Stream Report Mini DP

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Materials & Streams Report

June 9, 2016

for pfd
1. OVERALL PROCESS DATA
Annual Operating Time
Recipe Batch Time
Recipe Cycle Time
Number of Batches per Year
MP = Undefined

7,896.72h
43.35h
25.33h
311.00

- Page 1 -

2.1 STARTING MATERIAL REQUIREMENTS (per Section)

Section

Starting Material Active Product

Amount
Needed
(kg
Sin/kg
MP)

Main Section

(none)

Unknown Unknown Unknown Unknown

(none)

Molar
Yield
(%)

Mass
Yield
(%)

Gross
Mass
Yield
(%)

Sin = Section Starting Material, Aout = Section Active Product

2.2 BULK MATERIALS (Entire Process)


Material
Air
Lactic Acid
Lactic Acid (2)
Water
TOTAL

kg/yr

kg/batch

473
933,000
933,000
622,000
2,488,473

1.520
3,000.000
3,000.000
2,000.000
8,001.520

kg/yr

kg/batch

473
933,000
933,000
622,000
2,488,473

1.520
3,000.000
3,000.000
2,000.000
8,001.520

kg/kg MP

2.3 BULK MATERIALS (per Section)


SECTIONS IN: Main Branch
Main Section
Material
Air
Lactic Acid
Lactic Acid (2)
Water
TOTAL

kg/kg MP

- Page 2 -

2.4 BULK MATERIALS (per Material)


Air
Procedure
Main Section (Main Branch)
P-4
TOTAL

Lactic Acid
Procedure
Main Section (Main Branch)
P-1
TOTAL

Lactic Acid (2)


Procedure
Main Section (Main Branch)
P-1
TOTAL

Water
Procedure
Main Section (Main Branch)
P-1
P-2
TOTAL

% Total

kg/yr

kg/batch

100.00
100.00

473
473

1.520
1.520

% Total

kg/yr

kg/batch

100.00
100.00

933,000
933,000

3,000.000
3,000.000

% Total

kg/yr

kg/batch

100.00
100.00

933,000
933,000

3,000.000
3,000.000

% Total

kg/yr

kg/batch

50.00
50.00
100.00

311,000
311,000
622,000

1,000.000
1,000.000
2,000.000

kg/kg MP

kg/kg MP

kg/kg MP

kg/kg MP

2.5 BULK MATERIALS: SECTION TOTALS (kg/batch)


Raw Material
Air
Lactic Acid
Lactic Acid (2)
Water
TOTAL

Main Section
1.520
3,000.000
3,000.000
2,000.000
8,001.520

- Page 3 -

2.6 BULK MATERIALS: SECTION TOTALS (kg/yr)


Raw Material
Air
Lactic Acid
Lactic Acid (2)
Water
TOTAL

Main Section
473
933,000
933,000
622,000
2,488,473

- Page 4 -

3. STREAM DETAILS
Stream Name
Source
Destination
Stream Properties
Activity (U/ml)
Temperature (C)
Pressure (bar)
Density (g/L)
Total Enthalpy (kW-h)
Specific Enthalpy (kcal/kg)
Heat Capacity (kcal/kg-C)

Lactic acid
INPUT
P-1

water in
INPUT
P-1

water out
P-1
OUTPUT

lactide
P-1
P-2

0.00
25.00
1.01
1,220.91
97.68
14.01
0.56

0.00
25.00
1.01
994.70
29.00
24.96
1.00

0.00
37.00
10.54
990.33
91.86
36.93
1.00

0.00
37.00
2.79
1,001.55
31.69
5.61
0.15

3,000.000
3,000.000
0.000
0.000
0.000
6,000.000
4,914.369

0.000
0.000
0.000
1,000.000
0.000
1,000.000
1,005.324

0.000
0.000
0.000
1,569.976
569.976
2,139.952
2,160.847

150.000
150.000
4,560.124
0.000
0.000
4,860.124
4,852.623

PLA pellet
P-3
P-4

Hot air in
INPUT
P-4

Hot air out


P-4
OUTPUT

PLA final
P-4
OUTPUT

0.00
25.00
0.98
994.72
13.78
2.50
0.10

0.00
25.00
1.01
1.18
0.01
6.05
0.24

0.00
70.00
0.98
1.12
0.12
55.21
0.25

0.00
70.00
0.98
978.30
38.57
6.99
0.10

0.304
0.000
0.000
4,750.264
4,750.568
4,775.802

0.000
1.166
0.354
0.000
1.520
1,288.749

0.304
1.166
0.354
0.000
1.824
1,625.975

0.000
0.000
0.000
4,750.264
4,750.264
4,855.622

Component Flowrates (kg/batch)


Lactic Acid
Lactic Acid (2)
lactide
Water
Water(2)
TOTAL (kg/batch)
TOTAL (L/batch)

Stream Name
Source
Destination
Stream Properties
Activity (U/ml)
Temperature (C)
Pressure (bar)
Density (g/L)
Total Enthalpy (kW-h)
Specific Enthalpy (kcal/kg)
Heat Capacity (kcal/kg-C)

Component Flowrates (kg/batch)


Lactic Acid
Nitrogen
Oxygen
PLA
TOTAL (kg/batch)
TOTAL (L/batch)

- Page 5 -

Stream Name
Source
Destination
Stream Properties

water (2) in
INPUT
P-2

S-102
P-2
OUTPUT

water (2) out


P-2
OUTPUT

pure PLA
P-2
P-3

0.00
25.00
1.01
994.70
29.00
24.96
1.00

0.00
20.02
1.01
5.03
148.78
121.00
0.12

0.00
25.00
1.01
994.70
1.45
24.96
1.00

0.00
25.00
0.98
994.70
13.80
2.50
0.10

Lactic Acid
Lactic Acid (2)
lactide
Nitrogen
Oxygen
PLA
Water
TOTAL (kg/batch)
TOTAL (L/batch)

0.000
0.000
0.000
0.000
0.000
0.000
1,000.000
1,000.000
1,005.324

150.000
150.000
752.262
4.372
1.327
0.000
0.000
1,057.961
210,430.333

0.000
0.000
0.000
0.000
0.000
0.000
50.000
50.000
50.266

0.000
0.000
7.599
0.000
0.000
4,750.264
0.000
4,757.862
4,783.193

Stream Name
Source
Destination
Stream Properties

vapor
P-3
OUTPUT

Activity (U/ml)
Temperature (C)
Pressure (bar)
Density (g/L)
Total Enthalpy (kW-h)
Specific Enthalpy (kcal/kg)
Heat Capacity (kcal/kg-C)

Component Flowrates (kg/batch)

Activity (U/ml)
Temperature (C)
Pressure (bar)
Density (g/L)
Total Enthalpy (kW-h)
Specific Enthalpy (kcal/kg)
Heat Capacity (kcal/kg-C)

0.00
99.16
0.98
4.58
0.70
82.06
0.06

Component Flowrates (kg/batch)


lactide
TOTAL (kg/batch)
TOTAL (L/batch)

7.295
7.295
1,592.971

- Page 6 -

4. OVERALL COMPONENT BALANCE (kg/batch)


COMPONENT
Lactic Acid
Lactic Acid (2)
lactide
Nitrogen
Oxygen
PLA
Water
Water(2)
TOTAL

INITIAL

INPUT

OUTPUT

FINAL

IN-OUT

0.000
0.000
0.000
12.926
3.924
0.000
0.000
0.000
16.850

3,000.000
3,000.000
0.000
1.166
0.354
0.000
2,000.000
0.000
8,001.520

150.304
150.000
759.556
5.538
1.681
4,750.264
1,619.976
569.976
8,007.295

0.000
0.000
0.000
8.554
2.597
0.000
0.000
0.000
11.150
Overall Error:

2,849.696
2,850.000
- 759.556
0.000
0.000
- 4,750.264
380.024
- 569.976
0.076
0.001%

- Page 7 -

5. EQUIPMENT CONTENTS
R-101
Procedure

Operation

P-1
P-1
P-1
P-1
P-1
P-1

START
CHARGE-1 (Charge)
CHARGE-2 (Charge)
REACT-1 (Batch Stoich. Reaction)
SPLIT-1 (Batch Component Splitting)
TRANSFER-OUT-1 (Transfer Out)

R-102
Procedure

Operation

P-2
P-2
P-2
P-2
P-2
P-2

START
TRANSFER-IN-1 (Transfer In)
CHARGE-1 (Charge)
REACT-1 (Batch Stoich. Reaction)
SPLIT-1 (Batch Component Splitting)
TRANSFER-OUT-1 (Transfer Out)

Time (in h)

Volume (in L)

0.000
10.250
12.167
13.167
16.983
25.333

0.000
4,914.369
5,919.693
7,013.470
4,852.623
0.000

Time (in h)

Volume (in L)

25.333
33.684
35.600
36.600
36.934
37.267

0.000
4,852.565
5,846.838
4,833.459
4,783.193
0.000

- Page 8 -

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