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    CHM520 Quiz1 Sep15 PDF

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    Syafiqah Ck
    This document contains a 14-question quiz on physical chemistry by C. H. Chan. The questions cover various topics in thermochemistry, including calculation of heat, work, internal energy, and enthalpy changes. Students are instructed to show their work, provide full names and student details, and submit answers on the sheets provided. The questions involve balancing equations, determining heats of reaction from standard enthalpies of formation, calculating temperature changes during neutralization, and determining heats of fusion and combustion.

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    CHM520 Quiz1 Sep15 PDF

    Uploaded by

    Syafiqah Ck
    118 views14 pages
    This document contains a 14-question quiz on physical chemistry by C. H. Chan. The questions cover various topics in thermochemistry, including calculation of heat, work, internal energy, and enthalpy changes. Students are instructed to show their work, provide full names and student details, and submit answers on the sheets provided. The questions involve balancing equations, determining heats of reaction from standard enthalpies of formation, calculating temperature changes during neutralization, and determining heats of fusion and combustion.

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    CHM520_Quiz1_Sep15.pdf

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    This document contains a 14-question quiz on physical chemistry by C. H. Chan. The questions cover various topics in thermochemistry, including calculation of heat, work, internal energy, and enthalpy changes. Students are instructed to show their work, provide full names and student details, and submit answers on the sheets provided. The questions involve balancing equations, determining heats of reaction from standard enthalpies of formation, calculating temperature changes during neutralization, and determining heats of fusion and combustion.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    118 views14 pages

    CHM520 Quiz1 Sep15 PDF

    Uploaded by

    Syafiqah Ck
    This document contains a 14-question quiz on physical chemistry by C. H. Chan. The questions cover various topics in thermochemistry, including calculation of heat, work, internal energy, and enthalpy changes. Students are instructed to show their work, provide full names and student details, and submit answers on the sheets provided. The questions involve balancing equations, determining heats of reaction from standard enthalpies of formation, calculating temperature changes during neutralization, and determining heats of fusion and combustion.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 14

    Prepared by C. H.

    Chan

    Quiz 1 for CHM 520


    Print out these questions and answer ALL questions.
    In this section, the candidates of Physical Chemistry II shall work on the problems of Physical
    Chemistry I (Thermochemistry and introduction of first law of Thermodynamics). The
    knowledge in Physical Chemistry I for those contents is pre-requisite for Physical Chemistry
    II.
    Plot the needed figures with your own graph papers if applicable.
    FULL Name:
    Matric No:
    Group of your lab:
    Date of Submission:
    Name of evaluator:
    QUESTION 1
    A gas expands and does work (w) on the surroundings equal to 325 J. At the same time, it
    absorbs 127 J of heat (q) from the surroundings. Calculate the change in internal energy (U)
    (in unit J) of the gas.
    Hint and answer
    U = q + w ; U = 198 J
    _____________________________________________________________________
    (Answer the question in this sheet of paper only. Evaluation will only be made on the
    text written by pen)

    Page 1 of 14

    Prepared by C. H. Chan

    FULL Name:
    Matric No:
    Group of your lab:
    Date of Submission:
    Name of evaluator:

    QUESTION 2
    Determine the amount of heat (q) (in unit kJ) given off when 1.26104 g of NO2 are produced
    according to the equation
    2 NO (g) + O2 (g) 2 NO2 (g)
    Change of standard enthalpy (H) = - 114.6 kJ mol-1
    Hint and answer
    grams of NO2 moles of NO2 kilojoules of heat generated; q = -1.57104 kJ
    _____________________________________________________________________
    (Answer the question in this sheet of paper only. Evaluation will only be made on the
    text written in pen)

    Page 2 of 14

    Prepared by C. H. Chan

    FULL Name:
    Matric No:
    Group of your lab:
    Date of Submission:
    Name of evaluator:

    Question 3
    A quantity of 2.00102 mL of 0.862 M HCl is mixed with 2.00102 mL of 0.431 M Ba(OH)2
    in a constant-pressure calorimeter of negligible heat capacity (Cp). The initial temperature
    (Ti) of the HCl and Ba(OH)2 solutions is the same at 20.48 oC. For the process
    H+ (aq) + OH- (aq) H2O (l)
    The heat of neutralization is -56.2 kJ mol-1. Write the balanced equation for the
    neutralization of HCl and Ba(OH)2. What is the final temperature (Tf) of the mixed solution?
    Given that:
    Specific heat capacity of water (cp) = 4.184 J/gC
    Assume that the specific heat of the solution is the same as the specific heat of water.
    Hint and answer
    qsoln = msolnCpT; Tf = 26.3 C
    _____________________________________________________________________
    (Answer the question in this sheet of paper only. Evaluation will only be made on the
    text written in pen)

    Page 3 of 14

    Prepared by C. H. Chan

    Page 4 of 14

    Prepared by C. H. Chan

    FULL Name:
    Matric No:
    Group of your lab:
    Date of Submission:
    Name of evaluator:

    Question 4
    Calculate of standard enthalpy of combustion (H) for the following reactions from the
    standard enthalpies of formation (Hf) listed in Table 1:
    a) C2H4 (g) + 3 O2 (g) 2 CO2 (g) + 2 H2O (l)
    b) 2 H2S (g) + 3 O2 (g) 2 H2O (l) + 2 SO2 (g)
    Table 1 Thermodyanmics Data at 1 atm and 25 oC
    Substance
    Hf (kJ mol-1)
    C2H2 (g)
    226.6
    C2H4 (g)
    52.3
    C2H6 (g)
    -84.7
    CO (g)
    -110.5
    CO2 (aq)
    -412.9
    CO2 (g)
    -393.5
    H2O (l)
    -285.8
    H2O (g)
    -241.8
    H2O2 (l)
    -187.6
    H2S (g)
    -20.15
    H2S (s)
    -58.16
    O (g)
    249.4
    O2 (g)
    0
    O3 (g)
    142.2
    O3 (aq)
    -12.09
    SO2 (g)
    -296.4
    SO3 (g)
    -395.2
    Hint and answers
    H rxn = nH f
    product

    nH

    reactan

    a) H = 1411 kJ/mol
    b) H = 1124 kJ/mol

    _____________________________________________________________________
    (Answer the question in this sheet of paper only. Evaluation will only be made on the
    text written in pen)

    Page 5 of 14

    Prepared by C. H. Chan

    Page 6 of 14

    Prepared by C. H. Chan

    FULL Name:
    Matric No:
    Group of your lab:
    Date of Submission:
    Name of evaluator:

    Question 5
    Calculate the standard enthalpy change of the reaction (Hrxn) for
    2 C (graphite) + 3 H2 (g) C2H6 (g)
    From the following data,
    C (graphite) + O2 (g) CO2 (g)
    H2 (g) + O2 (g) H2O (l)
    2 C2H6 (g) + 7 O2 (g) 4 CO2 (g) + 6 H2O (l)
    Hint and answer
    H rxn = nH f
    product

    nH

    Hrxn = -393.5 kJ mol-1


    Hrxn = -285.8 kJ mol-1
    Hrxn = -3119.6 kJ mol-1

    ; Hrxn = 84.6 kJ mol-1

    reactan

    _____________________________________________________________________
    (Answer the question in this sheet of paper only. Evaluation will only be made on the
    text written in pen)

    Page 7 of 14

    Prepared by C. H. Chan

    Page 8 of 14

    Prepared by C. H. Chan

    FULL Name:
    Matric No:
    Group of your lab:
    Date of Submission:
    Name of evaluator:

    Question 6
    a) The molar heat capacity (Cp,m) of CH4 (g) at 2000 K and 1 bar is 94.4 J mol-1 K-1. Find
    the heat capacity (Cp) of 586 g of CH4 (g) at 2000 K and 1 bar.
    b) The Cp,m for C (diamond) is 6.115 J mol-1 K-1 at 25 oC and 1 bar. Determine the specific
    heat capacity (cp) of 10.0 carat of diamond. Calculate the heat capacity of a 10.0 carat of
    diamond. One carat = 200 mg.
    Hints and answers
    C
    a) Cp,m = p ; Cp = 3.45 kJ K 1
    n
    Cp
    b) cp =
    ; cp = 0.509 J g 1 K 1
    m
    _____________________________________________________________________
    (Answer the question in this sheet of paper only. Evaluation will only be made on the
    text written in pen)

    Page 9 of 14

    Prepared by C. H. Chan

    FULL Name:
    Matric No:
    Group of your lab:
    Date of Submission:
    Name of evaluator:

    Question 7
    A 0.1375 g sample of solid magnesium is burned in a constant-volume bomb calorimeter that
    has a heat capacity of 3024 J K-1. The temperature increases by 1.126 K. Calculate the heat
    (q) given off by the burning Mg in kJ g-1 and in kJ mol-1.
    Hint and answers
    q = Cpt; q = 24.76 kJ g-1 = 601.9 kg mol-1
    _____________________________________________________________________
    (Answer the question in this sheet of paper only. Evaluation will only be made on the
    text written in pen)

    Page 10 of 14

    Prepared by C. H. Chan

    FULL Name:
    Matric No:
    Group of your lab:
    Date of Submission:
    Name of evaluator:

    Question 7
    a) Write the balanced chemical equation when 50.0 g tin dissolves in excess acid.
    b) Calculate the work done (w) (in unit J) for the above reaction at 1.00 atm and 25 oC.
    Assume ideal gas behavior.
    Hint and answers
    a) Sn (s) + 2 H+ (aq) Sn2+ (aq) + H2 (g)
    b) w = -PexV; w = -1.04103 J
    _____________________________________________________________________
    (Answer the question in this sheet of paper only. Evaluation will only be made on the
    text written in pen)

    Page 11 of 14

    Prepared by C. H. Chan

    FULL Name:
    Matric No:
    Group of your lab:
    Date of Submission:
    Name of evaluator:

    Question 8
    The standard enthalpy of change for the following reaction is 436.4 kJ mol-1:
    H2 (g) H (g) + H (g)
    Calculate the standard enthalpy of formation (Hf) of atomic hydrogen (H).
    Hint and answer
    H rxn = nH f
    product

    nH

    ; Hf = 218.2.6 kJ mol-1

    reactan

    _____________________________________________________________________
    (Answer the question in this sheet of paper only. Evaluation will only be made on the
    text written in pen)

    Page 12 of 14

    Prepared by C. H. Chan

    FULL Name:
    Matric No:
    Group of your lab:
    Date of Submission:
    Name of evaluator:
    Question 9
    Considering the following two reactions:
    standard enthalpy of combustion (Hrxn)
    H1
    H2

    A 2B
    AC
    Determine the Hrxn for 2B C.
    Hint and answer
    H rxn = nH f
    product

    nH

    ; Hrxn = H2 - H1

    reactan

    _____________________________________________________________________
    (Answer the question in this sheet of paper only. Evaluation will only be made on the
    text written in pen)

    Page 13 of 14

    Prepared by C. H. Chan

    FULL Name:
    Matric No:
    Group of your lab:
    Date of Submission:
    Name of evaluator:

    Question 9
    The heat of fusion (Hfus) of water is 334 J g-1.
    a) How much heat (q) is required to melt 59.5 g of ice?
    b) What is the change of enthalpy (H) for this process?
    Hint and answer
    a) q = m H fus ; q = 1.99 104 J
    b) H = 1.99 10 4 J
    _____________________________________________________________________
    (Answer the question in this sheet of paper only. Evaluation will only be made on the
    text written in pen)

    Page 14 of 14

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