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    Safety Data Sheet: 34078 / 1,4-Butandiol Standard Page 1 of 5

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    Elham Drs
    This safety data sheet provides information on a 1,4-Butandiol Standard product. It identifies the product as highly flammable and toxic if swallowed, in contact with skin or inhaled. It lists methanol as a hazardous ingredient. It provides handling, storage, exposure and first aid information for the product.

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    Safety Data Sheet: 34078 / 1,4-Butandiol Standard Page 1 of 5

    Uploaded by

    Elham Drs
    29 views5 pages
    This safety data sheet provides information on a 1,4-Butandiol Standard product. It identifies the product as highly flammable and toxic if swallowed, in contact with skin or inhaled. It lists methanol as a hazardous ingredient. It provides handling, storage, exposure and first aid information for the product.

    Original Description:

    butanediol

    Original Title

    34078_useng

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    This safety data sheet provides information on a 1,4-Butandiol Standard product. It identifies the product as highly flammable and toxic if swallowed, in contact with skin or inhaled. It lists methanol as a hazardous ingredient. It provides handling, storage, exposure and first aid information for the product.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    29 views5 pages

    Safety Data Sheet: 34078 / 1,4-Butandiol Standard Page 1 of 5

    Uploaded by

    Elham Drs
    This safety data sheet provides information on a 1,4-Butandiol Standard product. It identifies the product as highly flammable and toxic if swallowed, in contact with skin or inhaled. It lists methanol as a hazardous ingredient. It provides handling, storage, exposure and first aid information for the product.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 5

    Safety Data Sheet

    Revision Date: 10/21/14


    www.restek.com

    1. IDENTIFICATION
    Catalog Number / Product Name:
    Company:
    Address:
    Phone#:
    Fax#:
    Emergency#:
    Email:
    Revision Number:
    Intended use:

    34078 / 1,4-Butandiol Standard


    Restek Corporation
    110 Benner Circle
    Bellefonte, Pa. 16823
    814-353-1300
    814-353-1309
    800-424-9300 (CHEMTREC)
    703-527-3887 (Outside the US)
    [email protected]
    4
    For Laboratory use only

    2. HAZARD(S)IDENTIFICATION
    Emergency Overview:
    GHS Hazard Symbols:

    GHS Classification:

    Specific Target Organ Systemic Toxicity (STOT) - Single Exposure


    Category 1
    Flammable Liquid Category 2
    Acute Toxicity - Inhalation Dust / Mist Category 3
    Acute Toxicity - Inhalation Vapour Category 3
    Acute Toxicity - Inhalation Gas Category 3
    Acute Toxicity - Dermal Category 3
    Acute Toxicity - Oral Category 3

    GHS Signal Word:

    Danger

    GHS Hazard:

    Highly flammable liquid and vapour.


    Toxic if swallowed, in contact with skin or if inhaled.
    Toxic if inhaled.
    Causes damage to organs.

    GHS Precautions:
    Safety Precautions:

    Keep away from heat/sparks/open flames/hot surfaces. No smoking.


    Ground/bond container and receiving equipment.
    Use explosion-proof electrical/ventilation and lighting equipment.
    Use only non-sparking tools.
    Take precautionary measures against static discharge.
    Do not breathe dust/fume/gas/mist/vapours/spray.
    Wash hands and skin thoroughly after handling.
    Do no eat, drink or smoke when using this product.
    Use only outdoors or in a well-ventilated area.
    Wear protective gloves/protective clothing/eye protection/face protection.

    First Aid Measures:

    IF SWALLOWED: Immediately call a POISON CENTER/doctor/....


    IF ON SKIN: Wash with plenty of soap and water.
    IF ON SKIN (or hair): Remove/Take off immediately all contaminated
    clothing. Rinse skin with water/shower.
    IF INHALED: Remove victim to fresh air and keep at rest in a position
    comfortable for breathing.
    IF exposed: Call a POISON CENTER or doctor/physician.
    Call a POISON CENTER or doctor/physician if you feel unwell.
    Specific treatment see section 4.

    34078 / 1,4-Butandiol Standard

    Page 1 of 5

    Specific measures see section 4.


    Rinse mouth.
    Remove/Take off immediately all contaminated clothing.
    Wash contaminated clothing before reuse.
    In case of fire: Use extinguishing media in section 5 for extinction.
    Storage:

    Store in a well-ventilated place. Keep container tightly closed.


    Store in a well-ventilated place. Keep cool.
    Store locked up.

    Disposal:

    Dispose of contents/container according to section 13 of the SDS.

    Single Exposure Target Organs:

    No data available.

    Repeated Exposure Target Organs:

    No data available.

    3. COMPOSITION / INFORMATION ON INGREDIENTS


    Chemical Name

    CAS #

    EINEC #

    % Composition

    methanol

    67-56-1

    200-659-6

    99.999900

    4. FIRST-AID MEASURES
    Inhalation:

    Eyes:

    Skin Contact:
    Ingestion:

    Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not
    breathing, give artificial respiration and have a trained individual administer oxygen. Get
    medical attention immediately
    Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to
    prevent chemical from transferring to the uncontaminated eye. Get immediate medical
    attention.
    Wash with soap and water. Remove contaminated clothing and launder. Get medical
    attention if irritation develops or persists.
    Do not induce vomiting and seek medical attention immediately. Drink two glasses of water
    or milk to dilute. Provide medical care provider with this SDS.

    5. FIRE- FIGHTING MEASURES


    Extinguishing Media:

    Fire and/or Explosion Hazards:

    Fire Fighting Methods and Protection:

    Hazardous Combustion Products:

    Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing


    agents. Water may be ineffective but water spray can be used extinguish
    a fire if swept across the base of the flames. Water can absorb heat and
    keep exposed material from being damaged by fire.
    Vapors may be ignited by sparks, flames or other sources of ignition if
    material is above the flash point giving rise to a fire (Class B). Vapors are
    heavier than air and may travel to a source of ignition and flash back.
    Do not enter fire area without proper protection including self-contained
    breathing apparatus and full protective equipment. Fight fire from a safe
    distance and a protected location due to the potential of hazardous
    vapors and decomposition products. Flammable component(s) of this
    material may be lighter than water and burn while floating on the surface.
    Carbon dioxide, Carbon monoxide

    6. ACCIDENTAL RELEASE MEASURES


    Personal Precautions and Equipment:

    Methods for Clean-up:

    34078 / 1,4-Butandiol Standard

    Exposure to the spilled material may be severely irritating or toxic. Follow


    personal protective equipment recommendations found in Section 8 of
    this SDS. Personal protective equipment needs must be evaluated based
    on information provided on this sheet and the special circumstances
    created by the spill including; the material spilled, the quantity of the spill,
    the area in which the spill occurred, and the expertise of employees in the
    area responding to the spill. Never exceed any occupational exposure
    limits.
    Prevent the spread of any spill to minimize harm to human health and the
    environment if safe to do so. Wear complete and proper personal
    protective equipment following the recommendation of Section 8 at a
    minimum. Dike with suitable absorbent material like granulated clay.
    Gather and store in a sealed container pending a waste disposal
    Page 2 of 5

    evaluation.
    7. HANDLING AND STORAGE
    Handling Technical Measures and Precautions:

    Storage Technical Measures and Conditions:

    Toxic or severely irritating material. Avoid contacting and avoid


    breathing the material. Use only in a well ventilated area. Use
    spark-proof tools and explosion-proof equipment
    Store in a cool dry ventilated location. Isolate from
    incompatible materials and conditions. Keep container(s)
    closed. Keep away from sources of ignition

    8. EXPOSURE CONTROLS / PERSONAL PROTECTION


    United States:
    Chemical Name
    methanol

    CAS No.
    67-56-1

    IDLH
    6000 ppm IDLH

    Personal Protection:
    Engineering Measures:

    ACGIH STEL
    250 ppm STEL

    ACGIH TLV-TWA
    200 ppm TWA

    OSHA Exposure Limit


    200 ppm TWA; 260
    mg/m3 TWA

    Local exhaust ventilation is recommended when generating excessive levels of


    vapors from handling or thermal processing.
    Respiratory protection may be required to avoid overexposure when handling this
    product. General or local exhaust ventilation is the preferred means of protection.
    Use a respirator if general room ventilation is not available or sufficient to
    eliminate symptoms.If an exposure limit is exceeded or if an operator is
    experiencing symptoms of inhalation overexposure as explained in Section 3,
    provide respiratory protection.
    Wear chemically resistant safety glasses with side shields when handling this
    product. Do not wear contact lenses.
    Wear protective gloves. Inspect gloves for chemical break-through and replace at
    regular intervals. Clean protective equipment regularly. Wash hands and other
    exposed areas with mild soap and water before eating, drinking, and when
    leaving work

    Respiratory Protection:

    Eye Protection:
    Skin Protection:

    9. PHYSICAL AND CHEMICAL PROPERTIES


    Appearance, color:
    Odor:
    Physical State:
    pH:
    Vapor Density:
    Melting Point:
    Flash Point:
    Flammability:
    Upper Flammable/Explosive Limit, % in air:
    Lower Flammable/Explosive Limit, % in air:
    Autoignition Temperature:
    Decomposition Temperature:
    Specific Gravity:
    Evaporation Rate:
    Odor Threshold:
    Solubility:
    Partition Coefficient: n-octanol in water:
    VOC % by weight:
    Molecular Weight:

    No data available.
    Mild
    No data available.
    No data available
    1.1 (air = 1)
    -98 C
    52
    Highly Flammable
    36.0
    6.0
    464 deg C
    No data available.
    0.791 - 0.792 g/cm3 at 20 C
    No data available.
    No data available.
    Moderate; 50-99%
    No data available.
    100.00
    32.04

    10. STABILITY AND REACTIVITY


    Stability:
    Conditions to Avoid:
    Materials to Avoid / Chemical Incompatiability:
    Hazardous Decomposition Products:

    Stable under normal conditions.


    No data available.
    Strong oxidizing agents
    Carbon dioxide Carbon monoxide

    11. TOXICOLOGICAL INFORMATION


    Routes of Entry:
    Inhalation, Skin Contact, Eye Contact, Ingestion
    Target Organs Potentially Affected By Exposure: Eyes, Central nervous system stimulation, Skin, GI
    Tract, Respiratory Tract
    Chemical Interactions That Change Toxicity:
    None Known

    34078 / 1,4-Butandiol Standard

    Page 3 of 5

    Immediate (Acute) Health Effects by Route of Exposure:


    Inhalation Irritation:
    Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea
    and headache.
    Inhalation Toxicity:
    Harmful! Can cause systemic damage (see "Target Organs)Methanol can cause
    central nervous system depression and overexposure can cause damage to the
    optic nerve resulting in visual impairment or blindness.
    Skin Contact:
    Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause
    permanent damage.
    Eye Contact:
    Can cause moderate irritation, tearing and reddening, but not likely to
    permanently injure eye tissue.
    Ingestion Irritation:
    Irritating to mouth, throat, and stomach. Can cause abdominal discomfort,
    nausea, vomiting and diarrhea.Highly toxic and may be fatal if swallowed.
    Ingestion Toxicity:
    Toxic if swallowed. May cause target organ failure and/or death.May be fatal if
    swallowed.
    Long-Term (Chronic) Health Effects:
    Carcinogenicity:
    Reproductive and Developmental Toxicity:
    Inhalation:

    Skin Contact:

    Ingestion:

    No data.
    Contains a known human reproductive and/or
    developmental hazard.
    Upon prolonged and/or repeated exposure, can cause
    moderate respiratory irritation, dizziness, weakness, fatigue,
    nausea and headache.Harmful! Can cause systemic
    damage upon prolonged and/or repeated exposure (see
    "Target Organs)
    Upon prolonged or repeated contact, can cause
    moderate skin irritation, defatting, and dermatitis. Not
    likely to cause permanent damage.
    Toxic if swallowed. May cause target organ failure
    and/or death.

    Component Toxicological Data:


    NIOSH:
    Chemical Name
    Methanol

    CAS No.
    67-56-1

    LD50/LC50
    Oral LD50 Rat 5628 mg/kg
    (Source: NLM_CIP); Inhalation
    LC50 Rat 83.2 mg/L 4 h (Source:
    IUCLID)

    Component Carcinogenic Data:


    OSHA:
    Chemical Name
    No data available.

    CAS No.

    ACGIH:
    Chemical Name
    No data available.

    CAS No.

    NIOSH:
    Chemical Name
    No data available.

    CAS No.

    NTP:
    Chemical Name
    No data available.

    CAS No.

    IARC:
    Chemical Name
    No data.
    No data.
    No data.

    CAS No.

    Group No.
    Group 1
    Group 2A
    Group 2B

    12. ECOLOGICAL INFORMATION


    Overview:
    Mobility:
    Persistence:
    Bioaccumulation:
    34078 / 1,4-Butandiol Standard

    Moderate ecological hazard. This product may be dangerous


    to plants and/or wildlife.
    No data
    No data
    No data
    Page 4 of 5

    Degradability:
    Ecological Toxicity Data:

    Biodegrades slowly.
    No data available.

    13. DISPOSAL CONSIDERATIONS


    Waste Description of Spent Product:
    Disposal Methods:

    Spent or discarded material is a hazardous waste.


    Dispose of by incineration following Federal, State, Local,
    or Provincial regulations.
    Comply with all Local, State, Federal, and Provincial
    Environmental Regulations.

    Waste Disposal of Packaging:

    14. TRANSPORTATION INFORMATION


    United States:
    DOT Proper Shipping Name:
    UN Number:
    Hazard Class:
    Packing Group:

    Methanol
    UN1230
    3
    II

    International:
    IATA Proper Shipping Name:
    UN Number:
    Hazard Class:
    Packing Group:

    Methanol
    UN1230
    3 (6.1)
    II

    Marine Pollutant:

    No

    15. REGULATORY INFORMATION


    United States:
    Chemical Name

    CAS#

    CERCLA

    SARA 313

    SARA EHS 313

    TSCA

    methanol

    67-56-1

    Pennsylvania
    X

    California
    X

    The following chemicals are listed on CA Prop 65:


    Chemical Name
    Methanol

    CAS #
    67-56-1

    Regulation
    Prop 65 Devolop Tox

    State Right To Know Listing:


    Chemical Name
    methanol

    CAS#
    67-56-1

    New Jersey
    X

    Massachusetts
    X

    16. OTHER INFORMATION


    Prior Version Date:
    Disclaimer:

    03/10/11
    Restek Corporation provides the descriptions, data and information contained
    herein in good faith but makes no representation as to its comprehensiveness or
    accuracy. It is provided for your guidance only. Because many factors may affect
    processing or application/use, Restek Corporation recommends you perform an
    assessment to determine the suitability of a product for your particular purpose
    prior to use. No warranties of any kind, either expressed or implied, including
    fitness for a particular purpose, are made regarding prodcuts described, data or
    information set forth. In no case shall the descriptions, information, or data provided
    be considered a part of our terms and conditions of sale. Further, the descriptions,
    data and information furnished hereunder are given gratis. No obligation or liability
    for the description, data and information given are assumed. All such being given
    and accepted at your risk.

    34078 / 1,4-Butandiol Standard

    Page 5 of 5

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