This document is a past exam for a First Year Pharm D Degree in Pharmaceutical Organic Chemistry. It contains 3 essay questions worth 30 marks total asking about nomenclature of alkanes, alkenes, and alkynes, Markovnikoff's and anti-Markovnikoff's rules and theory of resonance, and the Reimer-Tiemann and Williamson reactions and their mechanisms. It also contains 10 short answer questions worth 5 marks each and covering topics like the role of solvents in substitution reactions, aromatic group substitution and orientation, aldol condensation mechanism, preparation and uses of dimercaprol and saccharin, classification and examples of carboxylic acids, the role of carbocations and carbocation
This document is a past exam for a First Year Pharm D Degree in Pharmaceutical Organic Chemistry. It contains 3 essay questions worth 30 marks total asking about nomenclature of alkanes, alkenes, and alkynes, Markovnikoff's and anti-Markovnikoff's rules and theory of resonance, and the Reimer-Tiemann and Williamson reactions and their mechanisms. It also contains 10 short answer questions worth 5 marks each and covering topics like the role of solvents in substitution reactions, aromatic group substitution and orientation, aldol condensation mechanism, preparation and uses of dimercaprol and saccharin, classification and examples of carboxylic acids, the role of carbocations and carbocation
This document is a past exam for a First Year Pharm D Degree in Pharmaceutical Organic Chemistry. It contains 3 essay questions worth 30 marks total asking about nomenclature of alkanes, alkenes, and alkynes, Markovnikoff's and anti-Markovnikoff's rules and theory of resonance, and the Reimer-Tiemann and Williamson reactions and their mechanisms. It also contains 10 short answer questions worth 5 marks each and covering topics like the role of solvents in substitution reactions, aromatic group substitution and orientation, aldol condensation mechanism, preparation and uses of dimercaprol and saccharin, classification and examples of carboxylic acids, the role of carbocations and carbocation
This document is a past exam for a First Year Pharm D Degree in Pharmaceutical Organic Chemistry. It contains 3 essay questions worth 30 marks total asking about nomenclature of alkanes, alkenes, and alkynes, Markovnikoff's and anti-Markovnikoff's rules and theory of resonance, and the Reimer-Tiemann and Williamson reactions and their mechanisms. It also contains 10 short answer questions worth 5 marks each and covering topics like the role of solvents in substitution reactions, aromatic group substitution and orientation, aldol condensation mechanism, preparation and uses of dimercaprol and saccharin, classification and examples of carboxylic acids, the role of carbocations and carbocation
First Year Pharm D Degree Examinations - August 2013
Pharmaceutical Organic Chemistry Time: 3 Hours
Total Marks: 70
Answer all Questions.
Draw Diagrams wherever necessary.
Essay
(3x10=30)
1. Describe about the general nomenclature of alkanes, alkenes and alkynes.
2. Explain in detail: Markovnikoffs rule and anti markovnikoffs rule.
Theory of resonance.
3. Explain the following reaction with mechanism:
Reimer- Tiemann reaction.
Williamson synthesis.
Short notes:
(8x5=40)
4. Role of solvents/reagents in nucleophilic substitution reaction.
5. Aromatic group substitution and orientation. 6. General mechanism of aldol condensation. 7. Mention the preparation, assay and uses of dimercaprol and saccharin. 8. Define and classify carboxylic acids with suitable examples. 9. Explain the role of carbocation and brief about rearrangement of carbocation. 10. Explain briefly about 1, 4 addition and hyper conjugation. 11. Define isomerism with suitable examples.