve University, where he graduated with a
Ph.D. in Macromolecular Science.
Dr. Sehanobish currently is a senior scientist
with Dow Automotive Research, a marketfacing business unit of The Dow Chemical
Company. He has technical responsibility
for most of the new business opportunities
for that company, with a primary focus on materials science aspects. This
encompasses a broad range of technology solutions, such as intelligent foams
for acoustics and crash management, new heat storage materials to improve
powertrain efficiency, and identifying approaches to make crack-resistant
ceramic filters.
During his 20-year career with The Dow Chemical Company, Dr.Sehanobish
has been responsible for pioneering work in lifetime prediction modeling for
polyolefin pipes, structureproperty relationships of thermoplastic polymer
blends, and the engineering materials science aspects of metals, ceramics, and
hybrids.
Dr.Sehanobish was one of the early pioneers of developing applications for
metallocene-catalyzed polyethylene resins, known as polyolefins, plastomers,
and elastomers, starting from 1989. He was instrumental in developing a
broad variety of applications of metallocene-catalyzed polyethylene resins.
His efforts related to structureproperties relationships included pioneering
work in the area of mechanical properties and tie-chain concentration over
a broad range of crystallinity and the effect of processing on molecular
orientation and film properties. Dr.Sehanobish was instrumental in
developing applications of metallocene- and post-metallocene-catalyzed
45

resins, such as impact modifiers for thermoplastic olefins (TPO) that are used
today in almost all car bumper fascia applications, unique cast stretch films,
hot water pipes, and blown films.
Dr.Sehanobish has authored a series of publications and holds more
than 25patents in the areas of polyethylene pipes, blown and cast films,
speciality fibers and films, and TPOs. His research is the basis for the
INSITETM technology platform and new resin families such as ENGAGETM,
AFFINITYTM, NORDELTM IP, and ELITETM. The INSITE technology
received the R&D100 Award in 1994 from R&D Magazine, and the ELITE
enhanced polyethylenes received the R&D100 Award in 1999. These efforts
also resulted in currently more than one billion pounds per year of sales of
metallocene-catalyzed polyethylene resins by The Dow Chemical Company.
Since joining the automotive industry in 20042005 as part of Dow
Automotive Research, Dr.Sehanobish has worked on the development of
plastics and composites for automotive applications, including several new
products in safety, bonding, acoustics, and heat storage applications. Two of
these products received the R&D100Award in 2005 and 2007. Dr.Sehanobish
also has presented papers at numerous technical and industrial conferences,
often as an invited speaker.

46

Executive Summary

lastics have entered engineering applications within the automotive

industry at a significant rate during the last 30 years. Although plastics
have a poor strength-to-density ratio by themselves, plastics with
inorganic fillers and plastic composite systems have advanced as structural
materials while offering many advantages over metal. This book focuses
on some of the various types of plastics and plastic composites and their
applications within passenger vehicles. It also discusses the future of plastics
in the automotive industry.
Plastics are classified as thermoplastics, rubbers, or thermosets. Available in
a variety of forms and blends, their advantages include durability, strength,
lightness of weight, and excellent thermal and electrical insulating properties.
Progress made in the recycling of plastics has added to the acceptance of
plastics.
Interior components make up the largest use of plastics in automotive
vehicles, in applications such as instrument panels (IPs), body panels, door
panels, dashmats, seat backs, seat bases, steering wheels, and airbag covers.
The use of plastics in exterior horizontal and vertical body panels of vehicles
has been difficult, but some have found their way into the body panels,
hoods, and especially fenders of vehicles. Plastics are commonly used in
bumpers and are appearing as underbody shields and exterior door handles.
Environmental conditions and stresses have limited the use of plastics in the
exterior parts of vehicles.
While once viewed as unsuitable for the extreme environment found near
engines, plastics now are being used under the hood as replacements
for metal parts. These plastics meet the requirements for strength, high
temperatures, and even flame resistance needed for powertrain applications
while offering the advantages of lower weight and cost, improved air flow,
and corrosion resistance.
Plastics also are used in fuel systems, with the largest application being fuel
tanks. They are the predominant material today for headlight lenses and
ix

other automotive lighting. However, wheel systems remain primarily metal,

except for decorative uses of plastics such as found on hubcaps.
Plastics will continue to permeate automotive applications, and hybrid
polymermetal technologies are expected to be developed in the years ahead.
Increased use of airbags also will translate into the need for more plastic
solutions. Acceptance of plastics engineering into vehicles will be driven
by the need for lightness of weight, fuel efficiency, freedom from petroleum
dependence, and improved methods of reuse and recycling of plastics. The
future of plastics in the automotive industry depends largely on technological
and manufacturing innovation, as well as economic and environmental factors.

List of Acronyms
ABS

Acrylonitrile-butadiene-styrene

CFC

Carbon fiber composite

CLTE

Coefficient of linear thermal expansion

DBTT

Ductile-to-brittle transition temperature

EPDM

Ethylene propylene diene monomer

EVOH

Ethylene vinyl alcohol

FEC

Front-end carrier

HC

Hydrocarbon

HDPE

High-density polyethylene

HHABS

High-heat acrylonitrile-butadiene-styrene

IP

Instrument panel

41

LGF

Long-glass-filled

LGF PP

Long-glass-filled polyphenylene

OEM

Original equipment manufacturer

PA

Polyamide

PBT

Polybutylene terephthalate

PC

Polycarbonate

PE

Polyethylene

PET

Polyethylene terephthalate

PP

Polypropylene

PPE

Polyphenylene ether

PPO

Polyphenylene oxide

PS

Polystyrene

PU

Polyurethane

RIM

Reaction-injection-molded

r-TPV

Thermoplastics vulcanizate made by a reactive extrusion

process with EPDM, a cross linker, and PP.

42

SBC

Styrene block copolymer

SEB

Styrene-ethylene block (copolymer)

SMA

Styrene maleic anhydride

SMC

Sheet molding compound

TPO

Thermoplastic polyolefin

TSOP

Toyota Super Olefin Polymer

UV

Ultraviolet

43

References
1.

Ashby, F.M., Materials Selection in Mechanical Design, ButterworthHeinemann, 2005, ISBN 978-0-7506-6168-3.

2.

American Metal Market industry reports, American Metal Market LLC,

2003.

3.

Naranjo, Robert D., HuangFu, Her-Ping, and Gwyn, Mike, Lightweight

Castings Continue to Play an Important Role in Reducing Weight and
Increasing Fuel Efficiency of Vehicles, Modern Casting (online article),
September01, 2004.

4.

Fisher, M.M. and Cundiff, B.T., APC Vision and Technology Roadmap
for the Automotive MarketDefining Priority Research for Plastics in
21st Century Vehicles, SAE Technical Paper No. 2002-01-1890, SAE
International, Warrendale, PA, 2002.

5.

Patty, B.S., Calhoun, M.L., and Shields, N.A., Low Gloss ABS
Advancements for Automotive Interior Components, SAE Technical
Paper No.2006-01-0134, SAE International, Warrendale, PA, 2006.

6.

Sehanobish, K. and Traugott, T., Handbook of Plastics Technology, Charles A.

Harper, editor-in-chief, McGraw-Hill, New York, 2006, pp.2.392.40.

7.

Kawamura, N., Nomura, T., and Nishio, T., Super Olefin Polymer
for Material Consolidation of Automotive Interior Plastic Parts, SAE
Technical Paper No.960296, SAE International, Warrendale, PA, 1996.

8.

Sehanobish, K., et al., Constrained Geometry Single-Site Catalyst

Technology Elastomers and Plastomers for Impact Modifications and
Automotive Applications, Metallocene-Based Polyolefins, Preparation,
Properties, and Technology, Volume 2, John Scheirs and Walter Kaminsky,
eds., ISBN 978-0-471-99912-6, John Wiley & Sons, New York, 2000.

9.

Kotnis, A., Kauffman, K., Ahmed, M., and Naughton, P., A New Approach
to Seat Back DesignBlow Molded Seat Backs, proceedings of the Society
of Plastics Engineers Annual Technical Conference, Cincinnati, OH, 2007.

37

10. Costlow, T., Squeezing More Out and In, Automotive Engineering
International, SAE International, Warrendale, PA, January 2008, pp.5961.
11. Sweeney, F.M., Introduction to RIM, Technomic, Westport, CT, 1979.
12. Sweeny, F.M., RIM Machinery and Processes, Marcel Dekker, New York,
1987.
13. Macosko, C.W., Fundamentals of RIM, Hanser Gardner Publications, New
York, 1989, ISBN 978-1-5699-0055-0.
14. James, A. and Miller, T., Performance Comparison of Plastic Composites
with Metals for Vertical Body Panel Applications, SAE Technical Paper
No.1999-01-0848, SAE International, Warrendale, PA, 1999.
15. Naughton, P., Rottger, J., and Bowser, B., A New Approach to Hybrid
Front-End Systems, SAE Technical Paper No. 2002-01-1229, SAE
International, Warrendale, PA, 2002.
16. Gehm, R., Material Innovations, Automotive Engineering International,
SAE International, Warrendale, PA, December 2007, p.55.
17. Schramm, J.G., Design Considerations for the Use of Composite Materials
in Intake Manifolds and Fuel Rails, SAE Technical Paper No.922149, SAE
International, Warrendale, PA, 1992.
18. Einhorn, A., Annahlin 300, 135, 1898.
19. Tullo, A.H., POLYCARBONATE, Chemical & Engineering News, Vol. 79,
No. 3, April 2001.
20. Gehm, R., Plastics on the Outside, Automotive Engineering International,
SAE International, Warrendale, PA, August 2006, pp.4649.
21. Buchholtz, K., Plastic Mufflers, Automotive Engineering International, SAE
International, Warrendale, PA, January 2008, pp.4950.
22. Costlow, T., Recycled PET, Automotive Engineering International, SAE
International, Warrendale, PA, January 2008, pp.6465.

38

23. Staniulis, A.G., Recycled Automotive Plastics, SAE Technical Paper

No.941021, SAE International, Warrendale, PA, 2002.
24. Hock, H. and Maten, Jr., A., A Preliminary Study of the Recovery and
Recycling of Automotive Plastics, SAE Technical Paper No.930561, SAE
International, Warrendale, PA, 2002.
25. Fisher, M.M., Biddle, M.B., and Ryan, C., Size Reduction and Material
Separation Technologies for the Recovery of Automotive Interior Trim
ABS and PP Plastics from Dismantled End-of-Life Vehicles: Preliminary
Research into Continuous Processing, SAE Technical Paper No.2001-010697, SAE International, Warrendale, PA, 2002.
26. Ryntz, R.A., 2005 Mattielo Memorial Lecture, JCT Research, Vol.3, No.1,
January2006.

39