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Lecture 5

The document summarizes key concepts in crystallography including: 1) Max von Laue won the Nobel Prize in 1914 for his discovery of the diffraction of X-rays by crystals, establishing the field of crystallography. 2) William Henry Bragg and William Lawrence Bragg won the 1915 Nobel Prize for using X-ray crystallography to determine crystal structures. 3) Bragg's law (2d sinθ = nλ) relates the wavelength of electromagnetic radiation to the diffraction pattern of rays scattered from layers of atoms in a crystal.

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Mrunal Korwar
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0% found this document useful (0 votes)
32 views

Lecture 5

The document summarizes key concepts in crystallography including: 1) Max von Laue won the Nobel Prize in 1914 for his discovery of the diffraction of X-rays by crystals, establishing the field of crystallography. 2) William Henry Bragg and William Lawrence Bragg won the 1915 Nobel Prize for using X-ray crystallography to determine crystal structures. 3) Bragg's law (2d sinθ = nλ) relates the wavelength of electromagnetic radiation to the diffraction pattern of rays scattered from layers of atoms in a crystal.

Uploaded by

Mrunal Korwar
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Lecture 5 (16-Aug-2016)

Surjeet Singh

ab-plane
b
a

2p/b

FT

2p/a

Max von Laue Nobel Prize: 1914

k k = G
Reciprocal lattice= {Gi}

Nobel Prize: 1915


for their services in the analysis of crystal structure by means of X-rays

2d sinq = nl

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Using
(1) Rotating Crystal
(2) Fixed crystal but white radiation
(3) Powder sample (randomly oriented)

Same Crystal as in the previous slide


Measured in Bragg-Brentano geometry:
Left panel: Crystal specimen, Right panel: same specimen powdered

Note: in the powder patter, Si referes to Silicon. Powder of Silicon is mixed as


An internal standard to correct for 2q errors.

Lattice with basis

X-ray diffracted from the atoms of the BASIS interfere destructively leading
To an extinction in the LAUE allowed direction

XO + OY = (k k).T = G.T = 2pl

Thanks!

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