Composites Manufacturing January February 2015 Issue
Composites Manufacturing January February 2015 Issue
Composites Manufacturing January February 2015 Issue
January/February 2015
2015
Industry
Forecast
A M E R I C A N C O M P O S I T E S M A N U FA C T U R E R S A S S O C I AT I O N
www.compositesmanufacturingmagazine.com
www.compositesmanufacturingmagazine.com
A M E R I C A N C O M P O S I T E S M A N U FA C T U R E R S A S S O C I AT I O N
At Composites One, we
make it our business to
know your business.
Gary Yoder, Driver, Goshen, IN
CompositesManufacturing
January/February 2015
10
28
Market Segments
Architecture .......................................8
FRP Infoshop
Construction ....................................10
Green Roof
Transportation
Fuel-efficient Trucks ........................... 12
Departments
& Columns
Features
Composites
Manufacturing
Volume 31 | Number 1 | January/February 2015
Jay Merrell
Norplex-Micarta
ACMA Chairman of the Board
[email protected]
2
CompositesManufacturing
Styrene replacement
ac me made easy,
cha ge resins
r
...dont change
just
ange Monom
change
Monomers
Vinyl Toluene and Para
Methyl Styrene
are Non HAPS MACT Compliant
& Low vapor pressure Low VOC
Reduce workplace exposure and
your TRI.
Take advantage of the ANSI/
ACMA Unied Emission Factors
for methyl styrenes:
45% reduction in total VOC and
100% reduction in HAPS*
Deltech Monomers
are fully compatible with Styrene
monomer and common catalysts
so partial replacement is
possible and yields the same
100% HAPS elimination and 45%
VOC reduction for the portion of
Styrene that is replaced. Meet the
expected 20 ppm PEL for Styrene
with a partial replacement with
VT or pMS
*Non Atomized Mechanical spray
application.
800-535-9945
www.deltechcorp.com
Best Practices
CompositesManufacturing
R-OOH + Co g RO + OH- + Co
3+
SAERTEX Germany
E-Mail: [email protected]
SAERTEX France
E-Mail: [email protected]
SAERTEX USA
E-Mail: [email protected]
SAERTEX India
E-Mail: [email protected]
SAERTEX Brasil
E-Mail: [email protected]
SAERTEX Portugal
E-Mail: [email protected]
SAERTEX China
E-Mail: [email protected]
SAERTEX worldwide
www.saertex.com
Safe, Green
Acetone
Replacement
www.uspoly.com or
1 800 431 2072
1-800-431-2072
Recognized for
safer chemistry
www.epa.gov/dfe/
669099_USpoly.indd
1
04/12/13 2:34 PM
6
CompositesManufacturing
R CH CH R
At elevated temperatures, different types
of OPs that react due to heating are used.
The end result is the same: Free radicals
create the conditions for polymerization.
r
R-OO-R g RO + RO
The key to the manufacture of a
thermoset composite is then having a
good mix, which places the decomposing
organic peroxide near the double bonds of
the reactive monomer and UPR to have
an efficient polymerization.
Safe mixing can be demonstrated using
the example of an auto-cast application.
The prepromoted UPR (containing
materials ready to produce decomposition)
is first mixed with reinforcements through
the action of an auger or a static mixer
to reach a level of thoroughly wet out
reinforcement. This UPR matrix then
continues to where the OP is introduced
and also thoroughly augered in. The
OP is but a small percentage of the final
product (1 to 2.5 percent), and therefore
this mixing step is critical to give the end
composite the best physical properties.
The same order and attention to mixing
seen in this closed system should be
followed in an open-air process. The
closed system is very safe, but in open
application of peroxide there must be
other precautions taken.
With open systems like spray-up
laminating, the mixing of organic
peroxide with a resin could happen with
impingement of the peroxide into a
stream of resin. If the stream of peroxide
Architecture
Innovative
Infoshop
Made from
FRP
T
CompositesManufacturing
Workers at Compmillennia apply a coat of polyester resin with fillers to FRP wall panels.
Construction
Composites
Help a Green
Roof Grow
reenery and gardens arent just
found on the ground. Green roofs,
which partially or completely cover a
building with vegetation planted over
a waterproofing membrane, exist all
over the world, from the tops of small
houses on remote islands to congested
city skyscrapers. These roofs offer many
benefits, especially for urban buildings
such as the Gordon Persons Building in
Montgomery, Ala.
As part of a renovation in early 2014, a
green roof was installed on the Gordon
Persons Building, which houses Alabamas
Department of Revenue. The underlying
structure of most green roofs is often built
with steel parts. But contractor J.J. Morley
Enterprises Inc. opted to use composite
beams and grating from Strongwell to
complete the project.
Green roofs help to mitigate warm
temperatures in cities because they absorb
carbon dioxide and decrease the amount
of dark rooftop space that would absorb
heat. The roofs also reduce heating and
cooling loads on a building by 50 to
90 percent by adding mass and thermal
resistance and through evaporative
cooling, respectively. In addition,
green roofs absorb rainwater, reducing
stormwater runoff by up to 75 percent.
The Gordon Persons Buildings roof
features 26 separate planters, each in
varying geometric shapes spread across six
rooftop courtyards. A mix of perennial
plants suited to Alabamas climate were
pre-grown in vegetation trays with a
drainage layer made from 100 percent
CompositesManufacturing
maintenance
and allows for
simple landscape
maintenance and
replacement as
needed, says
Mark Kelley,
vice president of
operations at J.J.
Morley.
Wyatt says it
only took about
two weeks to get
all of the beams
and gratings laid
down during
the 14-month
Fiberglass beams are bolted to the planter area, then molded
total renovation
grating is laid on top to make a false bottom. Unlike steel green
project. The parts roofs, composite green roofs wont corrode from constant contact
with fertilizer and water.
are all cut to size
and all the holes
are pre-drilled, so all [the installers] have
their way into more architectural projects.
to do is lay it out, bolt it together and
I think [green roofs are] a growing market
lay the gratings on top, he says. Kelley
with a lot of potential, Wyatt says.
added that the J. J. Morley team was
very satisfied with the ease of use and
Mary Beck is the communications
outcome of the composite materials.
coordinator at ACMA. Email comments
Composites are slowly but surely finding
to [email protected].
Composite materials
Tooling systems
www.gurit.com
CompositesManufacturing
11
Transportation
12
CompositesManufacturing
Walmarts truck fleet includes 6,500 tractors, 55,000 trailers and more than 7,000
drivers. It remains to be seen whether this green concept vehicle, made from CFRP,
will become the norm for the multinational retailer: The technologies employed are in
different stages of market acceptance and regulatory approval.
HOW C
AN
INNOV
ATIVE
PRODU
CTS BY
MAR-B
AL ADD
VALUE
TO
YOU?
Mar-Bal Fact:
A QUIETER
PRODUCT
CAN ALSO BE A
MORE EFFECTIVE
PRODUCT
mar-bal.com
fiber is growing, which is helping to boost
production volumes, cut costs and drive
up material usage.
As Durnin says, As more and more
products use carbon fiber, we suspect that
the price of carbon fiber is going to be
13
Want
14
CompositesManufacturing
15
CompositesManufacturing
YOU INSPIRE US
TO INNOVATE
The latest generation
aircraft requires new repair
techniques. HEATCON
remains your partner to
develop innovative composite
repair systems.
Double Vacuum Debulking (DVD) Chamber HCS7600 enables nearautoclave quality material compaction
17
the
State of
Industry
What Will Drive Composites
Growth in 2015?
By Dr. Sanjay Mazumdar
Automotive/Transportation
In 2014, the U.S. automotive/transportation industry grew
for the fifth consecutive year. Auto sales were projected to
reach 16.5 million units, and light-duty vehicle production in
North America was projected to grow by 5.6 percent. Growth
in demand can be attributed to the easy availability of credit
at low interest rates, increasing consumer confidence and the
introduction of fuel-efficient vehicles.
Demand for composites in the U.S. automotive industry
grew by 6.3 percent in 2014 due to increasing use of fiberglass
Source: Lucintel
CompositesManufacturing
19
Source: Lucintel
20
CompositesManufacturing
Aerospace
Within aerospace, composite materials demand grew by 10.7
percent in 2014. Composites provide numerous advantages in
this segment: They are lightweight with higher strength than
competing materials, which results in improved fuel efficiency,
an increase in passenger carrying capacity, low emissions and low
maintenance costs.
Composite material consumption has increased significantly
in the commercial aerospace sector, from 5 to 6 percent in the
1990s to more than 50 percent in todays advanced aircraft
Source: Lucintel
Construction
Source: Lucintel
CompositesManufacturing
21
Source: Lucintel
Renewable Energy
Wind energy is another segment where composites are a
great fit. With ever-increasing blade lengths and boosts in the
megawatt capacity of turbines, the use of lightweight materials
has subsequently increased. Composite materials offer significant
weight reduction and increased blade stiffness, which in turn
raises the level of energy output. In addition, the burgeoning
offshore wind market compels blade manufacturers to use
advanced materials that can reduce system weight without
compromising mechanical properties.
The governments renewable energy incentives, such as the
Production Tax Credit (PTC) policy, impact the development of
wind energy in the United States. The PTC expired in 2013, but
22
CompositesManufacturing
U.S. legislation extended the term for availing PTC benefits until
2015. Wind farms will be eligible to derive optimum benefits
of the extended PTC on projects begun in 2013 and whose
construction will take subsequent years to complete.
As the figure above shows, when PTC benefits are extended, wind
installations rise. Conversely, the removal or expiration of PTC
policies have resulted in a decline in new capacity installations.
Industry Innovations
Although composite materials have successfully penetrated
various market segments, continuous innovations are required
to address arising needs. Industry leaders are developing new
resins, fibers, compounds, nano-materials, bioplastics and so on.
Technology suppliers also are developing new technologies for
rapid production, low energy consumption and low wastage of
raw materials.
Lightweighting and cost reduction are two trends that permeate
the industry. Innovation mega trends also are affecting individual
sectors of the composites industry, including fibers, resins,
composites technology and end-use applications:
Fiber Innovations: Significant innovation is expected in
future development of low-cost carbon fibers for automotive,
wind energy and industrial applications. Low-cost alternative
precursors such as textile polyacrylonitrile (PAN), lignin and
polyolefin also are being considered. In addition, there is a focus
on reducing energy cost.
Within the GFRP market, suppliers are developing highperformance glass fibers to meet higher mechanical and chemical
requirements. Finally, a growing focus on green materials
provides momentum to the development of high-strength natural
fibers that could ultimately increase penetration in automotive,
construction and other industries.
Resin Innovations: More new product launches in resin will
focus on shorter cure time (in the range of one to two minutes)
for mass volume applications. Momentive and Huntsman have
developed epoxy resin systems with short cycle times for high
There are thousands of composites applications with good track records. The penetration level of composites in each application differs according to performance requirements, functional requirements and other factors. Lucintel has identified two distinct
strategic viewpoints push and pull strategies that can help the composites industry grow. In marketing, push strategies involve taking products directly to customers, while pull strategies motivate customers to actively seek out products.
Looking Ahead
The aforementioned innovations are likely to address the unmet
needs of composite materials and will help to make composites a
material of choice in many segments. Prudent investments should
yield long-term growth in the marketplace.
Dr. Sanjay Mazumdar is CEO of Lucintel, a global market
research and management consulting firm. Email comments to
[email protected].
CompositesManufacturing
23
Layer
by
Layer
Additive manufacturing
is building its way into more projects,
on the shop floor
and at home.
Photo Credit: Martinde Bouter
By Mary Beck
decade, the rise of 3-D printing has brought manufacturing into homes and small businesses,
allowing users to bring to life on a desktop any item they can dream up with a CAD
program. Composites companies are jumping into the field, too, by 3-D printing items with
reinforced fibers.
24
CompositesManufacturing
The MarkOne may not look so different from other desktop 3-D
printers, but its the first one to print carbon fiber composites
continuously.
now its actually realistic for someone to not have any engineering
experience whatsoever, but still be able to print an idea and show
it to people.
Processes and Production Considerations
The overall process to 3-D print an object can be reduced to
the basic steps of creating a CAD file, converting it to STL,
transferring the STL file to the machine, preparing the machine,
waiting for the item to print, then removing it and completing
any post-processing by hand. This may be simple enough to do at
home, but there are still numerous considerations to make before
a manufacturer can begin printing.
The ease or difficulty of additive manufacturing varies for each
project, says Chad Duty, group leader of Oak Ridge National
Laboratorys Deposition Science & Technology Manufacturing
Demonstration Facility, who led a pre-conference tutorial
on additive manufacturing at CAMX 2014. Off the bat, the
manufacturer must make several decisions before the CAD file
is created, including choosing the best machines and materials
for the project that are compatible with one of many different
additive manufacturing processes.
Most 3-D printers, especially hobbyist and consumer-oriented
models, use fused deposition modeling, a special application of
plastic extrusion. Duty says electron beam melting a powder
bed fusion technique and direct laser metal sintering are two
other popular options.
Properties such as layer thickness and support materials
must also be considered before designing the object. Layer
thickness affects the finished products resolution, accuracy
and surface finish. Duty says that thinner layers are better and
produce less of a stair-step effect in between. Any section
of the design that abruptly hangs out from the rest requires
a support material during printing, which could be powder,
liquid or sacrificial deposit.
Where the process can get tricky is during post-processing,
which involves removing any support material and sanding edges.
Sometimes [the support material] is powder that you can easily
blow away, or sometimes its a brittle plastic that you have to
CompositesManufacturing
25
Tourists visit the 3-D Print Canal House in Amsterdam during its construction. The house is being printed using sustainable materials.
CompositesManufacturing
first functional 3-D printed car built by Local Motors and Oak
Ridge National Laboratory. (To read an article about the car,
visit CompositesManufacturingMagazine.com and click on the
Automotive link under the Market Segments tab.)
Perhaps the most exciting recent innovation in composite
applications is MarkForgeds MarkOne, the first and only 3-D
printer that prints continuous carbon fiber strands. Other
composite 3-D printers use chopped or discontinuous carbon
fibers, which are not as strong as the continuous strands of
carbon fiber, fiberglass, Kevlar, nylon and polylactic acid that the
MarkOne can print.
Parts printed on the MarkOne can be as large as 12 x 6 x
6 inches and are designed to be stronger than 6061-T6 grade
aluminum by weight and up to a third of the strength of carbon
fiber composites, according to the company. Manufacturers
can make parts on the MarkOne more cheaply than traditional
methods because the printers blend of thermoplastics
immediately hardens during printing without vacuum bagging,
post-curing or wasting material.
Greg Mark, CEO of MarkForged, thinks his companys
product has the potential to expand the use of composites in
additive manufacturing. You can take carbon fiber and sell it at
a reasonable rate so it [becomes] attainable to a much wider
engineering audience, Mark says.
Also appealing to a wider engineering audience is the printers
accompanying software. With it, users can simply run an
algorithm to add a sandwich panel to their design, instead of
THE FORMULA
@AOCresins
GEL COATS
COLORANTS
Advanced pigment
dispersions, colorants
and additives to improve
process efficiency.
CompositesManufacturing
27
Montreal
The EPAs planned action is part of its
program under the Montreal Protocol,
a 1987 treaty designed to phase out
the production of HFC-134a and
other hydrofluorocarbons (HFCs) that
contribute to the destruction of the
stratospheric ozone layer that shields the
earths surface from harmful ultraviolet radiation.
HFCs are also potent heat trapping gases, and the EPA wants
to prohibit or strictly limit the use of these compounds both to
protect stratospheric ozone and to reduce climate change. But
the agency recently proposed to eliminate use of HFC-134a by
Jan. 1, 2017, much too soon to allow composites manufacturers
to identify and fully qualify workable replacements.
In comments recently submitted to the EPA, ACMA argued
our industrys use of HFC-134a has the net effect of reducing the
emission of climate warming gases because of the fuel savings
accrued from the use of lighter and better insulated trailers. The
association asked the agency to delay phase-out of this important
substance until 2020.
Stockholm
Another call reached ACMAs
international switchboard from the U.N.s
Persistent Organic Pollutant Review
Committee (POPRC). Convened under
the 2001 Stockholm Convention, another
international treaty, the POPRC identifies
toxic substances that may accumulate in the
environment, evaluates the availability of feasible alternatives, and
then for each substance recommends either a complete phase-out,
a limited ban, or, if there are no alternatives, no action.
The POPRCs July 2014 risk assessment report for
pentachlorophenol (PCP), a toxic and environmentally
persistent substance widely used in the U.S. and Canada
for the preservation of wood utility poles and railroad ties,
included a lengthy evaluation of materials that may serve as
useful replacement for treated wood in these applications.
Unfortunately, the POPRCs discussion on composite utility
poles contained several critical misstatements.
In response, ACMA sent the POPRC information and
28
CompositesManufacturing
Rio de Janeiro
OSHAs major 2012 update
to its Hazard Communications
System (HCS) is designed to
harmonize U.S. requirements
with the Globally Harmonized
System of Classification
and Labelling of Chemicals,
developed by the Inter-Organization Program for Sound
Management of Chemicals, a U.N. program created under
a treaty singed at the 1992 Conference on Environment and
Development in Rio de Janeiro.
We can debate the public welfare value of global harmonization
and further question whether OSHAs 2012 HCS contributes
to it, but whatever its value, OSHAs new regulation requires
chemical importers, manufacturers, formulators (companies
producing mixtures, like many paints and coatings, and
unsaturated polyester resin), distributers and users to change over
to an entirely new system for characterizing and communicating
chemical hazard and safety information.
HCS-2012 requires suppliers to provide compliant new labels and
safety data sheets for hazardous substances by July 1, 2015. (Users
of chemicals employers in OSHAs vernacular were required
to train employees on the new label and SDS formats by December
2013.) For the most part, to properly characterize hazards on their
own, SDS chemical manufacturers and formulators will rely on
hazard characterizations provided by their suppliers via updated
SDS. But formulators are not likely to receive updated SDS from
their suppliers until just before the July 1 deadline for issuance of
their own updated SDS.
To get composites material suppliers out of this catch-22,
ACMA worked with a large coalition to delay the HCS-2012
compliance deadline for product labels and SDS. In its response
to this effort, OSHA agreed that companies relying on suppliers
for hazard information could continue to comply with the old
1994-HCS, as long as they were making good faith efforts to
obtain HCS-2012-compliant information from suppliers and had
written plans for updating labels and SDS when the information
was obtained.
Information about ACMAs portfolio of international (and U.S.)
regulatory activity is available at acmanet.org/advocacy.
John Schweitzer is vice president of government affairs for
ACMA. Email comments to [email protected].
Inside ACMA
CMYK
Seeking
Nominations for
the ACMA Board
Manufacturers
Need Infrastructure
Investment
RGB
Pantone 376 C
Pantone 3025 C
Pantone 180 C
Pantone 376 C
Pantone 3025 C
Pantone 180 C
c - 50
m-0
y - 100
k-0
c - 100
m - 17
y-0
k - 51
c-0
m - 79
y - 100
k - 11
r - 141
g - 198
b - 63
r-0
g - 89
b - 132
r - 217
g - 83
b - 30
processability.
Finally, theres a re retardant, low smoke/low smoke toxicity
phenolic FRP thats processed as easily as polyester. Its called
Cellobond FRP and its processed from phenolic resins available
in a wide range of viscosities for:
Hand lay-up/spray*
Filament winding*
Press molding
RTM
SCRIMP
Pultrusion
*FM approved
Gel coated Cellobond Phenolic FRP far exceeds DOT and FAA
requirements and meets all stringent European re performance
tests with ease. The low density, high temperature resistance, low
ame and low smoke / smoke toxicity properties make Cellobond
phenolic resins the hottest new material for re retardant
applications. For the aircraft and aerospace industries that
require ablative materials, we also offer Durite resins from
Momentive. Call or write today for more information.
Recycling
Committee Charts
the Future
ACMAs Green Composites Council
Recycling Committee is currently
working on a project to develop a White
Paper on the future of composites
recycling and the role the composites
industry should play to solve this
problem. The Recycling Committee
recognizes that future business could
CompositesManufacturing
660285_Mektech.indd 1
29
10/1/13 1:01 AM
New Members
Amerex Energy Services
Sugar Land, Texas
Eco-Wolf Inc.
Edgewater, Fla.
EPOXEMEX
Del Valle, Mexico City, Mexico
GEOTEK
Stewartville, Minn.
Composite
Materials
Adaptive
Strong
Lightweight
Non-corrosive
Organic
University of Miami
Civil, Architectural & Environmental Engineering
Coral Gables, Fla.
For more information on becoming a member of ACMA,
email [email protected]
or call 703-682-1665.
www.janicki.com | 360.856.5143
11/25/2014 11:20:39 AM
February 2-6
ACMA presents at World of Concrete
Las Vegas, Nev.
March 3-5
ACMA presents at the Lightweighting Summit
Detroit, Mich.
March 23-27
ACMA presents and exhibits at The International Plastics
Showcase (NPE)
Orlando, Fla.
April 14-15
ACMA National Policy Summit
Washington, D.C.
653882_REXCO.indd 1
April 23-25
ACMA presents at the ASCE Structures Congress
Portland, Ore.
30
14/08/13 2:58 PM
www.masterbond.com
CompositesManufacturing
2018AS_3.25x2.5b.indd 1
11/13/13 7:48 PM
Inside ACMA
Providing Building
Products
to the Federal
Government
The General Services Administration
(GSA) is considering the adoption of
LEEDv4 as the green code to apply
to all of the 9,600 federal buildings it
manages. LEEDv4 discourages the use of
building materials made using chemicals
like styrene that are found on various toxic
red lists, even if there are no exposures
and no health risks associated with use of
those materials in a building. The GSA
is planning a public listening session to
hear feedback from stakeholders such as
manufacturers and suppliers of building
components and materials.This session
Advertiser
Page
AOC Resins........................................... 27
CCP Composites ............................... IBC
Composites One ................................ IFC
Deltech Corporation Headquarters ......3
Elliott Company of Indianapolis, Inc. .....4
Gurit ..................................................... 11
HEATCON Composite Systems .......... 17
Janicki Industries Headquarters ......... 30
Mar-Bal, Inc. ........................................ 13
Master Bond ........................................ 30
Mektech Composites ............................ 29
PCCR USA Inc .......................................7
REXCO Mold Care Products ............... 30
Saertex USA ............................................5
Thermwood Corporation ...................... 31
US Polychemical .....................................6
Wisconsin Oven Corporation ............. BC
BC=Back Cover, IFC=Inside Front Cover
IBC=Inside Back Cover
CompositesManufacturing
712100_Thermwood.indd 1
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9/16/14 5:53 PM
Postcure Chatter
90,000+
50-90%
16+ processes
1.9 billion
mobile
phones
people
Since 2007, Walmart has delivered 830 million more cases while
driving 300 million fewer miles in its efforts to double fuel efficiency. As part of its strategy, the multinational retailer developed
a concept tractor-trailer thats nearly 4,000 pounds lighter than
typical trucks. The article on page 12 provides an in-depth look at
the vehicle.
32
CompositesManufacturing
We can be
the lightest
and the strongest
CCP Composites is a global leader for thermoset composites. The company specializes in the development and production of
unsaturated polyester resins, vinyl ester resins, gel coats and derivatives.
Present on four continents with manufacturing, commercial and R&D facilities, CCP Composites provides its customers with
innovative and sustainable solutions, supported by its three centers of expertise in France, Korea, and the United States.
Throughout its value chain, the company combines eco-design, quality and progress while protecting the environment, as a
responsible company pioneering innovation.
For further technical & product information, visit www.ccpcompositesus.com