Safety Data Sheet Bostik All Purpose Clear Adhesive: According To Regulation (EC) No 1907/2006

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Revision Date January 2014

Revision 14

Revision 14

SAFETY DATA SHEET


BOSTIK ALL PURPOSE CLEAR ADHESIVE
According to Regulation (EC) No 1907/2006
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name

BOSTIK ALL PURPOSE CLEAR ADHESIVE

Product No.

80203x, 80205x, 80207, 80208, 80252x, 802049x, 802063x, 802025, P038300, P038305, 802018,
802032, P039300, P039305, 30811432, 30811433, 30813290, 30813292, 30813296, 30803648,
30811351, 30811352, 802070, 802087

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses

Adhesive.

1.3. Details of the supplier of the safety data sheet


Supplier

BOSTIK LIMITED
COMMON ROAD
STAFFORD
STAFFORDSHIRE
ST16 3EH
+44 1785 272625
[email protected]

1.4. Emergency telephone number


+44 1785 272650 (24 Hours)

SECTION 2: HAZARDS IDENTIFICATION


2.1. Classification of the substance or mixture
Classification (EC 1272/2008)

Classification (1999/45/EEC)

Physical and Chemical Hazards Flam. Liq. 2 - H225


Human health
EUH066;Eye Irrit. 2 - H319;STOT SE 3 - H336
Environment
Not classified.
Xi;R36. F;R11. R66, R67.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

2.2. Label elements


Label In Accordance With (EC) No. 1272/2008

Signal Word

Danger

Hazard Statements
H225
H319
H336

Highly flammable liquid and vapour.


Causes serious eye irritation.
May cause drowsiness or dizziness.

P102
P210
P271

Keep out of reach of children.


Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Use only outdoors or in a well-ventilated area.

Precautionary Statements

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P280
P337+313
P501
Supplementary Precautionary Statements
P233
P240
P241
P242
P243
P261
P264
P370+378

Wear protective gloves/protective clothing/eye protection/face protection.


If eye irritation persists: Get medical advice/attention.
Dispose of contents/container in accordance with local regulations.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing vapour/spray.
Wash contaminated skin thoroughly after handling.

P312
P313
P403+233
P403+235
P405

In case of fire: Use foam, carbon dioxide, dry powder or water fog for
extinction.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower.
IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Call a POISON CENTER or doctor/physician if you feel unwell.
Get medical advice/attention.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.

EUH066

Repeated exposure may cause skin dryness or cracking.

P303+361+353
P304+340
P305+351+338

Supplemental label information

2.3. Other hazards


Vapours are heavier than air and can travel long distances to a source of ignition Pilot lights can ignite the vapour

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS


3.2. Mixtures
ACETONE
CAS-No.: 67-64-1

60-100%
Registration Number: 01-2119471330-49

EC No.: 200-662-2

Classification (EC 1272/2008)


Flam. Liq. 2 - H225
EUH066
Eye Irrit. 2 - H319
STOT SE 3 - H336

Classification (67/548/EEC)
F;R11
Xi;R36
R66
R67

BUTANONE
CAS-No.: 78-93-3

Classification (EC 1272/2008)


Flam. Liq. 2 - H225
EUH066
Eye Irrit. 2 - H319
STOT SE 3 - H336

10-30%
EC No.: 201-159-0

Registration Number: 01-2119457290-43

Classification (67/548/EEC)
F;R11
Xi;R36
R66
R67

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: FIRST AID MEASURES


4.1. Description of first aid measures

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Inhalation
Remove victim immediately from source of exposure. Move the exposed person to fresh air at once. Get medical attention.
Ingestion
DO NOT induce vomiting. Get medical attention immediately.
Skin contact
Promptly flush contaminated skin with water. Promptly remove clothing if soaked through and flush the skin with water. Wash skin with
soap and water. Get medical attention if irritation persists after washing.
Eye contact
Rinse the eye with water immediately. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation
No specific symptoms noted.
Ingestion
No specific symptoms noted.
Skin contact
No specific symptoms noted.
Eye contact
No specific symptoms noted.

4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Fire can be extinguished using: Powder. Foam.

5.2. Special hazards arising from the substance or mixture


Hazardous combustion products
Not known.
Unusual Fire & Explosion Hazards
Generates massive smoke during fire. Vapours are heavier than air and may spread near ground to sources of ignition. HIGHLY
FLAMMABLE! Risk of explosion in closed containers if pressure rises rapidly. Solvent vapours may form explosive mixtures with air.
Specific hazards
Toxic gases/vapours/fumes of: Carbon dioxide (CO2). Carbon monoxide (CO).

5.3. Advice for firefighters


Special Fire Fighting Procedures
Not known.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.

SECTION 6: ACCIDENTAL RELEASE MEASURES


6.1. Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes. Provide adequate ventilation. Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions


Prevent entry into drains. Avoid discharge into water courses or onto the ground.

6.3. Methods and material for containment and cleaning up


Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Runoff or release to sewer, waterway or ground is
forbidden. Absorb with sand or other inert absorbent. Collect with absorbent, non-combustible material into suitable containers.
Containers with collected spillage must be properly labelled with correct contents and hazard symbol.

6.4. Reference to other sections


Wear protective clothing as described in Section 8 of this safety data sheet.

SECTION 7: HANDLING AND STORAGE

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7.1. Precautions for safe handling
Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use
approved respirator if air contamination is above accepted level.

7.2. Conditions for safe storage, including any incompatibilities


Flammable/combustible - Keep away from oxidisers, heat and flames. Ground container and transfer equipment to eliminate static electric
sparks. Store at moderate temperatures in dry, well ventilated area.
Storage Class
Flammable liquid storage.

7.3. Specific end use(s)


The identified uses for this product are detailed in Section 1.2.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION


8.1. Control parameters
Name

STD

TWA - 8 Hrs

STEL - 15 Min

ACETONE

WEL

500 ppm

1210 mg/m3

1500 ppm

3620 mg/m3

BUTANONE

WEL

200
ppm(Sk)

600
mg/m3(Sk)

300
ppm(Sk)

899
mg/m3(Sk)

Notes

WEL = Workplace Exposure Limit.


Ingredient Comments
WEL = Workplace Exposure Limits

8.2. Exposure controls


Protective equipment

Engineering measures
Explosion-proof general and local exhaust ventilation.
Respiratory equipment
Respiratory protection must be used if air contamination exceeds acceptable level. Wear mask supplied with: Gas cartridge suitable for
organic substances.
Hand protection
Protective gloves must be used if there is a risk of direct contact or splash. Use protective gloves made of: Nitrile. Use thin cotton gloves
inside the rubber gloves if allergy risk.
Eye protection
Wear splash-proof eye goggles to prevent any possibility of eye contact.
Other Protection
Wear appropriate clothing to prevent repeated or prolonged skin contact.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash promptly if skin becomes contaminated. Wash hands at the end of each work shift and before
eating, smoking and using the toilet. Use appropriate skin cream to prevent drying of skin.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES


9.1. Information on basic physical and chemical properties
Appearance

Liquid

Colour

Colourless.

Odour

Ketonic.

Solubility

Miscible with water

Relative density

0.86 @ 25 c

Flash point (C)

- 18 CC (Closed cup).

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Flammability Limit - Lower(%)

2.0

Flammability Limit - Upper(%)

13.3

9.2. Other information


SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
No data available

10.2. Chemical stability


Avoid Heat, sparks, flames.

10.3. Possibility of hazardous reactions


Not available.
Hazardous Polymerisation
Unknown.

10.4. Conditions to avoid


Not known.

10.5. Incompatible materials


Materials To Avoid
Strong oxidising substances.

10.6. Hazardous decomposition products


Fire or high temperatures create: Toxic gases/vapours/fumes of: Carbon dioxide (CO2). Carbon monoxide (CO).

SECTION 11: TOXICOLOGICAL INFORMATION


11.1. Information on toxicological effects

Inhalation
Drowsiness, dizziness, disorientation, vertigo. Gas or vapour may irritate respiratory system.
Ingestion
Pneumonia may be the result if vomited material containing solvents reaches the lungs.
Skin contact
Prolonged contact may cause dryness of the skin. May cause skin irritation/eczema.
Eye contact
Irritating to eyes. Irritation, burning, lachrymation, blurred vision after liquid splash.
Health Warnings
Defats the skin. Prolonged or repeated exposure may cause severe irritation.
Medical Considerations
Skin disorders and allergies.

SECTION 12: ECOLOGICAL INFORMATION


Ecotoxicity
Not regarded as dangerous for the environment. However, contamination of the aquatic or terrestrial environments should be avoided

12.1. Toxicity
No data available

12.2. Persistence and degradability


Degradability
There are no data on the degradability of this product.

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12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.

12.4. Mobility in soil


Mobility:
Semi-mobile.

12.5. Results of PBT and vPvB assessment


No data available

12.6. Other adverse effects


Not available.

SECTION 13: DISPOSAL CONSIDERATIONS


General information
Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority.

13.1. Waste treatment methods


Dispose of waste and residues in accordance with local authority requirements. Do not allow runoff to sewer, waterway or ground.
Recover and reclaim or recycle, if practical.
Waste Class
Classified as Special Waste. Not permitted for landfill in liquid state.

SECTION 14: TRANSPORT INFORMATION


14.1. UN number
UN No. (ADR/RID/ADN)

1133

UN No. (IMDG)

1133

UN No. (ICAO)

1133

14.2. UN proper shipping name


Proper Shipping Name

ADHESIVES

14.3. Transport hazard class(es)


ADR/RID/ADN Class

ADR/RID/ADN Class

Class 3: Flammable liquids.

ADR Label No.

IMDG Class

ICAO Class/Division

Transport Labels

FLAMMABLE
LIQUID

3
14.4. Packing group
ADR/RID/ADN Packing group

III

IMDG Packing group

III

ICAO Packing group

III

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14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.

14.6. Special precautions for user


EMS

F-E, S-D

Emergency Action Code

3YE

Hazard No. (ADR)

33

Tunnel Restriction Code

(D/E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Statutory Instruments
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to
Health.
Approved Code Of Practice
Classification and Labelling of Substances and Preparations Dangerous for Supply.
Guidance Notes
Workplace Exposure Limits EH40. CHIP for everyone HSG(108). Introduction to Local Exhaust Ventilation HS(G)37.
EU Legislation
Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. Regulation (EC) No 1907/2006 of the
European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation
(EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives
91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2. Chemical Safety Assessment


SECTION 16: OTHER INFORMATION
General information
This product should be used as directed by Bostik Ltd. For further information consult the product data sheet or contact Technical Services.
Information Sources
This safety data sheet was compiled using current safety information supplied by distributor of raw materials.
Revision Comments
NOTE: Lines within the margin indicate significant changes from the previous revision. This safety data sheet supersedes all previous
issues and users are cautioned to ensure that it is current. Destroy all previous data sheets and if in doubt contact Bostik Limited.
Issued By
Approved LJ
Revision Date

January 2014

Revision

14

Date

December 2002

Risk Phrases In Full


R11

Highly flammable

R36

Irritating to eyes.

R66

Repeated exposure may cause skin dryness or cracking.

R67

Vapours may cause drowsiness and dizziness.

Hazard Statements In Full


EUH066

Repeated exposure may cause skin dryness or cracking.

H225

Highly flammable liquid and vapour.

H319

Causes serious eye irritation.

H336

May cause drowsiness or dizziness.

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