JMP-Molding Composition Optimization
JMP-Molding Composition Optimization
JMP-Molding Composition Optimization
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Himanshu Khandelwal
B. Ravi
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Article history:
Received 31 December 2015
Received in revised form 9 March 2016
Accepted 9 March 2016
Keywords:
Sand-casting
No-bake binder
Chemically bonded mold
Mechanical property
Shrinkage
Optimization
a b s t r a c t
Chemically bonded sand molds and cores have better mechanical properties and produce more dimensionally accurate castings, compared to green sand molds, and hence are being increasingly preferred for
near net shape metal parts. While it is well known that the properties and quality of a mold depend on
its material composition and molding process, this has not been investigated well for chemically bonded
molds. In this work, the effect of sand grain size, binder percentage and curing time (each varied in three
levels) on the mechanical properties (compression strength, shear strength and core hardness) as well as
dimensional changes (shrinkage) of no-bake chemically-bonded molds and cores was studied through
lab experiments. Their mechanical properties were found to increase with an increase in binder content and curing time; and decrease with increasing grain neness number. The shrinkage was found to
increase with an increase in all three process parameters. The results are explained in terms of bonding
and curing phenomena of binders, and evaporation of solvent. These are also supported by SEM analysis
of crosslinked resin bridges between sand grains. The ndings were incorporated into a multi-objective
optimization model to obtain the desired combination of mold properties, which is solved as a linear
programming problem. The model and its results were successfully veried through experiments. This
work paves the way for automatic optimization of molding parameters of chemically-bonded sand molds
and cores, to achieve the desired quality.
2016 The Society of Manufacturing Engineers. Published by Elsevier Ltd. All rights reserved.
1. Introduction
Near-net shape metal parts can be manufactured by many
routes; yet metal casting is still the most preferred process due
to its ability to produce intricate shaped parts in a variety of metals
and range of order quantity at a low cost compared to either subtractive or additive manufacturing [1]. Among various metal casting
processes, green sand casting is the most widely used one worldwide, due to the availability of raw materials (sand and bentonite),
established process equipment, and ease of recycling of molding
materials [24]. This process is however, unable to meet the evertightening requirements of original equipment manufacturers in
terms of internal soundness, dimensional accuracy and surface
nish, and has to be followed up with considerable machining
[5,6]. These limitations are reduced by some of the newer molding processes, which use various chemical binders instead of clay
or bentonite [7,8]. The binder systems are classied according to
the curing mechanism and the type of chemicals used: heat cured,
cold box, and no-bake [9,10]. The quality of the mold, in terms of
strength, hardness and dimensional stability plays a signicant role
in achieving dimensionally accurate castings with good mechanical properties [11,12]. The quality of the mold depends on the type
of sand used (silica or zircon; grain size and shape), binder composition (proportion of different chemicals), type of molding process
(manual, machine), and the curing time.
Several researchers have investigated the effect of molding composition on the dimensional stability and mechanical properties of
sand molds [9,11,1316]. Werling [14] conducted a set of experiments with different molding mixtures to investigate their effect
on core strength, shrinkage, and sand owability. Dimensional
changes in chemically bonded mold have been investigated by
Showman et al. [15], who reported continuous shrinkage of mold
over the curing time, and ascribed it to shortening of the resin
bridges. Khandelwal and Ravi [9] also observed the shrinkage in
cores prepared using alkyd urethane binder system, and linked
it to the evaporation of the solvent. Core shrinkage and hardness
were found to be affected by the amount of resin used and not
by the amount of catalyst. Lowe and Showman [16] used various
binder systems with different type of sands and process conditions.
Their research showed that sand grain size, shape, distribution and
http://dx.doi.org/10.1016/j.jmapro.2016.03.007
1526-6125/ 2016 The Society of Manufacturing Engineers. Published by Elsevier Ltd. All rights reserved.
128
Table 1
Experiment parameters and their levels.
Designation
Parameter (unit)
Level 1
Level 2
Level 3
G
B
T
40
1.6
1
60
2
2
80
2.4
4
Table 2
Experimental (L9) orthogonal array.
Experiment no.
1
2
3
4
5
6
7
8
9
Sand (G)
Binder (B)
Time (T)
Level
GFN
Level
Wt. % of sand
Level
Hour(s)
1
1
1
2
2
2
3
3
3
40
60
60
60
60
60
80
80
80
1
2
3
1
2
3
1
2
3
1.6
2
2.4
1.6
2
2.4
1.6
2
2.4
1
2
3
2
3
1
3
1
2
1
2
4
2
4
1
4
4
2
129
Fig. 2. Samples prepared for compression, shear, hardness, and shrinkage tests (left
to right).
shown in Fig. 4(a). For obtaining the hardness reading, the sharp
edge radius tipped plough of tester is pressed and pulled (up to
25 mm) against the surface of the sand mold. The shrinkage (dimensional change) of the sand cores was measured using a dial indicator
measurement, using a setup and protocol developed during a previous investigation [9]. The xture for core shrinkage is shown in
Fig. 4(b). The produced core specimens were placed in the xture
and the reading from the dial indicator was recorded in predened
time interval.
The Taguchi approach predicts the effect of individual process
parameters by the main effect plot. ANOVA analysis was performed
to observe the signicant effect of parameters. The Taguchi analysis will give the optimum setting among the selected levels, which
can be treated as local optimum values. Therefore, additionally
an optimization model was developed in for global optimization
of all four responses (mold compression strength, shear strength,
core shrinkage and core hardness). The optimization function was
designed to maximize compression strength, shear strength and
core hardness; and minimize the core shrinkage. The optimization
problem was constructed as a linear programming problem and
solved to predict the optimum mold properties. Further the model
was veried by comparing the solver result with conrmation
experiments.
3. Results and discussion
The quality attributes of sand molds and cores measured in this
work included compression strength, shear strength, hardness and
shrinkage. These properties were measured for all nine experimental conditions shown in Table 2 and are reported in Table 3. Their
main effects are plotted in Fig. 5 to gain a better understanding. The
compression strength was found to decrease with ner sand and
increase with binder content as well as curing time [Fig. 5(a)]. A
similar trend was observed in shear strength and hardness measurement, as shown in Fig. 5(b) and (c). The inuence of sand
grain size on core shrinkage was found to be the reverse of that
on mechanical properties [Fig. 5(d)]. The higher slop of the plots
shows the signicant effect of the individual parameters. Although
all the parameters have signicant inuence, the curing time was
Fig. 4. Hardness measurement with scratch tester (left) and shrinkage measurement with a dial indicator setup (right).
Table 3
Mold properties for different experiment trials.
Trial no.
Compression
strength CS
(kg/cm2 )
Shear strength
SS (kg/cm2 )
Core hardness
CH (Number)
Core shrinkage
SH (microns)
1
2
3
4
5
6
7
8
9
4.08
7.56
16.16
5.12
10.31
5.21
5.30
4.20
7.21
9.10
13.10
17.20
12.40
13.64
9.64
11.61
9.40
11.20
33
57
83
42
64
46
40
37
51
15.2
33.0
45.5
30.1
63.5
53.2
52.1
57.1
80.6
found to be the most dominant parameter for mechanical properties. The sand grain neness was found to be the most dominant
parameter for core shrinkage.
The phenomena can be explained in terms of the bonding and
curing mechanisms of chemically bonded mold. When the binder is
mixed with the silica sand, the mixing process allows a thin coating
of binders on individual sand particles. When the surfaces of two
binder coated sand particles come in close proximity, then they
crosslink with each other, and form a resin bridge. During curing,
these resin bridges shorten due to the evaporation of the solvent
present in binder, and result in hardening of the bridges. The curing generally takes about 24 h. To get a better insight in the curing
mechanism, the SEM analysis of a sample were carried out. The
SEM images of samples (after 24 h curing) taken at two different
locations are shown in Fig. 6. The images show the resign bridges
between two irregular shaped sand grains. The evidence of solvent
evaporation and shortening of resin bridges was obtained in an
earlier set of experiments [9], in which weight reduction of bare
chemical mixture with varying binder content was investigated.
The inuence of molding composition on mold properties can
be explained in term of curing phenomenon. The effect of molding parameters on compression strength, shear strength and core
hardness can be clearly observed from Fig. 5(a)(c). An increase in
Fig. 3. Sand strength testing machine (left) for compression (middle) and shear (right).
130
variables (sand grain size, binder content and curing time), through
general regression analysis performed using Minitab V17 statistical software. Variance analyses (ANOVA) were performed to
investigate the signicance of the parameters. The regression
model can determine how a response property changes when a
predictor variable changes. The equations were developed by least
square tting, which is suitable for tting data to a linear model. The
software uses the data obtained from the experiments (Table 2) to
develop these regression equations, which take the following form.
(1)
131
hardness and 94% for core shrinkage proves the stability of model
t. These two models were also found to be statistically signicant.
CH = 0.83 0.38G + 27.09B + 7.64T
(3)
(4)
The above empirical relations can be used to estimate the properties of alkyd no-bake bonded molds and cores, for a given set of
values of sand grain size, binder content and curing time.
4. Optimization model and validation
To determine the optimal values of the above parameters,
an optimization model has been formulated. For this purpose,
an objective function was designed to maximize compression
strength, shear strength and hardness, and to minimize shrinkage.
The values of sand grain size, binder content and curing time are
varied within the limits described earlier. The objective function
and the constraints are mathematically represented as follows.
Objective function:
Maximize
f (X) = CS + SS + CH SH
(5)
Subject to
Fig. 6. SEM micrograph shows irregular sand grains bonded with alkyd resin.
content, and curing time in determining mold shrinkage. The stability of the model t was determined by R2 values, which indicate the
total deviation of the response variable from the predictive model.
The adjusted R2 is a measure of the amount of variation around
the mean. In this work, the value of the determination coefcient
R2 = 92%, represents only 8% of the total variation. The high value of
the adjusted R2 (adj. R2 = 87%) also conrms a high signicance of
the predictor variable. Hence the predictive model of compression
strength has only linear terms as shown in Eq. (1). The higher coefcient of binder content in the regression model exhibits a more
signicant effect as compared to sand grain size and curing time.
The empirical relation between shear strength (in kg/cm2 ) as
response; and sand grain size, binder content and curing time as
predictor is given in the following equation:
SS = 7.91 0.06G + 2.05B + 1.50T
(2)
CS = f (G, B, T )
(6)
SS = f (G, B, T )
(7)
CH = f (G, B, T )
(8)
SH = f (G, B, T )
(9)
CH 100
(10)
SH 150
(11)
40 G 80
(12)
1.6 B 2.4
(13)
T 4
(14)
(15)
132
Table 4
Optimum values of process variables and responses.
5. Conclusion
Parameters/
responses
Case 1
(1,1,1,1)
Case 2
(1/2,1/2,1/2,1)
Case 3
(1/3,1/3,1/3,1)
40
40
40
2.4
1.6
4
14.81
4
10.11
1
4.04
16.44
14.80
10.30
81.40
59.74
36.81
51.78
24.49
13.07
1.6
(16)
(17)
f (X2) =
1
1
1
CS + SS + CHSH
2
2
2
(18)
f (X3) =
1
1
1
CS + SS + CH SH
3
3
3
(19)
Table 5
Comparison between predicted and experimental results.
Parameters/responses
Results using
optimization model
Experimental
results
50
2.4
4
13.88
15.84
78
59.79
50
2.4
4
14.12
15.28
75
55.6
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