Weatherability of

Thermoplastic Piping
Systems
TR-18/2005

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WEATHERABILITY OF THERMOPLASTIC PIPING SYSTEMS

Foreword
This report was developed and published with the technical help and financial support of the
members of the PPI (Plastics Pipe Institute). The members have shown their interest in
quality products by assisting independent standards-making and user organizations in the
development of standards, and also by developing reports on an industry-wide basis to help
engineers, code officials, specifying groups, and users.
The purpose of this technical report is to provide information on the weather resistance of
the basic plastic materials used in commercial plastic piping systems.
This report has been prepared by PPI as a service of the industry. The information in this
report is offered in good faith and believed to be accurate at the time of its preparation, but
is offered without any warranty, expressed or implied, including WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Consult the
manufacturer for more detailed information about the particular weathering package used for
its piping products. Any reference to or testing of a particular proprietary product should not
be construed as an endorsement by PPI, which do not endorse the proprietary products or
processes of any manufacturer. The information in this report is offered for consideration by
industry members in fulfilling their own compliance responsibilities. PPI assumes no
responsibility for compliance with applicable laws and regulations.
PPI intends to revise this report from time to time, in response to comments and
suggestions from users of the report. Please send suggestions of improvements to the
address below. Information on other publications can be obtained by contacting PPI directly
or visiting the web site.
The Plastics Pipe Institute
http://www.plasticpipe.org

October 2005

WEATHERABILITY OF THERMOPLASTIC PIPING SYSTEMS

1.0

INTRODUCTION

Thermoplastic polymers, like many other materials, are affected by weathering, which is a
general term used to cover the entire range of outdoor environmental conditions. However,
plastic piping made of thermoplastics that incorporate appropriate weathering protection
have been used in various outdoor applications and have given many years of service. For
those piping systems that are intended for continuous outdoor exposure, a material
composition must be selected that has the necessary weather resistance for the specific
conditions involved. Most thermoplastic piping has sufficient weather resistance to withstand
normal exposure that occurs before installation. In some instances this time period can be
as long as several years.
Thermoplastic polymers have definitive characteristics regarding weather deterioration:
Some are inherently resistant while others are less resistant. The weatherability of all
thermoplastics can be improved by the incorporation of select ingredients. The combination
of the basic thermoplastic polymer with these select ingredients results in the finished
material that is generally termed a thermoplastic compound.
This report covers the structure and inherent weather resistance of the basic thermoplastic
polymers used in commercial thermoplastic piping and discusses the weather resistance of
those thermoplastic compounds that are in established use. Much of the discussion focuses
on the effects of ultraviolet radiation exposure, as this is generally the weathering factor with
the greatest impact on the performance of thermoplastic piping.
2.0

FACTORS INFLUENCING WEATHERING

When making a determination for the suitability of a particular plastic material for either
outside storage or long term above ground service, the environment surrounding the piping
material must be considered. A brief description of the more important environmental
parameters follows:
2.1

Sunlight

Sunlight contains a significant amount of ultraviolet radiation. The ultraviolet radiation

that is absorbed by a thermoplastic material may result in actinic degradation (i.e., a
radiation promoted chemical reaction) and the formation of heat. The energy may be
sufficient to cause the breakdown of the unstabilized polymer and, after a period of
time, changes in compounding ingredients. Thermoplastic materials that are to be
exposed to ultraviolet radiation for long periods of time should be made from plastic
compounds that are properly stabilized for such conditions.

2.2

Temperature

The daily range of temperature varies considerably both with season and location
and can be quite large. Heat from solar radiation can raise the temperature of directly
exposed materials as much as 60F higher than ambient, depending on the pipe
color. Such extremes of temperature over an extended period can cause physical
damage to the polymer. Therefore, it is important that heat stabilizers be incorporated
into the compounding ingredients in order to offset the deleterious effects of high
temperature. In addition, it should be remembered that chemical reaction rates
increase exponentially as the temperature increases.
2.3

Moisture

Rain and humidity are the two main contributors of moisture with humidity having the
greater overall effect. In general, humidity contributes a moist continuum in constant
contact with the material to produce hydrolysis, leaching, etc. Rain produces a
washing and impacting action.
2.4

Wind

Wind acts as a carrier of impurities such as dust, gases and moisture that can
contribute to weathering effects. Similarly, the absence of wind can allow the
accumulation of air contaminants, as in smog areas, which could contribute
significantly to the weathering of a material.
2.5

Gases

The nature and quantity of gases vary widely but, in industrial areas especially, gases
are present which can result in chemical action on some materials.
2.6

Location

The geographical location is also a factor. Less effects are produced where there are
less sunlight hours per year and where the radiation is less intense. For example, a
specific period of exposure in Arizona is more detrimental than in New Hampshire
due to the obvious extra hours of UV (ultraviolet) exposure and, less obviously, to the
higher ambient temperatures encountered.

3.0

WEATHERING RESISTANCE OF BASIC THERMOPLASTIC POLYMERS

Some polymers are inherently quite resistant to weather, others less so, and some
deteriorate quite rapidly. For the purpose of this discussion, only those polymers commonly
used in piping applications are presented.

3.1

Polyethylene. Polypropylene. and Polyvinyl Chloride (Figure 1)

Polyethylene (PE), polypropylene (PP), and polyvinyl chloride (PVC) all have the
same basic structure as shown in Figure 1. They all have a backbone of carbon-tocarbon bonds with various side components: hydrogen (H) for PE, a methyl (CH3)
group for PP, and chlorine (Cl) for PVC. With UV stabilization, these polymers give
good long-term service in outdoor applications. The ability to withstand exposure to
weathering conditions is dependent on the type of UV stabilization and the amount of
UV exposure.
3.2

ABS (Acrylonitrile-Butadiene- Styrene) Terpolymers

Impact-modified styrenic polymers such as ABS (acrylonitrile-butadiene-styrene)

terpolymers are very sensitive to oxidation, essentially because of the polybutadiene
content. The carbon-carbon double bond (C=C), which is responsible for the
elastomeric behavior of the rubber, is extremely sensitive to UV energy. This energy
causes oxidation and crosslinking that modifies the materials rubbery behavior to one
of a more brittle nature. Degradation from weathering starts at the surface and results
in a rapid loss of mechanical properties such as ultimate elongation, toughness, and
impact strength.
To avoid degradation, ABS is frequently protected by the inclusion of carbon black in
the formulation. The addition of sufficient carbon black can make these polymers very
weather resistant, as evidenced by the good field history of black ABS (acrylonitrilebutadiene-styrene) pipe. Carbon black is the most common UV stabilizer used for
extended outdoor applications.
4.0

WEATHERING OF POLYETHYLENE (PE) PIPE

The basic polyethylene polymer has limited outdoor life. However, most polyethylene pipe
manufactured today contains an ultraviolet stabilization package. For typical outdoor
storage, ultraviolet stabilized non-black systems are satisfactory, but for prolonged outdoor
use, polyethylene should be formulated with a minimum of 2 percent finely dispersed carbon
black.
Incorporating carbon black in polyethylene compounds greatly increases their weather
resistance (1,2). Carbon black acts as a UV absorbent and screens the polyethylene from
damaging ultraviolet radiation. The aging resistance imparted by the carbon black depends
upon its type, particle size, concentration, and degree of dispersion in the polyethylene (3).

ASTM material standard D 3350 requires a minimum concentration of 2 percent carbon

black. It has been demonstrated that this amount of well-dispersed very fine particle carbon
black is sufficient protection for continuous outdoor service.

5.0

WEATHERING OF POLYPROPYLENE (PP) PIPE

Pigmented (non-black) polypropylene (PP) pipe, like pigmented (non-black) polyethylene

pipe, has a limited life when stored outdoors. The outdoor storage life of non-black
polypropylene should be limited to a total of three months unless the pipe is covered or
otherwise protected from sunlight (4).
Some PP piping is protected from ultraviolet radiation by the inclusion of carbon black in the
compound. Polypropylenes weatherability, like polyethylenes, is greatly enhanced by the
incorporation of carbon black. The degree of weatherability imparted by the carbon black
depends upon its type and particle size, concentration and dispersion in the compound. A
concentration of two percent generally results in the best resistance (5).
It should be noted that PP piping is available manufactured from both carbon black and noncarbon black UV stabilized compounds. Applications that are not subject to outdoor
exposure, such as indoor plumbing applications, may successfully utilize non-black PP
piping. Non-black PP pipe should not be installed above ground outdoors where it would be
continuously exposed to ultraviolet light or sunlight.

6.0

WEATHERING OF POLYVINYL CHLORIDE (PVC) PIPE

Generally, standard PVC pipe grade materials covered under ASTM D 1784 (such as PVC
1120 - cell classification 12454) include sufficient UV screen, usually titanium dioxide (TiO2),
to be stored outdoors for at least one year. Special care must be given to ensure that PVC
pipe used in outdoor applications has been formulated to be a highly weather resistant
product. Otherwise, it may not deliver equally satisfactory performance outdoors.
PVC materials can be compounded with a suitable amount of TiO2 to be a very highly
weatherable product, as can be seen in siding, windows, and furniture. These PVC
compounds use PVC resin, UV screens and other weather resistant ingredients.

7.0

WEATHERING OF ACRYLONITRILE-BUTADIENE-STYRENE (ABS)

ABS pipe usually contains carbon black to provide protection from sunlight. The effects of
ultraviolet radiation are substantially reduced in pipe so protected and permit the use of ABS
pipe in outdoor applications. The largest outdoor use is probably plumbing vent pipes of
drain, waste and vent (DWV) systems that are fully exposed to all climatic conditions.

Prolonged exposure of such plumbing vents has not affected their performance. Close
examination has shown that only a very thin surface layer of the pipe has been affected by
sunlight, even after several years exposure.
No adverse effects have been found from other weather conditions such as wet or cold, or
from geographical location where the intensity of ultraviolet radiation varies. Non-black ABS
compounds are not recommended for outdoor service.

8.0

EFFECTS OF WEATHERING

The effects of weathering can vary from a complete loss of tensile strength and reduction of
ductility to slight surface degradation that does not detract from performance. Generally
speaking, the first effect of weathering will be a slight discoloration of the pigment resulting
in a chalky surface or whitening of the coloration.
Plastic compounds that have been adversely affected by weathering will exhibit a reduction
in tensile strength and ductility. In all cases, surface degradation must be removed in order
to allow the plastic compound to be hot plate welded (heat fused) or solvent bonded. The
pipe and fitting manufacturer's recommended heat fusing or bonding procedures should be
consulted.

9.0

DESIGN CONSIDERATIONS

The following statements on weathering characteristics of plastic piping compounds may be

used for guidance on piping systems utilizing these materials. The weathering statements
are appropriate for piping systems that have been designed to withstand the temperatures
and other environmental conditions encountered in the specific application.
The service life of plastic pipe exposed simultaneously to weathering and external stresses
may be greatly reduced by acceleration of chemical and physical changes (6,7). For
example, unstressed control specimens of various polyethylene compounds required
considerably longer time to show signs of degradation from natural ultraviolet light than did
specimens exposed in the form of bent strips subjected to high stresses (8,9).

10.0

NATURAL WEATHERING

Most natural weathering studies are conducted in accordance with ASTM D 1435, "Standard
Practice for Outdoor Weathering of Plastics" (10). The intensity of solar radiation, of course,
varies widely with the geographical location and time of year. (One year's exposure in New
Jersey, for example, does not give the same degree of aging as a year's exposure in Florida
or Arizona). A month's exposure in July or August at any location is not the same as a
month's exposure during December or January. Even at one location, the variation in solar

radiation from year to year can be as great as the total radiation for a whole month.
Therefore, even a year as a unit for timing exposure is variable and cannot be used for
direct comparison of samples, unless they were exposed during the same period.
However, data and case histories from severe locations, where radiation is intense, enable
users to properly design for applications at less severe locations. Change in tensile
properties, color change, brittleness temperature and other significant properties are used
as criteria.

11.0

ACCELERATED WEATHERING

A number of devices are used to simulate outdoor exposure. These employ mercury
sunlamps, carbon arcs, xenon arcs or a combined fluorescent sunlamp-black light. ASTM
Standard Practices D 4329 (11), D 1499 (12) and D 2565 (13) cover the latter three.
None of these tests can be absolutely correlated with outdoor exposure. The reasons for
this lack of correlation are:
1.
2.
3.
4.

The extreme variations in outdoor environment.

The radiation spectrum does not exactly duplicate the solar spectrum.
Temperatures and temperature ranges differ from outdoor conditions.
Humidity difference.

However, in spite of this lack of correlation with outdoor exposure, accelerated testing is an
extremely useful tool for comparing the relative aging resistance of materials and rapidly
screening out materials that have a poor resistance. The same criteria of change in
properties and appearance used to evaluate natural weathering are used for accelerated
tests.
A very reliable index of weather resistance is provided by intensified natural sunlight testing
stations. These test stations use an equatorial mount that follows the sun and also
concentrates the sun's rays by a battery of mirrors. The sun's spectrum is used and the
accompanying heat generated is controlled with air and water streams. Results are obtained
in approximately one seventh of the time required in natural exposure. Reference numbers
14, 15, 16, 17 in Section 12.0 may be consulted for further information on this subject.

[ CH2 - CH2 ] n

Polyethylene

) ]

CH2 - CH ( CH3 )

Polypropylene

CH2 - CH CL

Polyvinyl chloride

CH2 - CH ( C6 H5 )

Polystyrene

FIGURE 1

12.0

REFERENCES

1.

Gilroy, H. M., "Polyolefin Longevity for Telephone Service," Antech '85, pp. 258-260.

2.

Whitney, Lynn, C., "Specifying Carbon Blacks for UV Light Protection," Plastics
Engineering, (December 1988), pp. 29-33.

3.

Wallder, V. T., Clarker, W. J., DeCoste, J. B., and J. B. Howard, "Weathering Studies
on Polyethylene," Industrial and Engineering Chemistrv Vol 42, No. 11, pp. 23202325.

4.

AWWA Standard C 902-88, "Polybutylene (PB) Pressure Pipe and Tubing, One-Half
Inch Through Three Inch for Water," American Water Works Association, Denver,
CO, 1988.

5.

Plastics Piping Manual, Plastics Pipe Institute, Washington, DC, 1976.

6.

Quackenbos, H. M. and Samuels, H., "Practical Problems for Predicting Weathering

Performance," Modern Plastics Vol. 44, No. 8, (April 1967), p. 143.

7.

Gary, V. E. and Cadoff, B. C., "Experimental Techniques for the Evaluation of the
Effects of Weathering on Plastics," Modem Plastics, Vol. 44, No. 8 (April 1967), p.
219.

8.

Kaufman, F. S., Jr., "Evaluating Weathering of High Density PE," Modern Plastics,
Vol. 44, No. 8 (April 1967), p. 146.

9.

Newland, G. C. and Tamblyn, J. W., "Weathering of Polyolefins Under Stress,"

Polvmer and Engineering Science (July 1965), pp. 148-151.

10.

ASTM D 1435-94, "Standard Practice for Outdoor Weathering of Plastics," American

Society for Testing and Materials, Philadelphia, PA, 1985.

11.

ASTM D 4329-92, "Standard Practices for Operating Light and Water Apparatus
(Fluorescent UV and Condensation Type) for Exposure of Plastics," American
Society for Testing and Materials, Philadelphia, PA, 1984.

12.

ASTM D 1499-92a, "Standard Practice for Operating Light and Water Exposure
Apparatus (Carbon-Arc Type) for Exposure of Plastics," American Society for Testing
and Materials, Philadelphia, PA, 1984.

13.

ASTM D 2565-92a, "Standard Practice for Operating Xenon ArcType Light Exposure
Apparatus With and Without Water for Exposure of Plastics," American Society for
Testing and Materials, Philadelphia, PA, 1988.

14.

DeBlieu, I. K. and Zerlaut, G. A., "Weathering of Plastics and Plastics Piping; Real
Time and Accelerated Outdoor Exposure Testing," American Gas Association
Distribution/Transmission Conference, May 1984.

15.

Engineering Plastics, Engineering Materials Handbook, Vol. 2, 1988, pp 575-580.

16.

Modern Plastics Encyclopedia. Vol. 67, No. 11, p. 216, McGraw-Hill Publishing Co.,
New

17.

Palermo, E. F., "New Outdoor Storage Requirements in ASTM D 2513," AGA Plastic
Materials Committee Workshop, February 1987.