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Batch Adsorption Process

The document describes an adsorption study using 1g of adsorbent. It presents data from three trials measuring the absorbance and concentration of samples over time as the adsorbent is exposed to the samples. The adsorption capacity (qe) increases over time as the concentration decreases, leveling off around 9.2 mg/g after 80 minutes of contact time. Percent removal also increases with contact time, leveling off at over 90% removal for all three trials.

Uploaded by

Paul Andrew Madlangbayan
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as XLSX, PDF, TXT or read online on Scribd
148 views42 pages

Batch Adsorption Process

The document describes an adsorption study using 1g of adsorbent. It presents data from three trials measuring the absorbance and concentration of samples over time as the adsorbent is exposed to the samples. The adsorption capacity (qe) increases over time as the concentration decreases, leveling off around 9.2 mg/g after 80 minutes of contact time. Percent removal also increases with contact time, leveling off at over 90% removal for all three trials.

Uploaded by

Paul Andrew Madlangbayan
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
You are on page 1/ 42

ADSORPTION STUDY USING 1 G ADSORBE

For Calculation of Concentration


Beer-Lambert's Law
=
Where:

A=
=
b=
C=

Using Blank Sample


Concentration (mg/L)
Absorbance
b (cm)
(L/mg-cm)

100
1.4509
10
0.0014509

Trial 1
Contact Time (min)

Trial 2
Contact Time (min)

Absorbance
0
20
40
60
80
100
120

Trial 1
Contact Time (min)

absorbance
molar absorption
path length
concentration

1.4509
0.40533
0.18624
0.127207
0.113998
0.114
0.114

0
20
40
60
80
100
120

Trial 2
Concentration (mg/L)
Contact Time (min)
0
100
0
20
27.94
20
40
12.84
40
60
8.77
60
80
7.86
80
100
7.86
100
120
7.86
120

Adsorption Capacity and Percent Removal


W (g)
V (L)

Trial 1
Contact Time (min)

1
0.1

Ci (mg/L)
0
20
40

Ct (mg/L)
100
100
100

100
27.94
12.84

60
80
100
120

100
100
100
100
9.21

qe (mg/g)

Trial 2
Contact Time (min)

Ci (mg/L)

Ct (mg/L)

0
20
40
60
80
100
120

100
100
100
100
100
100
100
9.21

qe (mg/g)

Trial 3
Contact Time (min)

8.77
7.86
7.86
7.86

Ci (mg/L)

100
27.93
12.85
8.39
7.86
7.86
7.86

Ct (mg/L)

0
20
40
60
80
100
120

100
100
100
100
100
100
100
9.21

qe(mg/g)

100
27.77
12.61
8.75
7.89
7.89
7.89

Adsorption Capacity vs Contact Time


10
8
6

qt (mg/g)

Trial 1
Trial 2

Trial 3

2
0

20

40

60

80

Contact Time (min)

100

120

140

qt (mg/g)

Trial 1
Trial 2

Trial 3

2
0

20

40

60

80

Contact Time (min)

100

120

140

TION STUDY USING 1 G ADSORBENT DOSAGE

Trial 3
Contact Time (min)

Absorbance
1.4509
0.40524
0.1864
0.12173
0.114
0.11402
0.11402

Absorbance

0
20
40
60
80
100
120

1.4509
0.40285
0.18294
0.1269
0.11454
0.11454
0.11454

Trial 3
Concentration (mg/L)
Contact Time (min) Concentration (mg/L)
100.00
0
100.00
27.93
20
27.77
12.85
40
12.61
8.39
60
8.75
7.86
80
7.89
7.86
100
7.89
7.86
120
7.89

Adsorption Capacity vs Con

q(t) (mg/g)

R (%)
0
7.21
8.72

0
72.06
87.16

qt (mg/g)

20

40

60

80

Contact Time (min)

qt (mg/g)

9.12
9.21
9.21
9.21

91.23
92.14
92.14
92.14

20

40

60

80

Contact Time (min)

Adsorption Capacity vs Con


q(t) (mg/g)

R(%)
0
7.21
8.72
9.16
9.21
9.21
9.21

10

0
72.07
87.15
91.61
92.14
92.14
92.14

8
6

qt (mg/g)

4
2
0

20

40

60

80

Contact Time (min)

AdsorptionCapacity vs Con
q(t) (mg/g)

10

R(%)
0
7.22
8.74
9.13
9.21
9.21
9.21

0
72.23
87.39
91.25
92.11
92.11
92.11

8
6

qt (mg/g(

4
2
0

20

40

60

80

Contact Time (min)

me

Percentage Removal vs Contact Time


100
80
Trial 1
Trial 2
Trial 3

60

Removal (%)

40
20

140

20

40

60

80

100

120

140

Trial 1
Trial 2
Trial 3

60

Removal (%)

40
20

140

20

40

60

80

Contact Time (min)

100

120

140

Percentage Removal vs C

rption Capacity vs Contact Time

100
80
60
Trial 1

Removal (%)

40
20
0

40

60

80

Contact Time (min)

100

120

140

20

40

60

80

Contact Time (min

Trial 1

Removal (%)

40
20
0

40

60

80

100

120

140

20

40

60

80

Contact Time (min

Contact Time (min)

Percentage Removal vs C

orption Capacity vs Contact Time

100
80
60
Trial 2

Removal (%)

40
20
0

40

60

80

100

120

140

20

40

60

80

Contavt Time (m

Contact Time (min)

Percentage Removal vs

orptionCapacity vs Contact Time

100
80
60
Trial 3

Removal (%)

40
20

40

60

80

100

120

Trial 1
Trial 2
Trial 3

100

120

140

140

20

40

60

Contact Time (

Contact Time (min)

s Contact Time

80

80

(min)

Trial 1
Trial 2
Trial 3

100

120

140

tage Removal vs Contact Time

Trial 1

40

60

80

Contact Time (min)

100

120

140

Trial 1

40

60

80

100

120

140

Contact Time (min)

ntage Removal vs Contact Time

Trial 2

20

40

60

80

100

120

140

Contavt Time (min)

entage Removal vs Contact Time

Trial 3

20

40

60

80

Contact Time (min)

100

120

140

ADSORPTION STUDY USING 1 G ADSORBENT


For Calculation of Concentration
Beer-Lambert's Law
=
Where:

A=
=
b=
C=

absorbance
molar absorption
path length
concentration

Using Blank Sample


Concentration (mg/L)
100
Absorbance
1.4509
b (cm)
10
(L/mg-cm)
0.0014509
Run 1
Trial 1
Trial 2
Contact Time (min)
Absorbance
Contact Time (min)
0
1.4509
0
20
0.41533
20
40
0.19624
40
60
0.137207
60
80
0.123998
80
100
0.104
100
120
0.104
120
W (g)
1
Trial 1
V (L)
0.1
Contact Time (min)
Ct (mg/L)
Ci (mg/L)
0
100
100
20
28.63
100
40
13.53
100
60
9.46
100
80
8.55
100
100
7.17
100
120
7.17
100
Trial 2
Contact Time (min)

Concentration (mg/L)
Ci (mg/L)
0
100.00
20
29.31
40
14.23
60
9.08
80
8.55
100
8.55
120
8.55

100
100
100
100
100
100
100

Trial 3
Contact Time (min)
0
20
40
60
80
100
120

Run 2
Trial 1
Contact Time (min)

Concentration (mg/L)
Ci (mg/L)
100.00
31.21
17.43
12.88
11.34
9.96
9.96

1.4509
0.40533
0.18624
0.127207
0.113998
0.114
0.114
W (g)
V (L)
Ct (mg/L)

Trial 1
Contact Time (min)
0
20
40
60
80
100
120
Trial 2
Contact Time (min)

0
20
40
60
80
100
120
1
0.1
Ci (mg/L)

100
27.94
12.84
8.77
7.86
7.86
7.86

100
100
100
100
100
100
100

Concentration (mg/L)
Ci (mg/L)
100.00
31.18
16.29
10.46
9.24
9.24
9.24

100
100
100
100
100
100
100

Concentration (mg/L)
Ci (mg/L)
0
100.00

100

0
20
40
60
80
100
120
Trial 3
Contact Time (min)

Trial 2
Contact Time (min)

Absorbance

0
20
40
60
80
100
120

100
100
100
100
100
100
100

20
40
60
80
100
120

Run 3
Trial 1
Contact Time (min)

29.83
17.43
13.57
11.34
10.62
10.62

Trial 2
Contact Time (min)

Absorbance

0
20
40
60
80
100
120

1.4509
0.41533
0.18624
0.12607
0.11998
0.116
0.116
W (g)
V (L)
Ct (mg/L)

Trial 1
Contact Time (min)
0
20
40
60
80
100
120

100
100
100
100
100
100

0
20
40
60
80
100
120
1
0.1
Ci (mg/L)

100
28.63
12.84
8.69
8.27
8.00
8.00

100
100
100
100
100
100
100

Trial 2
Contact Time (min)

Concentration (mg/L)
Ci (mg/L)
0
100.00
20
29.80
40
14.23
60
10.46
80
9.24
100
7.87
120
7.87

Trial 3
Contact Time (min)

Concentration (mg/L)
Ci (mg/L)
0
100.00
20
29.98
40
13.99
60
11.65

100
100
100
100
100
100
100

100
100
100
100

80
100
120

9.33
7.86
7.86

100
100
100

PTION STUDY USING 1 G ADSORBENT DOSAGE

Trial 3
Contact Time (min)

Absorbance
1.4509
0.42524
0.2064
0.13173
0.124
0.12402
0.12402

0
20
40
60
80
100
120

Absorbance
1.4509
0.45285
0.25294
0.1869
0.16454
0.14454
0.14454

Adsorption
10
8
6

qt (mg/g)

q(t) (mg/g)

R (%)

0
7.1374319388
8.6474601971
9.0543317941
9.1453718382
9.2832035288
9.2832035288

0
71.374319388
86.4746019712
90.5433179406
91.4537183817
92.8320352884
92.8320352884

20

Percentage
q(t) (mg/g)
0
7.0691295058
8.5774346957
9.0920807774
9.1453580536
9.1452202081
9.1452202081

R (%)

100

0
70.6912950582
85.7743469571
90.9208077745
91.4535805362
91.4522020815
91.4522020815

80
60

Removal (%)

40
20
0

40
20
0

q(t) (mg/g)

R (%)

0
6.8788338273
8.2566682749
8.711834034
8.865962506
9.0037897167
9.0037893721

0
68.7883382728
82.5666827486
87.1183403405
88.6596250603
90.0378971673
90.0378937211

Trial 3
Contact Time (min)

Absorbance
1.4509
0.4524
0.2364
0.15173
0.134
0.13402
0.13402

Absorbance

0
20
40
60
80
100
120

1.4509
0.43285
0.25294
0.1969
0.16454
0.15402
0.15402

Adsropt
10
8
6

qt (mg/g)

q(t) (mg/g)

R (%)

0
7.2063546764
8.7163829347
9.1232545317
9.2142945758
9.2142807912
9.2142807912

0
72.0635467641
87.1638293473
91.2325453167
92.1429457578
92.1428079123
92.1428079123

Percenta
100

q(t) (mg/g)

R (%)

0
6.8819353505
8.3706664829
8.9542353022
9.076435316
9.0762974705
9.0762974705

q(t) (mg/g)

0
68.8193535047
83.7066648287
89.5423530223
90.7643531601
90.7629747054
90.7629747054

R (%)
0

80
60

R (%)

40
20
0

20

7.0166793025
8.2566682749
8.6429112964
8.865962506
8.9384864567
8.9384519953

70.166793025
82.5666827486
86.4291129644
88.6596250603
89.3848645668
89.3845199531

Trial 3
Contact Time (min)

Absorbance
1.4509
0.4324
0.2064
0.15173
0.134
0.1142
0.1142

0
20
40
60
80
100
120

Absorbance
1.4509
0.43500
0.20294
0.169
0.13538
0.11402
0.11400

Adsorption
10
8
6

qt (mg/g)

4
2

q(t) (mg/g)

R (%)

0
7.1374319388
8.7163829347
9.1310910469
9.1730649941
9.2004962437
9.2004962437

0
71.374319388
87.1638293473
91.3109104694
91.7306499414
92.0049624371
92.0049624371

20

Percentage
100
80

q(t) (mg/g)

R (%)

0
7.0197808257
8.5774346957
8.9542353022
9.076435316
9.2129023365
9.2129023365

q(t) (mg/g)
0
7.0018609139
8.6012819629
8.8352057344

0
70.1978082569
85.7743469571
89.5423530223
90.7643531601
92.1290233648
92.1290233648

R (%)
0
70.0186091392
86.0128196292
88.3520573437

60

R (%)

40
20
0

20

9.0669584396
9.2141774071
9.2142807912

90.6695843959
92.1417740713
92.1428079123

Adsorption Capacity vs Contact Time - Run 1


10
8
6

qt (mg/g)

Trial 1
Trial 2

Trial 3

2
0

20

40

60

80

100

120

140

Contact Time (min)

Percentage Removal vs Contact Time - Run1


100
80
60

Removal (%)

Trial 1
Trial 2

40

Trial 3

20
0

20

40

60

80

Contact Time (min)

100

120

140

40

Trial 3

20
0

20

40

60

80

100

120

140

Contact Time (min)

Adsroption Capacity vs Contact Time - Run 2


10
8
6

qt (mg/g)

Trial 1
Trial 2

Trial 3

2
0

20

40

60

80

100

120

140

Contact Time (min)

Percentage Removal vs Contact Time - Run 2


100
80
60

R (%)

Trial 1
Trial 2

40

Trail 3

20
0

20

40

60

80

Contact Time (min)

100

120

140

Adsorption Capacity vs Contact Time - Run 3


10
8
6

qt (mg/g)

Trial 1
Trial 2

Trial 3

2
0

20

40

60

80

100

120

140

Contact Time (min)

Percentage Removal vs Contact Time - Run 3


100
80
60

R (%)

Trial 1
Trial 2

40

Trial 3

20
0

20

40

60

80

Contact Time (min)

100

120

140

ADSORPTION STUDY USING 1 G ADSORBE


For Calculation of Concentration
Beer-Lambert's Law
=
Where:

A=
=
b=
C=

Using Blank Sample


Concentration (mg/L)
Absorbance
b (cm)
(L/mg-cm)

100
0.41103
10
0.00041103

Trial 1
Contact Time (min)

Trial 2
Contact Time (min)

Absorbance
0
20
40
60
80
100
120

Trial 1
Contact Time (min)

absorbance
molar absorption
path length
concentration

0.41103
0.21054
0.104533
0.079502
0.068501
0.0595
0.059498

0
20
40
60
80
100
120

Trial 2
Concentration (mg/L)
Contact Time (min)
0
100
0
20
51.22
20
40
25.43
40
60
19.34
60
80
16.67
80
100
14.48
100
120
14.48
120

Adsorption Capacity and Percent Removal


W (g)
V (L)

Trial 1
Contact Time (min)

1
0.1

Ci (mg/L)
0
20
40

Ct (mg/L)
100
100
100

100
51.22
25.43

60
80
100
120

100
100
100
100
8.55

qe(mg/g)
Ce (mg/L)
Trial 2
Contact Time (min)

Ci (mg/L)

Ct (mg/L)

0
20
40
60
80
100
120

100
100
100
100
100
100
100
8.55

qe(mg/g)

Trial 3
Contact Time (min)

19.34
16.67
14.48
14.48

Ci (mg/L)

100
51.22
25.38
19.31
16.91
14.47
14.47

Ct (mg/L)

0
20
40
60
80
100
120

100
100
100
100
100
100
100
8.55

qe(mg/g)

100
51.22
25.41
19.32
16.91
14.47
14.47

Adsorption Capacity vs Contact Time


9
8
7
6

qt (mg/g)

Trial 1

Trial 2

Trial 3

3
2
1
0

20

40

60

80

Contact Time (min)

100

120

140

qt (mg/g)

Trial 1

Trial 2

Trial 3

3
2
1
0

20

40

60

80

Contact Time (min)

100

120

140

TION STUDY USING 1 G ADSORBENT DOSAGE

Trial 3
Contact Time (min)

Absorbance
0.41103
0.210524
0.10432
0.0793865
0.0695
0.05946
0.05946

Absorbance

0
20
40
60
80
100
120

0.41103
0.21053
0.1044265
0.07942725
0.06950
0.05948
0.05948

Trial 3
Concentration (mg/L)
Contact Time (min) Concentration (mg/L)
100.00
0
100.00
51.22
20
51.22
25.38
40
25.41
19.31
60
19.32
16.91
80
16.91
14.47
100
14.47
14.47
120
14.47

Adsorption Capacity vs Con

q(t) (mg/g)

R (%)
0
4.88
7.46

0
48.78
74.57

qt (mg/g)

20

40

60

80

Contact Time (min)

qt (mg/g)

8.07
8.33
8.55
8.55

80.66
83.33
85.52
85.52

20

40

60

80

Contact Time (min)

Adsorption Capacity vs Con


q(t) (mg/g)

R(%)
0
4.88
7.46
8.07
8.31
8.55
8.55

0
48.78
74.62
80.69
83.09
85.53
85.53

qt (mg/g)

9
8
7
6
5
4
3
2
1
0

20

40

60

80

Contact Time (min)

AdsorptionCapacity vs Cont
q(t) (mg/g)

R(%)
0
4.88
7.46
8.07
8.31
8.55
8.55

0
48.78
74.59
80.68
83.09
85.53
85.53

8
7
6

qt (mg/g(

5
4
3
2
1
0

20

40

60

80

Contact Time (min)

me

Percentage Removal vs Contact Time


90
80
70
60

Trial 1
Trial 2
Trial 3

Removal (%)

50
40
30
20
10

140

20

40

60

80

100

120

140

60

Trial 1
Trial 2
Trial 3

Removal (%)

50
40
30
20
10

140

20

40

60

80

Contact Time (min)

100

120

140

Percentage Removal vs C

rption Capacity vs Contact Time


90
80
70
60
Trial 1

Removal (%)

50
40
30
20
10
0

40

60

80

Contact Time (min)

100

120

140

20

40

60

80

Contact Time (min

Trial 1

Removal (%)

40
30
20
10
0

40

60

80

100

120

140

40

60

80

Contact Time (min

Contact Time (min)

Percentage Removal vs C

orption Capacity vs Contact Time


90
80
70
60
Trial 2

Removal (%)

50
40
30
20
10
0

40

60

80

100

120

140

20

40

60

80

Contavt Time (mi

Contact Time (min)

Percentage Removal vs

orptionCapacity vs Contact Time

90
80
70
60
Trial 3

Removal (%)

50
40
30
20
10

40

60

80

100

120

Trial 1
Trial 2
Trial 3

100

120

140

140

20

40

60

80

Contact Time (

Contact Time (min)

s Contact Time

20

min)

Trial 1
Trial 2
Trial 3

100

120

140

tage Removal vs Contact Time

Trial 1

40

60

80

Contact Time (min)

100

120

140

Trial 1

40

60

80

100

120

140

Contact Time (min)

ntage Removal vs Contact Time

Trial 2

40

60

80

100

120

140

Contavt Time (min)

entage Removal vs Contact Time

Trial 3

20

40

60

80

Contact Time (min)

100

120

140

ADSORPTION STUDY USING 1 G ADSORBENT


For Calculation of Concentration
Beer-Lambert's Law
=
Where:

A=
=
b=
C=

Using Blank Sample


Concentration (mg/L)
Absorbance
b (cm)
(L/mg-cm)
Run 1
Trial 1
Contact Time (min)
0
20
40
60
80
100
120
Trial 1
Contact Time (min)

100
0.41103
10
0.00041103
Trial 2
Contact Time (min)

Absorbance
0.41103
0.21054
0.104533
0.079502
0.068501
0.0595
0.059498

Concentration (mg/L)
0
20
40
60
80
100
120

Trial 2
Contact Time (min)

absorbance
molar absorption
path length
concentration

100
51.22
25.43
19.34
16.67
14.48
14.48

Concentration (mg/L)
0
100.00
20
51.22
40
25.38
60
19.31
80
16.91
100
14.47
120
14.47

0
20
40
60
80
100
120

Trial 3
Contact Time (min)
0
20
40
60
80
100
120

Concentration (mg/L)
100.00
51.22
25.41
19.32
16.91
14.47
14.47

TION STUDY USING 1 G ADSORBENT DOSAGE

Trial 3
Contact Time (min)

Absorbance
0.41103
0.210524
0.10432
0.0793865
0.0695
0.05946
0.05946

0
20
40
60
80
100
120

Absorbance
0.41103
0.21053
0.1044265
0.07942725
0.06950
0.05948
0.05948

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