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Calibration Curve: Concentration Absorbance (MG/L) F (X) 0.0374290909x R 0.9996352674 Absorbance

The document contains data from experiments measuring the degradation of hydrogen peroxide (H2O2) and the degradation of orange G dye using H2O2 catalyzed by different amounts of mineral hematite over time. The data shows that increasing the concentration of H2O2 or the amount of hematite increases the degradation rate. Calibration curves were generated showing degradation follows first-order kinetics for all conditions tested.

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96 views16 pages

Calibration Curve: Concentration Absorbance (MG/L) F (X) 0.0374290909x R 0.9996352674 Absorbance

The document contains data from experiments measuring the degradation of hydrogen peroxide (H2O2) and the degradation of orange G dye using H2O2 catalyzed by different amounts of mineral hematite over time. The data shows that increasing the concentration of H2O2 or the amount of hematite increases the degradation rate. Calibration curves were generated showing degradation follows first-order kinetics for all conditions tested.

Uploaded by

prmahajan18
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
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Concentration

Absorbance

( mg/l)
5
10
15
20
25

0.19
0.383
0.563
0.727
0.948

Calibration Curve
1

f(x) = 0.0374290909x
R = 0.9996352674

0.8
0.6

Absorbance 0.4
0.2
0
0

10

15

20

25

Concentration mg/l

Time in min

when H2O2 200ppm when H2O2 500ppm

when H2O2 800ppm

0
10
20
30
40
60

0
19.73
30
40
49
64

0
34.08
51.92
67.49
82.32
95.14

0
23.24
42.97
59.46
72.97
88.65

% degra

10

% degradation

200

0
10
20
30
40
60

0
0.22
0.36
0.51
0.67
1.02

500

0
0.3
0.65
1
1.45
2

800

0
0.45
0.85
1.32
1.73
2.8

Effec
3

2.5 f(x) = 0.0


R = 0.99
2
f(x) = 0.0
1.5 R = 0.99
Ln(C0/Ct)
1

f(x) = 0.0
0.5 R = 0.99
0
0

10

f(x) = 0.0
0.5 R = 0.99
0
0

150

0
10
20
30
40

0
17.12
35.14
51.35
60

100

0
10
20
30
40

0
34.08
51.92
67.49
82.32

20

0
10
20
30
40

0
10
20
30
40
60

0
34.08
51.92
67.49
82.32
95.14

0
27.03
43.24
55.41
68.38
80.54

0
25.405
39.189
48.108
59.459
71.622

0
10
20
30
40
60

0
0.45
0.85
1.32
1.73
2.8

0
0.32
0.57
0.81
1.15
1.64

0
0.29
0.5
0.66
0.9
1.26

10

0
45.95
72.97
86.49
94.59

% degr

Ln(Co/Ct

For H2O2

200 ppm

For 20 g/l mineral hematite


Time
in Absor
Remainin
min
bance g
concentra
tion
0
10
20
30
40
60

0.37
0.30
0..23
0.16
0.12
0.10

100
80.3
70.0
60.0

51.0
36.0

%
degradat
ion

Ln(C 0 /
Ct)

0
19.73
30
40
49
64

0
0.22
0.36
0.51
0.67

For 15g/l mineral hematite


Absor
Remain %
bance
ing
degrada
concent tion
ration

Ln(C 0 /
Ct)

For 10g/l mineral hematite


Absorb Remain
ance
ing
concent
ration

.37
.33
.29
.24
.21
.17

0.00
0.114
0.243
0.433
0.567
0.77

.37
0.35
0..3
0.26
0.24
0.19

100
89.18
78.37
64.8
56.7
45.94

0.00
10.82
21.63
35.2
43.3
54.06

0
10
20
30
40
60

0
19.73
30
40
49
64

0
10.82
21.63
35.2
43.3
54.06

0
5.41
18.92
29.73
35.14
48.65

0
10
20
30
40
60

0
0.22
0.36
0.51
0.67
1.02

0
0.114
0.243
0.433
0.567
0.77

0
0.05
0.209
0.352
0.432
0.666

100
94.5
81.08
70.27
64.86
51.37

1.2
1
0.8

Ln(Co/Ct) 0.6
0.4
0.2

f(x) = 0.0170757
R = 0.998463151
f(x) = 0.0133136
R
f(x)==0.996546815
0.0109818

R = 0.994623258

1
0.8
Ln(Co/Ct) 0.6
0.4

f(x) = 0.0170757
R = 0.998463151
f(x) = 0.0133136
R
f(x)==0.996546815
0.0109818

R = 0.994623258

0.2
0
0

10

20

30

Time

ve

90909x
2674

20

25

30

on mg/l

% degradation curve of orange-g


100

Hyrogen
peroxide: 200
mg/l

80
60

degradation

Hyrogen
peroxide: 500
mg/l

40
20
0
0

10

20

30

40

50

60

Hyrogen
peroxide: 800
mg/l

70

Time in min

Effect of varying H2O2

Hydrog
en per
oxide:
200
mg/l

2.5 f(x) = 0.0451969697x


R = 0.9986634416
2
f(x) = 0.0339393939x
1.5 R = 0.9983485545
C0/Ct)
1

f(x) = 0.0170757576x
0.5 R = 0.9984631518
0
0

10

20

30

40

Time in min

50

60

70

Linear
(Hydro
gen
per
oxide:
200
mg/l)

f(x) = 0.0170757576x
0.5 R = 0.9984631518
0
0

10

20

30

40

50

60

70

gen
per
oxide:
200
mg/l)

Time in min

100
80
Hematite: 20g/l

60
% degradation

Hematite: 15g/l
40

Hematite: 10g/l

20
0
0 10 20 30 40 50 60 70
Time in min

3
2.5 f(x) = 0.0451969697x
R = 0.9986634416

2
Ln(Co/Ct) 1.5 f(x) = 0.0277727273x
1

R
f(x)==0.9990660208
0.0218636364x
R = 0.9960921691

0.5
0
0

10 20 30 40 50 60 70
Time in min

or 10g/l mineral hematite


Remain %
degrad
concent ation
0
5.41
18.92
29.73
35.14
48.65

Ln(C 0 /
Ct)

0.00
0.05
0.209
0.352
0.432
0.666

f(x) = 0.0170757576x
R = 0.9984631518
f(x) = 0.0133136364x
R
f(x)==0.9965468155
0.0109818182x
R = 0.9946232583

Hematite:
20g/l
Linear
(Hematite:
20g/l)
Hematite:
15g/l

Hematite:
20g/l
Linear
(Hematite:
20g/l)
Hematite:
15g/l
Linear
(Hematite:
15g/l)
Hematite:
10g/l

Hematite:
20g/l

f(x) = 0.0170757576x
R = 0.9984631518
f(x) = 0.0133136364x
R
f(x)==0.9965468155
0.0109818182x

Linear
(Hematite:
20g/l)

R = 0.9946232583

10

20

30

Hematite:
15g/l
40

Time in min

50

60

70

Linear
(Hematite:
15g/l)

70
60
50
40
% degradation 30

Hematite: 20g/l
Hematite: 15g/l
Hematite: 10g/l

20
10
0
0 10 20 30 40 50 60 70
Time in min

Hematite: 20g/l
Hematite: 15g/l
Hematite: 10g/l

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