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Reading Assignment: Examples:: 10.5, 10.7, 10.8 Fogler

1) Temperature/time trajectories can be developed to maintain constant conversion with catalyst decay by increasing operating temperature over time according to kinetic rate equations. 2) The decay law for catalyst activity (a) over time (t) can be expressed through an equation incorporating activation energy and temperature. 3) By integrating this decay law equation from an initial catalyst activity (a0) to current activity (a), an expression can be derived relating time, temperature, and catalyst properties.

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26 views15 pages

Reading Assignment: Examples:: 10.5, 10.7, 10.8 Fogler

1) Temperature/time trajectories can be developed to maintain constant conversion with catalyst decay by increasing operating temperature over time according to kinetic rate equations. 2) The decay law for catalyst activity (a) over time (t) can be expressed through an equation incorporating activation energy and temperature. 3) By integrating this decay law equation from an initial catalyst activity (a0) to current activity (a), an expression can be derived relating time, temperature, and catalyst properties.

Uploaded by

BikashGupta
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Reading Assignment: Examples : 10.5 ,10.7, 10.

8 Fogler

Temperature/Time Trajectories
A control strategy involves maintaining a
constant conversion with catalyst decay by
increasing operating temperature.
develop a temperature/time trajectory to find T t
relationship:
-rA (t=0,T0) = -rA (t= t,T) = a(t ,T)[-rA (t=0,T) ]

k T a T, t = k o

k oe

Ea

1 - 1

R
T
T

a = ko

(For First order reaction )


1 R
1
=
ln a +

T Ea
To

Temperature/Time Trajectories
decay law is:

da
=k e
do
dt

da
r ==k e
d
d
dt

d
- lna

Ea

an

=k

E
d 1 - 1
R To T

do

an

E
d
nEa

1 R
1
=
ln
a
+

T Ea
To

Temperature/Time Trajectories
1 R
1
=
ln
a
+

T Ea
To

t=

a=e

1- n+ E Ea
d

1- a

1- n + E
do
d

Ea

Obtained after integration of

1 a

E
-n+ d
Ea

da = -k

t
dt

0
do

1- e

Ea 1 1

R T To

Ea -n Ea +E
d 1 - 1

T T
R

k 1- n + d
do
Ea

- n 1
E

External Mass Transfer Effects

Reading Assignment Chapter 11


Fogler

External Diffusion effects in Heterogeneous Reactions


TWO TYPES of Diffusion Resistance
1. External diffusion
2. Internal Diffusion

Mass Transfer Fundamentals


Diffusion : Spontaneous intermingling or mixing of Atoms or molecules
by random thermal motion.
Gives rise to motion of the species relative to motion of mixtures.

WA or NA= Molar flux of A relative to a fixed coordinates (Vector)

Molar flux of A = Diffusive flux (J A) +


(in direction of concn. Gradient)
BA = CA V due to bulk fluid motin,

Convective flux (B A)

V = Molar average velocity , V= yivi

For Binary system


10

Ficks Law of diffusion

Or

For Equi molar Counter Diffusion (EMCD): WA= -WB

EMCD
11

12

Boundary Conditions

13

For Equi molar counter diffusion

14

=>

Solve for concentration profile CA vs z

15

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