Nuclear Physics
Nuclear Physics
Nuclear Physics
B
a
92U
235
92U
236
K
r
Rutherford's -scattering experiment established that the mass of atom is concentrated with small
positively charged region at the centre which is called 'nucleus'.
e
e
e
Neutron.
Neutron is a fundamental particle which is essential constituent of all nuclei except that of hydrogen
atom. It was discovered by Chadwick.
(1) The charge of neutron : It is neutral
(2) The mass of neutron : 1.6750 1027 kg
(3) It's spin angular momentum :
1 h
J -s
2 2
0n
1
1H
Proton
0
1
Electron
Antinutrin o
Note :
Energy of thermal neutron is about 0.025 eV and speed is about 2.2 km/s.
Nucleus.
(1) Different types of nuclei
The nuclei have been classified on the basis of the number of protons (atomic number) or the total
number of nucleons (mass number) as follows
(i) Isotopes : The atoms of element having same atomic number but different mass number are called
isotopes. All isotopes have the same chemical properties. The isotopes of some elements are the following
1
H 1, 1H 2, 1H 3
8O
16
, 8 O 17 , 8 O 18
He 3 ,
2 He
17 Cl
35
17 Cl
37
92 U
235
92 U
238
genius PHYSICS
2 Nuclear Physics & Radioactivity
(ii) Isobars : The nuclei which have the same mass number (A) but different atomic number (Z) are
called isobars. Isobars occupy different positions in periodic table so all isobars have different chemical
properties. Some of the examples of isobars are
1
H 3 and
2 He
6C
14
and
7N
14
, 8 O 17 and
9F
17
(iii) Isotones : The nuclei having equal number of neutrons are called isotones. For them both the atomic
number (Z) and mass number (A) are different, but the value of (A Z) is same. Some examples are
4
Be 9 and
5B
10
, 6 C 13 and
7N
14
, 8 O 18 and
9F
19
, 3 Li 7 and
4 Be
, 1 H 3 and
2 He
(iv) Mirror nuclei : Nuclei having the same mass number A but with the proton number (Z) and
neutron number (A Z) interchanged (or whose atomic number differ by 1) are called mirror nuclei for
example.
1H
and 2 He 3 , 3 Li 7 and
4 Be
Note :
4
4
R 3 R 03 A V A
3
3
(iii) Nuclear density : Mass per unit volume of a nucleus is called nuclear density.
Nuclear density( )
Massof nucleus
mA
Volume of nucleus 4
(R 0 A 1 / 3 )3
3
where m = Average of mass of a nucleon (= mass of proton + mass of neutron = 1.66 1027 kg)
and mA = Mass of nucleus
3m
2 . 38 10 17 kg / m 3
4R 03
Note :
Density of a nucleus is maximum at it's centre and decreases as we move outwards from the
nucleus.
(3) Nuclear force
Forces that keep the nucleons bound in the nucleus are called nuclear
forces.
(i) Nuclear forces are short range forces. These do not exist at large
distances greater than 1015 m.
(ii) Nuclear forces are the strongest forces in nature.
(iii) These are attractive force and causes stability of the nucleus.
(iv) These forces are charge independent.
(v) Nuclear forces are non-central force.
- mesons are of three types Positive meson (+), negative meson ( ), neutral meson (0)
The force between neutron and proton is due to exchange of charged meson between them i.e.
p n,
n p
The forces between a pair of neutrons or a pair of protons are the result of the exchange of neutral meson
(o) between them i.e.
p p ' 0 and
n n' 0
Thus exchange of meson between nucleons keeps the nucleons bound together. It is responsible for the
nuclear forces.
Dog-Bone analogy
The above interactions can be explained with the dog bone analogy according to
which we consider the two interacting nucleons to be two dogs having a common bone
clenched in between their teeth very firmly. Each one of these dogs wants to take the
bone and hence they cannot be separated easily. They seem to be bound to each other
with a strong attractive force (which is the bone) though the dogs themselves are strong
enemies. The meson plays the same role of the common bone in between two nucleons.
(4) Atomic mass unit (amu)
The unit in which atomic and nuclear masses are measured is called atomic mass unit (amu)
1 amu (or 1u) =
1
th of mass of 6 C 12 atom = 1.66 1027 kg
12
Mass-energy equivalence
According to Einstein, mass and energy are inter convertible. The Einstein's mass energy relationship is given by
E mc 2
If m = 1 amu, c = 3 108 m/sec then E = 931 MeV i.e. 1 amu is equivalent to 931 MeV or 1 amu (or 1 u) = 931 MeV
(5) Pair production and pair-annihilation
When an energetic -ray photon falls on a heavy substance. It is absorbed by some nucleus of the
substance and an electron and a positron are produced. This phenomenon is called pair production and may be
represented by the following equation
( photon)
0
1
(Positron)
0
1
(Electron)
+1
+Ze
-photon
Nucleus
1 0
0
1
(Electron)
( - photon )
( - photon )
The chemical properties of an atom are governed entirely by the number of protons (Z) in the nucleus, the
stability of an atom appears to depend on both the number of protons and the number of neutrons.
For lighter nuclei, the greatest stability is achieved when the number of protons and neutrons are
N
approximately equal (N Z) i.e.
1
Z
Neutron
number (N)
Heavy nuclei are stable only when they have more neutrons than protons. Thus heavy nuclei are neutron
rich compared to lighter nuclei (for heavy nuclei, more is the number of protons in the nucleus, greater is the
electrical repulsive force between them. Therefore more neutrons are added to provide the strong attractive
forces necessary to keep the nucleus stable.)
Stable nuclei
(Line of
stability)
N=Z
10 20 30405060708090
Proton number
(Z)
Figure shows a plot of N verses Z for the stable nuclei. For mass number upto about A = 40. For larger
value of Z the nuclear force is unable to hold the nucleus together against the electrical repulsion of the protons
unless the number of neutrons exceeds the number of protons. At Bi (Z = 83, A = 209), the neutron excess in N
Z = 43. There are no stable nuclides with Z > 83.
Note :
The nuclide
83
A nuclide above the line of stability i.e. having excess neutrons, decay through emission
emission, the
N
ratio increases.
Z
Neutron
Number (N)
(neutron changes into proton). Thus increasing atomic number Z and decreasing neutron
N
number N. In emission,
ratio decreases.
Z
N=Z
+
Proton number (Z)
(ii) Even or odd numbers of Z or N : The stability of a nuclide is also determined by the consideration
whether it contains an even or odd number of protons and neutrons.
It is found that an even-even nucleus (even Z and even N) is more stable (60% of stable nuclide have even
Z and even N).
An even-odd nucleus (even Z and odd N) or odd-even nuclide (odd Z and even N) is found to be lesser
sable while the odd-odd nucleus is found to be less stable.
Only five stable odd-odd nuclides are known : 1 H 2 , 3 Li 6 , 5 Be 10 , 7 N 14 and
75 Ta
180
(iii) Binding energy per nucleon : The stability of a nucleus is determined by value of it's binding energy
per nucleon. In general higher the value of binding energy per nucleon, more stable the nucleus is
Note :
The mass of a typical nucleus is about 1% less than the sum of masses of nucleons.
m M A
A
A
40
30
20
10
0
10
20
N0/8
A > 240
Mass
number (A)
It is the graph between binding energy per nucleon and total number of nucleons (i.e. mass number A)
8.0 He
26Fe56
6.0
4.0
Li
2.0
H2
0
56
100
150
Mass number A
200
(1) Some nuclei with mass number A < 20 have large binding energy per nucleon than their neighbour
nuclei. For example 2 He 4 , 4 Be 8 , 6 C 12 , 8 O 16 and
10
(2) The binding energy per nucleon is maximum for nuclei of mass number A = 56 ( 26 Fe 56 ) . It's value is
8.8 MeV per nucleon.
(3) For nuclei having A > 56, binding energy per nucleon gradually decreases for uranium (A = 238), the
value of binding energy per nucleon drops to 7.5 MeV.
Note :
When a heavy nucleus splits up into lighter nuclei, then binding energy per nucleon of
lighter nuclei is more than that of the original heavy nucleus. Thus a large amount of energy is
liberated in this process (nuclear fission).
When two very light nuclei combines to form a relatively heavy nucleus, then binding energy per
nucleon increases. Thus, energy is released in this process (nuclear fusion).
B. E.
A
Fusion
Fission
Nuclear Reactions.
The process by which the identity of a nucleus is changed when it is bombarded by an energetic particle is
called nuclear reaction. The general expression for the nuclear reaction is as follows.
X
(Parent nucleus)
(Incident particle)
(Product particles)
(Energy )
Here X and a are known as reactants and Y and b are known as products. This reaction is known as (a, b)
reaction and can be represented as X(a, b) Y
He 4 7 N 14 8 O 17 1 H 1
2+7=9
8+1=9
(ii) Conservation of momentum : Linear momentum/angular momentum of particles before the reaction
is equal to the linear/angular momentum of the particles after the reaction. That is p = 0
(iii) Conservation of energy : Total energy before the reaction is equal to total energy after the reaction.
Term Q is added to balance the total energy of the reaction.
(3) Common nuclear reactions
The nuclear reactions lead to artificial transmutation of nuclei. Rutherford was the first to carry out
artificial transmutation of nitrogen to oxygen in the year 1919.
2
He 4 7 N 14 9 F 18 8 O 17 1 H 1
H 1 5 B 11 6 C 12 6 C 11 0 n 1
(p, ) reaction
H 1 3 Li 11 4 Be 8 2 He 4 2 He 4
(p, ) reaction
1H
6 C 12 7 N 13 7 N 13
(n, p) reaction
0n
(, n) reaction
1 H 2 1 H 1 0 n1
7 N 14 7 N 15 6 C 14 1 H 1
235
0 n1
236
92 U
(unstable nucleus)
56 Ba
141
36 Kr
92
3 0 n1 Q
(ii) The energy released in U235 fission is about 200 MeV or 0.8 MeV per nucleon.
(iii) By fission of
92 U
235
, on an average 2.5 neutrons are liberated. These neutrons are called fast neutrons
and their energy is about 2 MeV (for each). These fast neutrons can escape from the reaction so as to proceed
the chain reaction they are need to slow down.
(iv) Fission of U235 occurs by slow neutrons only (of energy about 1eV) or even by thermal neutrons (of
energy about 0.025 eV).
(v) 50 kg of U235 on fission will release 4 1015 J of energy. This is equivalence to 20,000 tones of TNT
explosion. The nuclear bomb dropped at Hiroshima had this much explosion power.
(vi) The mass of the compound nucleus must be greater than the sum of masses of fission products.
Binding energy
(vii) The
of compound nucleus must be less than that of the fission products.
A
(viii) It may be pointed out that it is not necessary that in each fission of uranium, the two fragments
and 36 Kr are formed but they may be any stable isotopes of middle weight atoms.
Ba
56
Same other U 235 fission reactions are
92 U
235
0 n 1 54 Xe 140
57 La 148
38 Sr
35 Br
94
85
2 0 n1
3 0 n1
Many more
(ix) The neutrons released during the fission process are called prompt neutrons.
(x) Most of energy released appears in the form of kinetic energy of fission fragments.
Ba
Energy
Slow
Neutron
Energy
92U236
92U235
Energy
Energy
Kr
(2) Chain reaction
In nuclear fission, three neutrons are produced along with the release of large energy. Under favourable
conditions, these neutrons can cause further fission of other nuclei, producing large number of neutrons. Thus
a chain of nuclear fissions is established which continues until the whole of the uranium is consumed.
Kr
Kr
n
U
Ba
Ba
Kr
Ba
In the chain reaction, the number of nuclei undergoing fission increases very fast. So, the energy produced
takes a tremendous magnitude very soon.
Difficulties in chain reaction
(i) Absorption of neutrons by U 238 , the major part in natural uranium is the isotope U238 (99.3%), the
isotope U 235 is very little (0.7%). It is found that U 238 is fissionable with fast neutrons, whereas U 235 is
fissionable with slow neutrons. Due to the large percentage of U 238 , there is more possibility of collision of
neutrons with U 238 . It is found that the neutrons get slowed on coliding with U 238 , as a result of it further
fission of U238 is not possible (Because they are slow and they are absorbed by U238). This stops the chain
reaction.
Removal : (i) To sustain chain reaction
obtained
92 U
235
92 U
235
is known as enriched uranium, which is fissionable with the fast and slow neutrons and
If k = 1, the chain reaction will be steady. The size of the fissionable material used is said to be the
critical size and it's mass, the critical mass.
If k > 1, the chain reaction accelerates, resulting in an explosion. The size of the material in this case is
super critical. (Atom bomb)
If k < 1, the chain reaction gradually comes to a halt. The size of the material used us said to be subcritical.
Types of chain reaction : Chain reactions are of following two types
Controlled chain reaction
Fast rate
Reproduction factor k = 1
Note :
The energy released in the explosion of an atom bomb is equal to the energy released by
2000 tonn of TNT and the temperature at the place of explosion is of the order of 107 oC.
Nuclear Reactor.
Coolant
Coolant out
Turbine
Concrete
wall
To electric
generator
Condenser
Moderator
Water
Coolant in
Heat
exchanger
Fuel elements
(i) Fissionable material (Fuel) : The fissionable material used in the reactor is called the fuel of the
reactor. Uranium isotope (U235) Thorium isotope (Th232) and Plutonium isotopes (Pu239, Pu240 and Pu241) are
the most commonly used fuels in the reactor.
(ii) Moderator : Moderator is used to slow down the fast moving neutrons. Most commonly used
moderators are graphite and heavy water (D2O).
(iii) Control Material : Control material is used to control the chain reaction and to maintain a stable
rate of reaction. This material controls the number of neutrons available for the fission. For example, cadmium
rods are inserted into the core of the reactor because they can absorb the neutrons. The neutrons available for
fission are controlled by moving the cadmium rods in or out of the core of the reactor.
(iv) Coolant : Coolant is a cooling material which removes the heat generated due to fission in the
reactor. Commonly used coolants are water, CO2 nitrogen etc.
(v) Protective shield : A protective shield in the form a concrete thick wall surrounds the core of the
reactor to save the persons working around the reactor from the hazardous radiations.
Note :
It may be noted that Plutonium is the best fuel as compared to other fissionable material.
It is because fission in Plutonium can be initiated by both slow and fast neutrons. Moreover it
can be obtained from U 238 .
Nuclear reactor is firstly devised by fermi.
Apsara was the first Indian nuclear reactor.
(2) Uses of nuclear reactor
(i) In electric power generation.
(ii) To produce radioactive isotopes for their use in medical science, agriculture and industry.
(iii) In manufacturing of PU 239 which is used in atom bomb.
(iv) They are used to produce neutron beam of high intensity which is used in the treatment of cancer and
nuclear research.
Note :
A type of reactor that can produce more fissile fuel than it consumes is the breeder
reactor.
Nuclear fusion
In nuclear fusion two or more than two lighter nuclei combine to form a single heavy nucleus. The mass of
single nucleus so formed is less than the sum of the masses of parent nuclei. This difference in mass results in
the release of tremendous amount of energy
or
H 2 1 H 2 1 H 3 1 H 1 4 MeV
H 3 1 H 2 2 He 4 0 n 1 17 .6 MeV
H 2 1 H 2 2 He 4 24 MeV
For fusion high pressure ( 106 atm) and high temperature (of the order of 107 K to 108 K) is required and
so the reaction is called thermonuclear reaction.
Fusion energy is greater then fission energy fission of one uranium atom releases about 200 MeV of
energy. But the fusion of a deutron (1 H 2 ) and triton (1 H 3 ) releases about 17.6 MeV of energy. However the
energy released per nucleon in fission is about 0.85 MeV but that in fusion is 4.4 MeV. So for the same mass of
the fuel, the energy released in fusion is much larger than in fission.
Plasma : The temperature of the order of 108 K required for thermonuclear reactions leads to the
complete ionisation of the atom of light elements. The combination of base nuclei and electron cloud is called
plasma. The enormous gravitational field of the sun confines the plasma in the interior of the sun.
The main problem to carryout nuclear fusion in the laboratory is to contain the plasma at a temperature
8
of 10 K. No solid container can tolerate this much temperature. If this problem of containing plasma is solved,
then the large quantity of deuterium present in sea water would be able to serve as in-exhaustible source of
energy.
Note :
To achieve fusion in laboratory a device is used to confine the plasma, called Tokamak.
Stellar Energy
Stellar energy is the energy obtained continuously from the sun and the stars. Sun radiates energy at the
rate of about 1026 joules per second.
Scientist Hans Bethe suggested that the fusion of hydrogen to form helium (thermo nuclear reaction) is
continuously taking place in the sun (or in the other stars) and it is the source of sun's (star's) energy.
The stellar energy is explained by two cycles
Proton-proton cycle
Carbon-nitrogen cycle
1H
1 H 1 H 1 e Q1
1H
1H
1 H 1 2 He 3 Q 2
He 3 2 He 3 2 He 4 2 1 H 1 Q 3
4 1 H 2 He 2
1
1 e
2 26 .7 MeV
6 C 12 7 N 13 Q1
N 13 6 C 13
0
1 e
14
1H
6 C 13 7 N
1H
7 N
1H
7N
15
1
14
7N
15
8O
15
15
Q2
Q3
1e Q4
0
6 C 12 2 He 4
4 1 H 1 2 He 4 2 1 e 0 24 .7 MeV
About 90% of the mass of the sun consists of hydrogen and helium.
Nuclear Bomb.
Hydrogen bomb
Concepts
A test tube full of base nuclei will weight heavier than the earth.
If the relative abundance of isotopes in an element has a ratio n1 : n2 whose atomic masses are m1 and m2 then atomic
n m n2 m 2
mass of the element is M 1 1
n1 n 2
The nucleus of hydrogen contains only one proton. Therefore we may say that the proton is the nucleus of hydrogen
atom.
Example
s
A heavy nucleus at rest breaks into two fragments which fly off with velocities in the ratio 8 : 1. The ratio
of radii of the fragments is
(a) 1 : 2
(b) 1 : 4
Solution : (a)
v1
(c) 4 : 1
m1
v1 8 m 2
v 2 1 m1
M
m2
(i)
Also from r A1 / 3
v2
Example: 2
(d) 2 : 1
27
13
Al and
(a) 6 : 10
(b) 13 : 52
1/3
r1 A1
r2 A2
125
52 Te
r1 A1
r2 A2
1/3
1/3
1
8
1
2
is approximately
(c) 40 : 177
1/3
27
125
(d) 14 : 7
8
6
5 10
Solution : (a)
By using r A1 / 3
Example: 3
If Avogadros number is 6 1023 then the number of protons, neutrons and electrons in 14 g of 6C14 are
respectively
Solution : (a)
Example: 4
14
of 6 C
are
6C
14
contains 6
14
6 6 10 23 36 10 23 ,
8 6 10 23 48 10 23 , 6 6 10 23 36 10 23 .
Two Cu64 nuclei touch each other. The electrostatics repulsive energy of the system will be
(a) 0.788 MeV
Solution : (c)
1023
6C
1/3
1 .2 (64 )
1/3
4 .8 fm
When
92 U
235
k q2
9 10 9 (1 .6 10 19 29 ) 2
undergoes fission. 0.1% of its original mass is changed into energy. How much energy is
released if 1 kg of
92 U
235
(a) 9 1010 J
undergoes fission
(b) 9 1011 J
(c) 9 1012 J
(d) 9 1013 J
Solution : (d)
0 .1
1 (3 10 8 )2 9 10 13 J
By using E m c 2 E
100
Example: 6
1 g of hydrogen is converted into 0.993 g of helium in a thermonuclear reaction. The energy released is
[EAMCET (Med.) 1995; CPMT 1999]
(a) 63
Solution : (b)
107
(b) 63
1010
(c) 63
1014
(d) 63 1020 J
m = 1 0.993 = 0.007 gm
E = mc2 = 0.007 103 (3 108)2 = 63 1010 J
Example: 7
The binding energy per nucleon of deuteron (12 H ) and helium nucleus (42 He ) is 1.1 MeV and 7 MeV
respectively. If two deuteron nuclei react to form a single helium nucleus, then the energy released is
[MP PMT 1992; Roorkee 1994; IIT-JEE 1996; AIIMS 1997; Haryana PMT 2000; Pb PMT 2001; CPMT 2001; AIEEE 2004]
1H
1 H 2 2 He 4 Q
The masses of neutron and proton are 1.0087 amu and 1.0073 amu respectively. If the neutrons and
protons combine to form a helium nucleus (alpha particles) of mass 4.0015 amu. The binding energy of
the helium nucleus will be [1 amu= 931 MeV]
[CPMT 1986; MP PMT 1995; CBSE 2003]
(a) 28.4 MeV
Solution : (a)
Example: 9
Solution : (c)
By using P
(b) 10 1020
W n E
t
t
300 10 6
(a) 3.52
Solution : (c)
(d) 30 1025
n 170 10 6 1.6 10 19
n = 40 1021
3600
The binding energy per nucleon of O16 is 7.97 MeV and that of O17 is 7.75 MeV. The energy (in MeV)
required to remove a neutron from O17 is
[IIT-JEE 1995]
each fission so
Example: 10
(c) 40 1021
(b) 3.64
(c) 4.23
(d) 7.86
O17 O16 0 n1
Energy required = Binding of O17 binding energy of O16 = 17 7.75 16 7.97 = 4.23 MeV
Example: 11
A gamma ray photon creates an electron-positron pair. If the rest mass energy of an electron is 0.5 MeV
and the total kinetic energy of the electron-positron pair is 0.78 MeV, then the energy of the gamma ray
photon must be
[MP PMT 1991]
(a) 0.78 MeV
Solution : (b)
Example: 12
Solution : (c)
1010
gm
(b) 2.348
(c) 1.48
(d) 6.25
[MNR 1985]
1023
gm
1011
gm
Example: 13
234 3 .71 10 10
6 .02 10 23
2
1H
234
1034
gm
234 gm
1 .48 10 11 gm
two nuclei is 7.7 10 14 J , the temperature at which the gases must be heated to initiate the reaction is
nearly [Boltzmanns constant k 1 .38 10 23 J /K ]
[AIEEE 2003]
(a) 10 9 K
Solution : (a)
(c) 10 5 K
(d) 10 3 K
Example: 14
(b) 107 K
3
kT 7 . 7 10 14 J T = 3.7 109 K.
2
A nucleus with mass number 220 initially at rest emits an -particle. If the Q value of the reaction is 5.5
MeV. Calculate the kinetic energy of the -particle
[IIT-JEE (Screening) 2003]
(a) 4.4 MeV
Solution : (b)
M = 220
k1
k2
p1
p2
m2 = 4
m1 = 216
2(216 )k 1
(i)
2(4 )k 2 k2 = 54 k1
(ii)
Ca nucleus. Then
20
10
(b) M 2 2M1
(c)
M 2 2M1
(d) M 1 10(m n m p )
Due to mass defect (which is finally responsible for the binding energy of the nucleus), mass of a nucleus
20
10
20
10
Ne nucleus M 1 10 (m p m n )
Also heavier the nucleus, more is he mass defect thus 20 (mn m p ) M 2 10(m p mn ) M1
or
10 (m p m n ) M 2 M 1
M 2 M1 10 (m p mn ) M 2 M 1 M 1 M 2 2M 1
Tricky example: 1
Binding energy per nucleon vs mass number curve for nuclei is shown in the figure. W, X, Y and Z
are four nuclei indicated on the curve. The process that would release energy is
[IIT-JEE 1999]
Binding energy
nucleon in
MeV
(a) Y 2Z
(c) W 2Y
5.0
(d) X Y + Z
Solution : (c)
8.5
8.0
7.5
(b) W X + Z
Z
30
60 90 120
Mass number of nuclei
Energy is released in a process when total binding energy of the nucleus (= binding energy per
nucleon number of nucleon) is increased or we can say, when total binding energy of products
is more than the reactants. By calculation we can see that only in case of option (c) this happens.
Given
W 2Y
Radioactivity.
The phenomenon of spontaneous emission of radiatons by heavy elements is called radioactivity. The
elements which shows this phenomenon are called radioactive elements.
(1) Radioactivity was discovered by Henery Becquerel in uranium salt in the year 1896.
(2) After the discovery of radioactivity in uranium, Piere Curie and Madame Curie discovered a new
radioactive element called radium (which is 106 times more radioactive than uranium)
(3) Some examples of radio active substances are : Uranium, Radium, Thorium, Polonium, Neptunium
etc.
(4) Radioactivity of a sample cannot be controlled by any physical (pressure, temperature, electric or
magnetic field) or chemical changes.
(5) All the elements with atomic number (Z ) > 82 are naturally radioactive.
(6) The conversion of lighter elements into radioactive elements by the bombardment of fast moving
particles is called artificial or induced radioactivity.
(7) Radioactivity is a nuclear event and not atomic. Hence electronic configuration of atom don't have any
relationship with radioactivity.
Nuclear radiatons
According to Rutherford's experiment when a sample of radioactive substance is put in a lead box and
allow the emission of radiation through a small hole only. When the radiation enters into the external electric
field, they splits into three parts
-rays
rays
-rays
+
+
+
+
+
-rays
rays
Magnetic
-rays field
(i) Radiations which deflects towards negative plate are called -rays (stream of positively charged
particles)
(ii) Radiations which deflects towards positive plate are called particles (stream of negatively charged
particles)
(iii) Radiations which are undeflected called -rays. (E.M. waves or photons)
Note :
Exactly same results were obtained when these radiations were subjected to magnetic
field.
No radioactive substance emits both and particles simultaneously. Also -rays are emitted
after the emission of or -particles.
-particles are not orbital electrons they come from nucleus. The neutron in the nucleus decays
into proton and an electron. This electron is emitted out of the nucleus in the form of -rays.
Properties of , and -rays
- particles
Features
1. Identity
- particles
Fast
2. Charge
+ 2e
Zero
4 mp
me
Massless
4. Speed
107 m/s
Speed of light
4 MeV to 9 MeV
Between a minimum
value to 2.23 MeV
6. Penetration power (, ,
)
100
10,000
(Stopped by a paper)
(100 times of )
10,000
100
8. Effect of
magnetic field
Deflected
Deflected
Not deflected
9. Energy spectrum
Continuous
Produces heat
Produces heat
Produces, photo-electric
effect, Compton effect,
pair production
or
decay
X A
Z 2 Y
X A
A 4
2 He 4
Z' Y
A'
electron
Helium nucleus or
doubly ionised helium
atom (2He4)
electric
moving
- rays
( or )
0
XA
X A
Z 1 Y
Z' X
1 e
n (2 n Z Z')
X A zXa
A' A
4
Radioactive Disintegration.
(1) Law of radioactive disintegration
According to Rutherford and Soddy law for radioactive decay is as follows.
"At any instant the rate of decay of radioactive atoms is proportional to the number of atoms present at
dN
dN
that instant" i.e.
N
N . It can be proved that N = N0et
dt
dt
This equation can also be written in terms of mass i.e. M = M0et
where N = Number of atoms remains undecayed after time t, N0 = Number of atoms present initially (i.e. at t =
0), M = Mass of radioactive nuclei at time t, M0 = Mass of radioactive nuclei at time t = 0, N0 N = Number of
disintegrated nucleus in time t
dN
= rate of decay, = Decay constant or disintegration constant or radioactivity constant or Rutherford
dt
Soddy's constant or the probability of decay per unit time of a nucleus.
Note :
depends only on the nature of substance. It is independent of time and any physical or
chemical changes.
N0
N = N0et
N
0
t
(2) Activity
It is defined as the rate of disintegration (or count rate) of the substance (or the number of atoms of any
dN
material decaying per second) i.e. A
N N 0 e t A0 e t
dt
where A0 = Activity of t = 0, A = Activity after time t
Note :
N0/8
2
Time (t)
t=0
Remaining fraction of
active atoms (N/N0)
probability of survival
1
(100%)
2T
3T
Fraction of atoms
decayed (N0 N) /N0
probability of decay
0
N0
2
N
1 N0
02
2
2
(2)
N
N
1
0 03
2 (2) (2)
t = 2(T1/2)
t = 3(T1/2)
t = 10 (T1/2)
N0
10
(2)
t = n (N1/2)
N
(2)
1
2
1
4
(50%)
1
8
(12.5%)
(25%)
1
2
10
1
2
1
2
3
4
(50%)
7
8
(87.5%)
(75%)
99.9%
0 .1 %
1 n
1
2
Useful relation
1
2
1
2
t / T1 / 2
N
ln
N
N0
t
ln
(ii) From N N 0 e
slope of the line shown in the graph
N0
Slope =
t
N
i.e. the magnitude of inverse of slope of ln
vs t curve is known as mean life ().
N0
t
(iii) From N N 0 e t
If t
1
N N 0 e 1 N 0 0 .37 N 0 37 % of N0.
i.e. mean life is the time interval in which number of undecayed atoms (N) becomes
or 37% of original number of atoms.
or
1
times or 0.37 times
e
It is the time in which number of decayed atoms (N0 N) becomes 1 times or 0.63 times or 63% of
e
0.693
i.e. mean life is about 44% more than that of half life. Which gives us > T(1/2)
Note :
Half life and mean life of a substance doesn't change with time or with pressure,
temperature etc.
Radioactive Series.
If the isotope that results from a radioactive decay is itself radioactive then it will also decay and so on.
The sequence of decays is known as radioactive decay series. Most of the radio-nuclides found in nature
are members of four radioactive series. These are as follows
Mass number
Series (Nature)
4n
Thorium (natural)
4n + 1
Neptunium
(Artificial)
Parent
90
93
Th 232
Np
Stable
product
82
Pb 208
Integer
n
52
83
Bi 209
52
237
and
Number
particles
= 8, = 5
= 6, = 4
of
lost
Uranium (Natural)
4n + 3
Actinium (Natural)
92 U
89
238
Ac
82
227
82
Pb 206
51
= 8, = 6
207
51
= 7, = 4
Pb
Note :
The 4n + 1 series starts from 94 PU 241 but commonly known as neptunium series because
neptunium is the longest lived member of the series.
The 4n + 3 series actually starts from 92 U 235 .
dN 1
1 N 1 (which is also the rate of formation of B)
dt
dN 2
Rate of disintegration of B
2 N 2
dt
Net rate of formation of B = Rate of disintegration of A Rate of disintegration of B
= 1N1 2N2
Equilibrium
In radioactive equilibrium, the rate of decay of any radioactive product is just equal to it's rate of
production from the previous member.
(T )
1 N 2 2
1/2
i.e.
1N1 = 2N2
2 N 2 1 (T1 / 2 )1
Rate of disintegration of A
Note :
1 N 0
(e 1 t e 2 t ) where 12 decay
( 2 1 )
constant of A and B.
Uses of radioactive isotopes
(1) In medicine
(i) For testing blood-chromium - 51
(ii) For testing blood circulation - Na - 24
(iii) For detecting brain tumor- Radio mercury - 203
(iv) For detecting fault in thyroid gland - Radio iodine - 131
(v) For cancer - cobalt - 60
(vi) For blood - Gold - 189
(vii) For skin diseases - Phospohorous - 31
(2) In Archaeology
(i) For determining age of archaeological sample (carbon dating) C 14
(ii) For determining age of meteorites - K 40
(iii) For determining age of earth-Lead isotopes
(3) In agriculture
(i) For protecting potato crop from earthworm- CO 60
(ii) For artificial rains - AgI (iii)
As
32
fertilizers - P
(4) As tracers - (Tracer) : Very small quantity of radioisotopes present in a mixture is known as tracer
(i) Tracer technique is used for studying biochemical reaction in tracer and animals.
(5) In industries
(i) For detecting leakage in oil or water pipe lines
(ii) For determining the age of planets.
Concept
If a nuclide can decay simultaneously by two different process which have decay constant 1 and 2, half life T1 and T2 and
mean lives 1 and 2 respectively then
= 1 + 2
1
1, T1, 1
2, T2, 2
228
Example: 16
When
Solution : (d)
(a) 8, 7
A 228
Z 90 Th
90 Th
transforms to
83 Bi
212
1 2
1 2
(b) 4, 7
Z ' 83 Bi
T1T2
T1 T2
(c) 4, 4
(d) 4, 1
A ' 212
4
4
4
2n Z Z ' 2 4 90 83 1 .
A radioactive substance decays to 1/16th of its initial activity in 40 days. The half-life of the radioactive
substance expressed in days is
(a) 2.5
(b) 5
(c) 10
(d) 20
t/T
Solution : (c)
Example: 18
40 / T
1/2
N
1
1
1 1/2
By using N N 0
T1 / 2 10 days.
N0
16 2
2
A sample of radioactive element has a mass of 10 gm at an instant t = 0. The approximate mass of this
element in the sample after two mean lives is
[CBSE PMT 2003]
(a) 2.50 gm
(b) 3.70 gm
(c) 6.30 gm
(d) 1.35 gm
1
10 1.359 gm
e
Solution : (d)
By using M M 0 e t M 10 e (2 ) 10 e
Example: 19
The half-life of 215 At is 100 s. The time taken for the radioactivity of a sample of 215 At to decay to 1/16th
of its initial value is
[IIT-JEE (Screening) 2002]
(a) 400 s
(b) 6.3 s
(c) 40 s
(d) 300 s
t/T
Solution : (a)
Example: 20
Solution : (c)
t / 100
N
1
1 1/2
1
1
By using N N 0
t = 400 sec.
N0 2
16 2
2
The mean lives of a radioactive substance for and emissions are 1620 years and 405 years respectively.
After how much time will the activity be reduced to one fourth
[RPET 1999]
(a) 405 year
(b) 1620 year
(c) 449 year
(d) None of these
1
1
per year and
per year and it is given that the fraction of the remained activity
405
1620
A
1
A0
4
1
1
1
per year
1620 405
324
A
1
1
2
We know that A A 0 e t t log e 0 t loge 4 loge 2 = 324 2 0.693 = 449 years.
At any instant the ratio of the amount of radioactive substances is 2 : 1. If their half lives be
respectively 12 and 16 hours, then after two days, what will be the ratio of the substances
(a) 1 : 1
(b) 2 : 1
(c) 1 : 2
(d) 1 : 4
Example: 21
2 24
Solution : (a)
Example: 22
1 12
n
n1
1
N
(
N
)
(
1
/
2
)
2
1
2
1
01
By using N N 0
n2
2
24
N 2 ( N 0 )2 (1 / 2)
1
1
2
1 16
2
From a newly formed radioactive substance (Half-life 2 hours), the intensity of radiation is 64 times the
permissible safe level. The minimum time after which work can be done safely from this source is
(a) 6 hours
(b) 12 hours
n
Solution : (b)
(c) 24 hours
0
A
1
1
1
1
By using A A 0
A0 64 2
2
2
t
6 t 6 2 12 hours.
T1 / 2
n=6
nucleus of mass number A, originally at rest, emits an -particle with speed v. The daughter nucleus
recoils with a speed
[DCE 2000; AIIMS 2004]
(a) 2v /( A 4)
(b) 4v /( A 4)
(c) 4v /( A 4)
(d) 2v /( A 4)
m
Solution : (c)
v
A4
4v
.
A4
The counting rate observed from a radioactive source at t = 0 second was 1600 co unts per second and
at t = 8 seconds it was 100 counts per second. The counting rate observed as counts per second at t =
6 seconds will be
[MP PET 1996; UPSEAT 2000]
(a) 400
(b) 300
(c) 200
(d) 150
Rest
8 / T1 / 2
1
1
By using A A0 100 1600
2
2
Example: 25
1
200 .
Again by using the same relation the count rate at t = 6 sec will be A 1600
2
The kinetic energy of a neutron beam is 0.0837 eV. The half-life of neutrons is 693s and the mass of
neutrons is 1.675 10 27 kg. The fraction of decay in travelling a distance of 40m will be
(a) 10 3
(b) 10 4
(c) 10 5
(d) 10 6
Solution : (c)
1 1
16 2
8 / T1 / 2
Solution : (c)
T1 / 2 2 sec
6/2
2E
2 0 . 0837 1 . 6 10 19
1 . 675 10 27
= 4 103 m/sec
40
4 10 3
10 2 sec
dN
dN
N
dt
dt
N
N
0 . 693
0 . 693
t
t
10 2 10 5
N
T
693
The fraction of atoms of radioactive element that decays in 6 days is 7/8. The fraction that decays in 10 days
will be
(a) 77/80
(b) 71/80
(c) 31/32
(d) 15/16
N
N
log e 0
T1 / 2 log e 0
t / T1 / 2
N 1
N
N
t
1
By using N N 0
t
t log e 0 1
N
log e (2)
t2
N
2
log e 0
N 2
N
N
log e (8 / 1)
10
6
log e (8 ) log e 32 0 32 .
Hence
log e 0
N
6
N
10 log e ( N 0 / N )
Solution : (c)
1
31
.
32 32
Tricky example: 2
Solution : (b)
Half-life of a substance is 20 minutes. What is the time between 33% decay and 67% decay [AIIMS 2000]
(a) 40 minutes
(b) 20 minutes
(c) 30 minutes
(d) 25 minutes
Let N0 be the number of nuclei at beginning
Number of undecayed nuclei after 33% decay = 0.67 N0
and number of undecayed nuclei after 67% of decay = 0.33 N0
0 . 67 N 0
0.33 N0 ~
and in the half-life time the number of undecayed nuclei becomes half.
2