Pers.

Antoine
A
B
C
Nitrogen
13.4477 658.22
Oksigen
13.6835 780.36
T

nitrogen
oksigen

-169 deg C
xi
P sat (kPa)Ki = P sat / Pyi = xi x Ki
0.79 3E+007 39862.842 31491.6
0.21 8E+007 99216.599 20835.5

P bubble

800 kPa

800 kPa

nitrogen
oksigen
T bubble

-2.854
-4.1758

52327.1

xi
P sat (kPa)Ki = P sat / Pyi = xi x Ki
0.79 930.436 1.1630448 0.91881
0.21 310.762 0.388453 0.08158
102.403 deg C

1.00038
goal seek = 1

nitrogen
oksigen
P dew

nitrogen
oksigen
T dew

yi
P sat (kPa)Ki = P sat / Pxi = yi / Ki
0.79 3E+007 39862.842 2E-005
0.21 8E+007 99216.599 2E-006
800 kPa

2E-005

yi
P sat (kPa)Ki = P sat / Pxi = yi / Ki
0.79 1115.53 1.3944155 0.56655
0.21 387.562 0.4844526 0.43348
105.211 deg C

1.00002
goal seek = 1

xi = yi / Ki

xi = yi / Ki

goal seek = 1

Pers. Antoine
A
B
C
NITROGEN
13.4477 658.22
OKSIGEN
13.6835 780.36
T

NITROGEN
OKSIGEN
P bubble

benzene
toluene
T bubble

-2.854
-4.1758

104 K
xi
P sat (kPa)Ki = P sat / Pyi = xi x Ki
0.65755 1032.85 1.2910626 0.84894
0.34245 352.89 0.4411128 0.15106
1
800 kPa
1

NITROGEN
OKSIGEN
P dew

yi
P sat (kPa)Ki = P sat / Pxi = yi / Ki
0.84894 1032.85 1.2910626 0.65755
0.15106 352.89 0.4411128 0.34245
1
800 kPa
1

120 kPa
xi
P sat (kPa)Ki = P sat / Pyi = xi x Ki
0.28177 1100.79 9.1732776 2.58479
0.71823 381.34 3.1778338 2.28241
1
105 deg C
4.8672
goal seek = 1

benzene
toluene
T dew

yi
P sat (kPa)Ki = P sat / Pxi = yi / Ki
0.48405 1100.79 9.1732776 0.05277
0.51595 381.34 3.1778338 0.16236
1
105 deg C
0.21513
goal seek = 1

xi = yi / Ki

xi = yi / Ki

goal seek = 1

A
Aseton
Metanol

B
14.7171
16.498

A
P

C
2975.95 -34.5228
3593.39 -35.2249

0.64
1 bar
100 kpa

Tsat1
Tsat2

328.8237 K
337.3725 K

T
x1
337.3725
336.5176
335.6627
334.8079
333.953
333.0981
332.2432
331.3883
330.5335
329.6786
328.8237

Psat1
Psat2

100
100

gamma1 gamma2 Psat1

y1
0 1.896481
1 133.0345
0
0.1 1.679339 1.006421 129.3849 0.217281
0.2 1.506215 1.02593 125.8156 0.379011
0.3 1.368342 1.059291 122.3253 0.502148
0.4 1.259104 1.107827 118.9126 0.598893
0.5 1.173511 1.173511 115.5765 0.678151
0.6 1.107827 1.259104 112.3156 0.746557
0.7 1.059291 1.368342 109.1287 0.809193
0.8 1.02593 1.506215 106.0146 0.870109
0.9 1.006421 1.679339 102.9721 0.932699
1
1 1.896481
100
1

340
338
336
334
332
330
328
326
324

x1

x2
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

T
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0

gamma1 gamma2 Psat1

337 1.896481 1.006421
1.679339 1.02593
1.506215 1.059291
1.368342 1.107827
1.259104 1.173511
1.173511 1.259104
1.107827 1.368342
1.059291 1.506215
1.02593 1.679339
1.006421 1.896481
1
1

0.2

0.4

0.6

0.8

T-x1
T-y1

0.2

0.4

0.6

0.8

1.2

Pers. Antoine
methanol
water
T

methanol
water
P bubble

A
B
C
16.5785 3638.27
16.3872 3885.7
60 C

239.5
230.17

A = 2.771 - 0.00523 T
Rumus pasti

y P = x gamma Psat

xi
P sat (kPa)
Ki = * P sat / P
0.72 83.9891 1.091298402
0.28 20.007 0.766388276
93.3134 kPa

yi = xi x Ki
0.7857348491
0.2145887173

2.4572 1.21245
2.4572 3.57445

1.0003235664

NRTL

12 =
21 =
=

methanol
water
P bubble

-2.12951
7.0895
0.2994

G12
G21

xi
P sat (kPa)
ln
0.72 83.9891 6.68982E-005
0.28 20.007 0.000442348
66.0757 kpa

1.8918871755
0.1197204517

1.0000669005
1.0004424454

Ki = * P sat / P
yi = xi x Ki
1.2711892137 0.91526
0.3029237271 0.08482
1.00007

tebak

ln1
ln 2

(G21/(X1+(X2*G21))((G21*12)/((X2+(X1*G12))^2)
0.0252432423
-1.4939784029
(G12/(x2+(x1*G12))((G21*21)?((x1+(x2*G21))^2)
1.3272727573
1.4948316967

yi
methanol
methyl acetat
P dew

methanol
water

P sat (kPa)Ki = * P sat / P xi = yi / Ki

0.6 83.9891 0.745863659 0.8044366
0.4 20.007 2.0453721351 0.1955634

48.5385 kPa

A
tebak
hitung galat
galat ^ 2
2.4572 0.431044989 1.09853 0.6674881 0.4455404
2.4572 4.962213567 4.90423 -0.0579801 0.0033617
0.4489021

xi
P sat (kPa)
ln
hit
tebakKi = * P sat / xi
P = yi / Kigalat
galat ^ 2
0.72 83.9891 6.68982E-005 1.0000669 1.00007 1.894992901 0.37995 5.845E-008 3.42E-015
0.28 20.007 0.0004423475 1.0004424 1.00044 0.451575804 0.62005 9.535E-008 9.09E-015
P dew
44.3246 kPa
1
1.25E-014

Pers. Antoine
A
B
C
Nitrogen
13.4477 658.22
Oksigen
13.6835 780.36
T

75 deg C
xi

oksigen
nitrogen
P bubble

nitrogen
oksigen
T bubble

-2.854
-4.1758

P sat (kPa)Ki = P sat / Pyi = xi x Ki

0.4 75.5093 1.9447881 0.77792
0.6 14.3713 0.3701412 0.22208

38.8265 kPa

yi
acetonitrile
nitromethane
P dew

P sat (kPa)Ki = P sat / Pxi = yi / Ki

0.4 75.5093 3.552507 0.1126
0.6 14.3713 0.6761299 0.8874

21.2552 kPa

800 kPa
xi
P sat (kPa)Ki = P sat / Pyi = xi x Ki
0.79 930.436 1.1630448 0.91881
0.21 310.762 0.388453 0.08158
102.403 deg C

1.00038
goal seek = 1

nitrogen
oksigen
T dew

yi
P sat (kPa)Ki = P sat / Pxi = yi / Ki
0.79 1115.53 1.3944155 0.56655
0.21 387.562 0.4844526 0.43348
105.211 deg C

1.00002
goal seek = 1

xi = yi / Ki

xi = yi / Ki

goal seek = 1

Pers. Antoine
A
B
C
n-heptane 13.8622 2910.26
216.432
n-pentane 13.7667 2451.88
232.014
T

30 deg C
xi

n-heptane
n-pentane
P bubble

52.4217 kPa

T bubble

yi
n-heptane
n-pentane
P dew

P sat (kPa)Ki = P sat / Pxi = yi / Ki

0.4 7.78823 0.4568641 0.87553
0.6 82.1773 4.8205908 0.12447

17.0471 kPa

100 kPa
xi

n-heptane
n-pentane

P sat (kPa)Ki = P sat / Pyi = xi x Ki

0.4 7.78823 0.1485688 0.05943
0.6 82.1773 1.5676208 0.94057

P sat (kPa)Ki = P sat / Pyi = xi x Ki

0.4 18.1371 0.1813712 0.07255
0.6 154.715 1.5471475 0.92829
49 deg C

1.00084
goal seek = 1

yi
n-heptane
n-pentane
T dew

P sat (kPa)Ki = P sat / Pxi = yi / Ki

0.4 48.9721 0.4897206 0.81679
0.6 327.655 3.2765546 0.18312

75.4419 kPa

0.99991
goal seek = 1

Pers. Antoine
A
B
C
acetonitrile
14.895 3413.1
250.523
nitromethane 14.7513 3331.7
227.6
acetone
14.3145 2756.22
228.06
T

75 deg C
xi

acetonitrile
nitromethane
acetone
P bubble

97.0034 kPa

T bubble

1.00008

yi
acetonitrile
nitromethane
acetone
P dew

P sat (kPa)Ki = P sat / Pxi = yi / Ki

0.3 82.2717
1.21437 0.24704
0.4 42.1424 0.6220432 0.64304
0.3 184.909 2.7293518 0.10992

67.7484 kPa

70 kPa
xi

acetonitrile
nitromethane
acetone

P sat (kPa)Ki = P sat / Pyi = xi x Ki

0.3 82.2717 0.8481319 0.25444
0.4 42.1424 0.4344431 0.17378
0.3 184.909 1.9062149 0.57186

P sat (kPa)Ki = P sat / Pyi = xi x Ki

0.3 59.0596 0.8437087 0.25311
0.4 28.9538 0.413626 0.16545
0.3 135.681 1.9382954 0.58149

65.0241 deg C

1.00005
goal seek = 1

yi
acetonitrile
nitromethane
acetone
T dew

P sat (kPa)Ki = P sat / Pxi = yi / Ki

0.3 84.8202 1.2117176 0.24758
0.4 43.6198 0.6231396 0.64191
0.3 190.239 2.717704 0.11039

75.9499 deg C

0.99988
goal seek = 1

xi = yi / Ki

xi = yi / Ki

goal seek = 1

Pers. Antoine
A
B
C
acetonitrile
14.895 3413.1
250.523
nitromethane 14.7513 3331.7
227.6
T

75 deg C
xi

acetonitrile
nitromethane
P bubble

58.1941 kPa

T bubble

yi
acetonitrile
nitromethane
P dew

P sat (kPa)Ki = P sat / Pxi = yi / Ki

0.4 82.2717 1.5713366 0.25456
0.6 42.1424 0.8048941 0.74544

52.3578 kPa

70 kPa
xi

acetonitrile
nitromethane

P sat (kPa)Ki = P sat / Pyi = xi x Ki

0.4 82.2717 1.4137449 0.5655
0.6 42.1424 0.7241701 0.4345

P sat (kPa)Ki = P sat / Pyi = xi x Ki

0.4 97.9491 1.399273 0.55971
0.6 51.3078 0.732968 0.43978

80.5068 deg C

0.99949
goal seek = 1

yi
acetonitrile
nitromethane
T dew

P sat (kPa)Ki = P sat / Pxi = yi / Ki

0.4 107.256 1.5322336 0.26106
0.6 56.8297 0.811853 0.73905

83.4471 deg C

1.00011
goal seek = 1

xi = yi / Ki

xi = yi / Ki

goal seek = 1

Pers. Antoine
A
B
C
14.7171 2975.95
16.4948 3593.39

ASETON
METANOL
T

318.15 K

-34.5228
-35.2249

A= 0.64

y P = x gamma Psat

xi
P sat (kPa)
Ki = * P sat / Pyi = xi x Ki
0.25 68.3492 1.319644589 0.3299111
0.75 44.4314 0.893453137 0.6700899
1
100 kPa
1.000001

aseton
metanol
P bubble

0.64 1.93074
0.64 2.01086

yi
methanol
methyl acetat
P dew

0.6
0.4
78.3759

101.33 kPa
xi
P sat (kPa)
Ki = * P sat / Pyi = xi x Ki
0.85 108.453 1.095603162 0.9312627
0.15 77.7991 1.626257285 0.2439386

methanol
methyl acetate
T bubble

331.204 K

AZEOTROPE
T=
A=
Psat 1 =
Psat 2 =

318.15 K
1.10708
68.3492 kPa
44.4314 kPa

x1

1
0
1

2
3.0255
1

1.0388 1.02365
1.0388 2.11813

1.1752013
goal seek = 1

yi
methanol
methyl acetat
T dew

methanol
methyl acetate

12
1 4.654142721
3.0255 0.508447523

syarat azeotrop 12 < 1 < 12

0.4
0.6
326.689

= 0.65007

ln (1 az/2 az -0.43068
1-2x1 az =
-0.38903
x1 az = Y1 az0.69451
2 az =
1.70574
P az =
75.7883 kPa

ln (1 az/2 az) = A(x2 az^2 - x1 az^2)

[ln (1 az/2 az)]/A = (1-x1 az)^2 - x1 az^2 = 1-2x1 az
1 az =

1.1088401

P sat (kPa)Ki = * P sat / P xi = yi / Ki

A
tebak hitung galat
galat ^ 2
68.3492 0.9050341136 0.6629584 1.10708 1.0378 1.13401 0.0962091 0.0092562
44.4314 1.1867972443 0.3370416 1.10708 2.09348 1.62674 -0.4667445 0.2178504
kPa

0.2271066

P sat (kPa)Ki = * P sat / P xi = yi / Ki

A
tebak hitung galat
galat ^ 2
92.8797 1.2493690136 0.3201616 1.06241 1.36304 1.82609 0.4630487 0.2144141
64.4612 0.7969600994 0.7528608 1.06241 1.25278 1.11505 -0.137732 0.0189701
K

1.0730224

0.2333842

2 = 1-2x1 az

Pers. Antoine
A
B
C
16.5785 3638.27
16.3872 3885.7

methanol
water
T

333.15 K

239.5
230.17

A = 2.771 - 0.00523 T
Rumus pasti

y P = x gamma Psat

xi
P sat (kPa)
Ki = * P sat / Pyi = xi x Ki
A

0.72 27587.2 1.074171487 0.7734035 1.02863 1.08399

0.28 13218.1 0.809273319 0.2265965 1.02863 1.70444

methanol
water
P bubble

27839.3 kPa

methanol
methyl acetat
P dew

yi
0.72
0.28
28355.1

101.33 kPa
xi
P sat (kPa)
Ki = * P sat / Pyi = xi x Ki
0.85 26996.1 272.7183226 231.81057
0.15 12905.9 269.7753628 40.466304

methanol
methyl acetate
T bubble

331.204 K

AZEOTROPE
T=
A=
Psat 1 =
Psat 2 =

318.15 K
1.10708
23253.5 kPa
10945.1 kPa

x1

1
0
1

2
3.0255
1

1.0388 1.02365
1.0388 2.11813

272.27688
goal seek = 1

yi
methanol
methyl acetat
T dew

methanol
methyl acetate

12
1 6.427858068
3.0255 0.702219228

syarat azeotrop 12 < 1 < 12

0.4
0.6
326.689

= 0.47069

ln (1 az/2 az -0.75357
1-2x1 az =
-0.68068
x1 az = Y1 az0.84034
2 az =
2.18537
P az =
23919 kPa

ln (1 az/2 az) = A(x2 az^2 - x1 az^2)

[ln (1 az/2 az)]/A = (1-x1 az)^2 - x1 az^2 = 1-2x1 az
1 az =

1.0286225

P sat (kPa)Ki = * P sat / P xi = yi / Ki

A
tebak hitung galat
galat ^ 2
27587.2 1.0096953605 0.7130864 1.02863 1.0378 1.08836 0.0505628 0.0025566
13218.1 0.9759034472 0.2869136 1.02863 2.09348 1.68716 -0.4063173 0.1650938
kPa

0.1676504

P sat (kPa)Ki = * P sat / P xi = yi / Ki

A
tebak hitung galat
galat ^ 2
25658 345.1386635 0.001159 1.06241 1.36304 1.00002 -0.3630218 0.1317848
12201.5 150.85261958 0.0039774 1.06241 1.25278
1 -0.2527826 0.063899
K

0.0051363

0.1956838

2 = 1-2x1 az

Pers. Antoine
A
B
C
methanol
16.5916 3643.31
methyl acetate 14.2533 2665.54
T

318.15 K

A = 2.771 - 0.00523 T
Rumus pasti

y P = x gamma Psat

xi
P sat (kPa)
Ki = * P sat / Pyi = xi x Ki
A

0.25 44.5109 1.128821958 0.2822055 1.10708 1.86401

0.75 65.6415 0.957059347 0.7177945 1.10708 1.07164

methanol
methyl acetate
P bubble

-33.424
-53.424

73.5003 kPa

yi
methanol
methyl acetat
P dew

0.6
0.4
62.8945

101.33 kPa
xi
P sat (kPa)
Ki = * P sat / Pyi = xi x Ki
0.85 77.9988 0.787953745 0.6697607
0.15 105.363 2.202425786 0.3303639

methanol
methyl acetate
T bubble

331.204 K

AZEOTROPE
T=
A=
Psat 1 =
Psat 2 =

318.15 K
1.10708
44.5109 kPa
65.6415 kPa

x1

1
0
1

2
3.0255
1

1.0388 1.02365
1.0388 2.11813

1.0001246
goal seek = 1

yi
methanol
methyl acetat
T dew

methanol
methyl acetate

12
1 2.051563528
3.0255 0.224125571

syarat azeotrop 12 < 1 < 12

0.4
0.6
326.689

= 1.47473

ln (1 az/2 az 0.38847
1-2x1 az =
0.3509
x1 az = Y1 az0.32455
2 az =
1.12368
P az =
73.7601 kPa

ln (1 az/2 az) = A(x2 az^2 - x1 az^2)

[ln (1 az/2 az)]/A = (1-x1 az)^2 - x1 az^2 = 1-2x1 az
1 az =

1.6571254

P sat (kPa)Ki = * P sat / P xi = yi / Ki

A
tebak hitung galat
galat ^ 2
44.5109 0.7344601788 0.8169265 1.10708 1.0378 1.0378 2.111E-007 4.46E-014
65.6415 2.1849150745 0.1830735 1.10708 2.09348 2.09348 4.632E-007 2.15E-013
kPa

2.59E-013

P sat (kPa)Ki = * P sat / P xi = yi / Ki

A
tebak hitung galat
galat ^ 2
64.6076 0.8690672495 0.4602636 1.06241 1.36304 1.36274 -0.0002983 8.90E-008
89.9148 1.1116537049 0.5397364 1.06241 1.25278 1.2524 -0.0003805 1.45E-007
K

2.34E-007

2 = 1-2x1 az

Pers. Antoine
A
B
C
benzene
13.7819 2726.81
217.572
toluene
13.932 3056.96
217.625
T

benzene
toluene
P bubble

benzene
toluene
T bubble

100 deg C
xi
P sat (kPa)Ki = P sat / Pyi = xi x Ki
0.33 180.453 1.6509343 0.54481
0.67 74.2597 0.6793905 0.45519
109.303 kPa

benzene
toluene
P dew

yi
P sat (kPa)Ki = P sat / Pxi = yi / Ki
0.33 180.453 1.9581151 0.16853
0.67 74.2597 0.8058012 0.83147
92.1564 kPa

120 kPa
xi
P sat (kPa)Ki = P sat / Pyi = xi x Ki
0.33 197.105 1.6425422 0.54204
0.67 81.9813 0.6831771 0.45773
103.299 deg C

0.99977
goal seek = 1

benzene
toluene
T dew

yi
P sat (kPa)Ki = P sat / Pxi = yi / Ki
0.33 229.372 1.9114308 0.17265
0.67 97.1638 0.8096979 0.82747
109.127 deg C

1.00011
goal seek = 1

xi = yi / Ki

xi = yi / Ki

goal seek = 1

Pers. Antoine
A
B
C
benzene
13.7819 2726.81
217.572
toluene
13.932 3056.96
217.625
T

benzene
toluene
P bubble

benzene
toluene
T bubble

105 deg C
xi
P sat (kPa)Ki = P sat / Pyi = xi x Ki
0.28177 206.141 1.7178452 0.48404
0.71823 86.2049 0.718374 0.51596
1
120 kPa
1

benzene
toluene
P dew

yi
P sat (kPa)Ki = P sat / Pxi = yi / Ki
0.48405 206.141 1.7178452 0.28178
0.51595 86.2049 0.718374 0.71822
1
120 kPa
1

120 kPa
xi
P sat (kPa)Ki = P sat / Pyi = xi x Ki
0.28177 206.141 1.7178452 0.48404
0.71823 86.2049 0.718374 0.51596
1
105 deg C
1
goal seek = 1

benzene
toluene
T dew

yi
P sat (kPa)Ki = P sat / Pxi = yi / Ki
0.48405 206.141 1.7178452 0.28177
0.51595 86.2049 0.718374 0.71823
1
105 deg C
1
goal seek = 1

xi = yi / Ki

xi = yi / Ki

goal seek = 1

ethyl ethanoat
n-heptane

343.15 K
xi
P sat (kPa)
Ki = * P sat / Pyi = xi x Ki
0.05
79.8 3.920842075 0.1960421
0.95
40.5 0.84627147 0.8039579

P bubble

47.9708 kPa

T=
A=
Psat 1 =
Psat 2 =

343.15 K
0.95
79.8 kPa
40.5 kPa

x1 = 0
x1 = 1

0.95 2.35697
0.95 1.00238

ethyl ethanoa
n-heptane
P dew

yi
0.05
0.95
42.2027

ethyl ethanoate
n-heptane

1
2
12
2.58571
1 5.094805699
1 2.58571 0.762023054

syarat azeotrop 12 < 1 < 12

= 0.50752

ln (1 az/2 az -0.67822
1-2x1 az =
-0.71392
x1 az = Y1 az0.85696
2 az =
2.00904
P az =
81.3663 kPa

ln (1 az/2 az) = A(x2 az^2 - x1 az^2)

[ln (1 az/2 az)]/A = (1-x1 az)^2 - x1 az^2 = 1-2x1 az
1 az =

1.0196279

P sat (kPa)Ki = * P sat / P xi = yi / Ki

A
tebak hitung galat
galat ^ 2
79.8 4.9215678694 0.0101594 0.97633 2.6028 2.6028 1.003E-006 1.01E-012
40.5 0.9597504543 0.9898406 0.97633 1.0001 1.0001 1.718E-007 2.95E-014
kPa

2 = 1-2x1 az

1.04E-012