4.3 TRB Polytechnic Syllabus PDF
4.3 TRB Polytechnic Syllabus PDF
4.3 TRB Polytechnic Syllabus PDF
2011
CIVIL ENGINEERING
Unit 1: Engineering Mathematics
Linear Algebra: Matrix algebra, Systems of linear equations, Eigen values and eigenvectors.
Calculus: Functions of single variable, Limit, continuity and differentiability, Mean value
theorems, Evaluation of definite and improper integrals, Partial derivatives, Total derivative,
Maxima and minima, Gradient, Divergence and Curl, Vector Identities, Directional
derivatives, Line, Surface and Volume integrals, Stokes, Gauss and Greens theorems.
Differential equations: First order equations ( linear and nonlinear), Higher order linear
differential equations with constant coefficients, Cauchys and Eulers equations, Initial and
boundary value problems, Laplace transforms, Solutions of one dimensional heat and wave
equations and Laplace equation.
Complex variables: Analytic functions, Cauchys Integral theorem, Taylor and Laurent series.
Probability and Statistics: Definitions of probability and sampling theorems, Conditional
probability, Mean, median, mode and standard deviation, Random variables, Poisson,
Normal and Binomial distributions.
Numerical Methods: Numerical solutions of linear and non-linear algebraic equations
Integration by trapezoidal and Simpsons rule, single and multi-step methods for differential
equations.
Unit 2: Mechanics
Bending moment and shear force in statically determinate beams. Simple stress and strain
relationship; Stress and strain in two dimensions, principal stresses, stress transformation,
Mohrs circle. Simple bending theory, flexural and shear stresses, unsymmetrical bending,
shear centre. Thin walled pressure vessels, uniform torsion, buckling of column, combined
and direct bending stresses.
Unit 3: Structural Analysis
Analysis of statically determinate trusses, arches, beams, cables and frames, displacements
in statically determinate structures and analysis of statically indeterminate structures by
force/energy methods, analysis by displacement methods (slope deflection and moment
distribution methods), influence lines for determinate and indeterminate structures. Basic
concepts of matrix methods of structural analysis.
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MECHANICAL ENGINEERING
Unit 1: Engineering Mathematics
Linear Algebra: Matrix algebra, Systems of linear equations, Eigen values and eigenvectors.
Calculus: Functions of single variable, Limit, continuity and differentiability, Mean value
theorems, Evaluation of definite and improper integrals, Partial derivatives, Total derivative,
Maxima and minima, Gradient, Divergence and Curl, Vector identities, Directional
derivatives, Line, Surface and Volume integrals, Stokes, Gauss and Greens theorems.
Differential equations: First order equations (linear and nonlinear), Higher order linear
differential equations with constant coefficients, Cauchys and Eulers equations, Initial and
boundary value problems, Laplace transforms, Solutions of one dimensional heat and wave
equations and Laplace equation.
Complex variables: Analytic functions, Cauchys integral theorem, Taylor and Laurent series.
Probability and Statistics: Definitions of probability and sampling theorems, Conditional
probability, Mean, median, mode and standard deviation, Random variables, Poisson,
Normal and Binomial distributions.
Numerical Methods: Numerical solutions of linear and non-linear algebraic equations
Integration by trapezoidal and Simpsons rule, single and multi-step methods for differential
equations.
Unit 2: Applied Mechanics and Design
Engineering Mechanics: Free body diagrams and equilibrium; trusses and frames; virtual
work; kinematics and dynamics of particles and of rigid bodies in plane motion, including
impulse and momentum (linear and angular) and energy formulations; impact.
Strength of Materials: Stress and strain, stress-strain relationship and elastic constants,
Mohrs circle for plane stress and plane strain, thin cylinders; shear force and bending
moment diagrams; bending and shear stresses; deflection of beams; torsion of circular
shafts; Eulers theory of columns; strain energy methods; thermal stresses.
Unit 3: Theory of Machines and Vibrations
Displacement, velocity and acceleration analysis of plane mechanisms; dynamic analysis of
slider-crank mechanism; gear trains; flywheels.
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Vibrations: Free and forced vibration of single degree of freedom systems; effect of
damping; vibration isolation; resonance, critical speeds of shafts.
Design: Design for static and dynamic loading; failure theories; fatigue strength and the S-N
diagram; principles of the design of machine elements such as bolted, riveted and welded
joints, shafts, spur gears, rolling and sliding contact bearings, brakes and clutches.
Unit 4: Fluid Mechanics
Fluid Mechanics: Fluid properties; fluid statics, manometry, buoyancy; control-volume
analysis of mass, momentum and energy; fluid acceleration; differential equations of
continuity and momentum; Bernoullis equation; viscous flow of incompressible fluids;
boundary layer; elementary turbulent flow; flow through pipes, head losses in pipes, bends
etc.
Unit 5: Heat-Transfer
Modes of heat transfer; one dimensional heat conduction, resistance concept, electrical
analogy, unsteady heat conduction, fins; dimensionless parameters in free and forced
convective heat transfer, various correlations for heat transfer in flow over flat plates and
through pipes; thermal boundary layer; effect of turbulence; radiative heat transfer, black
and grey surfaces, shape factors, network analysis; heat exchanger performance, LMTD and
NTU methods.
Unit 6: Thermodynamics and Applications
Zeroth, First and Second laws of thermodynamics; thermodynamic system and processes;
Carnot cycle. Irreversibility and availability; behaviour of ideal and real gases, properties of
pure substances, calculation of work and heat in ideal processes; analysis of thermodynamic
cycles related to energy conversion.
Power Engineering: Steam Tables, Rankine, Brayton cycles with regeneration and reheat. I.C.
Engines: air-standard Otto, Diesel cycles. Refrigeration and air-conditioning: Vapour
refrigeration cycle, heat pumps, gas refrigeration, Reverse Brayton cycle; moist air;
psychrometric chart, basic psychrometric processes. Turbomachinery: Pelton-wheel, Francis
and Kaplan turbines impulse and reaction principles, velocity diagrams.
Unit 7: Manufacturing Engineering
Engineering Materials: Structure and properties of engineering materials, heat treatment,
stress-strain diagrams for engineering materials.
Metal Casting: Design of patterns, moulds and cores; solidification and cooling; riser and
gating design, design considerations.
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Forming: Plastic deformation and yield criteria; fundamentals of hot and cold working
processes; load estimation for bulk (forging, rolling, extrusion, drawing) and sheet
(shearing, deep drawing, bending) metal forming processes; principles of powder
metallurgy.
Joining: Physics of welding, brazing and soldering; adhesive bonding; design considerations
in welding.
Unit 8: Machining and Machine Tool Operations
Mechanics of machining, single and multi-point cutting tools, tool geometry and materials,
tool life and wear; economics of machining; principles of non-traditional machining
processes; principles of work holding, principles of design of jigs and fixtures
Metrology and Inspection: Limits, fits and tolerances; linear and angular measurements;
comparators; gauge design; interferometry; form and finish measurement; alignment and
testing methods; tolerance analysis in manufacturing and assembly.
Computer Integrated Manufacturing: Basic concepts of CAD/CAM and their integration
tools.
Unit 9: Production Planning and Control
Forecasting models, aggregate production planning, scheduling, materials requirement
planning.
Inventory Control: Deterministic and probabilistic models; safety stock inventory control
systems.
Unit 10: Operations Research:
Linear programming, simplex and duplex method, transportation, assignment, network flow
models, simple queuing models, PERT and CPM.
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PLASTIC TECHNOLOGY
Unit 1: Polymer Chemistry and Polymer Physics
Basic concepts and terminology of polymers - classification of polymers - structure and
conformations - General characteristics of chain growth polymerisation - alkene
polymerisation by free radical, anionic and cationic initiators, their kinetics and mechanism General characteristics of step grow polymerization - Mechanism and kinetics of
co-polymerisation - Types of copolymers - Polymerisation Techniques - Bulk, solution,
suspension and Emulsion.
Elasticity of isolated polymer chain and of the network - Rubber elasticity - Glass transition:
its measurement, effect of various parameters on it, theoretical interpretations. Structure of
amorphous phase in bulk polymers - Two phase structure of semi crystalline polymers and
its characterisation and correlation with properties - Crystal morphologies: extended chain
crystals, chain folding, lamellae, spherulites - Concepts of unit cell, crystallite size and long
period crystallisation and its kinetics - Avrami equation - determination of melting point and
effects of various parameters on melting - Polymer solution thermodynamics.
Unit 2: Plastics materials
Plastics of commercial importance - Manufacture, properties and applications of major
Commodity, Engineering and High performance Thermoplastics and Thermosetting
polymers: Polyethylene, Polypropylene, Polyvinyl chloride, poly styrene and other styrenics,
polyamides, polyacetal, polyesters, Acrylics, cellulosics, polycarbonate, PTFE, polyurethane,
polyphenylene oxide, polyphenylene sulfide, PEEK, Phenol formaldehyde, Urea and
Melamine formaldehyde, unsaturated polyester, epoxy resins, silicones and Liquid
crystalline polymers.
Unit 3: Polymer Blends and Alloys
Definition of polymer blends and Alloys - General behaviour of polymer mixtureThermodynamics of polymer blends- Miscibility of Polymers - methods of determining
misability - Immiscible blends and compatiblisation - Compatiblising agents - morphology
and dispersion of immiscible blends - phase separation - Melt rheology of multiphase
blends - IPN - Thermoplastic Elastomers - Reaction blending and processing of specific
polymer blends, their properties and applications.
Unit 4: Plastics Processing and Compounding
Classification of plastics processing operations-primary and secondary processingDifference in approach to processing of thermoplastics and thermosets- Extrusion, Injection
Moulding, Blow moulding, thermoforming, rotational moulding, film blowing, Fibre
spinning, calendering, compression and transfer moulding, Reaction Injection Moulding.
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CHEMICAL TECHNOLOGY
Organic Chemistry:
Carbohydrates - oils, fats and waxes - heterocyclic compounds - proteins - dyes and dyeing pharmaceutical chemistry
Material Technology:
Ferrous and non-ferrous metals - Polymers, composites, ceramics and inorganic materials Single crystals - memory metals - intelligent materials.
Thermodynamics:
The first law and internal energy, statements of first law for the non flow and flow systems,
enthalpy and heat capacity limitations of the first law.
The PVT behavior of fluids, laws of corresponding states and equation of states approaches
to the PVT relationships of non ideal gas.
Statement of the second law of thermodynamics, available and unavailable energies.
Measurable quantities, basic energy relations, Maxwell relations the work expression for
different situations - Partial molar properties, ideal and non-ideal solutions, standard states
definition and choice, Gibbs-Duhem equation, excess properties of mixtures-standard free
energy change and reaction equilibrium constant, evaluation of reaction equilibrium
constant, prediction of free energy data, equilibria in chemical reactors, calculation of
equilibrium compositions for homogeneous chemical reactors.
Physical Chemistry:
Phase rule Azeotropic distillation Fractional distillation partially miscible liquid CST
Immiscible liquid Steam distillation photochemistry Quantum efficiency Hydrogen
chlorine reaction photosensitization Chemiluminescence.
Ionic equilibria Degree of hydrolysis Determination acid-base indicators their
applications solubility product principle Ionic equilibria involving complex ions Calloids
properties of colloids coagulation of solutions Origin of charge on colloidal particles
Determination of size of colloidal particles Donnan Membrane equilibrium Emulsions
Gels Applications of colloids Nuclear chemistry Applications of Radioactivity Nuclear
forces Packing fraction Binding energy Nuclear fission Nuclear reactors Nuclear
fusion Hydrogen bomb Nuclear reactions cyclotron Induced radioactivity.
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ARCHITECTURAL ASSISTANTSHIP
Unit 1: History of Architecture
Architectural character and style: Egyptian Architecture Temples and Tombs Great
Pyramids Cult temple. Greek Architecture Classical orders-Optical illusion Golden
Rectangle Theory Sport arenas. Roman Architecture Temples Construction Techniques
Public Baths Important buildings.
Indian Architecture Buddhist Stupas, Viharas and Chaityan Halls Hindu Architecture
Dravidian and Ariyan Islamic Architecture Imperial, Provincial and Mughal Important
buildings and features.
Modern Architecture Indian and International
Unit 2: Theory of Architecture
Introduction to Architecture Definitions of Architecture Context for Architecture
Functional aspects of Architecture Meaning and Interpretation of Architectural Factors like
architectural expression, symbolism, character and style, movements, philosophies,
ideologies and theories.
Ordering Elements of Architecture Point, line, plane, form, shape, pattern, light, texture
effects of the geometrical forms and their derivatives like sphere, cube, pyramid, cylinder
and cone Ordering Principles of Architecture proportion, scale, balance, rhythm, axis,
symmetry, hierarchy, datum, unity, harmony and dominance Organization of Form and Space spatial relationships spatial organization form space
relationship
Unit 3: Building Materials
Soil-Lime Rural building materials bricks and clay products Timber soft and hard
wood seasoning and preservation commercial forms Qualitative aspects of a good
timber products artificial timber
Cement properties and types Manufacturing process Tests for cement
Concrete Ingredients grading of aggregates Mixing, transportation and placing of
concrete Curing of concrete Joints in concrete Light weight concrete
Protective Coatings paints and varnishes Ferrous and Non ferrous metas properties
and applications Plastics, sealants and adhesives
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tone structure Sound transmission and absorption acceptable noise level reverberation
time echo absorption co-efficient
Unit 6: Environmental studies
Quantity of water need for protected supply demand forecasting population for towns
and cities sources of water intake types and reservoirs Quality of water Impurities in
water Potable water standards laid down by World Health Organization Water borne
diseases Treatment of water Sedimentation and filtration Hardness Chlorination
Water Supply and Distribution System Different systems of supplying Different layouts
of distribution system Appurtenances used in the distribution system wastage of water
detection methods
Collections and conveyance of sewage sanitation purpose definitions of various terms
Properties of sewage Methods of carrying sewage Treatments and disposal Septic tank
Soak pits Oxidation ponds
Environmental Pollution and Control water, land and air pollution conservation of water
resources rain water harvesting classification of air pollutants effects of air pollution on
human beings, animals, plants and materials acid rain Renewable energy resources
solar wind thermal and Bio-Mass energy
Unit 7: Landscape and Ecology
Basics of ecology and ecological balance global warming greenhouse effects acid rain
Ozone depletion reclamation process and environmental impact assessments - Common
landscape terms
Elements of Landscape Design definitions Hard and soft landscape elements plant
materials: classification, characteristics, use and application in design use of water and
landforms in landscape design landscape conservation
Garden Design History of landscape and garden design English, Italian, Japaneses,
Renaissance, Moghul styles
Site Planning Basics of Site planning, gradient, slopes, drainage details aspects like
circulation, distribution of built form and open spaces aspects of micro climate site
planning standards for neighbourhood parks, childrens play area, terrace gardening,
housing layouts and campus development
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ENGLISH
Unit 1: Chaucer to Shakespeare
Geoffrey Chaucer
Edmund Spenser
Shakespeare
John Donne
Andrew Marvell
Francis Bacon
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Christopher Marlowe
Thomas Middleton
John Webster
William Shakespeare
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William Collins
William Blake
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John Dryden
Jonathan Swift
Daniel Defoe
Addison and Steele
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Samuel Johnson
William Congreve
R.B.Sheridan
Goldsmith
Henry Fielding
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Coleridge
P.B.Shelley
John Keats
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Byron
Charles Lamb
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Intimation Ode
Tintern Abbey
Kubla Khan
The Rime of the Ancient Mariner
To a Skylark
Ode to a Nightingale
Ode on a Grecian Urn
Vision of Judgement
Essays of Elia
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Wordsworth
Walter Scott
Jane Austen
Emily Bronte
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Robert Browning
Matthew Arnold
D.G.Rossetti
Ulysses
The Lotus Eaters
My Last Duchess
Andrea Del Sarto
The Scholar Gipsy
Dover Beach
The Blessed Damozel
G.M.Hopkins
Matthew Arnold
Oscar Wilde
Charles Dickens
Thomas Hardy
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Sailing to Byzantium
The Waste Land
The Unknown Citizen
Church Going
Fern Hill
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5.
G.B.Shaw
John Osborn
T.S.Eliot
D.H.Lawrence
William Golding
Joseph Conrad
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Emerson
Poe
Whitman
Emily Dickinson
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Robert Frost
Wallace Stevens
Emerson
Henry James
ONeill
Edward Albe
Hawthorne
Mark Twain
Ernest Hemingway
Faulkner
Alice Walker
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Brahma
The Raven
When Lilacs Last in the Dooryard Bloomd
Success is Counted Sweetest
I Tasted a Liquor Never Brewed
Because I Could not Stop for Death
A Narrow Fellow in the Grass
Mending Wall Stopping By Woods on a Snowy Evening
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The Lotus
Our Casuarina Tree
Under Another Sky
A River Once
Indian Weavers
Introduction My Grandmothers House
Enterprise
Night of the Scorpion
R.Parthasarathy
Sarojini Naidu
Kamala Dass
Nissim Ezekiel
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A.K.Ramanujan
Sri Aurobindho
Tagore
Girish Kamard
R.K.Narayan
Chaman Nahal
Deshpande
Arundathi Roy
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Poetics
Life of Milton
The Function of Criticism
Four Types of Meaning
The Archetypes of Literature
The Meaning of a Literary Idea
The Death of the Author
Telling and Showing
A Historical Interpretation of Literature
Structure, Sign ad Play in the Discourse of Human Sciences
Capitalism, Modernism and Post Modernism
Towards a Feminist Poetics
Imperialism and Sexual Difference
Margeret at Wood
P.K.Page
Wilfered Campbell
George Ryga
Margaret Lawrance
Ondaatje
Sir Thomas More
Moliere
Ibsen
Wole Soyinka
Chinua Achebe
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MATHEMATICS
Unit 1: Real Analysis
Finite-countable and uncountable sets-Bounded and unbounded sets-Archimedean
Property-Ordered field-Completeness of R-Extended real number system-Sequences and
series-limsup and liminf of a sequence-convergence of sequences and series-uniform
convergence-continuity of a function-types of discontinuities-uniform continuitydifferentiability-Rolls theorem-mean value theorem monotone functions, functions of
bounded variations,-Riemann Integral and its properties-Improper integrals and their
convergence and uniform convergence- sequence of functions and series of functions-point
wise convergence and uniform convergence-Bolzano-Weierstrass Theorem-Compact
subsets of Rn-Heine-Borel Theorem-Riemann-Stieltjes integral and its properties- partial,
directional and total derivatives in Rn.
Unit 2: Complex Analysis
Algebra of complex numbers, Riemann Sphere, Stereographic projection, lines, circles, cross
ratio, Mobious transformation, Analytic functions, Cauchy-Riemann equations, line
integrals, Cauchys theorem for convex regions, Moreras theorem, Liouvilles theorem,
Fundamental Theorem of Algebra, Cauchys Integral formula, power series representation,
classification of singularities, Riemann theorem for removable singularities, Taylors and
Laurents series expansions, maximum modulus principle. Schwarz lemma, Open mapping
theorem, Contour integration, Conformal mapping, Entire functions, Harmonic functions,
Elliptic functions, Analytic continuation.
3. Algebra
Groups, subgroups, normal subgroups, quotient groups, homomorphisms, cyclic groups,
permutation groups, symmetric groups, alternating groups, simple groups, Sylows theorem,
Finite abelian groups, Rings, ideals, integral domains, polynomial rings, Euclidean ring,
Principal ideal domains, Unique factorisation domains, Finite fields, Extension fields,
Splitting fields, Galois Theorem.
Vector spaces, linear independence, bases, dimension, subspaces, quotient spaces, algebra
of linear transformations, kernel, range, isomorphism, matrix representation of a linear
transformation, change of bases, Dual bases, dual space, projection, transpose, trace,
determinant, Hermitian, Unitary and normal transformations, eigen values and eigen
vectors, Cayley-Hamilton theorem, Invariant subspaces, canonical forms: triangular form,
Jordan form, rational canonical form.
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4. Topology
Topological spaces-Basis for a topology-The product topology The subspace topologyClosed sets and limit points, Continuous functions-the product topology-The metric
topology. Connected spaces-connected subspaces of the Real line Components and local
connectedness, Compact spaces-compact subspaces of the Real line Limit Point
Compactness Local Compactness. The Countability Axioms The separation Axioms
Normal spaces The Urysohn Lemma The Tietze extension theorem.
5. Measure Theory and Functional Analysis
Measure Theory: Lebesgue Outer Measure-Measurable sets-Regularity Measurable
Functions-Borel and Lebesgue Measurablility- Integration of Non-negative functions The
General Integral Riemann and Lebesgue Integrals, Field of sets, sigma-field of sets, finitely
additive set function and countably additive set function, measure, Measurable and
measure spaces, Extension of measures, signed measures, Jordan, Hahn decomposition
theorem, Monotone convergence Theorem, Fatous lemma, Dominated convergence
theorem, absolute continuity, Lp spaces-Convex functions, Jensens inequality, Holders and
Minkowskis inequalities, Radon-Nikodym derivative, Fubinis Theorem.
Functional Analysis: Normed Linear space-Continuous Linear Transformations Banach
spaces-The Hahn-Banach Theorem The natural embedding of N in N** - Open mapping
theorem Closed graph Theorem Uniform boundedness theorem conjugate of an
operator Inner product space Orthogonalisation process Hilbert Space Orthonormal
sets-Orthogonal complements conjugate space H* - Adjoint of an operator Self-adjoint
Normal and Unitary Operators Projections.
6. Differential Equations
Ordinary Differential Equations : Second order homogeneous equations-Initial value
problems-Linear dependence and independence-Wronskian and a formula for WronskianNon-homogeneous equation of order two. Homogeneous and non-homogeneous equation
of order n Initial value problems- Annihilator method to solve non-homogeneous
equation- Algebra of constant coefficient operators. Initial value problems Existence and
uniqueness theorems- Solutions to solve a non-homogeneous equation Wronskian and
linear dependence reduction of the order of a homogeneous equation - homogeneous
equation with analytic coefficients The Legendre equation. Euler equation Second order
equations with regular singular points Exceptional cases Bessel Function. Equation with
variable separated Exact equation- method of successive approximations the Lipschitz
condition- convergence of the successive approximations and the existence theorem.
Partial Differential Equations: Linear and non-linear first order partial differential equations
Second order equations in two independent variables canonical forms equations with
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method of penalty Two phase technique - special cases in simplex method applications
Duality Economic Interpretation of duality- Dual Simplex method Generalised simplex
Tableau in Matrix Form Efficient Computational algorithm Transportation and
Assignment problems as linear programming problems.
Fluid Dynamics : Real fluids and Ideal fluids- Velocity of a fluid at a point, Stream lines, path
lines, steady and unsteady flows- Velocity potential The vorticity vector Local and
particle rates of changes Equations of continuity- Acceleration of a fluid Conditions at a
rigid boundary. Pressure at a point in a fluid at rest Pressure at a point in a moving fluid Conditions at a boundary of two inviscid immiscible fluids Eulers equation of motion
Steady motion under conservative body forces. Sources, sinks and doublets Images in a
rigid infinite plane - Axis symmetric flows Stokes stream function - Two dimensional flow
The stream function The complex potential for two dimensional, irrotational in
compressible flow- Complex velocity potentials for standard two dimensional flows Two
dimensional Image systems The Milne Thomson circle Theorem. Stress components in a
real fluid. Relations between Cartesian components of stress Translational motion of fluid
elements The rate of strain quadric and principle stresses Some further properties of the
rate of strain quadric - Stress analysis in fluid motion Relation between stress and rate of
strain The coefficient of viscosity and Laminar flow The Navier Stokes equations of
motion of a Viscous fluid.
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PHYSICS
Unit 1 : Mathematical Methods
Vector fields: Orthogonal curvilinear co-ordinate systems Expressions for gradient,
divergence, curl and Laplacian- Linear vector spaces: Linear independence, basis, dimension,
inner product Schwartz inequality Orthonormal basis Gram Schmidt
orthogonalization process Linear operators Representation of vectors and operators in a
basis Matrix theory Cayley - Hamilton theorem Inverse of a matrix Diagonalisation of
matrices Operational methods: Laplace transforms Solution of linear differential
equations with constant coefficients Fourier integral Fourier transforms - Convolution
theorems Applications Complex variables: Analytic function Cauchy - Riemann
conditions Singular points - Multivalued function and branch points Cauchys integral
theorem and formula Taylors and Laurentzs expansions - Residue theorem and its
applications.
Unit 2 : Classical Mechanics and Relativity
Lagrangian and Hamiltonian formulations Newtons equations and conservation laws for a
system of particles DAlmeberts principle and Lagranges equations of motion
Hamiltonian and Hamiltons equation of motion Application: Two-body central force
problem Scattering by central potential, two particle scattering Cross section in Lab
system-Small oscillations - Transformation to normal coordinates and frequencies of normal
modes - Mechanics of rigid bodies: Angular momentum and kinetic energy Moment of
inertia tensor Euler angels Eulers equation of motion Torque free motion Symmetric
top Wave motion Phase velocity - Group velocity Dispersion Relativity: Special theory
of relativity Lorentz transformation Addition of velocities Mass - energy equivalence.
Unit 3: Quantum Theory and its Applications
Basic principles: Wave particle duality Heisenbergs uncertainty principle Postulates of
quantum mechanics - Interpretation of wave function Schordingers wave equation and its
application to particle in a box- Harmonic oscillator- tunneling through a barrier Motion in
central field potential: Hydrogen atom angular momentum and spherical harmonics
Addition of two angular momenta Approximate methods: Time independent perturbation
theory for non-degenerate case application to anharmonic oscillator time dependent
perturbation theory Fermis golden rule - Scattering theory: Scattering amplitude cross
section Born approximation Partial wave analysis Identical particles and spin
Symmetric and antisymmetric wave functions Representation theory Coordinate and
momentum representations.
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CHEMISTRY
Unit -1
Analytical Chemistry: Classification of analytical Methods classical and instrumental.
Errors and Evaluation: Definition of terms in mean and median Types of errors,
propagation of errors, accuracy and precision, least squares analysis, average standard
deviation.
Analytical Techniques: Principle and applications of adsorption, partition, ion exchange and
solvent extraction chromatographic methods TLC HPLC and GC. Applications of atomic,
molecular and emission spectroscopy in quantitative analysis Electroanalytical techniques
cyclic and stripping voltametry, polarography, TGA, DTA, and DSC. Light scattering
techniques including nepelometry and Raman spectroscopy.
Unit-2
Structure and Bonding:
Atomic orbitals Types of chemical Bonds (weak and strong)
intermolecular forces. Theories of bonding (VB and MO) Concept of hybridization shapes
of polyatomic molecules VSEPR theory Structure of simple ionic and covalent
compounds lattice energy crystal defects Insulators and semiconductors,
superconductors, Band theory of solids Solid state reactions.
Acids and Bases :
Bronsted and Lewis acids and bases, pH and pKa, acid-base concept in
nonaqueous media, HSAB concept, Buffer solution.
Redox Reactions: Oxidation numbers, Redox potential, electrochemical series, Redox
indicators, Chemical principles involved in extractions and purification of Iron, Copper, Lead,
Zinc and Aluminium.
Unit-3
Nuclear Chemistry: Radioactive decay and equilibrium, Nuclear reactions: Q valve, cross
sections, types of reactions, Nuclear transmutations, fission and fusion Radioactive
techniques-tracer technique, neutron activation analysis. G.M, Ionization and proportional
counters. Radiolysis of water G value, dosimeters and Hydrated electron.
Chemistry of Non-transition elements: General properties and structure of their halides
and oxides. Polymorphism of carbon, phosphorus and sulphur. Synthesis, properties and
structure of boranes, carboranes and metallo carboranes - Wades rule - preparation,
properties and structure of borazines & phosphazenes.
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Complex reactions: simultaneous, parallel and consecutive reactions. Chain reactions: H2-Cl2
H2Br2 branching reaction- explosion limit.
Reactions in solution: factors determining reaction rate in solution, dielectric constant and
ionic strength, Kinetic isotopic effect, Linear free energy relations. Hammett and Taft
equations.
Homogenous Catalysis: acid base catalysis, enzyme catalysis Heterogeneous catalysis:
Adsorption, Langmuir and BET adsorption isotherms mechanism of heterogeneous
catalysis.
Thermodynamics: First and second Laws of thermodynamics- relation between cp and cv in
terms of coefficients of expansion and compressibility. Maxwell relations- partial molar
properties- Glibbs Duhem equation- variation of chemical potential with temperature and
pressure-fugacity- Third law and calculation of entropy.
Statistical thermodynamics: Maxwell Boltzmann, Bose-Einstein and Fermi-Dirac distributionPartition function, translational, rotational and vibrational partition function, calculation of
thermodynamic functions, equilibrium constant and heat capacity from partition functions.
Einstein and Debye theories of heat capacity of solids., concept of negative absolute
temperature.
Nonequilibrium, thermodynamics: Phenomenological laws- Onsagers reciprocity relationapplication to Diffusion potential, electrokinetic phenomena- entropy production.
Unit 11
Group theory: Symmetry elements and symmetry operations, point groups, reducible and
irreducible representations Direct product representation. Orthogonality theorem and its
consequences- construction of Character Tale (C2v C3v and C2h ) Applications: Selection rules
for IR, Raman and electronic spectra, Determining Symmetries of normal vibrational modes
of non linear molecules, construction of hybrid orbitals, application to electronic spectra of
ethylene and formaldehyde.
Spectroscopy: Rotational Spectra of rigid and non-rigid diatomic rotors, simple polyatomic
molecules.
Vibrational Spectra: harmonic and anharmonic oscillator, overtones, Fermi resonane-Raman
Spectra. Vibration-rotation Spectra-PQR branches, parallel and perpendicular vibrations.
Electronic Spectroscopy: Spectra of diatomic molecules- Frank condon principle-Morse
function. Polyatomic molecules, types of transition, solvent effects.
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Spin resonance Spectroscopy: NMR: Origin of nmr signal, Chemical Shift, factors affecting
chemical shift and spin spin coupling. NMR Spectra of simple AX and ABX type molecules.
13
C and 19F nmr.
ESR: Origin, g-factor, hyperfine structure- Mc Connel equations, Theory and simple
applications of Mossbauer and Photoelectron Spectroscopy.
Unit-12
Electrochemistry: Ion-solvent interaction- Born treatment- solvation number and its
determination. Ion-ion interaction: activity co-efficient, Debye-Huckel equation for activity
coeff - limitations and extension to concentrated solutions. Ion transport: Debye Huckel
Orsager equation for conductance- experimental validity. Ion association: its effect on
conductance and activity coefficient.
Electrode-electrolyte interface: Structure of double layer- electrode kinetics- overvoltage.
Butler Volmer equation for one electron transfer. Corrosion and Stability of metals:
construction and use of Pourbaix and Evans diagram-Prevention of corrosion, Primary and
Secondary cells- Various fuel cells.
Photochemistry: Photophysical processes- Theory of radiationless transition-fluorscence,
phosphorescence, fluorescence quenching- Stern-Volmer equation, excimer, exciplexes,
Quantum yield measurement, Kinetics of Photochemical reac.
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