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Table of Contents

Section 1 -- Refrigerants -- Technical Guidelines

Page
1

Part Numbers

2-6

Refrigerant Property Summary

7-8

Application Summary

9-10

Product Data Summary and Thermodynamic Tables


R-11 and R-12
R-13
R-22
R-23
R-123 and R-124
R-134a
R-401A and R-401B
R-402A and R-402B
R-403B
R-404A
R-407A
R-407C
R-408A
R-409A
R-410A
R-414B
R-416A
R-422A and R-422C
R-422B and R-422D
R-500 and R-502
R-503
R-507
R-508B

11-13
14-15
16-17
18-19
20-22
23-24
25-27
28-30
31-32
33-34
35-36
37-38
39-40
41-42
43-44
45-46
47-48
49-51
52-54
55-57
58-59
60-61
62-63

Ultra-Low Temperature Refrigeration

64-65

AHRI Chemical Names and Color Codes

66

Refrigerant Reference Guide

5th Edition 2010

Table of Contents
Section 2 -- Retrofits and Conversions

Page
67

Blend Behavior and Technical Issues

68-87

Retrofit Checklist and System Data Sheet

88-89

Retrofit Guidelines and Procedures

90-101

R-12 Retrofitting - General Considerations


R-12 to R-134a
R-12 to R-401A/B, R-409A, R-414B
R-12 to R-416A
R-22 to R-407A, R-407C
R-22 to R-422B, R-422D
R-22 to R-404A, R-507, R-422A, R-422C
R-500 to R-401A, R-401B, R-409A, R-414B
R-502 to R-402A, R402B, R-408A
R-502 to R-404A, R-507
R-502, R-402A, R-402B or R-408A to R-422C
R-13 and R-503 to R-23 or R-508B

Sizing Thermostatic Expansion Devices

90
91
92
93
94
95
96
97
98
99
100
101
102-104

Section 3 -- Refrigerant Management Services

105-119

Section 4 -- Miscellaneous Technical Literature

121-135

Section 5 -- Regulatory and EPA Updates

137-147

Refrigerant Reference Guide

ii

5th Edition 2010

1. Refrigerants: Technical Data


Page

NRI Part Numbers

Properties Summary Table

Thermodynamic Data

AHRI Cylinder Color Codes

Refrigerant Reference Guide

2-6

7-10
11- 65
66

5th Edition 2010

NRI PRODUCT PART NUMBERS


REFRIGERANTS
PART NO.

DESCRIPTION

100R11
200R11

100 LB. DRUM OF REFRIGERANT 11


200 LB. DRUM OF REFRIGERANT 11

30R12
145R12

30 LB. CYLINDER OF REFRIGERANT 12


145 LB. CYLINDER OF REFRIGERANT 12 RETURNABLE/DEPOSIT

5R13
9R13
23R13
80R13

5 LB. CYLINDER OF REFRIGERANT 13


9 LB. CYLINDER OF REFRIGERANT 13 RETURNABLE/DEPOSIT
23 LB. CYLINDER OF REFRIGERANT 13 RETURNABLE/DEPOSIT
80 LB. CYLINDER OF REFRIGERANT 13 RETURNABLE/DEPOSIT

5R13B1
10R13B1
28R13B1
90R13B1

5 LB. CYLINDER OF REFRIGERANT 13B1


10 LB. CYLINDER OF REFRIGERANT 13B1 RETURNABLE/DEPOSIT
28 LB. CYLINDER OF REFRIGERANT 13B1 RETURNABLE/DEPOSIT
90 LB. CYLINDER OF REFRIGERANT 13B1 RETURNABLE/DEPOSIT

30R22
50R22
125R22
1000R22
1750R22

30 LB. CYLINDER OF REFRIGERANT 22


50 LB. CYLINDER OF REFRIGERANT 22
125 LB. CYLINDER OF REFRIGERANT 22 RETURNABLE/DEPOSIT
1000 LB. CYLINDER OF REFRIGERANT 22 RETURNABLE/DEPOSIT
1750 LB. CYLINDER OF REFRIGERANT 22 RETURNABLE/DEPOSIT

5R23
9R23
20R23
70R23

5 LB. CYLINDER OF REFRIGERANT 23


9 LB. CYLINDER OF REFRIGERANT 23 RETURNABLE/DEPOSIT
20 LB. CYLINDER OF REFRIGERANT 23 RETURNABLE/DEPOSIT
70 LB. CYLINDER OF REFRIGERANT 23 RETURNABLE/DEPOSIT

100R113
200R113

100 LB. DRUM OF REFRIGERANT 113


200 LB. DRUM OF REFRIGERANT 113

30R114

30 LB. CYLINDER OF REFRIGERANT 114

100R123
200R123
650R123
100CR123
200CR123

100 LB. DRUM OF REFRIGERANT 123


200 LB. DRUM OF REFRIGERANT 123
650 LB. DRUM OF REFRIGERANT 123
100 LB. CYLINDER OF REFRIGERANT 123 RETURNABLE/DEPOSIT
200 LB. CYLINDER OF REFRIGERANT 123 RETURNABLE/DEPOSIT

30R124
145R124

30 LB. CYLINDER OF REFRIGERANT 124


145 LB. CYLINDER OF REFRIGERANT 124 RETURNABLE/DEPOSIT

012R134a
30R134a
A30R134a
125R134a
1000R134a
1750R134a

12 OZ. CAN OF REFRIGERANT 134a


30 LB. CYLINDER OF REFRIGERANT 134a
30 LB. CYLINDER OF REFRIGERANT 134a AUTOMOTIVE VALVE
125 LB. OF REFRIGERANT 134a RETURNABLE/DEPOSIT
1000 LB. CYLINDER OF REFRIGERANT 134a RETURNABLE/DEPOSIT
1750 LB. CYLINDER OF REFRIGERANT 134a RETURNABLE /DEPOSIT

Refrigerant Reference Guide

5th Edition 2010

NRI PRODUCT PART NUMBERS


REFRIGERANTS
PART NO.

DESCRIPTION

30R401A
125R401A

30 LB. CYLINDER OF REFRIGERANT 401A


125 LB. CYLINDER OF REFRIGERANT 401A RETURNABLE/DEPOSIT

30R401B
125R401B

30 LB. CYLINDER OF REFRIGERANT 401B


125 LB. CYLINDER OF REFRIGERANT 401B RETURNABLE/DEPOSIT

27R402A
110R402A

27 LB. CYLINDER OF REFRIGERANT 402A


110 LB. CYLINDER OF REFRIGERANT 402A RETURNABLE/DEPOSIT

13R402B

13 LB. CYLINDER OF REFRIGERANT 402B

25R403B
110R403B

25 LB. CYLINDER OF REFRIGERANT 403B


110 LB. CYLINDER OF REFRIGERANT 403B RETURNABLE/DEPOSIT

24R404A
100R404A
800R404A
1300R404A

24 LB. CYLINDER OF REFRIGERANT 404A


100 LB. CYLINDER OF REFRIGERANT 404A RETURNABLE/DEPOSIT
800 LB. CYLINDER OF REFRIGERANT 404A RETURNABLE/DEPOSIT
1300 LB. CYLINDER OF REFRIGERANT 404A RETURNABLE/DEPOSIT

25R407A
100R407A
925R407A
1550R407A

25 LB. CYLINDER OF REFRIGERANT 407A


100 LB. CYLINDER OF REFRIGERANT 407A RETURNABLE/DEPOSIT
925 LB. CYLINDER OF REFRIGERANT 407A RETURNABLE/DEPOSIT
1550 LB CYLINDER OF REFRIGERANT 407A RETURNABLE/DEPOSIT

25R407C
115R407C
925R407C
1550R407C

25 LB. CYLINDER OF REFRIGERANT 407C


115 LB. CYLINDER OF REFRIGERANT 407C RETURNABLE/DEPOSIT
925 LB. CYLINDER OF REFRIGERANT 407C RETURNABLE/DEPOSIT
1550 LB. CYLINDER OF REFRIGERANT 407C RETURNABLE/DEPOSIT

24R408A
100R408A

24 LB. CYLINDER OF REFRIGERANT 408A


100 LB. CYLINDER OF REFRIGERANT 408A RETURNABLE/DEPOSIT

30R409A
125R409A

30 LB. CYLINDER OF REFRIGERANT 409A


125 LB. CYLINDER OF REFRIGERANT 409A RETURNABLE/DEPOSIT

25R410A
100R410A
850R410A
1450R410A

25 LB. CYLINDER OF REFRIGERANT 410A


100 LB. CYLINDER OF REFRIGERANT 410A RETURNABLE/DEPOSIT
850 LB. CYLIDNER OF REFRIGERANT 410A RETURNABLE/DEPOSIT
1450 LB. CYLIDNER OF REFRIGERANT 410A RETURNABLE/DEPOSIT

25R414B

25 LB. CYLINDER OF REFRIGERANT 414B

25R422B
110R422B

25 LB. CYLINDER OF REFRIGERANT 422B


110 LB. CYLINDER OF REFRIGERANT 422B RETURNABLE/DEPOSIT

24R422C

24 LB. CYLINDER OF REFRIGERANT 422C

25R422D
110R422D

25 LB. CYLINDER OF REFRIGERANT 422D


110 LB. CYLINDER OF REFRIGERANT 422D RETURNABLE/DEPOSIT

Refrigerant Reference Guide

5th Edition 2010

NRI PRODUCT PART NUMBERS


REFRIGERANTS
PART NO.

DESCRIPTION

30R500
125R500

30 LB. CYLINDER OF REFRIGERANT 500


125 LB. CYLINDER OF REFRIGERANT 500 RETURNABLE/DEPOSIT

30R502
125R502

30 LB. CYLINDER OF REFRIGERANT 502


125 LB. CYLINDER OF REFRIGERANT 502 RETURNABLE/DEPOSIT

5R503
9R503
20R503
80R503

5 LB. CYLINDER OF REFRIGERANT 503


9 LB. CYLINDER OF REFRIGERANT 503 RETURNABLE/DEPOSIT
20 LB. CYLINDER OF REFRIGERANT 503 RETURNABLE/DEPOSIT
80 LB. CYLINDER OF REFRIGERANT 503 RETURNABLE/DEPOSIT

25R507
100R507
800R507
1400R507

25 LB. CYLINDER OF REFRIGERANT 507


100 LB. CYLINDER OF REFRIGERANT 507 RETURNABLE/DEPOSIT
800 LB. CYLINDER OF REFRIGERANT 507 RETURNABLE/DEPOSIT
1400 LB. CYLINDER OF REFRIGERANT 507 RETURNABLE/DEPOSIT

5R508B
10R508B
20R508B
70R508B

5 LB. CYLINDER OF REFRIGERANT 508B


10 LB. CYLINDER OF REFRIGERANT 508B RETURNABLE/DEPOSIT
20 LB. CYLINDER OF REFRIGERANT 508B RETURNABLE/DEPOSIT
70 LB. CYLINDER OF REFRIGERANT 508B RETURNABLE/DEPOSIT

3R170
004R170
004R1150
016R600
016R600a
014R290
016RPENTANE

3 LB. CYLINDER OF R-170 (ETHANE) RETURNABLE/DEPOSIT


4 OZ. CYLINDER OF R-170 (ETHANE)
4 OZ. CYLINDER OR R-1150 (ETHYLENE)
16 OZ. CYLINDER OF R-600 (BUTANE)
16 OZ. CYLINDER OF R-600A (ISOBUTANE)
14 OZ. CYLINDER OF R-290 (PROPANE)
16 OZ. METAL CAN OF PENTANE LIQUID

ANALYTICAL TESTING
PART NO.

DESCRIPTION

NRIHPN
NRILP
NRINCN
NRIOA
NRIHALON

HIGH PRESSURE LIQUID REFRIGERANT TEST KIT


LOW PRESSURE LIQUID REFRIGERANT TEST KIT
NON-CONDENSABLE VAPOR REFRIGERANT TEST KIT
OIL ANALYSIS TEST KIT
HALON ANALYSIS

LUBRICANTS
PART NO.

DESCRIPTION

1501G
3001G
5001G
WF32
1TD
150AKB1G
200AKB1G
300AKB1G
AKB500E1G
PE321G
PE681G
VPO1G

REFRIGERATION MINERAL OIL 150 SUS / 32 ISO VISCOSITY*


REFRIGERATION MINERAL OIL 300 SUS / 68 ISO VISCOSITY*
REFRIGERATION MINERAL OIL 500 SUS / 100 ISO VISCOSITY*
WAX-FREE REFRIGERATION MINERAL OIL 150 SUS / 32 ISO VISCOSITY*
WAX-FREE REFRIGERATION MINERAL OIL 300 SUS / 68 ISO VISCOSITY*
ALKYLBENZENE OIL 150 SUS / 32 ISO VISCOSITY*
ALKYLBENZENE OIL 200 SUS / 46 ISO VISCOSITY*
ALKYLBENZENE OIL 300 SUS / 68 ISO VISCOSITY*
ALKYLBENZENE OIL 500 SUS / 100 ISO VISCOSITY*
POLYOLESTER LUBRICANT 150 SUS / 32 ISO VISCOSITY**
POLYOLESTER LUBRICANT 300 SUS / 68 ISO VISCOSITY**
VACUUM PUMP OIL 200 SUS / 46 ISO VISCOSITY**

Refrigerant Reference Guide

* Also available in 5 gallon and 55 gallon containers.


**Also available in pint, quart and 5 gallon containers

5th Edition 2010

NRI PRODUCT PART NUMBERS


SOLEST LUBRICANTS
PART NO.
SOLEST321G
SOLEST461G
SOLEST681G
SOLEST1001G
SOLEST1201G
SOLEST1501G
SOLEST1701G
SOLEST2201G
CP4214-3201G
SOLEST3701G

DESCRIPTION
POLYOLESTER LUBRICANT 150 SUS / 32 ISO VISCOSITY*
POLYOLESTER LUBRICANT 200 SUS / 46 ISO VISCOSITY*
POLYOLESTER LUBRICANT 300 SUS / 68 ISO VISCOSITY*
POLYOLESTER LUBRICANT 500 SUS / 100 ISO VISCOSITY*
POLYOLESTER LUBRICANT 600 SUS / 120 ISO VISCOSITY*
POLYOLESTER LUBRICANT 700 SUS / 150 ISO VISCOSITY*
POLYOLESTER LUBRICANT 800 SUS / 170 ISO VISCOSITY*
POLYOLESTER LUBRICANT 1000 SUS / 220 ISO VISCOSITY*
CP4214-320 LUBRICANT 1500 SUS / 320 ISO VISCOSITY*
POLYOLESTER LUBRICANT 1700 SUS / 370 ISO VISCOSITY*
*Also available in 5 gallon and 55 gallon containers.

CHEMICALS
PART NO.
N4820
N4830
N4835
N4840
N4855
N4860
N4880
N4890
NDS17OZ
NDS1G

DESCRIPTION
12 OZ SPRAY ADHESIVE
14 OZ ELECTRIC CONTACT CLEANER
20 OZ ELECTRIC MOTOR CLEANER
11 OZ FOOD GRADE SILICONE
19 OZ PENETRATING LUBRICANT
19 OZ MULTI KLEEN, AEROSOL
20 OZ BLAST KLEEN CONDENSER COIL CLEANER
19 OZ EVAP KLEEN, EVAPORATOR COIL CLEANER
17 OZ HD SOLVENT
1 GALLON HD SOLVENT

NS16OZ
NS1G
NIMC
NIMC1G

16 OZ NICKEL SAFE ICE MACHINE CLEANER


1 GALLON NICKEL SAFE ICE MACHINE CLEANER
8 OZ ICE MACHINE CLEANER
1 GALLON ICE MACHINE CLEANER

NSR1G
NSR5G

1 GALLON SCALE REMOVER


5 GALLON SCALE REMOVER

AN1GN
KB1GN
KN1GN
KF1GN
MK1GN

1 GALLON CONTAINER OF ALKA KLEEN COIL CLEANER**


1 GALLON CONTAINER OF KLEEN BRITE COIL CLEANER**
1 GALLON CONTAINER OF KLEEN COIL CLEANER**
1 GALLON CONTAINER OF KLEEN FOAM COIL CLEANER**
1 GALLON CONTAINER OF MULTI KLEEN COIL CLEANER**
**Also available in 2.5 gallon and 55 gallon containers

5PG96
55PG96
1PG70
5PG70
55PG70
5PG40
55PG40
55PG35D
PROPYL55G

5 GALLON CONTAINER OF 96% INHIBITED PROPYLENE GLYCOL


55 GALLON CONTAINER OF 96% INHIBITED PROPYLENE GLYCOL
1 GALLON CONTAINER OF 70% INHIBITED PROPYLENE GLYCOL
5 GALLON CONTAINER OF 70% INHIBITED PROPYLENE GLYCOL
55 GALLON CONTAINER OF 70% INHIBITED PROPYLENE GLYCOL
5 GALLON CONTAINER OF 40% INHIBITED PROPYLENE GLYCOL
55 GALLON CONTAINER OF 40% INHIBITED PROPYLENE GLYCOL
55 GALLON CONTAINER OF 35% INHIBITED PROPYLENE GLYCOL
55 GALLON CONTAINER OF 99.9% UNINHIBITED USP FOOD GRADE PROPYLENE GLYCOL

Refrigerant Reference Guide

5th Edition 2010

NRI PRODUCT PART NUMBERS


RECOVERY CONTAINERS
PART NO.

DESCRIPTION

DC30
100RC30
100RC40
100RC50
125RC50F
125RC50HP
200RC125
1500RC1000
4500RC2000
130RC9
150RC23
200RC80

EZ ONE SHOT DISPOSABLE RECOVERY CYLINDER


30 LB. RECOVERY CYLINDER ($100.00 DEPOSIT)
40 LB. RECOVERY CYLINDER ($100.00 DEPOSIT)
50 LB. RECOVERY CYLINDER ($100.00 DEPOSIT)
50 LB. RECOVERY CYLINDER W/FLOAT ($125.00 DEPOSIT)
50 LB. RECOVERY CYLINDER RATED 400 PSI ($125.00 DEPOSIT)
125 LB. RECOVERY CYLINDER ($200.00 DEPOSIT)
1000 LB. RECOVERY CYLINDER ($1500.00 DEPOSIT)
2000 LB. RECOVERY CYLINDER ($4500.00 DEPOSIT)
9 LB. VERY HIGH PRESSURE RECOVERY CYLINDER ($130.00 DEPOSIT)
23 LB. VERY HIGH PRESSURE RECOVERY CYLINDER ($150.00 DEPOSIT)
80 LB. VERY HIGH PRESSURE RECOVERY CYLINDER ($200.00 DEPOSIT)
Deposits subject to change

CYLINDER REFURBISHING
PART NO.

DESCRIPTION

CYLDISP
DRUMDISP
HST
125HST
240HST
1/2TONHST
TONHST
HSTR
125HSTR
240HSTR
1/2TONHSTR
TONHSTR

DISPOSAL OF EMPTY NON-REFILLABLE CYLINDER


DISPOSAL OF EMPTY NON-REFILLABLE DRUMS
HYDROSTATIC TESTING - 30 / 40 / 50 LB. CYLINDER
HYDROSTATIC TESTING - 125 LB. CYLINDER
HYDROSTATIC TESTING - 240 LB. CYLINDER
HYDROSTATIC TESTING - 1/2 TON CYLINDER
HYDROSTATIC TESTING - TON CYLINDER
REFURBISHING & HYDROSTATIC TESTING - 30 / 40/ 50 LB. CYLINDER
REFURBISHING & HYDROSTATIC TESTING - 125 LB. CYLINDER
REFURBISHING & HYDROSTATIC TESTING - 240 LB. CYLINDER
REFURBISHING & HYDROSTATIC TESTING - 1/2 TON CYLINDER
REFURBISHING & HYDROSTATIC TESTING - TON CYLINDER

Refrigerant Reference Guide

5th Edition 2010

Property Summary

Refrigerant
Name

COMPONENTS
(Weight %)

TYPE

TEMP.
GLIDE (F)

LUBRICANTS

Technical
Guidelines

COMMENTS

R-22

PURE

HCFC

Mineral Oil or
Alkylbenzene

R-23

PURE

HFC

Polyolester

R-123

PURE

HCFC

Mineral Oil or
Alkylbenzene

Low pressure centrifugal chillers.


Can retrofit R-11 equipment with
modifications.

R-124

PURE

HCFC

Mineral Oil or
Alkylbenzene

High ambient air conditioning. Can


retrofit R-114 equipment with
modifications.

R-134a

PURE

HFC

Polyolester

Medium temperature refrigeration,


chillers, automotive A/C. Can retrofit
R-12 and R-500 equipment.

R-401A

22/152a/124
(53/13/34)

HCFC
BLEND

Alkylbenzene
or MO/AB Mix

Low/medium temperature refrigeration.


Can retrofit R-12 and R-500 equipment.

R-401B

22/152a/124
(61/11/28)

HCFC
BLEND

Alkylbenzene
or MO/AB Mix

Low/medium temperature refrigeration.


Can retrofit R-12 and R-500 equipment.

R-402A

125/290/22
(60/2/38)

HCFC
BLEND

2.5

Alkylbenzene
or MO/AB Mix

Low/medium temperature refrigeration.


Can retrofit R-502 equipment.

R-402B

125/290/22
(38/2/60)

HCFC
BLEND

2.5

Alkylbenzene
or MO/AB Mix

R-403B

290/22/218
(5/56/39)

HCFC
BLEND

Mineral Oil or
Alkylbenzene

R-404A

125/143a/134a
(44/52/4)

HFC
BLEND

1.5

Polyolester

Refrigerant Reference Guide

Refrigeration systems, commercial


refrigeration, air conditioning, chillers.
Very low temperature refrigeration.
Properties similar to R-13; can also
retrofit R-503.

Ice machines. Can retrofit R-502


equipment.
Has been used successfully to retrofit
R-13B1-type equipment, but has slightly
different operating conditions.
Low/medium temperature refrigeration.
Can retrofit R-502 or R-22 equipment
with modifications.

5th Edition 2010

Property Summary
TEMP.
GLIDE (F) LUBRICANTS

Technical
Guidelines

Refrigerant
Name

COMPONENTS
(Weight %)

TYPE

R-407A

32/125/134a
(20/40/40)

HFC
BLEND

10

Polyolester or
POE/MO Mix

Low/medium temperature refrigeration.


Can retrofit R-22 equipment.

R-407C

32/125/134a
(23/25/52)

HFC
BLEND

10

Polyolester or
POE/MO Mix

Low/medium temperature refrigeration,


air conditioning. Can retrofit R-22
equipment.

R-408A

125/143a/22
(7/46/47)

HCFC
BLEND

Mineral Oil or
Alkylbenzene

Low/medium temperature refrigeration.


Can retrofit R-502 equipment.

R-409A

22/124/142b
(60/25/15)

HCFC
BLEND

13

Mineral Oil or
Alkylbenzene

Low/medium temperature refrigeration,


some A/C. Can retrofit R-12 or R-500
equipment.

R-410A

32/125
(50/50)

HFC
BLEND

0.2

Polyolester

New residential A/C systems. Not for


retrofitting.

R-414B

22/124/600a/142b
(50/39/1.5/9.5)

HCFC
BLEND

13

Mineral Oil or
Alkylbenzene

Low/medium temperature refrigeration,


some A/C, automotive A/C. Can retrofit
R-12 equipment.

R-416A

134a/124/600
(59/39.5/1.5)

HCFC
BLEND

Mineral Oil,
Alkylbenzene or
Polyolester

Medium temperature refrigeration,


automotive A/C. Can retrofit R-12
equipment.

R-422B

125/134a/600a
(55/42/3)

Mineral Oil,
Alkylbenzene or
Polyolester

Medium temperature refrigeration,


air conditioning. Can retrofit R-22
equipment.

HFC
BLEND

COMMENTS

R-422C

125/134a/600a
(82/15/3)

HFC
BLEND

Mineral Oil,
Alkylbenzene or
Polyolester

R-422D

125/134a/600a
(65.1/13.5/3.4)

HFC
BLEND

Mineral Oil,
Alkylbenzene or
Polyolester

Low/medium temperature refrigeration.


Can retrofit R-22 equipment.

R-507

125/143a
(50/50)

HFC
BLEND

Polyolester

Low/medium temperature refrigeration.


Can retrofit R-502 or R-22 equipment
with modifications.

R-508B

23/116
(46/54)

HFC
BLEND

Refrigerant Reference Guide

Polyolester

Low/medium temperature refrigeration.


Can retrofit R-502 and R-22 equipment,
with modifications.

Very low temperature refrigeration.


Can retrofit R-13 or R-503 equipment.

5th Edition 2010

Application Summary
ASHRAE #

COMPONENTS
(WEIGHT %)

CHARGING
(% ORIGINAL)

Technical
Guidelines

APPLICATION COMMENTS

Low-Medium Temperature Refrigeration (R-502 type)


R-402A

125/290/22
(60/2/38)

95 -100%

R-402B

125/290/22
(38/2/60)

95 -100%

R-404A

125/143a/134a
(44/52/4)

85 - 90%

R-408A

125/143a/22
(7/46/47)

85 - 90%

R-422C

125/134a/600a
(82/15/3)

95 -100%

125/143a
(50/50)

85 - 90%

R-507

Overall Concerns:
Discharge temperature is important - cant tolerate large increase. Higher discharge
pressure can affect controls. If oil return is not already a problem with R-502, the blends
will not necessarily make things worse. HFC blends will need POE. Most of the blends
have very low glide.
Retrofit Recommendations (in order of preference based on performance/ease of use):
R-408A Closest match to R-502 properties and performance. Slightly higher discharge
temperature
R-402A Higher discharge pressure, lower discharge temperature than R-408A
R-402B Similar discharge pressure, higher discharge temperature. Good for ice
machines. ***R-408A, R-402A and R-402B might have problems with oil
circulation and will benefit from at least a partial change to alkylbenzene.
They are also HCFC-based and are subject to leak repair regulations.***
R-422C Similar in pressure/temperature to R-502, but will show some loss in capacity.
Hydrocarbon components in the blend will promote mineral oil circulation in
some systems. Addition of POE may be required in larger systems for proper
oil return.
R-404A & R-507
Can be used to retrofit R-502 but mineral oil must be flushed with POE.
Options in New Equipment
R-407A Being used in some supermarkets as a lower GWP option.
R-404A & R-507
Off the shelf equipment (standard design). These two are interchangeable
with each other in new equipment.

Low-Medium Temperature Refrigeration (R-22 type)


R-404A

125/143a/134a
(44/52/4)

85 - 90%

R-407A

32/125/134a
(20/40/40)

95 -100%

R-407C

32/125/134a
(23/25/52)

95 -100%

R-422B

125/134a/600a
(55/42/3)

95 -100%

R-422C

125/134a/600a
(82/15/3)

95 -100%

R-422D

125/134a/600a
(65.1/31.5/3.4)

95 -100%

125/143a
(50/50)

85 - 90%

R-507

Refrigerant Reference Guide

Overall Concerns:
Capacity match to R-22 is important in capacity-critical applications. Storage
applications can tolerate a loss of capacity traded off for longer run times. TXV
operation and distributor capacity should be close to R-22 to avoid costly component
changes. All retrofit blends will operate at lower discharge temperatures than R-22.
Retrofit Recommendations (in order of preference based on performance/ease of use):
R-407A Similar capacity and TXV/distributor/pressure drop performance.
R-407C Slightly lower capacity, similar TXV/distributor/pressure drop performance.
R-407A and R-407C will require a change from mineral oil to POE for proper
oil circulation. Partial POE replacement of mineral should work in most
systems.
R-422D Lower capacity, change in TXV/distributor/pressure drop performance.
R-422B Significant drop in capacity at lower temperatures, change in TXV/distributor/
pressure drop.
R-422C Higher capacity, TXV change. Similar to R-404A. All R-422 blends contain a
hydrocarbon that will promote mineral oil circulation in some systems.
Addition of POE may be required in larger systems for proper oil return.
R-404A & R-507
Can be used to retrofit, however mineral oil must be flushed, POE used
instead, and system components (TXVs, etc.) will need to be changed.
Options in New Equipment
R-407A Being used in some supermarkets as a lower GWP option.
R-404A & R-507
Off the shelf equipment (standard design). These two are interchangeable with each other in new equipment.

5th Edition 2010

Application Summary
ASHRAE #

COMPONENTS CHARGING
(WEIGHT %) (% ORIGINAL)

Technical
Guidelines

APPLICATION COMMENTS

Low-MediumTemperature Refrigeration (R-12 type)


R-134a

PURE

90%

R-401A

22/152a/124
(53/13/34)

80 - 85%

R-401B

22/152a/124
(61/11/28)

80 - 85%

R-409A

22/124/142b
(60/25/15)

80 - 85%

Overall Concerns:
Match R-12 evaporator conditions (slightly higher discharge pressures OK).
Oil return must be addressed. Temperature glide not a problem in most applications.
Retrofit Recommendations (in order of preference based on performance/ease of use):
R-409A Better at lower temperatures, maintains performance, higher discharge
temperature and pressure.
R-414B Better at warmer temperatures, lower discharge temperature than R-409A.
R-401A Good overall performance, need AB oil below 30F coil temperatures.
R-401B Better at lower temperatures, needs AB oil to replace 50% mineral oil.
R-416A Biggest change in properties, poor low temperature performance.

Medium-High Temperature Refrigeration (R-12 type), Automotive Air Conditioning


R-414B

22/124/600a/142b
(50/39/1.5/9.5)

80-85%

R-416A

134a/124/600
(59/39.5/1.5)

95 -100%

Overall Concerns:
At higher evaporator temperatures, blends that contain R-22 will cause higher discharge
temperatures. R-414B contains less R-22 and R-416A is based on R-134a. These products
will produce lower discharge temperatures, but they will also lose some capacity
compared to the other R-12 retrofit products listed above.
Retrofit Recommendations (in order of preference based on performance/ease of use):
R-414B, R-416A
Only these two products are approved for automotive A/C retrofit.
R-401A, R-401B, R-409A
For R-12 or R-500 air conditioning (direct expansion systems).

Air Conditioning (R-22 type)


R-407C

32/125/134a
(23/25/52)

95 -100%

R-410A

32/125
(50/50)

New Equip.
only

R-422B

125/134a/600a
(55/42/3)

9 5-100%

R-422D

125/134a/600a
(65.1/31.5/3.4)

95 -100%

Overall Concerns:
Keep component changes to a minimum (similar TXV or orifice size, minimize pressure
drop), maintain capacity unless the system is oversized enough to handle a drop in
capacity.
Retrofit Recommendations (in order of preference based on performance/ease of use):
R-407C Lowest GWP, similar capacity and component operation (TXV/orifice).
R-422B or R-422D
Slight drop in capacity, possible change of components based on pressure
drop. Hydrocarbon components in the blends will promote mineral oil
circulation in some systems. Addition of POE may be required in larger systems
for proper oil return.
New equipment is designed around R-410A. Higher pressure and capacity exclude
R-410A from being used as a retrofit blend.

High Ambient and Centrifugal Chillers


R-124

PURE

N/A

R-123

PURE

N/A

Existing R-114 high ambient A/C systems can be modified to use R-124. New
systems are available with R-134a. Centrifugal chillers require major equipment
upgrades to retrofit to another refrigerant. Chiller manufacturers will need to be
consulted for such jobs.

Very Low Temperature and Cascade Refrigeration (R-13 and R-503 type)
PURE

95%

R-508B

23/116
(46/54)

R-13: 105-110%
R-503: 90-95%

R-403B

290/22/218
(5/26/39)

R-23

R-13 systems can be retrofitted to R-23 or R-508B. R-23 will have similar run-time
properties to R-13 but there will be higher discharge temperatures. R-503 systems
should use R-508B
R-403B has been successfully used in R-13B1 systems but the evaporator will likely
run under vacuum conditions.

70 - 75%

Refrigerant Reference Guide

10

5th Edition 2010

R-11 and R-12


Physical Properties of Refrigerants

R-11

R-12

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating

CFC
137.4
74.7
639.3
388
34.6
92.73
0.365
77.9
0.2093
0.1444 (sat)
1.0
4750
A1

CFC
120.9
-21.6
600
233.5
35.3
82.96
0.393
71.2
0.2324
0.1455
1.0
10910
A1

Technical
Guidelines
Available in the
following sizes
R-11
100 LB DRUM
200 LB. DRUM
R-12
30 LB. CYLINDER
145 LB. CYLINDER

Pressure-Temp Chart
R-11
psig

R-11
Application:

Large low pressure centrifugal chillers

Lubricant
Recommendation: Compatible with mineral oil
Retrofitting:

R-123 is being successfully used to retrofit


R-11 chillers
Retrofit jobs are usually done in cooperation
with equipment manufacturers

R-12
Application:

Large centrifugal chillers, open drive A/C,


process cooling, high-medium-low temperature
refrigeration (large and small systems)

Lubricant
Recommendation: Compatible with mineral oil
Retrofitting to:

R-134a
R-401A, R-401B
R-409A
R-414B
R-416A

Refrigerant Reference Guide

page
page
page
page
page

90, 91
90, 92
90, 92
90, 92
90, 93

11

27.0
26.5
26.0
25.4
24.7
23..9
23.1
22.1
21.1
19.9
18.6
17.2
15.6
13.9
12.0
10.0
7.8
5.4
2.8
0.0
1.5
3.2
4.9
6.8
8.8
10.9
13.2
15.6
18.2
21.0
24.0
27.1
30.4
34.0
37.7

Temp
(F)
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150

R-12
psig
11.0
8.4
5.5
2.3
0.6
2.4
4.5
6.7
9.2
11.8
14.6
17.7
21.0
24.6
28.5
32.6
37.0
41.7
46.7
52.0
57.7
63.8
70.2
77.0
84.2
91.8
99.8
108
117
127
136
147
158
169
181
194
207
220
234

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-11
[F]

Pressure
Liquid
[psia]

Density
Liquid
[lb/ft3]

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

Entropy
Liquid
[Btu/R-lb]

Entropy
Vapor
[Btu/R-lb]

30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155
160
165
170
175
180
185
190
195
200
205
210
215
220
225
230
235
240

5.6
6.3
7.0
7.9
8.8
9.8
10.9
12.1
13.4
14.8
16.3
17.9
19.7
21.6
23.6
25.7
28.1
30.5
33.2
36.0
38.9
42.1
45.4
49.0
52.8
56.7
60.9
65.3
70.0
74.9
80.0
85.4
91.1
97.1
103.3
109.8
116.7
123.8
131.3
139.1
147.2
155.6
164.5

95.93
95.54
95.14
94.75
94.35
93.95
93.55
93.14
92.73
92.32
91.91
91.50
91.08
90.66
90.23
89.81
89.38
88.94
88.51
88.07
87.62
87.17
86.72
86.26
85.80
85.33
84.86
84.39
83.91
83.42
82.93
82.43
81.93
81.42
80.90
80.38
79.85
79.31
78.76
78.21
77.65
77.08
76.50

0.1481
0.1654
0.1842
0.2047
0.2269
0.2509
0.2769
0.3049
0.3351
0.3676
0.4024
0.4397
0.4797
0.5224
0.5680
0.6167
0.6684
0.7235
0.7820
0.8442
0.910
0.980
1.054
1.132
1.215
1.302
1.394
1.492
1.594
1.702
1.816
1.936
2.062
2.195
2.335
2.482
2.636
2.799
2.970
3.149
3.338
3.536
3.745

14.14
15.16
16.19
17.23
18.26
19.30
20.34
21.39
22.44
23.49
24.54
25.60
26.66
27.73
28.80
29.87
30.94
32.02
33.11
34.20
35.29
36.39
37.49
38.59
39.70
40.82
41.94
43.06
44.19
45.33
46.47
47.62
48.77
49.93
51.09
52.26
53.44
54.62
55.82
57.01
58.22
59.43
60.65

95.94
96.56
97.17
97.79
98.41
99.02
99.64
100.3
100.9
101.5
102.1
102.7
103.3
103.9
104.5
105.1
105.7
106.3
106.9
107.5
108.1
108.7
109.3
109.9
110.5
111.0
111.6
112.2
112.7
113.3
113.8
114.4
114.9
115.4
116.0
116.5
117.0
117.5
118.0
118.5
118.9
119.4
119.8

0.03112
0.03321
0.03528
0.03733
0.03937
0.04139
0.0434
0.0454
0.04738
0.04935
0.05131
0.05326
0.05519
0.05711
0.05902
0.06092
0.06281
0.06469
0.06656
0.06842
0.07027
0.07211
0.07394
0.07576
0.07758
0.07939
0.08119
0.08298
0.08476
0.08654
0.08832
0.09008
0.09184
0.09360
0.09535
0.09710
0.09884
0.1006
0.1023
0.1040
0.1058
0.1075
0.1092

0.1982
0.1977
0.1973
0.197
0.1966
0.1963
0.196
0.1957
0.1955
0.1952
0.1950
0.1948
0.1946
0.1945
0.1943
0.1942
0.1941
0.1940
0.1939
0.1939
0.1938
0.1937
0.1937
0.1937
0.1936
0.1936
0.1936
0.1936
0.1936
0.1936
0.1936
0.1936
0.1936
0.1937
0.1937
0.1937
0.1937
0.1937
0.1938
0.1938
0.1938
0.1938
0.1938

Temp

Refrigerant Reference Guide

12

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-12
[F]

Pressure
Liquid
[psia]

Density
Liquid
[lb/ft3]

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

Entropy
Liquid
[Btu/R-lb]

Entropy
Vapor
[Btu/R-lb]

-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155
160

5.4
6.2
7.1
8.1
9.3
10.6
12.0
13.5
15.2
17.1
19.2
21.4
23.8
26.4
29.3
32.4
35.7
39.3
43.1
47.2
51.6
56.3
61.3
66.6
72.3
78.4
84.8
91.5
98.7
106.3
114.3
122.7
131.6
141.0
150.8
161.1
172.0
183.3
195.2
207.7
220.7
234.4
248.6
263.5
279.0

96.63
96.14
95.66
95.17
94.68
94.18
93.68
93.18
92.67
92.16
91.65
91.13
90.61
90.08
89.55
89.02
88.48
87.93
87.38
86.82
86.25
85.68
85.10
84.52
83.92
83.32
82.71
82.09
81.47
80.83
80.18
79.52
78.85
78.16
77.46
76.75
76.02
75.28
74.51
73.73
72.93
72.10
71.24
70.36
69.45

0.1537
0.1756
0.1999
0.2268
0.2565
0.289
0.3247
0.3637
0.4063
0.4525
0.5028
0.5573
0.6162
0.6798
0.7483
0.8221
0.9013
0.9864
1.078
1.175
1.279
1.391
1.510
1.637
1.772
1.915
2.068
2.231
2.404
2.588
2.783
2.991
3.211
3.445
3.694
3.958
4.238
4.537
4.855
5.193
5.554
5.939
6.351
6.792
7.265

-4.145
-3.115
-2.081
-1.043
0.000
1.047
2.098
3.154
4.214
5.280
6.350
7.425
8.505
9.591
10.68
11.78
12.88
13.99
15.10
16.22
17.35
18.48
19.62
20.77
21.92
23.08
24.25
25.43
26.61
27.80
29.01
30.22
31.44
32.67
33.91
35.16
36.43
37.70
38.99
40.30
41.61
42.95
44.30
45.67
47.06

70.99
71.56
72.13
72.70
73.27
73.84
74.41
74.98
75.55
76.11
76.68
77.24
77.80
78.35
78.90
79.45
80.00
80.54
81.07
81.61
82.13
82.65
83.17
83.68
84.18
84.67
85.16
85.64
86.11
86.58
87.03
87.47
87.90
88.32
88.73
89.12
89.50
89.87
90.22
90.55
90.86
91.15
91.42
91.66
91.87

-0.01010
-0.00754
-0.00501
-0.00249
0.00000
0.00247
0.00493
0.00736
0.00978
0.01218
0.01457
0.01693
0.01929
0.02162
0.02395
0.02625
0.02855
0.03083
0.03310
0.03536
0.03761
0.03984
0.04207
0.04428
0.04649
0.04869
0.05088
0.05306
0.05524
0.05740
0.05957
0.06173
0.06388
0.06603
0.06818
0.07032
0.07247
0.07461
0.07676
0.07890
0.08106
0.08321
0.08538
0.08755
0.08973

0.1779
0.1770
0.1761
0.1753
0.1746
0.1739
0.1732
0.1726
0.1720
0.1715
0.1710
0.1705
0.1700
0.1696
0.1692
0.1688
0.1685
0.1681
0.1678
0.1675
0.1673
0.1670
0.1668
0.1665
0.1663
0.1661
0.1659
0.1657
0.1655
0.1653
0.1651
0.1649
0.1648
0.1646
0.1644
0.1642
0.1640
0.1638
0.1636
0.1634
0.1632
0.1629
0.1627
0.1624
0.1621

Temp

Refrigerant Reference Guide

13

5th Edition 2010

Technical
Guidelines

R-13
Physical Properties of Refrigerants

R-13

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (20 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (20 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 20 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating

CFC
104.5
-114.3
567.8
84.6
35.9
72.7
0.4332
64.35
0.2121
0.1451
1.0
14400
A1

Available in the
following sizes
R-13
5 LB. CYLINDER
9 LB. CYLINDER
23 LB. CYLINDER
80 LB. CYLINDER

Pressure-Temp Chart

R-13
Applications:

Very low temperature refrigeration

Performance:

Operates in the low temperature stage of the


cascade system because of its low boiling point

Lubricant
Recommendation: Compatible with mineral oil
Retrofitting to:

R-23
R-508B

page 101
page 101

See Ultra-Low Temperature Refrigeration Section - Pages 64 - 65

Refrigerant Reference Guide

14

Temp
(F)

R-13
(psig)

-120
-115
-110
-105
-100
-95
-90
-85
-80
-75
-70
-65
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40

4.5
0.3
2.1
4.7
7.6
10.8
14.3
18.2
22.5
27.2
32.3
37.8
43.9
50.4
57.5
65.1
73.3
82.1
91.6
102
113
122
136
149
163
177
193
209
226
244
264
284
305

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-13
[F]

Pressure
Liquid
[psia]

Density
Liquid
[lb/ft3]

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

Entropy
Liquid
[Btu/R-lb]

Entropy
Vapor
[Btu/R-lb]

-140
-135
-130
-125
-120
-115
-110
-105
-100
-95
-90
-85
-80
-75
-70
-65
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40

6.4
7.7
9.1
10.7
12.5
14.5
16.8
19.3
22.2
25.4
28.9
32.7
37.0
41.6
46.7
52.2
58.2
64.7
71.7
79.3
87.4
96.2
105.6
115.6
126.4
137.8
150.0
163.0
176.7
191.3
206.8
223.1
240.4
258.6
277.9
298.2
319.5

98.20
97.56
96.92
96.27
95.62
94.96
94.30
93.63
92.95
92.27
91.58
90.87
90.17
89.45
88.72
87.98
87.23
86.46
85.69
84.90
84.10
83.27
82.44
81.58
80.71
79.81
78.89
77.94
76.96
75.96
74.91
73.83
72.71
71.54
70.31
69.01
67.64

0.2008
0.2359
0.2756
0.3204
0.3707
0.4269
0.4894
0.5588
0.6356
0.7203
0.8135
0.9158
1.028
1.150
1.283
1.428
1.586
1.757
1.942
2.143
2.360
2.594
2.848
3.121
3.416
3.735
4.078
4.450
4.851
5.286
5.756
6.267
6.823
7.430
8.094
8.824
9.632

-21.91
-20.89
-19.86
-18.82
-17.78
-16.73
-15.67
-14.61
-13.54
-12.46
-11.37
-10.28
-9.173
-8.061
-6.939
-5.809
-4.668
-3.517
-2.356
-1.184
0.000
1.196
2.405
3.627
4.863
6.114
7.381
8.666
9.968
11.29
12.63
14.00
15.39
16.81
18.27
19.76
21.29

45.08
45.58
46.08
46.57
47.06
47.55
48.03
48.51
48.98
49.45
49.91
50.37
50.82
51.26
51.70
52.12
52.54
52.95
53.34
53.73
54.11
54.47
54.82
55.15
55.47
55.77
56.06
56.32
56.57
56.79
56.98
57.15
57.28
57.38
57.43
57.44
57.39

-0.059
-0.05582
-0.05268
-0.04957
-0.04649
-0.04343
-0.04040
-0.03739
-0.03441
-0.03145
-0.02851
-0.02559
-0.02269
-0.01980
-0.01693
-0.01408
-0.01124
-0.00841
-0.00560
-0.00280
0.00000
0.00279
0.00557
0.00834
0.01111
0.01388
0.01665
0.01943
0.02220
0.02499
0.02778
0.03059
0.03342
0.03627
0.03915
0.04206
0.04503

0.1506
0.1489
0.1473
0.1458
0.1444
0.1430
0.1418
0.1406
0.1394
0.1383
0.1373
0.1363
0.1353
0.1344
0.1335
0.1327
0.1319
0.1311
0.1304
0.1296
0.1289
0.1282
0.1276
0.1269
0.1262
0.1256
0.1249
0.1242
0.1236
0.1229
0.1222
0.1215
0.1207
0.1200
0.1191
0.1182
0.1173

Temp

Refrigerant Reference Guide

15

5th Edition 2010

Technical
Guidelines

R-22
Physical Properties of Refrigerants

R-22

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating

HCFC
86.5
-41.5
723.7
205.1
32.7
75.3
0.294
100.5
0.2967
0.1573
0.05
1810
A1

R-22
Applications:

Medium and low temperature commercial and


industrial refrigeration and air conditioning

Lubricant
Recommendation: Compatible with mineral, alkylbenzene
and polyolester lubricant

Retrofitting to:

R-407A or R-407C
R-422B
R-422C
R-422D
R-404A or R-507

Refrigerant Reference Guide

page
page
page
page
page

94
95
96
95
96

16

Available in the
following sizes
R-22
30 LB. CYLINDER
50 LB. CYLINDER
125 LB. CYLINDER
1000 LB. CYLINDER
1750 LB. CYLINDER

Pressure-Temp Chart
Temp
(F)

R-22
psig

-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150

0.5
2.6
4.9
7.4
10.1
13.2
16.5
20.1
24.0
28.2
32.8
37.7
43.0
48.8
54.9
61.5
68.5
76.0
84.0
92.6
102
111
121
132
144
156
168
182
196
211
226
243
260
278
297
317
337
359
382

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-22
Temp
[F]
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155
160

Pressure
Liquid
[psia]
8.8
10.2
11.7
13.4
15.3
17.3
19.6
22.1
24.9
27.9
31.2
34.8
38.7
43.0
47.5
52.5
57.8
63.5
69.7
76.2
83.3
90.8
98.8
107.3
116.3
125.9
136.1
146.9
158.3
170.4
183.1
196.5
210.6
225.5
241.1
257.5
274.7
292.7
311.6
331.4
352.1
373.7
396.4
420.0
444.7

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
89.82
89.33
88.83
88.33
87.82
87.32
86.80
86.29
85.76
85.24
84.71
84.17
83.63
83.08
82.52
81.96
81.39
80.82
80.24
79.65
79.05
78.44
77.83
77.20
76.57
75.92
75.27
74.60
73.92
73.23
72.52
71.80
71.06
70.30
69.52
68.72
67.90
67.05
66.18
65.27
64.32
63.34
62.31
61.22
60.07

Enthalpy
Liquid
[Btu/lb]
-5.189
-3.897
-2.602
-1.303
0.000
1.308
2.620
3.937
5.260
6.588
7.923
9.263
10.61
11.96
13.33
14.69
16.07
17.46
18.85
20.25
21.66
23.08
24.51
25.96
27.41
28.87
30.35
31.84
33.34
34.86
36.39
37.94
39.50
41.08
42.69
44.31
45.95
47.62
49.32
51.04
52.80
54.59
56.42
58.31
60.24

Density
Vapor
[lb/ft3]
0.1827
0.2087
0.2374
0.2692
0.3042
0.3427
0.3849
0.4310
0.4813
0.5360
0.5955
0.6600
0.7299
0.8054
0.8868
0.9746
1.069
1.171
1.280
1.396
1.522
1.656
1.799
1.952
2.116
2.291
2.478
2.678
2.891
3.118
3.361
3.620
3.897
4.193
4.510
4.849
5.213
5.604
6.024
6.477
6.966
7.497
8.075
8.706
9.400

17

Enthalpy
Vapor
[Btu/lb]
98.09
98.66
99.22
99.79
100.3
100.9
101.4
102.0
102.5
103.0
103.6
104.1
104.6
105.1
105.6
106.1
106.5
107.0
107.4
107.9
108.3
108.7
109.1
109.5
109.9
110.3
110.6
110.9
111.2
111.5
111.8
112.0
112.3
112.5
112.7
112.8
112.9
113.0
113.0
113.0
113.0
112.9
112.8
112.5
112.2

Entropy
Liquid
[Btu/R-lb]
-0.01264
-0.00943
-0.00626
-0.00311
0.00000
0.00309
0.00615
0.00918
0.01220
0.01519
0.01815
0.02110
0.02403
0.02694
0.02983
0.03270
0.03556
0.03841
0.04124
0.04406
0.04686
0.04966
0.05244
0.05522
0.05798
0.06074
0.06350
0.06625
0.06899
0.07173
0.07447
0.07721
0.07996
0.08270
0.08545
0.08821
0.09098
0.09376
0.09656
0.09937
0.1022
0.1051
0.1080
0.1110
0.1140

Entropy
Vapor
[Btu/R-lb]
0.2458
0.2440
0.2423
0.2407
0.2391
0.2376
0.2361
0.2348
0.2334
0.2321
0.2309
0.2296
0.2285
0.2273
0.2263
0.2252
0.2242
0.2231
0.2222
0.2212
0.2203
0.2194
0.2185
0.2176
0.2167
0.2159
0.2150
0.2142
0.2133
0.2125
0.2117
0.2108
0.2100
0.2091
0.2083
0.2074
0.2065
0.2056
0.2046
0.2036
0.2026
0.2015
0.2004
0.1992
0.1979

5th Edition 2010

Technical
Guidelines

R-23
Physical Properties of Refrigerants

R-23

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (20 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (20 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 20 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating

HFC
70
-115.6
701.4
78.7
32.8
67.46
0.29
102.7
0.4063
0.1663
0
14800
A1

Available in the
following sizes
R-23
5 LB. CYLINDER
9 LB. CYLINDER
20 LB. CYLINDER
70 LB. CYLINDER

Pressure-Temp Chart

R-23
Applications:

Very low temperature refrigeration

Performance:

Operates in the low temperature stage of a cascade system

Lubricant
Recommendation: Compatible with polyolester lubricant
Retrofitting:

Replacement for R-13

page 101

See Ultra-Low Temperature Refrigeration Section - page 64-65

Refrigerant Reference Guide

18

Temp
(F)

R-23
psig

-125
-120
-115
-110
-105
-100
-95
-90
-85
-80
-75
-70
-65
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20

7.8
4.0
0.3
2.9
5.8
9.0
12.7
16.7
21.3
26.3
31.8
37.9
44.6
52.0
60.0
68.7
78.1
88.3
99.4
111
124
138
152
168
185
203
222
242
264
287

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-23
[F]

Pressure
Liquid
[psia]

Density
Liquid
[lb/ft3]

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

Entropy
Liquid
[Btu/R-lb]

Entropy
Vapor
[Btu/R-lb]

-140
-135
-130
-125
-120
-115
-110
-105
-100
-95
-90
-85
-80
-75
-70
-65
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40

6.3
7.6
9.1
10.8
12.8
15.1
17.6
20.6
23.8
27.5
31.6
36.1
41.2
46.7
52.9
59.6
67.0
75.0
83.7
93.2
103.5
114.6
126.6
139.5
153.3
168.1
184.0
201.0
219.1
238.4
258.9
280.8
303.9
328.5
354.6
382.1
411.3

92.72
92.20
91.66
91.12
90.57
90.00
89.43
88.84
88.24
87.63
87.00
86.36
85.70
85.03
84.35
83.64
82.93
82.19
81.43
80.66
79.86
79.04
78.20
77.34
76.44
85.52
74.57
73.58
72.55
71.49
70.38
69.22
68.00
66.72
65.36
63.92
62.36

0.1312
0.1562
0.1850
0.2178
0.2550
0.2972
0.3446
0.3978
0.4572
0.5234
0.5970
0.6784
0.7684
0.8675
0.9765
1.096
1.227
1.370
1.527
1.698
1.884
2.087
2.307
2.547
2.808
3.092
3.402
3.739
4.106
4.508
4.948
5.431
5.963
6.551
7.206
7.940
8.769

-30.60
-29.15
-27.70
-26.25
-24.78
-23.31
-21.84
-20.35
-18.86
-17.35
-15.84
-14.32
-12.78
-11.23
-9.671
-8.097
-6.509
-4.906
-3.288
-1.653
0.000
1.671
3.361
5.072
6.806
8.563
10.34
12.15
13.99
15.87
17.77
19.72
21.71
23.76
25.86
28.03
30.28

77.43
77.98
78.52
79.05
79.58
80.09
80.59
81.09
81.56
82.03
82.48
82.92
83.34
83.75
84.14
84.51
84.86
85.19
85.50
85.79
86.06
86.30
86.52
86.70
86.86
86.98
87.06
87.11
87.11
87.07
86.97
86.81
86.59
86.28
85.89
85.39
84.75

-0.08247
-0.07799
-0.07356
-0.06919
-0.06486
-0.06058
-0.05634
-0.05214
-0.04798
-0.04385
-0.03975
-0.03568
-0.03163
-0.02762
-0.02362
-0.01964
-0.01569
-0.01175
-0.00782
-0.00390
0.00000
0.00390
0.00779
0.01168
0.01556
0.01946
0.02335
0.02726
0.03119
0.03513
0.03910
0.04310
0.04715
0.05124
0.05541
0.05966
0.06402

0.2555
0.2520
0.2486
0.2455
0.2424
0.2394
0.2366
0.2339
0.2312
0.2287
0.2262
0.2238
0.2215
0.2193
0.2171
0.2150
0.2129
0.2109
0.2089
0.2070
0.2051
0.2032
0.2013
0.1995
0.1976
0.1958
0.1940
0.1921
0.1903
0.1884
0.1864
0.1844
0.1824
0.1802
0.1780
0.1756
0.1730

Temp

Refrigerant Reference Guide

19

5th Edition 2010

R-123 and R-124


Physical Properties of Refrigerants

R-123

R-124

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating

HCFC
152.9
82.1
531.1
362.6
34.3
91.95
0.404
73.2
0.2329
0.1645(sat)
0.0015
77
B1

HCFC
136.5
10.3
527.1
252.5
34.6
85.5
0.419
70.6
0.265
0.1762
0.03
609
A1

R-123
Replaces:

R-11

Applications:

Large low presure centrifugal chillers

Performance:

May require replacement seals, gaskets and other


components to obtain the correct operating
conditions and prevent leakage

Lubricant
Recommendation: Compatible with mineral and alkylbenzene oil
Retrofitting:

Consult equipment manufacturer to retrofit


R-11 chiller to R-123

R-124
Replaces:

R-114

Applications:

High ambient air conditioning

Performance:

Slightly higher pressures and slightly lower


capacity when used in an R-114 system

Lubricant
Recommendation: Compatible with mineral oil and alkylbenzene oil
Retrofitting:

Technical
Guidelines
Available in the
following sizes
R-123
100 LB DRUM
200 LB. DRUM
650 LB. DRUM
R-124
30 LB. CYLINDER
145 LB. CYLINDER

Pressure-Temp Chart
R-123
psig

Temp
(F)

R-124
psig

27.8
27.4
26.9
26.4
25.9
25.2
24..5
23.8
22.8
21.8
20.7
19.5
18.1
16.6
14.9
13.0
11.2
8.9
6.5
4.1
1.2
0.9
2.5
4.3
6.1
8.1
10.3
12.6
15.1
17.8
20.6
23.6
26.8
30.2
33.9

-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150

16.1
14.1
12.0
9.6
6.9
3.9
0.6
1.6
3.5
5.7
8.1
10.5
13.2
16.1
19.2
22.6
26.3
30.2
34.4
38.9
43.7
48.8
54.2
60.0
66.1
72.6
79.5
86.8
94.5
103
111
120
130
140
150

Consult equipment manufacturers guidelines

Refrigerant Reference Guide

20

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-123
Temp
[F]
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155
160
165
170
175
180
185
190
195
200

Pressure
Liquid
[psia]
1.0
1.2
1.4
1.7
2.0
2.3
2.6
3.0
3.5
4.0
4.5
5.1
5.8
6.5
7.3
8.2
9.2
10.3
11.4
12.7
14.1
15.6
17.2
18.9
20.8
22.8
25.0
27.3
29.8
32.4
35.3
38.3
41.5
44.9
48.5
52.3
56.4
60.7
65.2
70.0
75.0
80.3
85.9
91.7
97.9

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
99.54
99.14
98.73
98.33
97.92
97.51
97.10
96.69
96.28
95.86
95.44
95.02
94.60
94.17
93.74
93.31
92.88
92.44
92.01
91.56
91.12
90.67
90.22
89.77
89.31
88.85
88.39
87.92
87.45
86.98
86.50
86.01
85.52
85.03
84.53
84.03
83.52
83.01
82.49
81.96
81.43
80.89
80.34
79.79
79.23

Density
Vapor
[lb/ft3]
0.03413
0.03978
0.04618
0.05339
0.06149
0.07055
0.08067
0.09192
0.1044
0.1182
0.1334
0.1502
0.1686
0.1887
0.2106
0.2346
0.2606
0.2889
0.3195
0.3526
0.3883
0.4268
0.4682
0.5128
0.5605
0.6117
0.6664
0.7249
0.7874
0.8540
0.9249
1.000
1.081
1.166
1.256
1.353
1.454
1.562
1.676
1.797
1.925
2.060
2.203
2.354
2.513

Enthalpy Enthalpy
Vapor
Liquid
[Btu/lb]
[Btu/lb]
87.35
4.558
88.05
5.706
88.75
6.857
89.46
8.012
90.16
9.170
90.87
10.33
91.58
11.50
92.29
12.67
93.01
13.84
93.72
15.02
94.44
16.20
95.16
17.38
95.88
18.57
96.60
19.76
97.32
20.96
98.04
22.16
98.76
23.36
99.48
24.57
100.2
25.78
100.9
27.00
101.6
28.22
102.4
29.44
103.1
30.67
103.8
31.90
104.5
33.14
105.2
34.38
106.0
35.63
106.7
36.88
107.4
38.13
108.1
39.39
108.8
40.66
109.5
41.93
110.2
43.20
110.9
44.48
111.6
45.76
112.3
47.05
113.0
48.35
113.7
49.65
114.3
50.95
115.0
52.27
115.7
53.58
116.3
54.91
117.0
56.24
117.7
57.57
118.3
58.92

21

Entropy
Liquid
[Btu/R-lb]
0.01061
0.01320
0.01578
0.01833
0.02086
0.02337
0.02587
0.02834
0.03080
0.03324
0.03566
0.03806
0.04045
0.04282
0.04518
0.04752
0.04984
0.05215
0.05444
0.05673
0.05899
0.06124
0.06348
0.06571
0.06792
0.07012
0.07231
0.07449
0.07665
0.07881
0.08095
0.08308
0.08520
0.08732
0.08942
0.09151
0.09359
0.09567
0.09773
0.09979
0.1018
0.1039
0.1059
0.1079
0.1100

Entropy
Vapor
[Btu/R-lb]
0.1989
0.1984
0.1979
0.1975
0.1971
0.1967
0.1964
0.1961
0.1958
0.1956
0.1954
0.1953
0.1952
0.1951
0.1950
0.1950
0.1949
0.1949
0.1949
0.1950
0.1950
0.1951
0.1952
0.1953
0.1955
0.1956
0.1958
0.1959
0.1961
0.1963
0.1965
0.1967
0.1969
0.1972
0.1974
0.1976
0.1979
0.1981
0.1984
0.1987
0.1989
0.1992
0.1995
0.1997
0.2000

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-124
Temp
[F]
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155
160
165
170
175
180

Pressure
Liquid
[psia]
3.8
4.5
5.2
5.9
6.8
7.8
8.9
10.1
11.4
12.9
14.5
16.3
18.3
20.4
22.7
25.2
27.9
30.8
34.0
37.4
41.0
44.9
49.1
53.6
58.4
63.5
69.0
74.8
80.9
87.4
94.3
101.6
109.3
117.5
126.0
135.1
144.6
154.6
165.1
176.2
187.7
199.9
212.6
225.9
239.8

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
97.03
96.55
96.06
95.57
95.08
94.58
94.08
93.57
93.06
92.55
92.04
91.52
90.99
90.46
89.93
89.39
88.84
88.29
87.73
87.17
86.60
86.03
85.44
84.85
84.25
83.65
83.03
82.41
81.77
81.13
80.48
79.81
79.13
78.44
77.73
77.01
76.28
75.52
74.75
73.96
73.14
72.30
71.44
70.54
69.61

Density
Vapor
[lb/ft3]
0.1181
0.1359
0.1557
0.1779
0.2024
0.2295
0.2594
0.2924
0.3285
0.3680
0.4112
0.4583
0.5095
0.5651
0.6253
0.6904
0.7608
0.8366
0.9183
1.006
1.100
1.202
1.310
1.426
1.551
1.683
1.825
1.977
2.139
2.311
2.495
2.691
2.900
3.123
3.360
3.614
3.884
4.172
4.480
4.809
5.161
5.538
5.942
6.377
6.845

22

Enthalpy
Liquid
[Btu/lb]
0
1.222
2.449
3.681
4.918
6.159
7.406
8.657
9.914
11.18
12.44
13.72
15.00
16.28
17.57
18.87
20.17
21.48
22.80
24.12
25.45
26.79
28.13
29.48
30.84
32.21
33.58
34.97
36.36
37.76
39.17
40.59
42.02
43.46
44.92
46.38
47.86
49.35
50.85
52.37
53.91
55.46
57.03
58.62
60.23

Enthalpy
Vapor
[Btu/lb]
76.75
77.46
78.17
78.88
79.59
80.30
81.01
81.72
82.43
83.14
83.84
84.55
85.25
85.95
86.65
87.35
88.05
88.74
89.43
90.11
90.79
91.47
92.14
92.81
93.47
94.13
94.78
95.42
96.06
96.69
97.31
97.92
98.53
99.12
99.70
100.3
100.8
101.4
101.9
102.4
102.9
103.4
103.8
104.3
104.7

Entropy
Liquid
[Btu/R-lb]
0
0.00289
0.00576
0.00861
0.01143
0.01424
0.01702
0.01978
0.02253
0.02525
0.02796
0.03065
0.03332
0.03597
0.03861
0.04124
0.04385
0.04644
0.04902
0.05159
0.05415
0.05669
0.05922
0.06174
0.06425
0.06676
0.06925
0.07173
0.07420
0.07667
0.07913
0.08158
0.08403
0.08648
0.08892
0.09135
0.09379
0.09622
0.09866
0.1011
0.1035
0.1060
0.1084
0.1109
0.1134

Entropy
Vapor
[Btu/R-lb]
0.1829
0.1824
0.1820
0.1816
0.1813
0.1810
0.1807
0.1805
0.1803
0.1801
0.1800
0.1799
0.1798
0.0797
0.1797
0.1797
0.1797
0.1797
0.1798
0.1798
0.1799
0.1800
0.1801
0.1802
0.1803
0.1804
0.1806
0.1807
0.1809
0.1810
0.1812
0.1813
0.1815
0.1817
0.1818
0.1820
0.1821
0.1823
0.1824
0.1825
0.1826
0.1827
0.1828
0.1828
0.1828

5th Edition 2010

Technical
Guidelines

R-134a
Physical Properties of Refrigerants

R-134a

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating

HFC
102.3
-14.9
588.3
213.8
32.0
76.2
0.328
93.3
0.3366
0.2021
0
1430
A1

Available in the
following sizes
R-134a
12 oz. can
30 LB. CYLINDER
30 LB CYLINDER/with
Automotive Fitting
125 LB. CYLINDER
1000 LB. CYLINDER
1750 LB. CYLINDER

Pressure-Temp Chart

R-134a
Replaces:

R-12

Applications:

Household appliances, refrigeration (commercial and


self-contained equipment), centrifugal chillers and
automotive air conditioning

Performance:

Similar PT properties in air-conditioning


Slight drop in capacity at lower temperature applications
(below -10F)

Lubricant
Recommendation: Compatible with polyolester lubricant for stationary
equipment and polyalkaline glycol for automotive
A/C systems

Retrofitting:

Replacement for R-12

Refrigerant Reference Guide

page

23

90, 91

Temp
(F)

R-134a
psig

-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150

14.8
12.5
9.9
6.9
3.7
0.6
1.9
4.0
6.5
9.1
11.9
15.0
18.4
22.1
26.1
30.4
35.0
40.1
45.5
51.3
57.5
64.1
71.2
78.8
86.8
95.4
104
114
124
135
147
159
171
185
199
214
229
246
263

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-134a
Temp
[F]
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155
160

Pressure
Liquid
[psia]
4.0
4.7
5.5
6.4
7.4
8.6
9.9
11.3
12.9
15.3
16.6
18.8
21.2
23.8
26.6
29.7
33.1
36.8
40.8
45.1
49.7
54.8
60.2
65.9
72.2
78.8
85.8
93.5
101.4
109.9
119.0
128.6
138.9
149.7
161.1
173.1
185.9
199.3
213.4
228.3
243.9
260.4
277.6
295.7
314.7

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
90.49
90.00
89.50
89.00
88.50
88.00
87.49
86.98
86.47
85.95
85.43
84.90
84.37
83.83
83.29
82.74
82.19
81.63
81.06
80.49
79.90
79.32
78.72
78.11
77.50
76.87
76.24
75.59
74.94
74.27
73.58
72.88
72.17
71.44
70.69
69.93
69.14
68.32
67.49
66.62
65.73
64.80
63.83
62.82
61.76

Density
Vapor
[lb/ft3]
0.09689
0.1127
0.1305
0.1505
0.1729
0.1978
0.2256
0.2563
0.2903
0.3277
0.3689
0.4140
0.4634
0.5173
0.5761
0.6401
0.7095
0.7848
0.8663
0.9544
1.050
1.152
1.263
1.382
1.510
1.647
1.795
1.953
2.123
2.305
2.501
2.710
2.935
3.176
3.435
3.713
4.012
4.333
4.679
5.052
5.455
5.892
6.366
6.882
7.447

Enthalpy
Liquid
[Btu/lb]
-5.957
-4.476
-2.989
-1.498
0.000
1.503
3.013
4.529
6.051
7.580
9.115
10.66
12.21
13.76
15.33
16.90
18.48
20.07
21.67
23.27
24.89
26.51
28.15
29.80
31.45
33.12
34.80
36.49
38.20
39.91
41.65
43.39
45.15
46.93
48.73
50.55
52.38
54.24
56.12
58.02
59.95
61.92
63.91
65.94
68.00

24

Enthalpy
Vapor
[Btu/lb]
94.13
94.89
95.65
96.41
97.17
97.92
98.68
99.43
100.2
100.9
101.7
102.4
103.2
103.9
104.6
105.3
106.1
106.8
107.5
108.2
108.9
109.5
110.2
110.9
111.5
112.2
112.8
113.4
114.0
114.6
115.2
115.7
116.3
116.8
117.3
117.8
118.3
118.7
119.1
119.5
119.8
120.1
120.4
120.6
120.7

Entropy
Liquid
[Btu/R-lb]
-0.01452
-0.01085
-0.00720
-0.00358
0.00000
0.00356
0.00708
0.01058
0.01406
0.01751
0.02093
0.02433
0.02771
0.03107
0.03440
0.03772
0.04101
0.04429
0.04755
0.05079
0.05402
0.05724
0.06044
0.06362
0.06680
0.06996
0.07311
0.07626
0.07939
0.08252
0.08565
0.08877
0.09188
0.09500
0.09811
0.1012
0.1044
0.1075
0.1106
0.1138
0.1169
0.1201
0.1233
0.1265
0.1298

Entropy
Vapor
[Btu/R-lb]
0.2359
0.2347
0.2336
0.2325
0.2315
0.2306
0.2297
0.2289
0.2282
0.2274
0.2268
0.2262
0.2256
0.2250
0.2245
0.2240
0.2236
0.2232
0.2228
0.2224
0.2221
0.2217
0.2214
0.2212
0.2209
0.2206
0.2204
0.2201
0.2199
0.2197
0.2194
0.2192
0.2190
0.2187
0.2185
0.2183
0.2180
0.2177
0.2174
0.2171
0.2167
0.2163
0.2159
0.2154
0.2149

5th Edition 2010

Technical
Guidelines

R-401A and R-401B


Physical Properties of Refrigerants

R-401A

R-401B

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating
Temperature Glide (F) (see section 2)

HCFC
94.4
-29.9
669
221
30.9
74.6
0.306
97.5
0.3037
0.1755
0.037
1182
A1
8

HCFC
92.8
-32.3
679.1
218.3
31.1
74.6
0.303
98.2
0.3027
0.1725
0.039
1288
A1
8

R-401A

R-401B

(R-22 /152a/124)

(R-22 /152a/124)
(61 / 11 / 28 wt%)

(53 / 13 / 34 wt%)

Replaces:

R-12 and R-500

Applications:
R-401A:

Medium and low temperature commercial


and industrial direct expansion refrigeration

R-401B:

Low temperature commercial and industrial


direct expansion refrigeration, R-12 air
conditioning, R-500 systems

Performance:

Very similar capacity, higher glide


Similar evaporator pressure when average
evaporator temperature is the same as R-12
Head pressure runs higher

Lubricant
Recommendation: Compatible with a combination of mineral oil
and alkylbenzene or polyolester lubricants.

Retrofitting:

Replacement for R-12


Replacement for R-500

Refrigerant Reference Guide

page 90, 92
page 97

25

Available in the
following sizes
R-401A
30 LB. CYLINDER
125 LB. CYLINDER
R-401B
30 LB. CYLINDER
125 LB. CYLINDER

Pressure-Temp Chart
R-401A
Liquid
Vapor
(psig)
(psig)
13.2
8.1
10.7
5.1
7.9
1.7
4.8
1.0
1.4
3.0
1.2
5.2
3.3
7.7
5.5
10.3
8.0
13.2
10.7
16.3
13.7
19.7
16.9
23.4
20.4
27.4
24.2
31.7
28.3
36.4
32.8
41.3
37.6
46.6
42.7
52.4
48.2
58.5
54.1
65.0
60.4
71.9
67.2
79.3
74.4
87.1
82.1
95.4
90.2
104
98.9
114
108
123
118
134
128
145
139
156
151
169
163
181
176
195
189
209
203
224
218
239
234
255
250
272
267
290

Temp
(F)
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150

R-401B
Liquid
Vapor
(psig)
(psig)
6.5
11.8
3.3
9.1
0.2
6.1
2.1
2.8
4.3
0.5
6.6
2.5
9.2
4.7
12.0
7.1
15.1
9.7
18.4
12.6
22.0
15.8
25.9
19.2
30.1
23.0
34.6
27.0
39.5
31.4
44.8
36.1
50.4
41.1
56.4
46.6
62.8
52.4
69.6
58.7
76.9
65.4
84.7
72.5
92.9
80.1
102
88.2
111
96.8
121
106
131
116
142
126
153
137
166
148
178
160
192
173
206
187
220
201
236
216
252
231
269
248
287
265
305
283

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-401A
Temp
[F]
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155

Pressure
Liquid
[psia]
6.5
7.5
8.7
9.9
11.4
12.9
14.7
16.6
18.7
21.0
23.6
26.4
29.4
32.7
36.2
40.1
44.2
48.7
53.5
58.6
64.2
70.1
76.4
83.1
90.2
97.8
105.9
114.5
123.5
133.1
143.2
153.9
165.2
177.0
189.5
202.6
216.3
230.7
245.8
261.7
278.2
295.5
313.6
332.6

Pressure
Vapor
[psia]
4.7
5.5
6.4
7.4
8.6
9.9
11.3
12.9
14.7
16.6
18.8
21.2
23.8
26.6
29.7
33.1
36.7
40.7
45.0
49.6
54.6
59.9
65.6
71.8
78.3
85.3
92.8
100.7
109.2
118.1
127.6
137.7
148.3
159.6
171.4
183.9
197.1
211.0
225.6
240.9
257.1
274.0
291.7
310.3

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
88.18
87.71
87.24
86.77
86.29
85.82
85.33
84.85
84.36
83.86
83.37
82.86
82.36
81.84
81.33
80.80
80.27
79.74
79.20
78.65
78.10
77.54
76.97
76.39
75.81
75.21
74.61
74.00
73.37
72.74
72.09
71.43
70.76
70.08
69.38
68.66
67.93
67.17
66.40
65.60
64.77
63.92
63.04
62.12

Enthalpy
Liquid
[Btu/lb]
-5.371
-4.035
-2.694
-1.350
0.000
1.354
2.714
4.078
5.449
6.825
8.207
9.595
10.99
12.39
13.80
15.21
16.64
18.07
19.51
20.95
22.41
23.88
25.35
26.83
28.33
29.83
31.35
32.87
34.41
35.96
37.52
39.10
40.69
42.30
43.92
45.56
47.21
48.89
50.58
52.30
54.04
55.81
57.61
59.43

Density
Vapor
[lb/ft3]
0.1049
0.1215
0.1401
0.1610
0.1842
0.2101
0.2386
0.2701
0.3048
0.3429
0.3846
0.4302
0.4799
0.5340
0.5927
0.6563
0.7251
0.7995
0.8798
0.9662
1.059
1.159
1.267
1.382
1.505
1.637
1.779
1.930
2.092
2.265
2.449
2.647
2.858
3.083
3.324
3.581
3.857
4.152
4.468
4.807
5.171
5.564
5.987
6.444

26

Enthalpy
Vapor
[Btu/lb]
94.93
95.60
96.26
96.93
97.59
98.25
98.91
99.56
100.2
100.9
101.5
102.1
102.8
103.4
104.0
104.6
105.2
105.8
106.4
107.0
107.6
108.2
108.7
109.3
109.8
110.4
110.9
111.4
111.9
112.4
112.8
113.3
113.7
114.1
114.5
114.9
115.2
115.6
115.9
116.2
116.4
116.6
116.8
116.9

Entropy
Liquid
[Btu/R-lb]
-0.01309
-0.00977
-0.00648
-0.00323
0.00000
0.00320
0.00637
0.00952
0.01265
0.01575
0.01882
0.02188
0.02492
0.02793
0.03093
0.03391
0.03687
0.03982
0.04275
0.04566
0.04857
0.05145
0.05433
0.05720
0.06005
0.06290
0.06573
0.06856
0.07138
0.07420
0.07701
0.07981
0.08261
0.08541
0.08822
0.09102
0.09382
0.09663
0.09945
0.1023
0.1051
0.1080
0.1108
0.1137

Entropy
Vapor
[Btu/R-lb]
0.2418
0.2402
0.2386
0.2372
0.2358
0.2345
0.2333
0.2321
0.2310
0.2299
0.2289
0.2279
0.2269
0.2261
0.2252
0.2244
0.2236
0.2229
0.2221
0.2214
0.2208
0.2201
0.2195
0.2189
0.2183
0.2178
0.2172
0.2167
0.2162
0.2156
0.2151
0.2146
0.2141
0.2136
0.2131
0.2126
0.2120
0.2115
0.2110
0.2104
0.2098
0.2092
0.2085
0.2078

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-401B
Temp
[F]
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155

Pressure
Liquid
[psia]
6.9
8.0
9.2
10.6
12.1
13.7
15.6
17.6
19.8
22.3
25.0
27.9
31.1
34.5
38.3
42.3
46.7
51.4
56.4
61.8
67.6
73.8
80.4
87.5
95.0
102.9
111
120
130
140
150
162
173
186
199
212
227
242
258
274
291
309
328
348

Pressure
Vapor
[psia]
5.2
6.1
7.1
8.2
9.4
10.8
12.4
14.1
16.0
18.1
20.5
23.0
25.8
28.9
32.2
35.8
39.7
43.9
48.5
53.4
58.7
64.4
70.5
77.0
84.0
91.4
99.3
108
117
126
136
147
158
170
182
195
209
224
239
255
272
290
309
328

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
88.34
87.87
87.40
86.92
86.44
85.96
85.47
84.98
84.48
83.99
83.48
82.97
82.46
81.94
81.42
80.89
80.35
79.81
79.26
78.71
78.15
77.58
77.00
76.42
75.82
75.22
74.61
73.99
73.36
72.71
72.06
71.39
70.70
70.01
69.29
68.56
67.81
67.04
66.25
65.44
64.59
63.72
62.81
61.87

Density
Vapor
[lb/ft3]
0.1145
0.1324
0.1524
0.1748
0.1997
0.2273
0.2577
0.2914
0.3283
0.3688
0.4131
0.4614
0.514
0.5713
0.6333
0.7005
0.7732
0.8516
0.9362
1.027
1.125
1.23
1.343
1.464
1.594
1.732
1.881
2.039
2.209
2.39
2.584
2.791
3.012
3.248
3.501
3.771
4.06
4.369
4.701
5.058
5.441
5.854
6.3
6.783

Enthalpy
Liquid
[Btu/lb]
-5.346
-4.016
-2.681
-1.343
0.000
1.348
2.701
4.059
5.422
6.791
8.166
9.548
10.94
12.33
13.73
15.14
16.56
17.98
19.42
20.86
22.31
23.76
25.23
26.71
28.20
29.70
31.21
32.73
34.26
35.81
37.37
38.94
40.53
42.13
43.75
45.39
47.05
48.72
50.42
52.14
53.88
55.66
57.46
59.30

27

Enthalpy
Vapor
[Btu/lb]
95.56
96.21
96.86
97.51
98.16
98.80
99.44
100.1
100.7
101.3
102.0
102.6
103.2
103.8
104.4
105.0
105.6
106.2
106.7
107.3
107.8
108.4
108.9
109.5
110.0
110.5
111.0
111.4
111.9
112.4
112.8
113.2
113.6
114.0
114.3
114.7
115.0
115.3
115.5
115.8
116.0
116.1
116.3
116.3

Entropy
Liquid
[Btu/R-lb]
-0.01302
-0.00972
-0.00645
-0.00321
0.00000
0.00318
0.00634
0.00947
0.01258
0.01567
0.01873
0.02177
0.02479
0.02779
0.03077
0.03374
0.03669
0.03962
0.04253
0.04544
0.04832
0.05120
0.05406
0.05692
0.05976
0.06259
0.06542
0.06824
0.07105
0.07385
0.07665
0.07945
0.08224
0.08504
0.08783
0.09063
0.09343
0.09624
0.09905
0.1019
0.1047
0.1076
0.1105
0.1134

Entropy
Vapor
[Btu/R-lb]
0.2430
0.2414
0.2398
0.2383
0.2369
0.2355
0.2343
0.2330
0.2318
0.2307
0.2296
0.2286
0.2276
0.2267
0.2258
0.2249
0.2241
0.2233
0.2225
0.2218
0.2211
0.2204
0.2197
0.2190
0.2184
0.2178
0.2172
0.2166
0.2160
0.2154
0.2149
0.2143
0.2137
0.2131
0.2126
0.2120
0.2114
0.2108
0.2102
0.2095
0.2089
0.2082
0.2074
0.2067

5th Edition 2010

Technical
Guidelines

R-402A and R-402B


Physical Properties of Refrigerants

R-402A

R-402B

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating
Temperature Glide (F) (see section2)

HCFC
101.6
-56.5
600
168
33.8
72.61
0.356
83.58
0.3254
0.1811
0.019
2788
A1
2.5

HCFC
94.7
-52.9
645
180.7
33.1
72.81
0.328
90.42
0.317
0.1741
0.03
2416
A1
2.5

(R-125/290/22)

R-402A

(60 / 2 / 38 wt%)

Replaces:

R-502

Applications:

Low temperature commercial and industrial


direct expansion refrigeration
Lower discharge temperature,
Higher discharge pressure

Performance:

Lubricant
Recommendation: Compatible with mineral and alkylbenzene oil.
If oil return becomes a concern, addition of
polyolester lubricant in 5% increments could help
resolve the issue.

R-402B

(R-125/290/22)
(38 / 2 / 60 wt%)

Replaces:

R-502

Applications:

Ice machines

Performance:

Higher discharge temperature,


Lower discharge pressure

Lubricant
Recommendation: Compatible with mineral and alkylbenzene oil.
If oil return becomes a concern, addition of
polyolester lubricant in 5% increments could help
resolve the issue.

Retrofitting:

Replacement for R-502


to R422C

Refrigerant Reference Guide

page 98
page 100
28

Available in the
following sizes
R-402A
27 LB. CYLINDER
110 LB. CYLINDER
R-402B
13 LB. CYLINDER

Pressure-Temp Chart
R-402A
(psig)

Temp
(F)

R-402B
(psig)

6.3
9.1
12.1
15.4
18.9
22.9
27.1
31.7
36.7
42.1
48.0
54.2
60.9
68.1
75.8
84.0
92.8
102
112
123
134
146
158
171
185
200
215
232
249
267
286
305
326
347
370
393
418
443
470

-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150

3.6
6.0
9.0
12.0
15.4
18.6
22.6
27.0
31.0
36.0
42.0
47.0
54.0
60.0
67.0
75.0
83.4
91.6
100
110
120
133
143
155
170
183
198
213
230
247
262
283
303
323
345
-

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-402A
Temp
[F]
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

Pressure
Liquid
[psia]
13.4
15.3
17.4
19.8
22.3
25.2
28.3
31.7
35.4
39.4
43.8
48.6
53.7
59.2
65.2
71.6
78.4
85.8
93.6
102.0
110.9
120.3
130.4
141.1
152.4
164.4
177.1
190.5
204.6
219.5
235.1
251.6
269.0
287.2
306.3
326.4
347.4
369.5
392.6
416.9
442.2

Pressure
Vapor
[psia]
12.0
13.8
15.8
18.0
20.5
23.2
26.1
29.4
32.9
36.8
41.0
45.6
50.6
56.0
61.7
68.0
74.7
81.8
89.5
97.7
106.4
115.8
125.7
136.2
147.4
159.2
171.8
185.0
199.0
213.8
229.3
245.7
263.0
281.1
300.2
320.2
341.3
363.3
386.5
410.8
436.3

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
89.70
89.14
88.58
88.01
87.44
86.86
86.28
85.69
85.09
84.48
83.87
83.25
82.62
81.99
81.34
80.68
80.02
79.34
78.65
77.95
77.24
76.51
75.76
75.00
74.23
73.43
72.61
71.78
70.91
70.02
69.10
68.15
67.17
66.14
65.06
63.93
62.74
61.48
60.13
58.67
57.07

Enthalpy
Liquid
[Btu/lb]
-5.410
-4.067
-2.718
-1.362
0.000
1.369
2.746
4.130
5.522
6.923
8.331
9.749
11.18
12.61
14.06
15.52
16.98
18.46
19.95
21.46
22.97
24.50
26.04
27.60
29.18
30.77
32.38
34.00
35.65
37.32
39.01
40.73
42.48
44.25
46.07
47.92
49.81
51.76
53.76
55.84
58.01

Density
Vapor
[lb/ft3]
0.2946
0.3355
0.3807
0.4305
0.4854
0.5455
0.6113
0.6832
0.7615
0.8467
0.9392
1.039
1.148
1.265
1.392
1.528
1.675
1.834
2.004
2.187
2.383
2.595
2.821
3.065
3.326
3.607
3.909
4.233
4.583
4.959
5.366
5.805
6.281
6.799
7.362
7.979
8.658
9.408
10.25
11.19
12.26

29

Enthalpy
Vapor
[Btu/lb]
78.16
78.80
79.45
80.09
80.73
81.37
82.00
82.62
83.24
83.85
84.46
85.06
85.65
86.23
86.81
87.37
87.93
88.48
89.01
89.53
90.05
90.54
91.02
91.49
91.94
92.37
92.78
93.17
93.54
93.88
94.19
94.47
94.71
94.91
95.07
95.18
95.22
95.20
95.09
94.88
94.55

Entropy
Liquid
[Btu/R-lb]
-0.01316
-0.00983
-0.00653
-0.00325
0.00000
0.00323
0.00644
0.00962
0.01279
0.01594
0.01906
0.02218
0.02527
0.02835
0.03142
0.03448
0.03752
0.04055
0.04357
0.04659
0.04959
0.05259
0.05559
0.05858
0.06157
0.06456
0.06755
0.07054
0.07354
0.07654
0.07956
0.08259
0.08564
0.08871
0.09181
0.09494
0.09812
0.1013
0.1046
0.1080
0.1115

Entropy
Vapor
[Btu/R-lb]
0.1968
0.1958
0.1948
0.1939
0.1931
0.1923
0.1915
0.1908
0.1901
0.1895
0.1889
0.1883
0.1878
0.1873
0.1868
0.1863
0.1858
0.1854
0.1850
0.1846
0.1842
0.1838
0.1834
0.1830
0.1826
0.1822
0.1818
0.1814
0.1810
0.1806
0.1801
0.1797
0.1791
0.1786
0.1780
0.1773
0.1766
0.1758
0.1748
0.1738
0.1725

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-402B
Temp
[F]
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

Pressure
Liquid
[psia]
12.2
13.9
15.9
18.0
20.4
23.0
25.9
29.1
32.5
36.2
40.3
44.7
49.5
54.7
60.2
66.2
72.6
79.4
86.7
94.6
102.9
111.8
121.2
131.2
141.9
153.1
165.0
177.6
190.8
204.8
219.5
235.0
251.3
268.4
286.3
305.2
324.9
345.6
367.3
390.0
413.7

Pressure
Vapor
[psia]
10.8
12.4
14.2
16.2
18.5
20.9
23.6
26.6
29.9
33.4
37.3
41.5
46.1
51.1
56.4
62.2
68.3
75.0
82.1
89.7
97.8
106.5
115.7
125.5
136.0
147.0
158.7
171.1
184.1
197.9
212.5
227.8
243.9
260.9
278.7
297.4
317.1
337.7
359.3
382.0
405.7

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
88.76
88.23
87.70
87.16
86.62
86.07
85.52
84.96
84.40
83.83
83.25
82.67
82.08
81.48
80.88
80.26
79.64
79.01
78.37
77.72
77.05
76.38
75.69
74.99
74.28
73.55
72.81
72.05
71.27
70.47
69.64
68.80
67.92
67.02
66.08
65.11
64.09
63.03
61.91
60.73
59.47

Density
Vapor
[lb/ft3]
0.2454
0.2798
0.3178
0.3598
0.4061
0.4568
0.5124
0.5731
0.6392
0.7112
0.7894
0.8742
0.9659
1.065
1.172
1.287
1.412
1.545
1.689
1.843
2.008
2.186
2.376
2.580
2.798
3.032
3.283
3.552
3.840
4.149
4.482
4.839
5.224
5.638
6.086
6.572
7.099
7.674
8.303
8.996
9.764

30

Enthalpy
Liquid
[Btu/lb]
-5.366
-4.033
-2.694
-1.350
0.000
1.356
2.719
4.089
5.466
6.850
8.242
9.643
11.05
12.47
13.89
15.33
16.78
18.23
19.70
21.18
22.67
24.17
25.68
27.21
28.75
30.31
31.88
33.47
35.08
36.70
38.35
40.01
41.70
43.42
45.16
46.94
48.74
50.59
52.48
54.42
56.41

Enthalpy
Vapor
[Btu/lb]
85.51
86.14
86.76
87.38
87.99
88.61
89.21
89.81
90.40
90.99
91.57
92.15
92.71
93.27
93.82
94.36
94.89
95.41
95.92
96.42
96.91
97.38
97.84
98.29
98.71
99.13
99.52
99.89
100.2
100.6
100.9
101.2
101.4
101.6
101.8
101.9
102.0
102.1
102.1
102.0
101.8

Entropy
Liquid
[Btu/R-lb]
-0.01306
-0.00975
-0.00647
-0.00322
0.00000
0.00320
0.00638
0.00953
0.01266
0.01577
0.01877
0.02194
0.02500
0.02804
0.03107
0.03408
0.03708
0.04006
0.04304
0.04600
0.04896
0.05191
0.05485
0.05778
0.06071
0.06364
0.06657
0.06949
0.07242
0.07525
0.07828
0.08123
0.08418
0.08715
0.09013
0.09314
0.09617
0.09924
0.1024
0.1055
0.1087

Entropy
Vapor
[Btu/R-lb]
0.2154
0.2141
0.2129
0.2117
0.2106
0.2095
0.2085
0.2075
0.2066
0.2057
0.2049
0.2041
0.2033
0.2025
0.2018
0.2011
0.2005
0.1998
0.1992
0.1986
0.1980
0.1974
0.1968
0.1963
0.1957
0.1952
0.1946
0.1940
0.1935
0.1929
0.1923
0.1917
0.1911
0.1904
0.1898
0.1891
0.1883
0.1875
0.1866
0.1856
0.1846

5th Edition 2010

Technical
Guidelines

R-403B
Physical Properties of Refrigerants

R-403B

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating
Temperature Glide (F) (see section 2)

HCFC
103.25
-46.8
637.7
191.6
32.9
72.8
0.35
82.1
0.313
0.182
0.028
4460
A1
2

R-403B

Available in the
following sizes
R-403B
25 LB. CYLINDER
110 LB. CYLINDER

Pressure-Temp Chart

(R-290/22/218)
(5 / 56 / 39 wt%)

Replaces:

R-13B1

Applications:

Very low temperature single-stage refrigeration

Performance:

Evaporator operates in a vacuum when the low side


temperature is below -55F
Capillary tube must be replaced with a longer/
more restrictive size

Lubricant
Recommendation: Compatible with mineral and alkylbenzene oil. If oil
return becomes a concern, addition of polyolester lubricant
in 5% increments could help resolve the issue

Retrofitting:

Follow equipment manufacturers guidelines

Refrigerant Reference Guide

31

Temp
(F)
-70
-65
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120

R-403B
(psig)
10.5
7.8
4.5
1.2
1.3
3.3
4.8
7.4
10.1
13.2
16.5
20.1
24.0
28.2
32.8
37.7
43.0
48.7
54.9
61.4
68.4
75.9
84.8
93.3
102
112
122
132
144
156
168
181
195
210
225
242
258
276
295

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-403B
Temp
[F]
-70
-65
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120

Pressure
Liquid
[psia]
9.7
11.0
12.6
14.2
16.1
18.1
20.2
22.8
25.6
28.6
32.0
35.6
39.5
43.8
48.4
53.3
58.6
64.4
70.5
77.1
84.1
91.6
99.5
108.0
117.0
126.6
136.7
147.4
158.7
170.6
183.2
196.4
210.4
225.0
240.4
256.5
273.4
291.0
309.5

Pressure
Vapor
[psia]
9.4
10.8
12.3
14.0
15.8
17.8
19.5
22.1
24.8
27.9
31.2
34.8
38.7
42.9
47.5
52.4
57.7
63.4
69.6
76.1
83.1
90.6
98.5
107.0
116.0
125.5
135.6
146.3
157.6
169.5
182.1
195.3
209.2
223.9
239.2
255.3
272.2
289.9
308.3

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
88.22
87.65
87.07
86.50
85.92
85.35
84.77
84.23
83.69
83.14
82.58
82.02
81.45
80.87
80.29
79.70
79.10
78.49
77.87
77.25
76.61
75.96
75.30
74.63
73.94
73.24
72.53
71.80
71.06
70.29
69.51
68.71
67.89
67.05
66.18
65.29
64.37
63.41
62.43

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

Entropy
Liquid
[Btu/R-lb]

Entropy
Vapor
[Btu/R-lb]

0.470
0.527
0.590
0.658
0.731
0.812
0.898
0.992
1.094
1.203
1.321
1.448
1.584
1.730
1.888
2.056
2.237
2.431
2.638
2.860
3.098
3.352
3.624
3.915
4.227
4.560
4.918
5.301
5.711
6.153
6.627
7.138
7.689

4.23
5.52
6.83
8.14
9.46
10.79
12.13
13.48
14.83
16.20
17.58
18.96
20.36
21.76
23.18
24.61
26.04
27.49
28.95
30.43
31.91
33.41
34.92
36.45
37.99
39.55
41.12
42.71
44.32
45.94
47.59
49.26
50.95

82.89
83.54
84.18
84.82
85.46
86.08
86.70
87.31
87.91
88.51
89.09
89.66
90.22
90.78
91.31
91.84
92.35
92.85
93.33
93.80
94.25
94.68
95.09
95.48
95.85
96.20
96.53
96.83
97.10
97.34
97.55
97.73
97.87

0.02197
0.02501
0.02804
0.03105
0.03405
0.03703
0.03999
0.04294
0.04587
0.04880
0.05171
0.05460
0.05749
0.06036
0.06322
0.06608
0.06892
0.07176
0.07458
0.07740
0.08022
0.09303
0.08583
0.08863
0.09143
0.09423
0.09702
0.09982
0.1026
0.1054
0.1082
0.1111
0.1139

0.2087
0.2080
0.2073
0.2067
0.2062
0.2056
0.2051
0.2046
0.2042
0.2037
0.2033
0.2029
0.2025
0.2021
0.2018
0.2014
0.2011
0.2007
0.2004
0.2000
0.1997
0.1993
0.1990
0.1986
0.1982
0.1978
0.1974
0.1970
0.1966
0.1961
0.1956
0.1951
0.1946

32

5th Edition 2010

Technical
Guidelines

R-404A
Physical Properties of Refrigerants

R-404A

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating
Temperature Glide (F) (see section 2)

HFC
97.6
-51.8
548.2
162.5
35.84
66.37
0.342
86.1
0.3600
0.2077
0
3920
A1
1.5

R-404A

Available in the
following sizes
R-404A
24 LB. CYLINDER
100 LB. CYLINDER
800 LB. CYLINDER
1300 LB. CYLINDER

Pressure-Temp Chart

(R-125/143a/134a)
(44 / 52 / 4 wt%)

Replaces:

R-22 & R-502

Applications:

Medium and low temperature commercial and industrial


direct expansion refrigeration and ice machines

Performance:

Similar PT and flow properties to R-502


Higher capacity than R-22, therefore requires TXV change

Lubricant
Recommendation: Compatible with polyolester lubricant

Retrofitting:

Replacement for R-502


Replacement for R-22

Refrigerant Reference Guide

page 99
page 96

33

Temp
(F)
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

R-404A
psig
4.3
6.8
9.5
12.5
15.7
19.3
23.2
27.5
32.1
37.0
42.4
48.2
54.5
61.2
68.4
76.1
84.4
93.2
103
113
123
135
147
159
173
187
202
218
234
252
270
289
310
331
353
377
401

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-404A
Temp
[F]
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155

Pressure
Liquid
[psia]
11.8
13.5
15.4
17.6
19.9
22.5
25.4
28.5
31.9
35.6
39.7
44.1
48.8
54.0
59.5
65.5
71.9
78.7
86.1
93.9
102.3
111.2
120.7
130.7
141.4
152.8
164.7
177.4
190.8
204.9
219.9
235.6
252.1
269.5
287.8
307.0
327.2
384.4
370.6
394.0
418.5
444.3
471.4
500.0

Pressure
Vapor
[psia]
11.3
13.0
14.9
16.9
19.3
21.8
24.6
27.7
31.0
34.7
38.7
43.0
47.7
52.8
58.3
64.2
70.5
77.3
84.6
92.4
100.7
109.5
118.9
128.9
139.6
150.8
162.8
175.4
188.8
202.8
217.7
233.4
249.9
267.3
285.5
304.7
324.9
346.1
368.4
391.8
416.4
442.3
469.6
498.4

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
82.53
82.01
81.48
80.94
80.40
79.86
79.31
78.75
78.19
77.62
77.05
76.46
75.87
75.27
74.66
74.05
73.42
72.78
72.13
71.46
70.79
70.10
69.39
68.67
67.93
67.16
66.38
65.58
64.75
63.89
62.99
62.07
61.10
60.09
59.03
57.91
56.73
55.46
54.08
52.58
50.92
49.01
46.73
43.74

Density
Vapor
[lb/ft3]
0.2671
0.3044
0.3457
0.3913
0.4414
0.4965
0.5568
0.6228
0.6947
0.7730
0.8582
0.9506
1.051
1.159
1.276
1.403
1.539
1.686
1.845
2.016
2.200
2.397
2.610
2.839
3.086
3.352
3.638
3.947
4.281
4.642
5.033
5.458
5.921
6.426
6.981
7.592
8.271
9.029
9.886
10.87
12.01
13.39
15.13
17.55

34

Enthalpy
Liquid
[Btu/lb]
-5.913
-4.447
-2.973
-1.490
0.000
1.499
3.007
4.524
6.051
7.587
9.133
10.69
12.26
13.84
15.43
17.03
18.64
20.27
21.91
23.57
25.24
26.92
28.62
30.34
32.08
33.84
35.62
37.42
39.24
41.09
42.97
44.87
46.81
48.79
50.81
52.88
54.99
57.18
59.43
61.79
64.26
66.9
69.81
73.21

Enthalpy
Vapor
[Btu/lb]
81.19
81.92
82.64
83.36
84.08
84.79
85.50
86.20
86.90
87.59
88.28
88.95
89.62
90.29
90.94
91.58
92.21
92.83
93.44
94.04
94.62
95.19
95.74
96.28
96.80
97.29
97.76
98.21
98.63
99.03
99.39
99.71
100.0
100.2
100.4
100.5
100.6
100.5
100.4
100.1
99.60
98.89
97.78
95.98

Entropy
Liquid
[Btu/R-lb]
-0.01439
-0.01075
-0.00714
-0.00356
0.00000
0.00354
0.00705
0.01054
0.01402
0.01747
0.02091
0.02433
0.02773
0.03112
0.03449
0.03785
0.04120
0.04454
0.04787
0.05120
0.05451
0.05782
0.06113
0.06443
0.06774
0.07104
0.07435
0.07767
0.08099
0.08433
0.08768
0.09105
0.09444
0.09786
0.1013
0.1048
0.1084
0.1120
0.1157
0.1196
0.1236
0.1278
0.1324
0.1378

Entropy
Vapor
[Btu/R-lb]
0.2041
0.2032
0.2023
0.2015
0.2008
0.2001
0.1994
0.1988
0.1982
0.1977
0.1972
0.1967
0.1963
0.1959
0.1955
0.1951
0.1948
0.1945
0.1941
0.1938
0.1935
0.1932
0.1930
0.1927
0.1924
0.1921
0.1918
0.1915
0.1911
0.1908
0.1904
0.1900
0.1895
0.1890
0.1884
0.1878
0.1870
0.1862
0.1852
0.1840
0.1825
0.1807
0.1783
0.1748

5th Edition 2010

Technical
Guidelines

R-407A
Physical Properties of Refrigerants

R-407A

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating
Temperature Glide (F) (see section 2)

HFC
90.1
-49.9
658.6
181
31.4
72.6
0.291
100.8
0.3554
0.1967
0
2110
A1
10

(R-32 /125 /134a)


(20 / 40 / 40 wt%)

Replaces:

R-22

Applications:

Medium and low temperature commercial


and industrial direct expansion refrigeration

Performance:

Slightly lower discharge temperature


Closest capacity match
Similar PT and flow properties =
no component changes

Lubricant
Recommendation: Compatible with polyolester lubricant
R-407A in R-22 Refrigeration

Refrigerant Reference Guide

R-407A
25 LB. CYLINDER
100 LB. CYLINDER
925 LB. CYLINDER
1550 LB. CYLINDER

Pressure-Temp Chart
Temp
(F)

R-407A

Retrofitting to:

Available in the
following sizes

page

35

94

-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

R-407A
Liquid
Vapor
(psig)
(psig)
1.0
3.9
1.0
6.4
3.3
9.2
5.8
12.2
8.5
15.6
11.5
19.2
14.9
23.2
18.5
27.5
22.5
32.2
26.9
37.3
31.6
42.8
36.7
48.7
42.3
55.1
48.3
62.0
54.8
69.3
61.8
77.2
69.4
85.6
77.4
94.6
86.1
104
95.3
114
105
125
116
137
127
149
139
162
152
175
165
190
179
205
194
221
210
238
227
255
245
274
264
293
284
314
305
335
327
358
350
382
375
406

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-407A
[F]

Pressure
Liquid
[psia]

Pressure
Vapor
[psia]

Density
Liquid
[lb/ft3]

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

Entropy
Liquid
[Btu/R-lb]

Entropy
Vapor
[Btu/R-lb]

-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

10.8
12.5
14.3
16.4
18.6
21.1
23.9
26.9
30.3
33.9
37.9
42.2
46.9
52.0
57.5
63.4
69.8
76.7
84.0
91.9
100
109
119
129
140
151
164
176
190
204
220
236
252
270
289
308
329
350
373
396
421

7.6
8.9
10.3
11.9
13.7
15.7
18.0
20.4
23.2
26.2
29.6
33.2
37.2
41.6
46.3
51.4
57.0
63.0
69.5
76.5
84.1
92.1
101
110
120
130
142
154
166
180
194
209
225
242
260
279
299
320
342
365
390

88.81
88.26
87.72
87.17
86.61
86.05
85.49
84.92
84.35
83.77
83.18
82.59
81.99
81.39
80.77
80.15
79.52
78.88
78.23
77.57
76.90
76.21
75.52
74.81
74.08
73.34
72.58
71.80
71.01
70.19
69.34
68.48
67.58
66.65
65.69
64.69
63.64
62.55
61.39
60.17
58.87

0.164
0.189
0.218
0.250
0.285
0.325
0.368
0.416
0.469
0.527
0.591
0.660
0.736
0.818
0.908
1.005
1.111
1.225
1.349
1.482
1.626
1.782
1.949
2.130
2.325
2.534
2.760
3.003
3.265
3.548
3.853
4.183
4.539
4.925
5.345
5.801
6.298
6.843
7.443
8.106
8.843

-6.1454
-4.6163
-3.0826
-1.5440
0.000
1.5496
3.1052
4.6672
6.2358
7.8114
9.3945
10.99
12.58
14.19
15.81
17.44
19.07
20.72
22.38
24.05
25.73
27.42
29.13
30.85
32.59
34.35
36.12
37.91
39.72
41.55
43.40
45.27
47.17
49.10
51.06
53.06
55.09
57.16
59.28
61.45
63.69

95.41
96.12
96.82
97.52
98.21
98.90
99.59
100.3
100.9
101.6
102.3
102.9
103.6
104.2
104.8
105.4
106.0
106.6
107.2
107.8
108.3
108.9
109.4
109.9
110.4
110.9
111.3
111.7
112.1
112.5
112.9
113.2
113.4
113.7
113.9
114.1
114.2
114.2
114.2
114.1
113.9

-0.01496
-0.01117
-0.00741
0.00369
0.00000
0.00366
0.00729
0.01088
0.01446
0.01800
0.02152
0.02502
0.02849
0.03195
0.03538
0.03880
0.04219
0.04558
0.04894
0.05230
0.05564
0.05897
0.06229
0.06561
0.06892
0.07222
0.07552
0.07882
0.08213
0.08543
0.08874
0.09206
0.09539
0.09874
0.1021
0.1055
0.1089
0.1124
0.1159
0.1194
0.1230

0.2434
0.2418
0.2404
0.2390
0.2376
0.2364
0.2351
0.2340
0.2329
0.2319
0.2309
0.2299
0.2290
0.2281
0.2273
0.2264
0.2257
0.2249
0.2242
0.2235
0.2228
0.2221
0.2214
0.2208
0.2202
0.2195
0.2189
0.2182
0.2176
0.2169
0.2163
0.2156
0.2148
0.2141
0.2133
0.2125
0.2116
0.2107
0.2097
0.2086
0.2074

Temp

Refrigerant Reference Guide

36

5th Edition 2010

Technical
Guidelines

R-407C
Physical Properties of Refrigerants

R-407C

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating
Temperature Glide (F) (see section 2)

HFC
86.2
-43.6
672.1
187
32
72.4
0.289
106.7
0.3597
0.1987
0
1770
A1
10

(R-32 /125 /134a)


(23 / 25 / 52 wt%)

Replaces:

R-22

Applications:

Medium temperature commercial and industrial


direct expansion refrigeration and A/C

Performance:

Slightly lower discharge temperature


Closest capacity match
Similar PT and flow properties =
no component changes

Lubricant
Recommendation: Compatible with polyolester lubricant
R-407C in R-22 Refrigeration
R-407C in R-22 Air Conditioning

Refrigerant Reference Guide

R-407C
25 LB. CYLINDER
115 LB. CYLINDER
925 LB. CYLINDER
1550 LB. CYLINDER

Pressure-Temp Chart
Temp
(F)

R-407C

Retrofitting to:

Available in the
following sizes

page 94
page 94

37

-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

R-407C
Liquid
Vapor
(psig)
(psig)
3.0
4.4
5.4
0.6
8.0
1.8
10.9
4.1
14.1
6.6
17.6
9.4
21.3
12.5
25.4
15.9
29.9
19.6
34.7
23.6
39.9
28.0
45.6
32.8
51.6
38.0
58.2
43.6
65.2
49.6
72.6
56.1
80.7
63.1
89.2
70.6
98.3
78.7
108
87.3
118
96.8
129
106
141
117
153
128
166
140
180
153
195
166
210
181
226
196
243
211
261
229
280
247
300
266
321
286
342
307
365
329
389
353

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-407C
[F]

Pressure
Liquid
[psia]

Pressure
Vapor
[psia]

Density
Liquid
[lb/ft3]

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

Entropy
Liquid
[Btu/R-lb]

Entropy
Vapor
[Btu/R-lb]

-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

10.2
11.8
13.5
15.4
17.6
19.9
226
25.4
28.6
32.0
35.8
39.9
44.3
49.1
54.3
59.9
66.0
72.5
79.4
86.9
94.9
103.4
112.5
122.2
132.4
143.4
154.9
167.2
180.2
193.8
208.3
223.5
239.6
256.5
274.3
292.9
312.5
333.0
354.6
377.1
400.7

6.9
8.0
9.4
10.8
12.5
14.3
16.4
18.7
21.2
24.0
27.1
30.5
34.2
38.3
42.7
47.4
52.6
58.3
64.3
70.9
77.9
85.4
93.5
102.2
111.5
121.4
131.9
143.1
155.1
167.7
181.2
195.4
210.5
226.5
243.4
261.2
280.0
299.9
320.8
342.9
366.1

87.66
87.14
86.61
86.08
85.55
85.01
84.46
83.91
83.36
82.80
82.23
81.66
81.08
80.50
79.90
79.30
78.70
78.08
77.46
76.82
76.18
75.52
74.85
74.18
73.48
72.78
72.06
71.32
70.57
69.80
69.00
68.19
67.35
66.48
65.59
64.66
63.70
62.70
61.65
60.55
59.39

0.1418
0.1641
0.1890
0.2169
0.2480
02825
0.3206
0.3628
0.4092
0.4602
0.5160
0.5771
0.6438
0.7164
0.7954
0.8812
0.9742
1.075
1.184
1.302
1.429
1.566
1.714
1.873
2.044
2.229
2.428
2.642
2.872
3.120
3.387
3.675
3.985
4.321
4.684
5.078
5.505
5.971
6.479
7.037
7.652

-6.192
-4.653
-3.108
-1.557
0.000
1.564
3.134
4.711
6.296
7.888
9.488
11.10
12.71
14.34
15.97
17.62
19.27
20.94
22.62
24.30
26.00
27.72
29.44
31.18
32.94
34.71
36.49
38.30
40.12
41.96
43.82
45.71
47.62
49.55
51.52
53.51
55.54
57.60
59.71
61.86
64.06

100.9
101.6
102.3
103.0
103.7
104.4
105.1
105.8
106.5
107.2
107.9
108.5
109.2
109.8
110.5
111.1
111.7
112.3
112.9
113.5
114.1
114.6
115.1
115.7
116.2
116.7
117.1
117.6
118.0
118.4
118.8
119.1
119.4
119.7
120.0
120.2
120.3
120.4
120.5
120.5
120.4

-0.01508
-0.01126
-0.00747
-0.00372
-0.00000
0.00369
0.00735
0.01099
0.01460
0.01818
0.02174
0.02528
0.02879
0.03229
0.03576
0.03922
0.04265
0.04608
0.04948
0.05288
0.05626
0.05963
0.06298
0.06633
0.06968
0.07301
0.07635
0.07968
0.08301
0.08634
0.08967
0.09301
0.09636
0.09972
0.1031
0.1065
0.1099
0.1133
0.1168
0.1203
0.1239

0.2575
0.2558
0.2542
0.2527
0.2512
0.2498
0.2484
0.2472
0.2459
0.2448
0.2437
0.2426
0.2416
0.2406
0.2396
0.2387
0.2378
0.2370
0.2361
0.2353
0.2346
0.2338
0.2331
0.2323
0.2316
0.2309
0.2302
0.2295
0.2288
0.2281
0.2274
0.2266
0.2259
0.2251
0.2243
0.2235
0.2226
0.2217
0.2208
0.2197
0.2186

Temp

Refrigerant Reference Guide

38

5th Edition 2010

Technical
Guidelines

R-408A
Physical Properties of Refrigerants

R-408A

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating
Temperature Glide (F) (see section 2)

HCFC
87
-49.8
641.6
182
30
66.9
0.303
96.74
0.3416
0.1901
0.024
3152
A1
1

R-408A

(R-125/143a/22)
(7 / 46 / 47 wt%)

Replaces:

R-502

Applications:

Medium and low temperature commercial and


industrial direct expansion refrigeration

Performance:

Similar PT properties across the whole operating


range of temperatures
Slightly higher discharge temp

Lubricant
Recommendation: Compatible with mineral oil, alkylbenzene and
polyolester lubricant

Retrofitting:

from R-502
to R-422C

Refrigerant Reference Guide

page 98
page 100

39

Available in the
following sizes
R-408A
24 LB. CYLINDER
100 LB. CYLINDER

Pressure-Temp Chart
Temp
(F)
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

R-408A
(psig)
2.8
5.1
7.6
10.4
13.5
16.8
20.4
24.4
28.7
33.3
38.3
43.7
49.5
55.8
62.5
69.7
77.4
85.6
94.3
104
114
124
135
147
159
173
186
201
217
233
250
268
287
307
327
349
372

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-408A
[F]

Pressure
Liquid
[psia]

Pressure
Vapor
[psia]

Density
Liquid
[lb/ft3]

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

Entropy
Liquid
[Btu/R-lb]

Entropy
Vapor
[Btu/R-lb]

-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

11.2
12.8
14.6
16.7
18.9
21.4
24.1
27.1
30.3
33.9
37.7
41.9
46.4
51.3
56.6
62.3
68.4
74.9
81.9
89.4
97.4
105.9
115.0
124.6
134.8
145.6
157.1
169.2
181.9
195.4
209.6
224.6
240.3
256.9
274.3
292.6
311.7
331.8
352.8
374.9
398.0

10.9
12.5
14.3
16.3
18.5
21.0
23.7
26.6
29.8
33.3
37.1
41.3
45.8
50.7
55.9
61.5
67.6
74.1
81.1
88.5
96.5
104.9
113.9
123.5
133.7
144.5
155.9
167.9
180.7
194.1
208.3
223.2
238.9
255.5
272.8
291.1
310.2
330.3
351.3
373.3
396.4

81.70
81.21
80.72
80.22
79.72
79.21
78.70
78.18
77.65
77.13
76.59
76.05
75.50
74.95
74.39
73.82
73.24
72.65
72.06
71.45
70.84
70.21
69.58
68.93
68.26
67.59
66.90
66.19
65.46
64.72
63.95
63.16
62.34
61.50
60.62
59.71
58.76
57.76
56.71
55.60
54.41

0.2288
0.2604
0.2954
0.3339
0.3763
0.4228
0.4736
0.5291
0.5896
0.6554
0.7268
0.8042
0.8879
0.9784
1.076
1.181
1.295
1.416
1.547
1.688
1.839
2.001
2.175
2.361
2.561
2.775
3.005
3.251
3.515
3.799
4.104
4.433
4.787
5.169
5.583
6.031
6.520
7.053
7.638
8.284
9.002

-5.734
-4.311
-2.881
-1.444
0.000
1.451
2.910
4.376
5.851
7.334
8.826
10.33
11.84
13.36
14.89
16.43
17.98
19.54
21.12
22.71
24.31
25.92
27.55
29.19
30.85
32.52
34.22
35.93
37.66
39.41
41.18
42.98
44.80
46.65
48.53
50.45
52.40
54.40
56.44
58.54
60.71

92.47
93.14
93.79
94.45
95.10
95.74
96.38
97.01
97.64
98.26
98.87
99.47
100.1
100.7
101.2
101.8
102.4
102.9
103.4
103.9
104.4
104.9
105.4
105.9
106.3
106.7
107.1
107.5
107.9
108.2
108.5
108.8
109.0
109.2
109.4
109.5
109.6
109.6
109.5
109.4
109.2

-0.01396
-0.01043
-0.00692
-0.00345
0.00000
0.00342
0.00682
0.01020
0.01356
0.01689
0.02021
0.02350
0.02678
0.03005
0.03329
0.03653
0.03975
0.04295
0.04615
0.04934
0.05251
0.05568
0.05885
0.06200
0.06516
0.06831
0.07146
0.07461
0.07776
0.08092
0.08409
0.08726
0.09045
0.09365
0.09688
0.1001
0.1034
0.1067
0.1101
0.1135
0.1170

0.2320
0.2306
0.2293
0.2280
0.2268
0.2257
0.2246
0.2235
0.2225
0.2215
0.2206
02197
0.2189
0.2181
0.2173
0.2165
0.2158
0.2150
0.2143
0.2137
0.2130
0.2124
0.2117
0.2111
0.2105
0.2098
0.2092
0.2086
0.2079
0.2073
0.2066
0.2060
0.2052
0.2045
0.2037
0.2029
0.2021
0.2012
0.2002
0.1991
0.1979

Temp

Refrigerant Reference Guide

40

5th Edition 2010

Technical
Guidelines

R-409A
Physical Properties of Refrigerants

R-409A

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating
Temperature Glide (F) (see section 2)

HCFC
97.4
-31.8
680.7
224.4
31.7
76.1
0.313
94.75
0.2908
0.1685
0.047
1585
A1
13

R-409A

Available in the
following sizes
R-409A
30 LB. CYLINDER
125 LB. CYLINDER

Temp
(F)

(R-22 /124/142b)
(60 / 25 / 15 wt%)

Replaces:

R-12 and R-500

Applications:

Medium and low temperature commercial and industrial


direct expansion refrigeration and non-centrifugal air
conditioning

Performance:

Pressure and system capacity match R-12 when


operating at an average evaporator temperature
10F to 20F.
Discharge pressure and temperature are higher than R-12
Capacity match to R-500 at air conditioning temperatures

Lubricant
Recommendation: Compatible with mineral oil, alkylbenzene and polyolester
lubricant

Retrofitting:

from R-12
from R-500

Refrigerant Reference Guide

Pressure-Temp Chart

page 90, 92
page 97

41

-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

R-409A
Liquid
Vapor
(psig)
(psig)
0.2
9.8
1.8
7.0
3.9
3.8
6.2
0.3
8.7
1.7
11.4
3.8
14.4
6.1
17.6
8.6
21.1
11.4
24.9
14.4
29.0
17.6
33.4
21.2
38.1
25.0
43.2
29.2
48.6
33.6
54.4
38.5
60.6
43.6
67.2
49.2
74.2
55.2
81.7
61.5
89.6
68.4
98.0
75.6
107
83.4
116
91.6
126
100
137
110
148
120
159
130
172
141
184
153
198
165
212
178
227
192
242
207
258
222

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-409A
Temp
[F]
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155
160

Pressure Pressure
Liquid
Vapor
[psia]
[psia]
11.9
13.6
15.4
17.4
19.5
21.9
24.6
27.4
30.5
33.9
37.5
41.5
45.7
50.3
55.2
60.5
66.1
72.1
78.5
85.4
92.6
100.3
108.5
117.2
126.3
136.0
146.2
157.0
168.3
180.2
192.7
205.9
219.6
234.1
249.2
265.0
281.5
298.8
316.8
335.6
355.2

8.0
9.3
10.6
12.1
13.8
15.7
17.7
20.0
22.5
25.2
28.2
31.4
34.9
38.7
42.8
47.3
52.0
57.2
62.7
68.6
74.9
81.7
88.9
96.6
104.8
113.4
122.7
132.4
142.7
153.7
165.2
177.4
190.2
203.7
217.9
232.9
248.6
265.1
282.5
300.7
319.8

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

Entropy
Liquid
[Btu/R-lb]

Entropy
Vapor
[Btu/R-lb]

87.87
87.38
86.90
86.41
85.92
85.42
84.92
84.41
83.90
83.38
82.86
82.34
81.80
81.26
80.72
80.17
79.61
79.04
78.47
77.89
77.30
76.70
76.09
75.48
74.85
74.21
73.56
72.90
72.22
71.54
70.83
70.11
69.38
68.62
67.85
67.05
66.22
65.38
64.50
63.58
62.63

0.1779
0.2030
0.2308
0.2616
0.2954
0.3326
0.3734
0.4180
0.4666
0.5196
0.5771
0.6395
0.7070
0.7800
0.8588
0.9437
1.035
1.133
1.239
1.352
1.473
1.603
1.742
1.891
2.050
2.219
2.401
2.594
2.801
3.022
3.258
3.510
3.779
4.068
4.376
4.707
5.062
5.443
5.853
6.296
6.775

0.000
1.295
2.594
3.899
5.209
6.524
7.846
9.174
10.51
11.85
13.20
14.55
15.91
17.28
18.66
20.05
21.44
22.84
24.25
25.67
27.11
28.55
30.00
31.46
32.93
34.42
35.92
37.43
38.95
40.49
42.04
43.61
45.19
46.80
48.42
50.06
51.72
53.41
55.13
56.87
58.65

94.00
94.64
95.28
95.92
96.55
97.18
97.81
98.43
99.05
99.67
100.3
100.9
101.5
102.1
102.6
103.2
103.8
104.4
104.9
105.5
106.0
106.5
107.0
107.5
108.0
108.5
109.0
109.4
109.9
110.3
110.7
111.1
111.4
111.8
112.1
112.4
112.6
112.9
113.1
113.2
113.4

0.00000
0.00306
0.00609
0.00910
0.01209
0.01505
0.01799
0.02092
0.02382
0.02670
0.02957
0.03242
0.03525
0.03807
0.04088
0.04367
0.04645
0.04921
0.05197
0.05471
0.05744
0.06017
0.06288
0.06559
0.06829
0.07089
0.07367
0.07636
0.07904
0.08172
0.08440
0.08708
0.08977
0.09245
0.09515
0.09785
0.1006
0.1033
0.1060
0.1088
0.1116

0.2287
0.2274
0.2262
0.2250
0.2239
0.2229
0.2219
0.2209
0.2200
0.2191
0.2182
0.2174
0.2167
0.2159
0.2152
0.2145
0.2139
0.2132
0.2126
0.2120
0.2115
0.2109
0.2104
0.2099
0.2093
0.2088
0.2083
0.2078
0.2074
0.2069
0.2064
0.2059
0.2054
0.2049
0.2043
0.2038
0.2033
0.2027
0.2021
0.2014
0.2008

42

5th Edition 2010

Technical
Guidelines

R-410A
Physical Properties of Refrigerants

R-410A

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating
Temperature Glide (F) (see section 2)

HFC
72.6
-61
691.8
158.3
34.5
67.74
0.261
116.8
0.3948
0.1953
0
2088
A1
0.2

R-410A

Available in the
following sizes
R-410A
25LB. CYLINDER
100 LB. CYLINDER
850LB. CYLINDER
1450 LB. CYLINDER

Pressure-Temp Chart

(R-32/125)
(50 / 50 wt%)

Replaces:

R-22

Applications:

Air conditioning equipment and heat pumps. Only for


newly manufactured equipment, not for retrofitting R-22
systems

Performance:

Presures are 60% higher than R-22, therefore should be used


only in new equipment

Lubricant
Recommendation: Compatible with polyolester lubricant

Retrofitting:

For new equipment only

Refrigerant Reference Guide

43

Temp
(F)
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150

R-410A
psig
11.6
14.9
18.5
22.5
26.9
31.7
36.8
42.5
48.6
55.2
62.3
70.0
78.3
87.3
96.8
107
118
130
142
155
170
185
201
217
235
254
274
295
317
340
365
391
418
446
476
507
539
573
608

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-410A
Temp
[F]
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

Pressure
Liquid
[psia]
25.6
28.9
32.6
36.7
41.1
46.0
51.2
56.9
63.1
69.8
77.1
84.9
93.2
102.2
111.9
122.2
133.2
144.9
157.4
170.7
184.8
199.8
215.7
232.5
250.3
269.1
289.0
310.0
332.0
355.3
379.8
405.6
432.7
461.2
491.2
522.7
555.9

Pressure
Vapor
[psia]
25.5
28.9
32.6
36.6
41.0
45.8
51.1
56.8
63.0
69.7
76.9
84.6
93.0
101.9
111.5
121.8
132.8
144.5
156.9
170.2
184.3
199.2
215.1
231.8
249.6
268.3
288.2
309.1
331.1
354.3
378.8
404.5
431.6
460.1
490.1
521.6
554.8

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
82.02
81.45
80.88
80.30
79.71
79.12
78.51
77.91
77.29
76.66
76.03
75.38
74.73
74.06
73.38
72.69
71.99
71.27
70.53
69.78
69.01
68.22
67.41
66.58
65.71
64.82
63.90
62.95
61.95
60.90
59.81
58.65
57.42
56.11
54.68
53.12
51.38

Density
Vapor
[lb/ft3]
0.4384
0.4929
0.5526
0.6179
0.6892
0.7669
0.8514
0.9431
1.043
1.151
1.267
1.394
1.530
1.677
1.836
2.007
2.192
2.391
2.606
2.838
3.088
3.357
3.648
3.963
4.304
4.674
5.075
5.513
5.990
6.513
7.089
7.725
8.434
9.230
10.13
11.17
12.40

44

Enthalpy
Liquid
[Btu/lb]
0.000
1.648
3.303
4.967
6.640
8.321
10.01
11.71
13.42
15.15
16.88
18.63
20.39
22.16
23.95
25.75
27.58
29.41
31.27
33.14
35.04
36.96
38.90
40.87
42.87
44.90
46.96
49.06
51.21
53.39
55.63
57.93
60.30
62.76
65.31
67.99
70.84

Enthalpy
Vapor
[Btu/lb]
112.5
113.1
113.7
114.3
114.8
115.4
115.9
116.4
116.9
117.4
117.9
118.3
118.8
119.2
119.6
119.9
120.3
120.6
120.9
121.2
121.4
121.6
121.8
121.9
122.0
122.0
122.0
122.0
121.8
121.6
121.4
121.0
120.5
119.9
119.2
118.2
117.0

Entropy
Liquid
[Btu/R-lb]
0.00000
0.00389
0.00774
0.01157
0.01537
0.01915
0.02290
0.02663
0.03035
0.03404
0.03771
0.04137
0.04502
0.04865
0.05227
0.05588
0.05949
0.06309
0.06668
0.07028
0.07387
0.07747
0.08107
0.08469
0.08832
0.09196
0.09562
0.09932
0.1030
0.1068
0.1106
0.1145
0.1185
0.1225
0.1267
0.1310
0.1356

Entropy
Vapor
[Btu/R-lb]
0.2682
0.2664
0.2647
0.2631
0.2615
0.2599
0.2584
0.2570
0.2555
0.2541
0.2528
0.2514
0.2501
0.2488
0.2476
0.2463
0.2451
0.2438
0.2426
0.2413
0.2401
0.2388
0.2376
0.2363
0.2350
0.2336
0.2322
0.2308
0.2293
0.2277
0.2261
0.2243
0.2224
0.2203
0.2180
0.2155
0.2125

5th Edition 2010

Technical
Guidelines

R-414B
Physical Properties of Refrigerants

R-414B

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating
Temperature Glide (F) (see section 2)

HCFC
101.6
-29.9
665.4
226.4
31.6
76.02
0.325
91.5
0.2913
0.1723
0.043
1365
A1
13

R-414B

(R-22 /124 /600a /142b)


(50 / 39 / 1.5 / 9.5 wt%)
R-12 and R-500

Applications:

Medium and low temperature commercial and


industrial direct expansion refrigeration and
stationary and automotive air-conditioning

Performance:

Pressure and capacity match R-12 in 30F to 40F


evaporators
Slightly higher discharge pressure

Lubricant
Recommendation: Compatible with mineral oil, alkylbenzene and
polyolester lubricant
from R-12
from R-500

Refrigerant Reference Guide

R-414B
25 LB. CYLINDER

Pressure-Temp Chart
Temp
(F)

Replaces:

Retrofitting:

Available in the
following sizes

page 90, 92
page 97

45

-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150

R-414B
Liquid
Vapor
(psig)
(psig)
0.0
9.7
1.9
6.8
4.0
3.6
6.3
0.0
8.8
2.0
11.5
4.1
14.5
6.5
17.7
9.0
21.2
11.9
25.0
14.9
29.0
18.3
33.4
21.9
38.1
25.8
43.1
30.0
48.5
34.6
54.3
39.5
60.4
44.8
67.0
50.4
73.9
56.5
81.3
62.9
89.1
69.8
97.4
77.1
106
85.0
116
93.3
125
102
136
111
146
121
158
132
170
143
183
155
196
167
210
180
224
193
239
208
255
223
272
239
289
255

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-414B
Temp
[F]
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155
160

Pressure
Liquid
[psia]
11.4
12.9
14.7
16.6
18.7
21.0
23.5
26.2
29.2
32.4
35.9
39.7
43.7
48.1
52.8
57.8
63.2
69.0
75.1
81.7
88.6
96.0
103.8
112.1
120.9
130.2
140.0
150.3
161.1
172.5
184.6
197.2
210.4
224.2
238.7
253.9
269.7
286.3
303.6
321.7
340.5

Pressure
Vapor
[psia]
7.5
8.6
9.9
11.4
12.9
14.7
16.7
18.8
21.2
23.7
26.6
29.6
33.0
36.6
40.5
44.7
49.3
54.2
59.5
65.1
71.2
77.6
84.5
91.8
99.7
108.0
116.8
126.1
136.0
146.5
157.5
169.2
181.5
194.4
208.1
222.4
237.5
253.3
270.0
287.4
305.7

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
87.77
87.29
86.81
86.32
85.83
85.33
84.83
84.32
83.81
83.30
82.78
82.25
81.72
81.18
80.64
80.09
79.53
78.96
78.39
77.81
77.23
76.63
76.02
75.41
74.78
74.15
73.50
72.84
72.17
71.48
70.78
70.06
69.33
68.57
67.80
67.00
66.18
65.34
64.46
63.55
62.60

Density
Vapor
[lb/ft3]
0.1727
0.1973
0.2247
0.2549
0.2883
0.3250
0.3652
0.4093
0.4573
0.5097
0.5666
0.6284
0.6953
0.7677
0.8458
0.9300
1.021
1.118
1.223
1.335
1.456
1.585
1.723
1.871
2.029
2.198
2.379
2.572
2.778
2.998
3.233
3.484
3.753
4.040
4.348
4.677
5.031
5.412
5.821
6.263
6.741

46

Enthalpy
Liquid
[Btu/lb]
0.000
1.298
2.601
3.909
5.222
6.542
7.867
9.198
10.54
11.88
13.23
14.59
15.96
17.33
18.71
20.10
21.49
22.90
24.32
25.74
27.17
28.62
30.07
31.53
33.01
34.50
35.99
37.51
39.03
40.57
42.12
43.69
45.28
46.88
48.50
50.14
51.80
53.49
55.20
56.94
58.71

Enthalpy
Vapor
[Btu/lb]
90.85
91.51
92.17
92.83
93.48
94.13
94.78
95.43
96.07
96.71
97.34
97.97
98.59
99.21
99.82
100.4
101.0
101.6
102.2
102.8
103.3
103.9
104.4
105.0
105.5
106.0
106.5
107.0
107.5
107.9
108.4
108.8
109.2
109.6
110.0
110.3
110.6
110.9
111.1
111.4
111.5

Entropy
Liquid
[Btu/R-lb]
0.00000
0.00307
0.00611
0.00913
0.01212
0.01509
0.01804
0.02098
0.02389
0.02678
0.02966
0.03251
0.03536
0.03818
0.04100
0.04379
0.04658
0.04935
0.05211
0.05486
0.05760
0.06033
0.06305
0.06577
0.06847
0.07117
0.07387
0.07656
0.07924
0.08193
0.08461
0.08729
0.08998
0.09267
0.09536
0.09806
0.1008
0.1035
0.1062
0.1090
0.1118

Entropy
Vapor
[Btu/R-lb]
0.2212
0.2200
0.2189
0.2179
0.2169
0.2159
0.2151
0.2142
0.2134
0.2127
0.2119
0.2112
0.2106
0.2100
0.2094
0.2088
0.2083
0.2078
0.2073
0.2068
0.2063
0.2059
0.2055
0.2051
0.2047
0.2043
0.2039
0.2035
0.2031
0.2027
0.2024
0.2020
0.2016
0.2012
0.2008
0.2004
0.1999
0.1995
0.1990
0.1984
0.1979

5th Edition 2010

Technical
Guidelines

R-416A
Physical Properties of Refrigerants

R-416A

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating
Temperature Glide (F) (see section 2)

HCFC
111.9
-10
582
227
32.3
77.68
0.354
85.51
0.3139
0.1949
0.012
1085
A1
3

R-416A

(59 / 1.5 / 39.5 wt%)

R-12

Applications:

Automotive air conditioning and higher


temperature refrigeration

Performance:

Capacity matches R-12 at condenser temperatures;


pressures in the evaporator will need to be a few psi
lower than R-12 to maintain proper temperature

Lubricant
Recommendation: Compatible with mineral oil, aklylbenzene and
polyolester lubricant
for R-12

Refrigerant Reference Guide

R-416A
25 LB. CYLINDER

Pressure-Temp Chart
Temp
(F)

(R-134a /600/124)

Replaces:

Retrofitting:

Available in the
following sizes

page 90, 93

47

-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150

R-416A
Liquid
Vapor
(psig)
(psig)
12.1
13.4
9.6
11.0
6.7
8.3
3.5
5.3
0.0
2.0
1.9
0.8
4.0
2.8
6.3
5.0
8.9
7.4
11.6
10.0
14.6
12.8
17.8
15.9
21.4
19.3
25.2
22.9
29.3
26.8
33.7
31.1
38.4
35.6
43.5
40.5
49.0
45.7
54.8
51.3
61.1
57.3
67.7
63.7
74.8
70.6
82.3
77.8
90.3
85.5
98.8
93.7
108
102
117
112
127
121
138
132
149
143
161
154
173
166
186
179
200
192
214
206
229
221

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-416A
Temp
[F]
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155
160

Pressure
Liquid
[psia]
6.6
7.6
8.7
10.0
11.4
13.0
14.7
16.7
18.8
21.1
23.6
26.3
29.3
32.6
36.1
39.9
44.0
48.4
53.2
58.3
63.7
69.6
75.8
82.4
89.5
97.0
105.0
113.5
122.4
131.9
141.9
152.5
163.6
175.4
187.7
200.7
214.4
228.7
243.8
259.5
276.0

Pressure
Vapor
[psia]
6.1
7.0
8.1
9.3
10.6
12.1
13.8
15.6
17.5
19.7
22.1
24.7
27.6
30.7
34.0
37.6
41.6
45.8
50.3
55.2
60.4
66.0
72.0
78.4
85.2
92.5
100.2
108.4
117.0
126.2
136.0
146.2
157.1
168.5
180.6
193.3
206.6
220.7
235.4
250.9
267.2

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
88.98
88.49
88.00
87.50
87.00
86.50
86.00
85.49
84.97
84.45
83.93
83.40
82.86
82.32
81.78
81.22
80.66
80.10
79.52
78.94
78.35
77.76
77.15
76.53
75.90
75.27
74.62
73.95
73.28
72.59
71.88
71.16
70.42
69.67
68.89
68.09
67.26
66.41
65.52
64.61
63.65

Density
Vapor
[lb/ft3]
0.1541
0.1765
0.2015
0.2292
0.2598
0.2935
0.3306
0.3713
0.4159
0.4646
0.5177
0.5754
0.6381
0.7060
0.7796
0.8591
0.9448
1.037
1.137
1.244
1.359
1.483
1.615
1.757
1.909
2.072
2.247
2.433
2.633
2.847
3.076
3.322
3.584
3.866
4.168
4.492
4.841
5.216
5.622
6.060
6.534

48

Enthalpy
Liquid
[Btu/lb]
0.000
1.413
2.832
4.257
5.688
7.125
8.569
10.02
11.48
12.94
14.41
15.89
17.37
18.87
20.37
21.88
23.39
24.92
26.46
28.00
29.55
31.12
32.69
34.28
35.87
37.48
39.10
40.73
42.38
44.04
45.71
47.40
49.11
50.83
52.57
54.33
56.12
57.92
59.75
61.61
63.50

Enthalpy
Vapor
[Btu/lb]
89.58
90.33
91.09
91.84
92.60
93.35
94.10
94.84
95.59
96.33
97.07
97.80
98.53
99.26
100.0
100.7
101.4
102.1
102.8
103.5
104.2
104.9
105.5
106.2
106.8
107.5
108.1
108.7
109.3
109.9
110.5
111.0
111.6
112.1
112.6
113.1
113.5
113.9
114.3
114.7
115.0

Entropy
Liquid
[Btu/R-lb]
0.00000
0.00334
0.00666
0.00995
0.01322
0.01646
0.01968
0.02288
0.02605
0.02921
0.03235
0.03546
0.03856
0.04164
0.04471
0.04776
0.05079
0.05381
0.05681
0.05981
0.06279
0.06575
0.06871
0.07166
0.07460
0.07753
0.08045
0.08337
0.08629
0.08920
0.09210
0.09501
0.09791
0.1008
0.1037
0.1066
0.1096
0.1125
0.1154
0.1184
0.1214

Entropy
Vapor
[Btu/R-lb]
0.2142
0.2135
0.2128
0.2122
0.2116
0.2110
0.2105
0.2101
0.2097
0.2093
0.2089
0.2086
0.2083
0.2081
0.2078
0.2076
0.2074
0.2073
0.2071
0.2070
0.2069
0.2068
0.2067
0.2066
0.2065
0.2064
0.2064
0.2063
0.2063
0.2062
0.2061
0.2061
0.2060
0.2059
0.2058
0.2057
0.2056
0.2054
0.2052
0.2050
0.2048

5th Edition 2010

Technical
Guidelines

R-422A and R-422C


Physical Properties of Refrigerants

R-422A

R-422C

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating
Temperature Glide (F) (see section 2)

HFC
113.6
-51.7
543.7
161.2
33.63
72.03
0.394
76.8
0.3385
0.1976
0
3145
A1
5

HFC
113.5
-50.7
547.7
163.5
33.7
72.5
0.391
77.0
0.3373
0.1973
0
3085
A1
5

R-422C

R-422A
(R-125 /134a /600a)

(R-125 /134a /600a)

(85.1 / 11.5 / 3.4 wt%)

(82 / 15 / 3 wt%)

Replaces:

R-502 / R-22

Applications:

Medium and low temperature


commercial and industrial direct
expansion refrigeration

Performance:

Slightly lower discharge temperature


TXV may appear undersized when
retrofitting a R-22 application
Up to 10% lower capacity

Lubricant
Recommendation: Compatible with mineral and alkylbenzene
oil and if oil return becomes a concern,
addition of polyolester lubricant in 5%
increments could help resolve the issue

Retrofitting:

from R-22
from R-502
from R-402A and R-402B
from R-408A

Refrigerant Reference Guide

page
page
page
page

49

96
100
100
100

Available in the
following sizes
R-422C
24 LB. CYLINDER
100 LB. CYLINDER

Pressure-Temp Chart

R-422A
Liquid
Vapor
(psig)
(psig)
3.2
5.2
5.6
7.8
8.3
10.7
11.3
13.9
14.6
17.3
18.2
21.1
22.1
25.2
26.3
29.6
30.9
34.4
35.6
39.6
41.4
45.2
47.2
51.3
53.5
57.8
60.2
64.7
67.5
72.2
75.2
80.1
83.5
88.6
92.3
97.6
102
107
112
117
122
128
134
140
146
152
158
165
172
179
186
193
201
208
217
224
234
241
251
258
270
277
289
296
310
317
331
338
354
361
378
385
403
410

Temp
(F)
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

R-422C
Liquid
Vapor
(psig)
(psig)
2.2
4.7
4.5
7.2
7.1
10.1
10.0
13.1
13.2
16.5
16.6
20.2
20.4
24.2
24.5
28.6
29.0
33.3
33.8
38.4
39.1
43.9
44.7
49.8
50.8
56.1
57.4
63.0
64.4
70.3
72.0
78.1
80.1
86.4
88.7
95.3
97.9
105
108
115
118
125
129
137
141
149
153
161
167
175
181
189
195
204
211
219
227
236
244
253
263
272
282
291
302
311
323
332
345
354
369
377
394
402

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-422A
[F]

Pressure
Liquid
[psia]

Pressure
Vapor
[psia]

Density
Liquid
[lb/ft3]

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

Entropy
Liquid
[Btu/R-lb]

Entropy
Vapor
[Btu/R-lb]

-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150

13.1
14.9
16.9
19.1
21.5
24.2
27.1
30.2
33.7
37.5
41.7
46.0
50.8
56.1
61.7
67.8
74.1
81.1
88.5
96.5
104.7
113.8
123.4
133.7
144.6
155.7
167.9
180.8
194.4
208.2
223.2
239.1
255.8
273.3
291.0
310.2
330.4
351.3
372.5
395.4
419.3
444.3
470.2

11.7
13.3
15.1
17.1
19.4
22.0
24.7
27.7
31.0
34.6
38.6
42.7
47.4
52.4
57.8
63.7
69.8
76.6
83.8
91.6
99.6
108.5
117.9
128.0
138.7
149.6
161.6
174.4
187.8
201.5
216.5
232.3
248.9
266.5
284.1
303.4
323.6
346.0
367.6
390.9
415.2
440.7
467.2

89.74
89.16
88.60
88.01
87.41
86.82
86.21
85.62
85.00
84.38
83.74
83.12
82.47
81.80
81.13
80.45
79.78
79.07
78.35
77.62
76.89
76.13
75.34
74.54
73.72
72.90
72.03
71.13
70.21
69.29
68.29
67.26
66.17
65.04
63.89
62.63
61.27
59.82
58.30
56.55
54.58
52.27
49.39

0.2803
0.3217
0.3659
0.4166
0.4727
0.5346
0.6027
0.6745
0.7558
0.8446
0.9415
1.0430
1.1572
1.2809
1.4151
1.5604
1.7116
1.881
2.063
2.260
2.465
2.694
2.940
3.206
3.493
3.791
4.125
4.486
4.876
5.284
5.743
6.242
6.788
7.387
8.020
8.746
9.556
10.47
11.47
12.66
14.07
15.82
18.11

-5.602
-4.200
-2.848
-1.446
0
1.446
2.848
4.255
5.731
7.177
8.666
10.10
11.59
13.08
14.60
16.13
17.62
19.16
20.73
22.29
23.85
25.42
27.06
28.67
30.33
31.94
33.62
35.35
37.07
38.75
40.53
42.34
44.18
46.04
47.88
49.85
51.86
53.91
55.99
58.25
60.63
63.19
66.07

71.10
71.82
72.56
73.24
73.97
74.69
75.41
76.11
76.79
77.51
78.19
78.84
79.52
80.20
80.85
81.52
82.16
82.77
83.41
84.01
84.59
85.20
85.75
86.32
86.85
87.36
87.84
88.32
88.76
89.16
89.52
89.89
90.17
90.45
90.63
90.79
90.87
90.85
90.73
90.46
90.01
89.30
88.13

-0.01365
-0.01015
-0.00683
-0.00339
0
0.00339
0.00676
0.00997
0.01329
0.01659
0.01987
0.02301
0.02626
0.02950
0.03271
0.03590
0.03897
0.04216
0.04533
0.04847
0.05153
0.05467
0.05780
0.06095
0.06408
0.06710
0.07025
0.07339
0.07654
0.07958
0.08275
0.08593
0.08915
0.09240
0.09556
0.09887
0.1023
0.1057
0.1091
0.1128
0.1166
0.1207
0.1253

0.1798
0.1791
0.1785
0.1780
0.1774
0.1770
0.1765
0.1762
0.1758
0.1755
0.1752
0.1750
0.1748
0.1746
0.1744
0.1742
0.1741
0.1739
0.1738
0.1737
0.1736
0.1735
0.1734
0.1733
0.1732
0.1731
0.1729
0.1728
0.1726
0.1724
0.1722
0.1719
0.1716
0.1712
0.1708
0.1703
0.1697
0.1690
0.1681
0.1671
0.1658
0.1640
0.1616

Temp

Refrigerant Reference Guide

50

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-422C
[F]

Pressure
Liquid
[psia]

Pressure
Vapor
[psia]

Density
Liquid
[lb/ft3]

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

Entropy
Liquid
[Btu/R-lb]

Entropy
Vapor
[Btu/R-lb]

-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150

11.4
13.1
15.0
17.1
19.4
21.9
24.7
27.8
31.2
34.9
38.9
43.3
48.0
53.1
58.6
64.5
70.8
77.6
84.9
92.8
101
110
119
129
140
151
163
176
189
204
218
234
251
268
286
305
326
347
369
392
416
442
469

9.6
11.1
12.8
14.8
16.9
19.2
21.8
24.7
27.9
31.3
35.1
39.2
43.7
48.5
53.8
59.4
65.5
72.1
79.1
86.7
94.8
103
113
122
133
144
156
168
181
195
210
225
242
259
277
296
317
338
360
384
408
434
462

90.27
89.70
89.12
88.54
87.95
87.36
86.76
86.16
85.54
84.92
84.30
83.66
83.02
82.36
81.70
81.03
80.34
79.64
78.93
78.21
77.47
76.72
75.95
75.16
74.35
73.52
72.66
71.78
70.87
69.93
68.96
67.95
66.89
65.78
64.62
63.39
62.09
60.69
59.17
57.52
55.67
53.54
51.00

0.26
0.30
0.34
0.39
0.45
0.50
0.57
0.64
0.72
0.80
0.89
0.99
1.10
1.22
1.35
1.49
1.64
1.80
1.98
2.16
2.37
2.59
2.82
3.08
3.35
3.65
3.97
4.31
4.69
5.09
5.53
6.01
6.53
7.09
7.72
8.41
9.17
10.02
10.99
12.09
13.38
14.94
16.90

-5.616
-4.222
-2.822
-1.414
0.000
1.422
2.851
4.287
5.732
7.185
8.647
10.12
11.60
13.09
14.59
16.10
17.62
19.15
20.70
22.25
23.82
25.41
27.01
28.62
30.25
31.90
33.56
35.25
36.96
38.69
40.44
42.22
44.03
45.88
47.76
49.68
51.65
53.68
55.78
57.97
60.27
62.72
65.41

71.83
72.55
73.27
73.98
74.70
75.41
76.11
76.82
77.51
78.21
78.90
79.58
80.25
80.92
81.59
82.24
82.88
83.52
84.14
84.76
85.36
85.94
86.52
87.07
87.61
88.13
88.62
89.10
89.54
89.96
90.35
90.70
91.02
91.29
91.52
91.69
91.79
91.82
91.75
91.55
91.20
90.63
89.72

-0.01367
-0.01021
-0.00678
-0.00338
0.00000
0.00335
0.00669
0.01000
0.01328
0.01655
0.01980
0.02303
0.02625
0.02945
0.03263
0.03580
0.03896
0.04210
0.04524
0.04837
0.05148
0.05460
0.05770
0.06081
0.06391
0.06701
0.07011
0.07322
0.07633
0.07945
0.08258
0.08573
0.08890
0.09210
0.09532
0.09859
0.1019
0.1053
0.1087
0.1123
0.1160
0.1199
0.1242

0.1819
0.1812
0.1805
0.1800
0.1794
0.1789
0.1785
0.1781
0.1777
0.1773
0.1770
0.1768
0.1765
0.1763
0.1761
0.1759
0.1757
0.1756
0.1754
0.1753
0.1752
0.1751
0.1750
0.1748
0.1747
01.746
0.1745
0.1743
0.1741
0.1739
0.1737
0.1734
0.1731
0.1728
0.1724
0.1719
0.1713
0.1707
0.1699
0.1689
0.1677
0.1662
0.1642

Temp

Refrigerant Reference Guide

51

5th Edition 2010

Technical
Guidelines

R-422B and R-422D


Physical Properties of Refrigerants

R-422B

R-422D

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating
Temperature Glide (F) (see section 2)

HFC
108.5
-42.4
574.1
181.8
32.9
73.05
0.363
84.2
0.3385
0.201
0
2525
A1
5

HFC
109.9
-45.8
566.2
175.2
33.0
70.9
0.372
81.8
0.339
0.20
0
2730
A1
5

R-422D

R-422B
(R-125 /134a /600a)

(R-125 /134a /600a)

(55 / 42 / 3 wt%)

(65.1 / 31.5 / 3.4 wt%)

Replaces:

R-22

Applications:
R-422B:

R-422D:

Performance:

Medium temperature commercial and


industrial direct expansion refrigeration
and A/C
Medium and low temperature commercial
and industrial direct expansion refrigeration
Slightly lower discharge temperature
Possible undersized TXV based on
pressure drop
Up to 10% lower capacity

Lubricant
Recommendation: Compatible with mineral and alkylbenzene
oil and if oil return becomes a concern,
addition of polyolester lubricant in 5%
increments could help resolve the issue

Retrofitting to:

R-422B for R-22 Air Conditioning page 95


R-422B for R-22 Refrigeration
page 95
R-422D for R-22 Refrigeration
page 95

Refrigerant Reference Guide

52

Available in the
following sizes
R-422D
25 LB. CYLINDER
110 LB. CYLINDER

Pressure-Temp Chart

R-422B
Liquid
Vapor
(psig)
(psig)
2.7
0.9
0.9
3.0
1.1
5.4
3.2
7.9
5.7
10.7
8.3
13.8
11.3
17.1
14.5
20.7
18.0
24.7
21.9
29.0
26.1
33.6
30.6
38.6
35.5
43.9
40.8
49.7
46.6
55.9
52.7
62.5
59.4
69.6
66.5
77.2
74.1
85.3
82.2
94
90.9
103
100
113
110
123
120
134
132
145
143
158
156
170
169
184
183
198
198
213
213
229
230
246
247
263
265
281
284
301
304
321
326
342

Temp
(F)
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

R-422D
Liquid
Vapor
(psig)
(psig)
2.4
2.3
4.6
0.8
7.1
3.0
9.9
5.4
12.9
8.1
16.2
11.0
19.8
14.3
23.7
17.8
27.9
21.7
32.5
25.8
37.5
30.4
42.8
35.3
48.5
40.7
54.7
46.4
61.3
52.6
68.4
59.3
75.9
66.4
84.0
74.0
92.6
82.2
102
90.9
111
100
122
110
133
121
144
132
156
144
169
156
183
170
197
184
212
198
228
214
245
231
262
248
281
266
300
286
320
306
341
327
364
350

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-422B
[F]

Pressure
Liquid
[psia]

Pressure
Vapor
[psia]

Density
Liquid
[lb/ft3]

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

9.1
10.5
12.0
13.7
15.6
17.7
20.0
22.6
25.4
28.5
31.8
35.4
39.4
43.7
48.3
53.3
58.6
64.4
70.6
77.2
84.3
91.9
100.0
109
118
127
138
149
160
172
185
199
213
228
244
260
278
296
315
335
357

6.6
7.7
9.0
10.4
12.0
13.8
15.7
17.9
20.4
23.0
26.0
29.2
32.7
36.6
40.8
45.3
50.2
55.5
61.3
67.4
74.1
81.2
88.8
96.9
106
115
125
135
146
158
170
184
198
212
228
244
262
280
299
319
340

89.17
88.63
88.09
87.54
86.99
86.44
85.88
85.32
84.75
84.17
83.59
83.00
82.41
81.81
81.20
80.58
79.95
79.32
78.67
78.01
77.35
76.67
75.97
75.27
74.55
73.81
73.05
72.28
71.49
70.67
69.83
68.96
68.07
67.14
66.18
65.17
64.13
63.03
61.87
60.64
59.32

0.17
0.20
0.23
0.26
0.30
0.34
0.39
0.44
0.49
0.56
0.62
0.70
0.78
0.86
0.96
1.06
1.17
1.29
1.42
1.57
1.72
1.88
2.06
2.25
2.45
2.68
2.91
3.17
3.45
3.74
4.06
4.41
4.78
5.19
5.63
6.11
6.63
7.21
7.83
8.53
9.31

-5.810
-4.366
-2.916
-1.461
0.000
1.467
2.941
4.421
5.908
7.402
8.904
10.41
11.93
13.46
14.99
16.54
18.09
19.66
21.23
22.82
24.42
26.03
27.65
29.28
30.93
32.60
34.28
35.97
37.69
39.42
41.17
42.95
44.74
46.57
48.42
50.30
52.21
54.16
56.15
58.20
60.29

79.45
80.19
80.94
81.68
82.42
83.16
83.89
84.63
85.35
86.08
86.80
87.51
88.22
88.92
89.62
90.31
90.99
91.66
92.33
92.99
93.63
94.26
94.89
95.50
96.09
96.67
97.23
97.78
98.30
98.81
99.29
99.74
100.2
100.6
100.9
101.2
101.5
101.8
101.9
102.0
102.1

Temp

Refrigerant Reference Guide

53

Entropy
Entropy
Liquid
Vapor
[Btu/R-lb] [Btu/R-lb]
-0.01415
-0.01057
-0.00701
-0.00349
0.00000
0.00346
0.00690
0.01031
0.01370
0.01707
0.02041
0.02373
0.02703
0.03031
0.03358
0.03682
0.04006
0.04327
0.04648
0.04967
0.05285
0.05601
0.05917
0.06233
0.06547
0.06861
0.07175
0.07489
0.07802
0.08116
0.08430
0.08745
0.09060
0.09377
0.09696
0.1002
0.1034
0.1067
0.1100
0.1133
0.1167

0.2022
0.2013
0.2004
0.1996
0.1989
0.1982
0.1976
0.1970
0.1964
0.1959
0.1955
0.1951
0.1947
0.1943
0.1940
0.1937
0.1934
0.1931
0.1929
0.1927
0.1925
0.1923
0.1921
0.1919
0.1918
0.1916
0.1914
0.1912
0.1911
0.1909
0.1907
0.1904
0.1902
0.1899
0.1896
0.1893
0.1889
0.1885
0.1879
0.1874
0.1867

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-422D
Temp
[F]
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

Pressure Pressure
Liquid
Vapor
[psia]
[psia]
10.0
11.5
13.1
15.0
17.1
19.3
21.8
24.6
27.6
30.9
34.5
38.4
42.6
47.2
52.2
57.5
63.2
69.4
76.0
83.1
90.6
98.7
107
116
126
136
147
159
171
184
197
212
227
243
259
277
295
315
335
356
378

7.5
8.8
10.2
11.8
13.5
15.5
17.7
20.1
22.8
25.7
29.0
32.5
36.3
40.5
45.1
50.0
55.4
61.1
67.3
74.0
81.1
88.7
96.9
106
115
125
135
147
158
171
184
198
213
229
245
263
281
300
321
342
364

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

89.08
88.53
87.98
87.42
86.86
86.30
85.73
85.15
84.57
83.98
83.39
82.79
82.18
81.56
80.93
80.30
79.66
79.00
78.34
77.66
76.97
76.27
75.55
74.82
74.07
73.30
72.52
71.71
70.88
70.03
69.15
68.23
67.29
66.31
65.28
64.21
63.08
61.89
60.63
59.28
57.82

0.20
0.23
0.26
0.30
0.34
0.39
0.44
0.50
0.56
0.63
0.71
0.79
0.88
0.98
1.08
1.20
1.32
1.46
1.60
1.76
1.93
2.11
2.30
2.52
2.74
2.99
3.25
3.54
3.84
4.18
4.53
4.92
5.34
5.80
6.30
6.84
7.44
8.09
8.82
9.63
10.55

-5.756
-4.326
-2.890
-1.448
0.000
1.455
2.916
4.384
5.860
7.343
8.835
10.34
11.84
13.36
14.89
16.42
17.97
19.53
21.10
22.68
24.27
25.87
27.49
29.12
30.77
32.43
34.11
35.81
37.53
39.26
41.02
42.80
44.61
46.44
48.31
50.21
52.15
54.13
56.16
58.25
60.41

76.71
77.45
78.19
78.92
79.65
80.39
81.11
81.84
82.56
83.27
83.98
84.69
85.39
86.08
86.77
87.45
88.12
88.78
89.43
90.08
90.71
91.33
91.93
92.53
93.10
93.66
94.21
94.73
95.23
95.70
96.16
96.58
96.97
97.32
97.64
97.91
98.14
98.30
98.40
98.42
98.35

54

Entropy
Entropy
Liquid
Vapor
[Btu/R-lb] [Btu/R-lb]
-0.01402
-0.01047
-0.00695
0.00346
0.00000
0.00343
0.00684
0.01023
0.01359
0.01693
0.02024
0.02354
0.02682
0.03008
0.03332
0.03655
0.03977
0.04297
0.04615
0.04933
0.05250
0.05565
0.05880
0.06194
0.06508
0.06822
0.07135
0.07448
0.07762
0.08076
0.08391
0.08706
0.09023
0.09342
0.09662
0.09986
0.1031
0.1064
0.1098
0.1132
0.1167

0.1951
0.1943
0.1935
0.1928
0.1921
0.1915
0.1909
0.1904
0.1899
0.1894
0.1890
0.1886
0.1883
0.1880
0.1877
0.1874
0.1872
0.1870
0.1868
0.1866
0.1864
0.1863
0.1861
0.1860
0.1858
0.1857
0.1855
0.1853
0.1852
0.1850
0.1848
0.1845
0.1843
0.1840
0.1836
0.1832
0.1828
0.1823
0.1817
0.1810
0.1802

5th Edition 2010

R-500 and R-502


Physical Properties of Refrigerants

R-500

R-502

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating

CFC
99.3
-28.5
605.2
215.8
30.7
73
0.329
86.4
0.2782
0.1725
0.66
8077
A1

CFC
111.6
-49.5
582.8
177.3
35.5
77
0.388
74.2
0.2958
0.1641
0.23
4657
A1

R-500
(R-12/152a)
(73.8 / 26.2 wt%)

Application:

Air conditioning, dehumidifiers and centrifugal chillers

Lubricant
Recommendation: Compatible with mineral and alkylbenzene oil
Retrofitting to:

R-134a
R-401A, R-401B
R-409A
R-414B

consult equipment manufacturer


page 97
page 97
page 97

R-502
(R-22/115)
(48.8 / 51. 2 wt%)

Application:

Low temperature commercial and industrial direct


expansion refrigeration and ice machines

Lubricant
Recommendation: Compatible with mineral and alkylbenzene oil
Retrofitting to:

R-402A, R-402B
R-404A, R-507
R-408A
R-422C

Refrigerant Reference Guide

page
page
page
page

98
99
98
100

55

Technical
Guidelines
Available in the
following sizes
R-500
30 LB. CYLINDER
125 LB. CYLINDER
R-502
30 LB. CYLINDER
125 LB. CYLINDER

Pressure-Temp Chart
R-500
(psig)

Temp
(F)

R-502
(psig)

7.6
4.6
1.2
1.2
3.2
5.4
7.8
10.4
13.3
16.4
19.7
23.4
27.3
31.5
36.0
40.9
46.1
51.6
57.6
63.9
70.6
77.8
85.4
93.5
102
111
121
131
141
152
164
177
189
203
217
232
248

-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

4.1
6.5
9.2
12.1
15.3
18.8
22.6
26.7
31.1
35.9
41.0
46.5
52.4
58.8
65.6
72.8
80.5
88.7
97.4
107
116
127
138
149
161
174
187
201
216
232
248
265
283
301
321
341
363

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-500
Temp
[F]
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155

Pressure
Liquid
[psia]
6.3
7.3
8.4
9.6
11.0
12.5
14.2
16.0
18.0
20.2
22.6
25.3
28.1
31.3
34.6
38.3
42.2
46.4
50.9
55.8
61.0
66.6
72.5
78.9
85.6
92.8
100.4
108.4
116.9
125.9
135.4
145.5
156.1
167.2
178.9
191.2
204.1
217.7
231.9
246.8
262.4
278.7
295.7
313.6

Pressure
Vapor
[psia]
6.3
7.3
8.4
9.6
11.0
12.5
14.2
16.0
18.0
20.2
22.6
25.3
28.1
31.2
34.6
38.2
42.1
46.4
50.9
55.7
60.9
66.5
72.4
78.7
85.4
92.5
100.1
108.1
116.6
125.5
135.0
145.0
155.5
166.6
178.2
190.4
203.3
216.8
230.9
245.7
261.2
277.4
294.4
312.1

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
85.26
84.81
84.35
83.89
83.43
82.97
82.50
82.03
81.55
81.07
80.59
80.10
79.61
79.11
78.61
78.10
77.59
77.07
76.55
76.01
75.48
74.93
74.38
73.82
73.25
72.67
72.08
71.48
70.87
70.25
69.62
68.98
68.32
67.64
66.95
66.25
65.52
64.77
64.00
63.21
62.39
61.54
60.66
59.73

Density
Vapor
[lb/ft3]
0.1498
0.1713
0.1951
0.2215
0.2506
0.2826
0.3177
0.3561
0.3980
0.4436
0.4932
0.5470
0.6053
0.6682
0.7362
0.8095
0.8883
0.9730
1.064
1.161
1.266
1.378
1.497
1.625
1.761
1.907
2.062
2.228
2.405
2.593
2.794
3.008
3.236
3.479
3.739
4.016
4.313
4.630
4.970
5.335
5.726
6.148
6.604
7.097

56

Enthalpy
Liquid
[Btu/lb]
-5.016
-3.770
-2.519
-1.262
0.000
1.268
2.541
3.820
5.106
6.397
7.695
9.000
10.31
11.63
12.96
14.29
15.63
16.98
18.34
19.70
21.08
22.46
23.85
25.25
26.66
28.09
29.52
30.96
32.42
33.89
35.37
36.86
38.37
39.89
41.43
42.99
44.56
46.15
47.77
49.40
51.06
52.74
54.45
56.20

Enthalpy
Vapor
[Btu/lb]
85.98
86.63
87.27
87.92
88.56
89.20
89.83
90.47
91.10
91.73
92.35
92.97
93.58
94.19
94.80
95.40
95.99
96.58
97.16
97.73
98.29
98.85
99.40
99.94
100.5
101.0
101.5
102.0
102.5
102.9
103.4
103.8
104.3
104.7
105.0
105.4
105.8
106.1
106.4
106.6
106.9
107.1
107.2
107.3

Entropy
Liquid
[Btu/R-lb]
-0.01222
-0.00913
0.00606
0.00302
0.00000
0.00299
0.00597
0.00892
0.01185
0.01476
0.01765
0.02052
0.02337
0.02621
0.02903
0.03184
0.03463
0.03741
0.04017
0.04292
0.04566
0.04838
0.05110
0.05381
0.05650
0.05919
0.06187
0.06455
0.06722
0.06988
0.07254
0.07520
0.07785
0.08051
0.08316
0.08582
0.08849
0.09115
0.09383
0.09652
0.09922
0.1019
0.1047
0.1074

Entropy
Vapor
[Btu/R-lb]
0.2155
0.2143
0.2131
0.2120
0.2110
0.2100
0.2091
0.2083
0.2074
0.2066
0.2059
0.2052
0.2045
0.2039
0.2033
0.2027
0.2022
0.2016
0.2011
0.2007
0.2002
0.1998
0.1993
0.1989
0.1985
0.1982
0.1978
0.1974
0.1970
0.1967
0.1963
0.1960
0.1956
0.1952
0.1949
0.1945
0.1941
0.1937
0.1933
0.1928
0.1923
0.1918
0.1913
0.1907

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-502
Temp
[F]
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

Pressure
Liquid
[psia]
11.1
12.7
14.5
16.5
18.7
21.1
23.7
26.6
29.8
33.2
37.0
41.0
45.4
50.1
55.2
60.7
66.6
72.9
79.6
86.8
94.5
102.7
111.4
120.6
130.4
140.7
151.7
163.3
175.5
188.4
201.9
216.2
231.3
247.1
263.6
281.0
299.3
318.4
338.5
359.5
381.4

Pressure
Vapor
[psia]
10.9
12.5
14.3
16.3
18.5
20.9
23.5
26.4
29.6
33.0
36.8
40.8
45.2
50.0
55.1
60.6
66.5
72.8
79.5
86.7
94.4
102.6
111.3
120.5
130.3
140.7
151.6
163.2
175.4
188.3
201.9
216.2
231.2
247.0
263.6
281.0
299.3
318.4
338.5
359.5
381.4

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
93.91
93.35
92.78
92.20
91.62
91.04
90.45
89.85
89.25
88.64
88.03
87.40
86.78
86.14
85.49
84.84
84.17
83.50
82.82
82.12
81.42
80.70
79.97
79.22
78.46
77.68
76.88
76.07
75.23
74.37
73.49
72.58
71.64
70.66
69.65
68.59
67.48
66.32
65.08
63.77
62.36

Density
Vapor
[lb/ft3]
0.2941
0.3342
0.3786
0.4273
0.4808
0.5394
0.6034
0.6731
0.7490
0.8313
0.9205
1.017
1.121
1.234
1.355
1.486
1.626
1.777
1.939
2.113
2.299
2.499
2.712
2.942
3.187
3.450
3.731
4.033
4.357
4.705
5.079
5.481
5.914
6.382
6.889
7.438
8.037
8.692
9.412
10.21
11.10

57

Enthalpy
Liquid
[Btu/lb]
-4.736
-3.561
-2.380
-1.193
0.000
1.200
2.406
3.619
4.839
6.066
7.301
8.544
9.795
11.05
12.32
13.60
14.89
16.18
17.49
18.80
20.13
21.47
22.82
24.18
25.56
26.95
28.35
29.77
31.20
32.66
34.13
35.62
37.13
38.67
40.23
41.82
43.44
45.10
46.80
48.55
50.36

Enthalpy
Vapor
[Btu/lb]
70.99
71.59
72.18
72.77
73.36
73.95
74.53
75.11
75.68
76.25
76.81
77.37
77.92
78.47
79.00
79.53
80.06
80.57
81.07
81.57
82.05
82.52
82.98
83.43
83.86
84.28
84.68
85.07
85.43
85.78
86.10
86.40
86.67
86.91
87.11
87.28
87.41
87.49
87.51
87.47
87.35

Entropy
Liquid
[Btu/R-lb]
-0.01153
-0.00861
-0.00572
-0.00285
0.00000
0.00283
0.00564
0.00843
0.01121
0.01397
0.01671
0.01944
0.02216
0.02486
0.02755
0.03023
0.03290
0.03556
0.03821
0.04085
0.04348
0.04611
0.04874
0.05135
0.05397
0.05658
0.05920
0.06181
0.06442
0.06704
0.06967
0.07230
0.07495
0.07761
0.08029
0.08298
0.08571
0.08847
0.09127
0.09412
0.09704

Entropy
Vapor
[Btu/R-lb]
0.1781
0.1772
0.1764
0.1756
0.1749
0.1742
0.1736
0.1730
0.1724
0.1719
0.1713
0.1709
0.1704
0.1700
0.1696
0.1692
0.1688
0.1684
0.1681
0.1677
0.1674
0.1671
0.1668
0.1665
0.1662
0.1659
0.1656
0.1652
0.1649
0.1646
0.1642
0.1639
0.1635
0.1630
0.1626
0.1621
0.1616
0.1610
0.1603
0.1596
0.1587

5th Edition 2010

Technical
Guidelines

R-503
Physical Properties of Refrigerants

R-503

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (20 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (20 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 20 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating

CFC
87.25
-125.5
618.6
65.2
34.4
68.4
0.373
77.1
0.3671
0.1537
0.06
14560
A1

Available in the
following sizes
R-503
5 LB. CYLINDER
9 LB. CYLINDER
20 LB. CYLINDER
80 LB. CYLINDER

Pressure-Temp Chart

R-503

(R-23/13)
(40.1 / 59.9 wt%)

Applications:

Very low temperature refrigeration


(low stage of a cascade system)

Performance:

R-503 runs with better capacity and lower discharge


pressure than R-13
Operates in the low temperature stage of the cascade
system because of its low boiling point

Lubricant
Recommendation: Compatible with mineral oil
Retrofitting to:

R-508B

page 101

See Ultra Low Temperature Refrigeration Section page 64-65

Refrigerant Reference Guide

58

Temp
(F)

R-503
(psig)

-125
-120
-115
-110
-105
-100
-95
-90
-85
-80
-75
-70
-65
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
-0
5
10
15
20

0.5
3.1
6.0
9.3
12.9
16.9
21.4
26.3
31.8
37.7
44.2
51.3
59.0
67.3
76.4
86.1
96.6
108
120
133
147
161
177
194
212
230
250
272
294
318

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-503
Temp
[F]
-140
-135
-130
-125
-120
-115
-110
-105
-100
-95
-90
-85
-80
-75
-70
-65
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
5
0
5
10
15
20

Pressure Pressure
Vapor
Liquid
[psia]
[psia]
9.1
10.8
12.7
14.9
17.4
20.3
23.5
27.0
31.0
35.4
40.2
45.6
51.4
57.9
64.9
72.5
80.8
89.7
99.4
109.9
121.1
133.2
146.1
160.0
174.8
190.5
207.3
225.2
244.1
264.2
285.6
308.1
332.0

9.1
10.8
12.7
14.9
17.4
20.2
23.4
26.9
30.9
35.2
40.0
45.3
51.1
57.5
64.4
72.0
80.1
89.0
98.6
108.9
120.0
131.9
144.7
158.3
172.9
188.5
205.1
222.7
241.5
261.4
282.5
304.8
328.5

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]

Density
Vapor
[lb/ft3]

Enthalpy
Liquid
[Btu/lb]

Enthalpy
Vapor
[Btu/lb]

Entropy
Liquid
[Btu/R-lb]

Entropy
Vapor
[Btu/R-lb]

94.67
94.04
93.40
92.75
92.09
91.43
90.75
90.06
89.36
88.65
87.93
87.19
86.44
85.67
84.89
84.09
83.28
82.45
81.60
80.72
79.83
78.91
77.96
76.99
75.99
74.95
73.87
72.76
71.59
70.37
69.09
67.74
66.31

0.2374
0.2788
0.3257
0.3785
0.4377
0.5039
0.5776
0.6595
0.7500
0.8500
0.9601
1.081
1.214
1.359
1.517
1.690
1.878
2.083
2.306
2.549
2.812
3.097
3.408
3.745
4.112
4.511
4.946
5.421
5.941
6.512
7.142
7.839
8.616

-25.81
-24.60
-23.39
-22.16
-20.94
-19.70
-18.46
-17.21
-15.95
-14.68
-13.40
-12.12
-10.82
-9.512
-8.192
-6.861
-5.517
-4.159
-2.788
-1.402
0.000
1.419
2.855
4.312
5.789
7.289
8.813
10.37
11.95
13.56
15.22
16.92
18.67

53.32
53.82
54.30
54.79
55.26
55.73
56.19
56.64
57.08
57.51
57.93
58.34
58.74
59.12
59.49
59.85
60.19
60.51
60.82
61.11
61.37
61.62
61.84
62.04
62.21
62.35
62.45
62.52
62.54
62.52
62.44
62.30
62.09

-0.06936
-0.06562
-0.06192
-0.05826
-0.05464
-0.05105
-0.04748
-0.04395
-0.04045
-0.03698
-0.03352
-0.03010
-0.02669
-0.02330
-0.01993
-0.01658
-0.01324
-0.00992
-0.00660
-0.00330
0.00000
0.00329
0.00659
0.00988
0.01318
0.01648
0.01980
0.02313
0.02648
0.02987
0.03329
0.03676
0.04029

0.1782
0.1759
0.1737
0.1717
0.1697
0.1678
0.1660
0.1643
0.1627
0.1611
0.1595
0.1580
0.1566
0.1552
0.1539
0.1525
0.1513
0.1500
0.1488
0.1476
0.1464
0.1452
0.1440
0.1428
0.1416
0.1404
0.1392
0.1379
0.1367
0.1353
0.1339
0.1325
0.1309

59

5th Edition 2010

Technical
Guidelines

R-507
Physical Properties of Refrigerants

R-507

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (70 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (70 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 70 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating

HFC
98.9
-52.8
539
159
30.7
66.65
0.349
84.35
0.3593
0.2064
0
3985
A1

R-507

(R-125/143a)
(50 / 50 wt%)

Applications:

Medium and low temperature commercial refrigeration


and industrial refrigeration

Performance:

Similar to R-404A in operation


Pressure and capacity are slightly higher than R-404A

Lubricant
Recommendation: Compatible with polyolester lubricant
Retrofitting:

from R-502
from R-22

Refrigerant Reference Guide

page 99
page 96

60

Available in the
following sizes
R-507
25 LB. CYLINDER
100 LB. CYLINDER
800 LB. CYLINDER
1400 LB. CYLINDER

Pressure-Temp Chart
Temp
(F)

R-507
(psig)

-40
-35
-30
-25
-20
-15
-10
-5
-0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150

5.5
8.2
11.1
14.3
17.8
21.7
25.8
30.3
35.2
40.5
46.1
52.2
58.8
65.8
73.3
81.3
89.8
98.9
109
119
130
141
154
167
180
195
210
226
244
252
281
301
322
344
368
393
419
446
475

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-507
Temp
[F]
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140

Pressure
Liquid
[psia]
12.1
13.9
15.8
18.0
20.4
23.1
26.0
29.2
32.7
36.5
40.7
45.2
50.1
55.3
61.0
67.1
73.6
80.6
88.1
96.1
104.7
113.8
123.5
133.8
144.7
156.3
168.5
181.5
195.1
209.6
224.8
240.8
257.7
275.5
294.2
313.8
334.4
356.1
378.8
402.7
427.9

Pressure
Vapor
[psia]
12.1
13.9
15.8
18.0
20.4
23.1
26.0
29.2
32.7
36.5
40.7
45.2
50.0
55.3
60.9
67.0
73.6
80.6
88.1
96.1
104.6
113.7
123.4
133.7
144.6
156.1
168.3
181.3
194.9
209.4
224.6
240.6
257.5
275.2
293.9
313.5
334.1
355.8
378.6
402.5
427.6

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
83.10
82.57
82.03
81.49
80.94
80.39
79.83
79.27
78.70
78.12
77.53
76.94
76.34
75.73
75.11
74.48
73.84
73.18
72.52
71.84
71.15
70.45
69.73
68.99
68.23
67.45
66.65
65.82
64.97
64.08
63.17
62.21
61.21
60.17
59.07
57.91
56.67
55.34
53.89
52.29
50.50

Density
Vapor
[lb/ft3]
0.2899
0.3298
0.3738
0.4223
0.4756
0.5340
0.5980
0.6678
0.7439
0.8267
0.9166
1.014
1.120
1.234
1.357
1.491
1.634
1.789
1.956
2.136
2.329
2.537
2.761
3.002
3.262
3.541
3.843
4.169
4.521
4.902
5.315
5.764
6.255
6.792
7.382
8.035
8.762
9.580
10.51
11.59
12.86

61

Enthalpy
Liquid
[Btu/lb]
-5.871
-4.416
-2.952
-1.480
0.000
1.489
2.987
4.494
6.010
7.537
9.073
10.62
12.18
13.75
15.33
16.92
18.52
20.14
21.77
23.42
25.08
26.76
28.45
30.17
31.90
33.65
35.42
37.21
39.03
40.87
42.75
44.65
46.59
48.57
50.59
52.66
54.79
56.98
59.26
61.64
64.17

Enthalpy
Vapor
[Btu/lb]
79.54
80.26
80.98
81.69
82.40
83.11
83.81
84.51
85.20
85.88
86.56
87.23
87.89
88.55
89.19
89.83
90.45
91.07
91.67
92.26
92.84
93.40
93.94
94.47
94.97
95.46
95.92
96.36
96.77
97.15
97.50
97.80
98.07
98.28
98.43
98.52
98.53
98.44
98.24
97.87
97.30

Entropy
Liquid
[Btu/R-lb]
-0.01429
-0.01068
-0.00709
-0.00354
0.00000
0.00351
0.00700
0.01047
0.01392
0.01735
0.02077
0.02417
0.02755
0.03091
0.03427
0.03761
0.04094
0.04426
0.04757
0.05087
0.05417
0.05746
0.06075
0.06404
0.06733
0.07062
0.07392
0.07722
0.08053
0.08386
0.08720
0.09056
0.09395
0.09737
0.1008
0.1043
0.1079
0.1116
0.1153
0.1192
0.1233

Entropy
Vapor
[Btu/R-lb]
0.1994
0.1986
0.1978
0.1970
0.1964
0.1957
0.1951
0.1946
0.1940
0.1935
0.1931
0.1927
0.1923
0.1919
0.1915
0.1912
0.1909
0.1906
0.1903
0.1900
0.1898
0.1895
0.1892
0.1890
0.1887
0.1884
0.1882
0.1879
0.1875
0.1872
0.1868
0.1864
0.1859
0.1854
0.1848
0.1842
0.1834
0.1825
0.1814
0.1801
0.1785

5th Edition 2010

Technical
Guidelines

R-508B
Physical Properties of Refrigerants

R-508B

Environmental Classification
Molecular Weight
Boiling Point (1 atm, F)
Critical Pressure (psia)
Critical Temperature (F)
Critical Density, (lb./ft^ 3)
Liquid Density (20 F, lb./ft ^ 3)
Vapor Density (bp, lb./ft ^ 3)
Heat of Vaporization (bp, BTU/lb.)
Specific Heat Liquid (20 F, BTU/lb. F)
Specific Heat Vapor (1 atm, 20 F, BTU/lb. F)
Ozone Depletion Potential (CFC 11 = 1.0)
Global Warming Potential (CO2 = 1.0)
ASHRAE Standard 34 Safety Rating

HFC
95.4
-125.3
556.1
53.7
35.6
65.4
0.426
71.4
0.4221
0.1701
0
13400
A1

R-508B

(R-23/116)
(46 / 54 wt%)

Available in the
following sizes
R-508B
5 LB. CYLINDER
10 LB. CYLINDER
20 LB. CYLINDER
70 LB. CYLINDER

Pressure-Temp Chart

Replaces:

R-503 and R-13

Applications:

Very low temperature refrigeration


(low stage of a cascade system)

Performance:

PT properties are very similar to R-503 and can be used to


replace R-13 or R-503 in an existing system
Higher capacity and lower discharge temperature
compared to R-23

Lubricant
Recommendation: Compatible with polyolester lubricant; it may still be
necessary to use hydrocarbon additives to help with
oil circulation

Retrofitting:

from R-503
from R-13

page 101
page 101

See Ultra Low Temperature Refrigeration Section - page 64-65

Refrigerant Reference Guide

62

Temp
(F)

R-508B
(psig)

-125
-120
-115
-110
-105
-100
-95
-90
-85
-80
-75
-70
-65
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20

0.5
3.1
6.0
9.3
12.9
16.9
21.4
26.4
31.8
37.8
44.4
51.5
59.3
67.8
76.9
86.8
97.5
109
121
135
149
164
180
197
216
235
256
278
301
326

5th Edition 2010

Technical
Guidelines
THERMODYNAMIC PROPERTIES OF R-508B
Temp
[F]
-160
-155
-150
-145
-140
-135
-130
-125
-120
-115
-110
-105
-100
-95
-90
-85
-80
-75
-70
-65
-60
-55
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20

Pressure
Liquid
[psia]
4.1
5.1
6.2
7.5
8.9
10.6
12.6
14.8
17.4
20.2
23.4
27.0
31.0
35.5
40.4
45.8
51.7
58.3
65.4
73.2
81.6
90.7
100.6
111.3
122.8
135.2
148.4
162.6
177.8
194.0
211.3
229.7
249.3
270.1
292.2
315.7
340.6

Pressure
Vapor
[psia]
3.9
4.8
5.9
7.2
8.6
10.3
12.3
14.5
17.1
19.9
23.1
26.7
30.8
35.2
40.1
45.6
51.6
58.1
65.3
73.0
81.5
90.7
100.6
111.3
122.8
135.1
148.4
162.6
177.8
194.0
211.3
229.6
249.2
270.0
292.1
315.6
340.5

Refrigerant Reference Guide

Density
Liquid
[lb/ft3]
100.7
99.96
99.24
98.52
97.80
97.08
96.37
95.65
94.92
94.19
93.45
92.70
91.94
91.18
90.39
89.60
88.79
87.96
87.12
86.25
85.36
84.45
83.51
82.55
81.55
80.52
79.45
78.34
77.18
75.98
74.72
73.40
72.02
70.56
69.02
67.39
65.63

Density
Vapor
[lb/ft3]
0.1181
0.1438
0.1737
0.2083
0.2482
0.2937
0.3455
0.4041
0.4701
0.5441
0.6269
0.7191
0.8214
0.9347
1.060
1.198
1.349
1.515
1.697
1.896
2.114
2.351
2.611
2.893
3.202
3.539
3.906
4.308
4.748
5.231
5.763
6.350
7.000
7.725
8.540
9.461
10.52

63

Enthalpy
Liquid
[Btu/lb]
-32.27
-30.98
-29.70
-28.42
-27.14
-25.86
-24.57
-23.29
-22.00
-20.70
-19.40
-18.09
-16.77
-15.45
-14.11
-12.76
-11.40
-10.03
-8.648
-7.249
-5.834
-4.403
-2.955
-1.487
0.000
1.509
3.041
4.598
6.182
7.796
9.441
11.12
12.84
14.59
16.40
18.26
20.18

Enthalpy
Vapor
[Btu/lb]
44.15
44.72
45.29
45.85
46.40
46.95
47.49
48.03
48.56
49.08
49.59
50.10
50.59
51.08
51.56
52.02
52.48
52.92
53.35
53.76
54.17
54.55
54.92
55.27
55.60
55.90
56.18
56.44
56.66
56.85
56.99
57.10
57.15
57.13
57.05
56.88
56.60

Entropy
Liquid
[Btu/R-lb]
-0.08953
-0.08527
-0.08109
-0.07699
-0.07297
-0.06900
-0.06509
-0.06124
-0.05743
-0.05366
-0.04993
-0.04623
-0.04256
-0.03892
-0.03531
-0.03172
-0.02815
-0.02460
-0.02106
-0.01753
-0.01402
-0.01051
-0.00701
-0.00350
0.00000
0.00351
0.00702
0.1055
0.01409
0.01765
0.02123
0.02484
0.02849
0.03218
0.03592
0.03972
0.04361

Entropy
Vapor
[Btu/R-lb]
0.1664
0.1640
0.1618
0.1596
0.1576
0.1557
0.1539
0.1522
0.1505
0.1490
0.1476
0.1462
0.1449
0.1436
0.1424
0.1412
0.1401
0.1391
0.1381
0.1371
0.1361
0.1352
0.1343
0.1334
0.1325
0.1316
0.1307
0.1298
0.1289
0.1280
0.1270
0.1260
0.1249
0.1237
0.1225
0.1211
0.1195

5th Edition 2010

Ultra-Low Temperature Refrigeration


Ultra-low temperature systems are used to achieve low temperature baths or boxes for laboratory
use, storage of pharmaceutical or biological samples, low temperature manufacturing of metals, or
extreme-temperature-environment testing.
The lowest temperature that can practically be achieved in single-stage refrigeration systems is
about -40F to -50F. A single-stage system is limited by the compression ratio of the compressor
and the ambient temperature in which it must condense the refrigerant. Temperatures from -50F
down to -120F or lower can only be achieved economically by using cascade refrigeration systems.
A typical cascade system is shown in Figure 1. A standard refrigeration system is used on the high
side (a) to create a cold temperature in the cascade condenser (b). The low side system (c) is able
to condense at -20F to -30F and evaporate as low as -120F with the available refrigerants before
they go into vacuum. Larger systems tend to have some kind of oil separator and oil management
system (d) to keep the oil in the compressor. Some systems also employ an expansion tank (e) to
keep the refrigerant from generating extreme pressures at room temperature when the system is off.

Refrigerant Reference Guide

64

5th Edition 2010

Ultra-Low Temperature Refrigeration


Traditional High Side Refrigerants:
Alternative High Side Refrigerants:

R-12,
R-134a,

R-22,
R-404A,

Traditional Low Side Refrigerants:


Alternative Low Side Refrigerants:

R-13,
R-23,

R-503
R-508B

R-502
R-507

Oil Circulation: Standard refrigeration oils will become very thick at low temperatures and will not
flow around the system back to the compressor. If the compressor gets too cold, the oil will gel inside
the compressor sump and not provide lubrication. Many systems rely on the refrigerant to soak into
the oil and move it around the system. This method of oil circulation works well down to about -100F
evaporator temperature. In addition, systems with short run times will allow the oil to return to the
compressor when the evaporator warms.
Systems that run for longer times at colder temperatures, or involve complicated piping, will need to
use an oil separator after the low stage compressor(s). In addition, hydrocarbon refrigerants are
typically added to the system so they can soak into the oil and keep it fluid at very low temperatures.
The amount of hydrocarbon used is typically between 5 - 10% (by weight) of the refrigerant charge.
National Refrigerants, Inc. supplies these hydrocarbons for use in cascade systems:
Part No.
3R170
004R170
004R1150
016R600
016R600a
014R290
016RPENTANE

Size
3 lb. cyl
4 oz. cyl.
4 oz cyl.
16 oz. cyl
16 oz. cyl
14 oz. cyl.
16 oz. can

Product
R-170 (ETHANE)
R-170 (ETHANE)
R-1150 (ETHYLENE)
R-600 (BUTANE)
R-600a (ISOBUTANE)
R-290 (PROPANE)
PENTANE LIQUID

Moisture: Removal of moisture is more important in cascade systems than it is at higher temperature
ranges. Refrigerants such as R-22 and R-404A can absorb and carry much more water than the
10 ppm specification and the 30 to 50 ppm indication level of a sight glass. In contrast, R-13 is estimated to only hold about 0.1 ppm of water at -80F. Excess moisture will definitely separate from the
refrigerant and clog capillary tubes or cause other problems. Maintenance of driers is very important
in the low stage of a cascade system.
Expansion Volume: Refrigerants in the low stage must maintain normal operating pressures in the
compressor at very low temperatures. These refrigerants will condense around -30F to -20F at
pressures from 110 psig to 160 psig. When these refrigerants warm up to room temperature,
however, the saturation pressure, or in some cases the critical pressure, can exceed 700 psig.
Rather than going to the expense of building systems to withstand these pressures, an expansion
tank or other system volume is provided. The charge expands into the extra volume, allowing all
liquid to boil completely to vapor. Simple gas laws dictate how much volume is needed to keep the
charge at a gas pressure of usually no more than 250 psig. Consequently, systems are often charged
simply by bringing the empty system up to some static pressure.
For additional information on Retrofitting, see page 101
Refrigerant Reference Guide

65

5th Edition 2010

Refrigerant Reference Guide

66

5th Edition 2010

PMS #
0211
N/A
2975
266
302
413
177
352
428
428
335
2975
177
124
461
385
413
021
368
471
248
465
507
2995
381
3275
1495
375
109
251
3268
326
302

Color
Orange
White
Light Blue
Dark Purple
Navy Blue
Light Gray
Pinkish-Red
Light Green
Light Blue Gray
Light Blue Gray
DOT Green
Light Blue
Pinkish-Red
Yellow-Brown
Light Brown
Green-Brown
Light Gray
Orange
Lime Green
Brown
Medium Purple
Medium Brown
Rose
Medium Blue
Yellow-Green
Green
Pale Orange
Navy Blue
Yellow
Green-Yellow
Yellow
Light Purple
Blue -Green
Aqua Blue
Navy Blue

Chemical Name
Trichlorofluoromethane
Dichlorodifluoromethane
Chlorotrifluoromethane
Trichlorotrifluoroethane
Dichlorotetrafluoroethane
Dichlorodifluoromethane, Dichlorotetrafluoroethane
Bromotrifluoromethane
Chlorodifluoromethane
Trifluoromethane
Dichlorotrifluoroethane
Chlorotetrafluoroethane
Tetrafluoroethane
Chlorodifluoromethane, Difluoroethane, Chlorotetrafluoroethane
Chlorodifluoromethane, Difluoroethane, Chlorotetrafluoroethane
Chlorodifluoromethane, Pentafluoroethane, Propane
Chlorodifluoromethane, Pentafluoroethane, Propane
Chlorodifluoromethane, Pentafluoroethane, Propane
Pentafluoroethane, Trifluoroethane, Tetrafluoroethane
Difluoromethane,Pentafluoroethane, Tetrafluoroethane
Difluoromethane, Pentafluoroethane, Tetrafluoroethane
Chlorodifluoromethane, Trifluoroethane, Pentafluoroethane
Chlorodifluoromethane, Chlorotetrafluoroethane, Chlorodifluoroethane
Difluoromethane, Pentafluoroethane
Chlorodifluoromethane, Chlorotetrafluoroethane, Chlorodifluoroethane, Isobutane
Tetrafluoroethane, Chlorotetrafluoroethane, Butane
Pentafluoroethane, Tetrafluoroethane, Butane
Pentafluoroethane, Tetrafluoroethane, Isobutane
Pentafluoroethane, Tetrafluoroethane, Isobutane
Pentafluoroethane, Tetrafluoroethane, Isobutane
Pentafluroroethane, Tetrafluoroethane, Isobutane
Dichlorodifluoromethane, Difluoroethane
Chlorodifluoromethane, Chloropentafluoroethane
Chlorotrifluoromethane, Trifluoroethane
Pentafluoroethane, Trifluoroethane
Trifluoromethane, Hexafluoroethane

Refrigerant

R-11
R-12
R-13
R-113
R-114
R-12/114
R-13B1
R-22
R-23
R-123
R-124
R-134a
R-401A
R-401B
R-402A
R-402B
R-403B
R-404A
R-407A
R-407C
R-408A
R-409A
R-410A
R414B
R-416A
R-417A
R-422A
R-422B
R-422C
R-422D
R-500
R-502
R-503
R-507
R-508B

Refrigerant Color Codes (AHRI Guideline N)

2. Retrofits and Conversions

Blend Terminology and Issues


- Fractionation
- Temperature Glide
- Application Property Match

General Retrofit Guidelines


- Checklist and Data Sheet
- Retrofit Procedures by Product
- Sizing Thermostatic Expansion
Devices (TXV)

Refrigerant Reference Guide

67

Page
68 - 87
68
77
85

88 - 89
90 -101
102 - 104

5th Edition 2010

Introduction to Retrofitting
Background
The components of a specific piece of air conditioning or refrigeration equipment have been
engineered specifically around the properties of the refrigerant used. When replacement of that
refrigerant becomes necessary for technical, regulatory, or economic reasons, the replacement
refrigerant should have as many properties similar to the original refrigerant as possible. This will
minimize hardware changes, controls adjustments, or other time consuming operations such as
oil changes.
Since the late 1980s, the development of blends has focused on matching the properties of the
original refrigerant in order to offer some advantage over the competing blends. Early R-12 blends
focused on evaporator performance in refrigeration systems; however, it became clear that more
R-12 was sold for use in automotive air conditioning rather than in refrigeration. Since these
systems experience higher condenser temperatures, a second wave of blends came into the
market that had lower head pressures.
Manufacturers introduced R-502 retrofit blends that simply removed the R-115, a CFC, and mixed
HFC components with R-22. While this approach was very effective at reducing R-502 use during
the transition away from CFCs in the mid 1990s, it now leaves equipment owners with the challenge
of replacing the HCFC-based blends again.
As early as 1992, manufacturers and suppliers of R-22 based air conditioning equipment were
looking for alternatives. While the focus was mainly on replacing R-22 for newly built equipment,
several retrofit blends were also identified in the process.

Today
2010 begins the first year of restriction on the use of R-22 in new equipment. Although R-22 will
still be available for servicing, available quantities will be more and more limited and the need for
retrofitting will increase. Some market applications, such as residential and commercial air conditioning, have not had to deal with the product restrictions that have occurred over the last 15 years.
They will now see many new products that behave dramatically different than R-22.

Blends Tutorial
The following information is designed to help technicians understand how blends are different
from single-component refrigerants. Fractionation and temperature glide are explained in a way
that shows the effect on system operation and controls. Actual products and their impact on the
market are discussed, and retrofit procedures are provided for a variety of products and equipment.

Refrigerant Reference Guide

68

5th Edition 2010

Blends
Tutorial

Single Components vs. Blends

P=P*A

P=P*B

B
A+ B

By Convention, Higher Pressure Component is First (P*A > P*B )

Blends are made up of two or more single component refrigerants. When mixing refrigerants,
for example, refrigerant A and refrigerant B, we generally speak about the higher pressure,
higher capacity component first. For purposes of this tutorial, A will be the higher pressure product.
When two or more refrigerants are placed into the same container, one of two situations will
occur, depending on how strongly the different molecules are attracted to each other:
Azeotrope: a blend that behaves like a single component refrigerant. When a blend
forms an azeotrope, it displays unique and unexpected properties.
Zeotrope: a blend that behaves like a mixture of the individual components. Zeotropes
have predictable properties based on combinations of the pure components properties.
Two properties of concern are Fractionation and Temperature Glide. We can split the zeotropic
blends into Low Fractionation Potential, which also exhibit Low Temperature Glide, and High
Fractionation Potential, which also exhibit High Temperature Glide. Generally speaking, zeotropic
blends with lower temperature glides do not show the same problems with fractionation
that are seen with higher glide blends.

Refrigerant Reference Guide

69

5th Edition 2010

Blends
Tutorial

Pressure Temperature Curves


for Refrigerant Blends
Azeotropic Behavior

Zeotropic Behavior

BPA

BPA
Max

Liq.

OR
Vap.

Min
BPB

BPB

(A+B)

(A+B)

Azeotrope: a special case where the refrigerants combine in a unique way. In an azeotropic composition,
the blend behaves like a single refrigerant with its own pressure-temperature (P-T) relationship. The
pressure after mixing is either higher than the pressures of the individual components, or is lower than
either component. Because the refrigerants are attracted to each other in a special way, the vapor in
equilibrium with the liquid is at the same composition during phase change.
Note: The azeotropic composition depends on temperature. The same combination
of refrigerants may form an azeotrope at a different ratio, or not at all, at some other
temperature.
Zeotrope: the P-T relationship is a natural combination of the components properties. The pressure
for the blend falls between the pressures of its components and can be calculated according to
established formulas. Considering the P-T relationship for each refrigerant, the resulting pressure and
the vapor composition above the liquid for any given liquid composition can be calculated.
In general, if a lot of A is mixed with B, then the blend will have a pressure close to A. If more B is in the
mix, then the blend will have a pressure close to B. If you mix equal amounts, the resulting pressure will
fall in between. Blend compositions can be adjusted so the blend properties fall exactly where you want.
The problem, however, is that you usually cant get all the properties to match the original refrigerant
under all conditions. You must trade off which properties you want to match and which ones that will
be different.
Refrigerant Reference Guide

70

5th Edition 2010

Blends
Tutorial

New Variable: Composition


C1

C2

C3

Pressure

HCFC

*
(evap.)

(cyl.)

(cond.)

Temperature

Once a blend is mixed at a given composition, the pressure-temperature relationships follow


the same general rules for pure components; for example, the pressure goes up when the
temperature goes up. For three blends containing different amounts of A and B, the pressure
curve is similarly shaped, but the resulting pressure will be higher for the blend which contains
more of the A (higher pressure) component.
Refrigerant blends that are intended to match some other product (R-22, for example) will rarely
match the pressure at all points in the desired temperature range. More commonly, the pressure
of the blend will match in one temperature range, but will be different elsewhere.
In the above example, the blend with concentration C1 matches the pure refrigerant at cold
evaporator temperatures, but the pressure runs higher at condenser conditions. The blend with
composition C2 matches closer to room temperature and, for example, might show the same
pressure in a cylinder being stored. The operating pressures at evaporator and condenser
temperatures, however, will be somewhat different. Finally, the blend at C3 will generate the same
pressures at hot condenser conditions, but the evaporator must run at lower pressures to get the
same temperature. The choice of where the blend matches the pressure relationship can solve
(or cause) certain retrofit-related problems.
The other thing that can be seen from this graph is that if a blend loses some of the higher-pressure
component through fractionation, the remaining blend will have lower operating pressures in
order to achieve the same temperatures.(*)

Refrigerant Reference Guide

71

5th Edition 2010

Blends
Tutorial

Introduction to Fractionation:
Behavior of Individual Refrigerant Molecules
In Zeotropic Mixtures
A refrigerant molecules
move independently from
B refrigerant molecules.

A
PA Is Higher
(more movement)

A+B

Combined P
A more active than B

P.B Is Lower
(less movement)

There are two basic behaviors of refrigerant molecules that will help explain why fractionation
occurs.
1. Pure refrigerants, A or B, exert pressure on the cylinder (or a system) because the molecules
are moving around. At higher temperatures, they move around faster, which creates more
pressure. At lower temperatures there is less movement, so the pressure is lower.
Different refrigerants have different energies at the same temperature, and
therefore, generate higher or lower pressures.
2. Molecules of refrigerant are constantly moving from liquid to vapor and vapor to liquid at the
surface of the liquid. Vapor and liquid at equilibrium transfer the same number of molecules
back and forth; boiling liquid transfers more from liquid to vapor; and condensing vapor
transfers more from vapor to liquid.
Different refrigerants transfer molecules back and forth to the vapor at different rates.
When you mix A and B together, and they dont form an azeotrope, the individual refrigerant
molecules behave as if the other type is not there. The As bounce harder than the Bs, contributing more pressure to the blend, but more importantly - the As transfer back and forth to the
vapor faster than the Bs. This means there are more As in the vapor than there are Bs.

Refrigerant Reference Guide

72

5th Edition 2010

Blends
Tutorial

Fractionation of Blends
Low Fractionation
Potential (Low glide)

High Fractionation
Potential (High glide)

55% A, 45% B

80% A, 20% B

55/45

80/20

50% A
50% B

50% A
50% B

PA > PB

PA >>>>P B

When vapor is removed from a cylinder or system containing a zeotropic blend, two things are
going to happen: 1) the vapor being removed is at the wrong composition, so it will have more of
the higher pressure/higher capacity refrigerant component; and 2) the liquid that is left behind boils
more of the higher pressure component out of the liquid to replace the vapor. Eventually, the liquid
composition changes because more of the A component leaves the container or system compared
to the bulk liquid composition.
FRACTIONATION is the change in composition of a blend because one (or more) of
the components is lost or removed faster than the other(s).
A large difference between the pressures of the starting components will cause a greater difference
in the vapor composition compared to the liquid composition. This will worsen the effect of fractionation on that blend. The High Fractionation Potential blend shown above will produce a vapor
composition of 80% A and 20% B above the liquid composition of 50/50.
Molecules will transfer back and forth to the vapor at a similar rate when the pressures of the individual
components are close to each other. The Low Fractionation Potential blend shown above will have a
very similar vapor composition compared to the liquid. In this case, it will take a long time to noticeably
change the liquid composition away from 50/50.
Temperature Glide will be higher for High Fractionation blends, and lower for Low Fractionation blends.

Refrigerant Reference Guide

73

5th Edition 2010

Blends
Tutorial

Effects of Fractionation in a Cylinder


Charge wrong composition - poor system behavior
Leave behind wrong composition - rest of cylinder
no good
50/50

80% A, 20% B

Invert
Cylinder

50% A
50% B

80% A, 20% B

Dip
Tube

50% A
50% B

50/50

To avoid charging the wrong composition and fractionating the remaining blend, zeotropic blends
must be removed from the cylinder as a liquid. This can be done by turning the cylinder over so the
valve is on the bottom. For larger cylinders with two valves, use the liquid valve. Liquid refrigerant
will come up through a dip tube to the valve.
* All refrigerant suppliers have removed dip tubes in their 30 lb. packages.
Check the box or cylinder label for instructions on which side should be up for
liquid removal.
Liquid charging does not mean that liquid refrigerant should be pushed into the suction line of
the system, allowing it to slug the compressor. After the initial charge into the high side of a
system, the technician should start the compressor and complete the charging process by flashing
the refrigerant from liquid to vapor in the charging hose or across specially designed valves. Any
method that allows the refrigerant to go to vapor before it hits the compressor should work.
Generally, the refrigerant needs to be added slowly at this point.
Please note: When liquid and vapor are together in a cylinder or in a system, IT IS ALWAYS THE
VAPOR THAT WILL BE AT THE WRONG COMPOSITION.

Refrigerant Reference Guide

74

5th Edition 2010

Blends
Tutorial

Fractionation Effects on
System Charge
At Rest

Running
V
(frac)

L+V
(turbulence)

V
(frac)

V
(circ)
L
(circ)
V
(circ)

V
L

L
V

L+V
(turbulence)

A system at rest will allow the refrigerant to pool and the vapor to come to an equilibrium concentration
above the liquid. Leaks that occur in vapor areas of the equipment will fractionate the blend. The
worst case will occur when about half of the refrigerant charge has leaked. Small amounts leaked from
a system will not change the remaining blend by much. Large leaks will shift the composition, but the
majority of the pounds after recharge will be from fresh product at the correct composition.
Recharging the system after repair will result in a blend with slightly reduced capacity and operating
pressures. In smaller systems, where charge size is critical, it will be best to recover any remaining
refrigerant and charge with fresh blend. In larger systems, you will need to make a decision whether the
remaining charge should be recovered or not. Note: for Low Fractionation Potential blends you will not
see much shift in composition anyway, and therefore the charge can be topped off after repair without
loss of properties.
In running systems it has been found that the circulating composition is the original blend composition.
In liquid and suction lines there is no second phase, and in the heat exchangers there is much turbulence
so leaks will lose both vapor and liquid. Testing has shown that leaks from a running system do not
cause fractionation, and a normally cycling system will not fractionate much during the off cycle.
In other words, in most refrigeration applications, servicing systems with blends does not require full recovery of the charge. After repair, most systems can be topped off with the blend. In most air conditioning
systems, however, a leak during the off season will likely require a full change of refrigerant charge.
Refrigerant Reference Guide

75

5th Edition 2010

Blends
Tutorial

Fractionation Effects on
Some System Components
Flooded Evaporator
Li q.

Suction Accumulator
Vap .

V: 80 / 20

Vap.
Vap.
(Liq.
Slug)

L: 50 / 50

V: 50 / 50
V: 80 / 20

L: 50 / 50
Periodic

Continuous

Flooded Evaporators are designed to keep a pool of boiling liquid refrigerant surrounding a bundle of
tubes. The water, brine, or product to be cooled flows through the tubes. The vapor that boils off this
pool is returned to the compressor, condensed, and then poured back into the pool.
In the case of zeotropic blends, the vapor that boils off this pool of refrigerant will be at the fractionated composition. If the properties at this composition differ significantly from what the compressor
expects, then the system could develop high head pressures, high amperage draw at the compressor,
reduced cooling effectiveness (capacity) in the evaporator, etc. Normally the use of blends in this type
of system is not recommended.
Suction Accumulators are placed in the suction line before the compressor to keep liquid from flowing
into the compressor. The liquid slug is trapped in the accumulator where it can boil off to vapor,
combining with other suction gas. Zeotropic blends will fractionate in the accumulator, giving a
short-lived spike of higher-pressure vapor back to the compressor.
Systems with suction accumulators should not be overcharged with the expectation that the
accumulator will protect the compressor. (This may lead to frequent pressure spikes.) Also, this type
of system should never be charged by dumping liquid refrigerant into the suction line and allowing
it to vaporize in the accumulator. (High pressure trips may occur.)

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Blends
Tutorial
Temperature Glide in the Evaporator
Relationship between blend fractionation and
temperature glide through evaporator tube:
1

3
Liquid with a
few bubbles
L = 50 / 50
V=80 / 20
Temp = 40F

Equal vapor
and liquid
L = 37 / 63
V = 65 / 35
Temp = 45F
Vapor and
last few
drops liquid
L = 25 / 75
V = 50 / 50
Temp = 50F

Lets assume that a blend of 50% A refrigerant and 50% B refrigerant flows across a valve into an
evaporator coil. If we follow a small piece of the blend as it flows along the tube we can see the
effect of fractionation:
1.

At the beginning of the tube the blend is mostly liquid with a few bubbles in it. The liquid
composition is 50/50 and the boiling point is (for purposes of discussion ) 40F.

2.

As the piece of refrigerant marches along the tube, more liquid is boiled to vapor. Since
A transfers to vapor faster than B, a larger proportion of A (than B) is transferred to vapor.
This makes the composition of the liquid change along the length of the tube. In this
example, the piece of blend which started at 50/50, now has a liquid composition at
37% A and 63% B. (The vapor has the extra A - at 65%.) The important point is that the
boiling temperature of the current liquid composition is now about 45F.

3.

When our piece of the blend gets to the end of the evaporator it is now almost all vapor.
This vapor contains almost all of the refrigerant that we started with at the beginning of
the tube, so the composition is almost back to 50/50. The last few remaining drops are
now concentrated in the B component (about 75% in this example). The boiling point of
this liquid composition is now about 50F.

Overall Temperature Glide: The difference in temperature between the Saturated Vapor blend
at the end of the evaporator and the liquid entering the evaporator is 50F-40F = 10F.
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Tutorial

Effects of Temperature Glide


Frost formation?
Colder
Region
Avg. Temp
Warmer
Region
Superheat setting?

For pure refrigerants, the evaporator coil is at a constant temperature throughout. For blends,
however, the temperature glide causes the tubing to be at different temperatures.
If you stand back and blow a fan across the evaporator coil, the air that blows out the other side
looks like it saw an average temperature. Part of the evaporator is colder, and part is warmer, but the
air mixes and generally gives the equivalent house or box temperature as if it passes over a constant
temperature coil at this average. There are, however, some potential problems that can occur:

The colder part of the coil may form frost faster than an equivalent coil at constant temp.
The warmer part of the coil may cause hot spots in the case or cold box, affecting product quality.
Temperature control sensors located in hot or cold spots may affect cycle times.
Ice machines will produce thicker ice on the bottom of the plate and thinner ice at the top.
TXV sensor bulbs located at the outlet of the evaporator will now see warmer gas.

Generally the temperature glide does not affect the systems ability to remove heat from the air
or from product, but the glide will probably affect some of the systems controls. Superheat
settings and pressure controls will be discussed further.
Frost formation and hot or cold spots must be addressed outside the refrigeration loop (defrost
strategies, product placement, etc.). Making the whole coil warmer or colder will change the
overall air or box temperature, not solve the glide-related problem.
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Blends
Tutorial
R-12

High Glide Blends


401A: 13F
409A: 15F
414B: 15F

10F

Water Flow

Refrigerant Flow

Thickness
Sensor

10F

10F

401A: 9F
409A: 8.5F
414B: 8.5F

Suc. P = 15 psig
Ice Wt. = 30 oz
Cycle
Time = 20 min

Thickness
Sensor - No
Adjustment

Needs to be
moved in

401A: 5F
409A: 2F
414B: 2F

Side View of an Ice Machine Grid/Ice Profile near Harvest - R-12 and High Glide Blends

ICE MACHINE TEST RESULTS


Various R-12 retrofit blends were tested in an R-12 ice machine. The picture above represents a
side-view of the plate as the water freezes.
For R-12, the water froze in a nearly constant thickness all the way down the plate. The evaporator,
mounted on the back side of the plate, held a constant 10F along the entire length. The ice thickness
sensor was located at about row 3.
For each of the blends tested, R-401A, R-409A and R-414B, the glide of the blend caused the lower
portion of the plate to be from 8F to 13F colder than the upper portion of the plate. The top rows
did not fill in as quickly as the bottom, and the overall ice bank that formed was weighted more
towards the lower portion of the plate.
The ice machine was still operating at the same suction pressure and was generating the same
30 ounces of ice every 20 minutes. The biggest difference was the setting of the thickness sensor.
For the first run, the machine did not shut off because the ice surface near the 3rd row was not
forming as fast as the lower portion of the plate. When the sensor was adjusted inward to take this
into account, the machine ran fine.

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Blends
Tutorial

Bubble Point / Dew Point


Blends
TEMPERAT URE

TEMPERAT URE

Single Component

Superheated

Boiling
Subcooled

Superheated
glide
Boiling
Subcooled

Evaporating ---------->
<-----------Condensing

Bubble
Point

(Constant Pressure)

Dew
Point

(Liquid with a
(Vapor with a
bubble in it) dew drop in it)

The process of phase change (boiling or condensing) is the same for blends as it is for pure refrigerants:
Boiling: liquid reaches a temperature where bubbles form and then the liquid boils to vapor.
When the last drops of liquid disappear, any additional heat input causes the vapor to
superheat.
Condensing: vapor cools to a temperature where liquid drops start to form, then the vapor
condenses to liquid. When the last of the vapor disappears, any additional removal of heat
causes the liquid to subcool.
When these phase changes occur in a pure refrigerant, at constant pressure, the temperature stays
constant at what we normally call the boiling point.
For blends the process is the same but, the shift in composition during phase change causes the
temperature glide to occur. The vapor will still superheat and the liquid will still subcool; however,
the Saturated Vapor temperature and the Saturated Liquid temperature are now the temperatures
at the ends of the temperature glide for a given pressure.
Saturated Liquid = Bubble Point (Liquid with bubbles starting to form)
Saturated Vapor = Dew Point (Vapor with dew drops starting to form)
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Blends
Tutorial

Two-Column PT Charts
T ra d itio n a l P T C h a rts
Tem perature in left colum n, press ure in the
rem aining columns
S aturated pres sure listed - sam e for boiling
or condensing / saturated liquid or vapor

N e w B len d s N e e d T w o C o lu m n s
Zeotropic blends hav e different tem peratures
for s aturated liquid and s aturated vapor at
constant pressure
B ubble Point (or Liquid) gives pres sure for
saturated liquid; us ed as the reference point
for s ubc ooling c alculations
D ew P oint (or V apor) gives pres sure for
saturated v apor; used as the reference point
for s uperheat c alc ulations
Pressure-Temperature (PT) charts traditionally have listed the temperature in the left column and
pressures for various refrigerants in the remaining columns. For blends, we now need two columns
per refrigerant: one for Vapor Pressures and one for Liquid pressures.
Note: You should not read a PT chart across - heat exchanges run at constant pressure,
not constant temperature.
Superheat Setting: the process for obtaining superheat is the same as it has always been - measure
the temperature on the suction line, for example, at the TXV bulb. To find the saturated vapor
temperature you measure the suction pressure, and then refer to the PT chart for the corresponding
temperature. For blends you must use the Vapor (Dew Point) column. Subtract the saturated
temperature from the measured temperature to get the amount of superheat.
Subcooling: the process for obtaining subcooling is also the same as it has been - measure the
temperature of the line at the point of interest. To find the saturated temperature of the liquid you
measure the pressure on the condenser, and then refer to the PT chart for the corresponding temperature. For blends you must use the Liquid (Bubble Point) column. Subtract the measured value
from the saturated value to get degrees of subcooling.
Keep in mind the state of the refrigerant (liquid or vapor) where the measurement is being taken to
determine which column you need to use. Also keep in mind that the only practical place that you
find saturated vapor, at the correct composition, is at the end of the evaporator when measuring
superheat. Do not use the vapor column when liquid is present, since the vapor is at the wrong
composition.

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Blends
Tutorial
Refrigeration Example:
Average Evaporator Temperature
and Superheat
TEMPERATURE

Single Component

Blend after Retrofit

Superheat = 2F

Bulb Setting
Superheat = 7F

Avg. Evap.
Temp.

Boiling Point

Evaporator
Length

Suction
Line

Evaporator
Length

Suction
Line

Assume a refrigeration system has been retrofitted from a single component refrigerant to a blend
with a temperature glide of about 10F. The blend will run with an average evaporator temperature
that matches the constant evaporator temperature of the refrigerant that was replaced. About half
of the glide is making the front of the evaporator colder, and the other half of the glide is making the
back of the evaporator warmer. The outlet is about 5F warmer than it used to be.
The TXV bulb has not been adjusted, and it was initially set for 7F superheat above the saturated
temperature of the original refrigerant. With the blend, the same average evaporator temperature
is achieved - but now this only provides 2F of superheat above the blends vapor temperature.
If the safety margin provided by the superheat setting is reduced too far, it is possible that the
refrigerant may flood back to the compressor. In many cases, reducing the superheat by 4F or 5F
may not be a problem, but, it is always a good idea to check the superheat to make sure.
Some R-12 retrofit blends have as high as 14F glide -- enough to completely overcome an original
superheat setting of 7F. Many of the current R-22 retrofit blends have temperature glides from
5F to 10F.
See pages 102 - 104 for a more detailed discussion of TXV operation after retrofitting.

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Blends
Tutorial
Air Conditioning Example:
Average Evaporator Temperature
and Superheat
TEMPERATURE

Single Component

Blend after Retrofit

Bulb Setting
Superheat = 10F

Superheat = 15F

Avg. Evap.
Temp.

Boiling Point

Evaporator
Length

Suction
Line

Evaporator
Length

Suction
Line

For air conditioning, the effects of temperature glide will be somewhat less severe. Using the
same blend with a 10F glide, this example looks at the effects of temperature glide using typical
superheat settings for an air conditioner (10F to 15F).
The blend will run with an average evaporator temperature that matches the constant evaporator
temperature of the refrigerant that was replaced. About half of the glide is making the front of the
evaporator colder, and the other half of the glide is making the back of the evaporator warmer.
The outlet will be 5F warmer than it used to be.
The TXV bulb has not been adjusted, and it was initially set for 15F superheat above the saturated
temperature of the original refrigerant. With the blend, the same average evaporator temperature
is achieved - but now the superheat drops to 10F.
For most running conditions this should not be an immediate problem; however, air conditioners
are critically charged to cover the worst case scenario of a hot day and cool house. In this case,
the refrigerant is in danger of flooding back from the evaporator so correct superheat settings will
be important. If the valve is adjustable, then superheat should be increased to compensate for the
glide. If not, the system should be charged with slightly less refrigerant than the indicated amount.

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Blends
Tutorial
Cut In / Cut Out Pressure Control
Using Blends
R-12: Running System

Blend: Running System

Cut Out pressure=15 psig


Corresponds to 10F boiling temp

Cut Out pressure=15 psig


Corresponds to 10Favg. evap. temp

R-12: System is Off

Blend: System is Off

Cut In pressure=35 psig


Corresponds to 38F Liquid Pool temp

Cut In pressure=45 psig


Corresponds to 38F Liquid Pool temp

With R-12, a Cut In/Cut Out Pressure Control work as follows:

The R-12 coil gets down to about 10F and the pressure is about 15 psig. This means the
box temperature is somewhere in the 20s F. The pressure switch knows the box is cold
enough and it turns off the compressor.

Liquid R-12 pools in the evaporator coil and warms up to box temperature. As the box
warms to about 38F, the R-12 in the coil generates 35 psig and the pressure switch turns
the system on again.

With the R-12 Retrofit Blends, the control works similarly:

The average blend coil temperature gets down to about 10F at about 15 to 16 psig
(depending on the blend). The box temperature is about the same as it was with R-12,
and the pressure switch shuts off the system.

LIQUID blend settles in the coil and warms to box temperature. The blends have higher
liquid pressures than R-12 - if no adjustment is made, the pressure switch will kick the
system back on at 35 psig. For R-401A, this happens at 29F; for R-406A it is 32F; for
R-409A it is 27F; for R-414B it is 28F; and for R-416A it is 43F. Most of the blends will
turn the system on too cold, and short cycling will cause the system to freeze up.

You will need to check the liquid pressure at 38F and reset the cut in pressure accordingly.
(Note: the vapor is at the wrong composition; do not use the vapor column.)
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Blends
Tutorial
R-12 Replacement Refrigerants
Property Comparison
Refrigerant

Components

R-12
(pure)
R-134a
(pure)
Refrigeration Blends
R-401A
22 / 152a / 124
R-401B
22 / 152a / 124
R-409A
22 / 124 / 142b
Automotive Blends
22 / 600a / 142b
R-406A
22/600a/124/142b
R-414B
134a / 600 / 124
R-416A

Composition

Glide

Lube

100
100

0
0

M
P

53 / 13 / 34
61 / 11 / 28
60 / 25 / 15

8
8
13

MAP
AP
MAP

55 / 4 / 41
50 / 1.5 / 39 / 9.5
59 / 2 / 39

15
13
3

MAP
MAP
P

M: Mineral Oil

A: Alkylbenzene

Pressure Match
-20 10 40 90F
0.6 14.6 37 100
4v 12 35 104

1
2
0

16 41 115
19 46 124
15 39 116

4v 12 33 105
0
14 37 105
7.5v 8 28 97

P: Polyolester

R-134a: At first look, R-134a pressures match R-12 pretty well, but other properties show that R-134a
needs larger equipment to perform the same job (higher compressor displacement and more surface
area in the condenser). In effect, R-134a in an R-12 system has lower capacity and higher discharge
pressures than expected. In addition, it requires POE flushing to remove mineral oil during a retrofit.
R-401A and R-401B: These are R22 based blends that tend to have higher temperature glide.
The presence of R-152a, an HFC, hurts miscibility with mineral oil. It is recommended to change
some of the mineral oil to alkylbenzene unless it is a hermetic system running at warmer temperatures. R-401A matches R-12 capacity at around 20F evaporator; warmer conditions will begin
to show effects from being over-capacity (higher amperage draw, shorter cycle times). R-401B offers
a boost in capacity at lower temperatures (-30F).
R-409A: This R-22 based-blend has higher temperature glide. It has moderate miscibility with mineral
oil, and generally offers good oil return in systems down to 0F evaporator. R-12 capacity match is
about 10F and it still works well at lower evaporator temperatures. Higher discharge temperatures
and pressures can develop, especially in warmer applications.
R-414B: This R-22 based blend has been formulated to keep the head pressure down. It is approved
for automotive applications, although nylon barrier hoses and special fittings are required. In refrigeration equipment there may be a drop in capacity at colder temperatures.
R-416A : This R-134a based blend has an added HCFC component that keeps the head pressure
lower upon retrofit. There will be a drop in capacity compared to R-12, which could be significant
in colder applications. Lower suction pressures must also be taken into account. This blend also has
lower temperature glide. The manufacturer claims it is OK to use with mineral oil, however the blend
does not actually mix with the oil (return is helped by a hydrocarbon component.) Adding POE
lubricant is recommended for more complicated piping arrangements.

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Blends
Tutorial
R-22 Replacements for
Refrigeration and Air Conditioning
Components

Glide

Lube

22

MA

-20
10

10
33

40
68

110 130F
226 279

Look-alike Blends
R-407A
32 / 125 / 134a
R-407C
32 / 125 / 134a
R-422B
125 / 134a / 600a
R422D
125 / 134a / 600a
R-404A(507)
125 / 143a / 134a
R-422C
125 / 134a / 600a

10
10
5
5
1.5
4.5

p
p
MAP?
MAP?
P
MAP?

12
10
8
10
16
16

37
34
30
34
44
43

78
71
65
71
86
86

259
245
221
238
271
273

34
324
292
313
355
356

New Only
R-410A

0.2

27

62 118

365

476

Refrigerant
R-22

32 / 125

M: Mineral Oil

A: Alkylbenzene

Pressure Match

P: Polyolester

R-407A and R-407C: Both products have the closest capacity and run-time property match to
R-22. All products will have lower discharge temperatures than R-22. R-407A is a closer
match at lower application temperatures, such as in commercial refrigeration applications. R-407C
will work better in medium temperature and air conditioning applications. Replacement of mineral
oil with polyolester (POE) is recommended

R-422B and R-422D: These blends will have lower capacity than R-22 in the same system, and
in many cases there will be an increase in pressure drop that may require changing TXVs or distributors. They contain hydrocarbons that will help circulate mineral oil in smaller systems.
Larger systems, especially ones with receivers, will need addition of POE to help keep the mineral
oil from being stranded.

R-404A and R-507: These blends can be used to retrofit R-22 systems that would otherwise be
able to run R-404A , such as in commercial refrigeration applications. TXVs would need to be
changed to the appropriate R-404A model. Discharge pressures would also increase, although
discharge temperatures would come down. An oil change to POE is also required.

R-422C: This blend can be used to retrofit low temperature R-22 systems. The performance
characteristics (pressure/temperature) will look much like R-404A, but with a drop in capacity of
up to 10%. The hydrocarbon additive will help circulate mineral oil around the system. In larger
systems, however, some oil holdup may occur in the receiver. Addition of POE will solve this problem.

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Blends
Tutorial
R-502 Replacement Refrigerants
Property Comparison
Refrigerant

Components

Composition

Glide

Lube

R-502
22 / 115
HCFC Blends
R-402A
125 / 290 / 22
R-402B
125 / 290 / 22
R-408A
125 / 143a / 22

49 / 51

MA

60 / 2 / 38
38 / 2 / 60
7 / 46 / 47

2.5
2.5
1

M+AP
M+AP
M+AP

HFC Blends
R-404A
125 / 143a / 134a
R-507
125 / 143a
R-422C
125 / 134a / 600a

44 / 52 / 4
50 / 50
82 / 15 / 3

1.5
0
5

P
P
MAP

M: Mineral Oil

A: Alkylbenzene

Pressure Match
-20 10 40 90F
15 41 81 187
19 48 93
15 42 83
14 38 77

215
198
186

16
18
18

202
210
205

48
46
44

84
89
87

P: Polyolester

R-402A and R-402B: R-402A shows higher discharge pressures than R-502, however the
discharge temperature is lower. R-402B is a closer match in pressure, but the discharge
temperature runs higher (this is good for ice machines, which is where R-402B is primarily used).
Although propane is added to improve oil circulation, it is still recommended to replace some
mineral oil with alkylbenzene oil.

R-408A: R-408A has the closest PT match to R-502 across the whole application range. It also has
very low temperature glide. R-408A does generate higher discharge temperatures than R-502, and
this could be a problem in extreme application conditions, such as transport refrigeration in hot
climates. R-408A can be used in most refrigeration systems.

R-404A and R-507: These two blends are virtually the same in terms of operation and equipment.
In a retrofit situation, they will require POE flushing to be performed. They will also generate higher
discharge pressures. Generally speaking, retrofitting with these HCFC blends will add more complexity
and cost to a retrofit job, especially when compared to using one of the other blends.
R-422C : This blend can be used to retrofit low temperature R-22 systems. The performance
characteristics (pressure/temperature) will look much like R404A, but with a drop in capacity of up
to 10%. The hydrocarbon additive will help circulate mineral oil around the system. In larger systems,
however, some oil holdup may occur in the receiver. Addition of POE oil will solve this problem.

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Refrigerant Retrofit Checklist


______________________________________________________________________________________________________________________________

SYSTEM IDENTIFICATION

LOCATION

ADDRESS

REFRIGERANT CHARGE / TYPE

LUBRICANT CHARGE / TYPE

COMPRESSOR MODEL(S)

CONDENSER MODEL(S)

For larger systems: Fill in overall system data then use subsequent charts for case/evaporator run data.
For small systems: Use subsequent tables - one row for each system retrofit.
For distributed or stand-alone systems: Reference individual condensing unit(s) in the following tables.
NOTES:

Additional copies of page 88 and 89 are available in NRIs R-22 Retrofit Guideline and Procedures Handbook.

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______________________________________________________________________________________________________________________________

SYSTEM DATA COLLECTION


System/Case Numbers
CONDENSING UNIT MODEL
EVAPORATOR MODEL

AFTER
BEFORE
AFTER
BEFORE
RETROFIT RETROFIT RETROFIT RETROFIT

AFTER
BEFORE
RETROFIT RETROFIT

AFTER
BEFORE
RETROFIT RETROFIT

EXPANSION DEVICE
AMBIENT TEMPERATURE/RH
SUCTION TEMPERATURE
SUCTION PRESSURE
CONDENSER PRESSURE
CASE/BOX TEMPERATURE
SUPERHEAT SETTING
SUBCOOLING SETTING
SIGHT GLASS APPEARANCE

System/Case Numbers
CONDENSING UNIT MODEL
EVAPORATOR MODEL

AFTER
BEFORE
AFTER
BEFORE
RETROFIT RETROFIT RETROFIT RETROFIT

BEFORE
RETROFIT

AFTER
RETROFIT

BEFORE
AFTER
RETROFIT RETROFIT

EXPANSION DEVICE
AMBIENT TEMPERATURE/RH
SUCTION TEMPERATURE
SUCTION PRESSURE
CONDENSER PRESSURE
CASE/BOX TEMPERATURE
SUPERHEAT SETTING
SUBCOOLING SETTING
SIGHT GLASS APPEARANCE

Additional copies of page 88 and 89 are available in NRIs R-22 Retrofit Guideline and Procedures Handbook.

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R-12 Retrofitting
R-12 Systems - General Considerations
R-12 and R-500 Air Conditioning
1.
For centrifugal compressors, it is recommended that the manufacturers engineering staff
become involved in the project - special parts or procedures may be required. This will
ensure proper capacity and reliable operation after the retrofit.
2.
Most older, direct expansion systems can retrofit to R-401A, R-409A, R-414B or R-416A
(R-500 to R-401B or R-409A), as long as there are not components that will cause
fractionation within the system to occur.
3.
Filter driers should be changed at the time of conversion.
4.
System should be properly labeled with refrigerant and lubricant type.
R-12 Medium / High Temperature Refrigeration (>0F evap)
1.
See Recommendation Table for blends that work better in high ambient heat conditions.
2.
Review the properties of the new refrigerant you will use, and compare them to R-12.
Prepare for any adjustments to system components based on pressure difference or
temperature glide.
3.
Filter driers should be changed at the time of conversion.
4.
System should be properly labeled with refrigerant and lubricant type.
R-12 Low Temperature Refrigeration (<20F evap)
1.
See Recommendations Table for blends that have better low temperature capacity.
2.
Review the properties of the new refrigerant you will use, and compare them to R-12.
Prepare for any adjustments to system components based on pressure difference or
temperature glide.
3.
Filter driers should be changed at the time of conversion.
4.
System should be properly labeled with refrigerant and lubricant type.
Recommendations for R-12 Retrofit Products
Closest Match / Easiest
R-12 small equipment
R-12 AC

R-500 AC

Higher T

Lower T

R-12 larger equipment


Lower T
Higher T

R-414B

R-409A

R-416A

R-409A

R-414B

R-409A

R-416A

R-401B

R-414B

R-401A

R-409A

R-401A

R-401A

R-401A

R-401A

R-414B

R-401A

R-414B

R-409A

R-414B

R-409A

R-416A

R-416A

R-416A

R-134a

R-134a

R-134a

R-134a

R-134a

R-134a

R-416A
Most Different / Hardest
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R-12 to R-134a
General Retrofit Procedure: Centrifugal, Reciprocating AC and Refrigeration Systems
1.

If the system is able to run -- collect system data and operating conditions prior to retrofit.

2.

Isolate the compressor and recover the R-12. Change the lubricant in the compressor to
polyolester (POE). For hermetic compressors this may require removal of the compressor.

3.

Replace any oil in auxiliary components such as oil separators or oil feed systems.

4.

Close the system and run with R-12 for 24 hours to circulate the POE and flush the mineral
oil back to the compressor.

5.

Repeat steps 2-4 until residual mineral oil level is below manufacturers recommendations
(typically 5%). (If the unit is not operational, then perform the oil flushing procedure
immediately after startup with R-134a.)

6.

Recover the R-12 from the entire system.

7.

Perform any maintenance, repair, or component replacements, and change filter/driers.

8.

Evacuate the system to manufacturers specifications.

9.

Charge the system with the proper amount of R-134a (usually 85% to 90% of the
original R-12 charge by weight).

10.

Operate the system and record new system operation data. Make adjustments to controls
as needed to ensure proper operation.

11.

Label the system with the new refrigerant and lubricant type.

Most common areas that require adjustment or attention:

Changing the lubricant to POE


TXV valve adjustment / superheat setting

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91

5th Edition 2010

R-12 to R-401A/B, R-409A, R-414B


General Retrofit Procedure: Reciprocating AC and Refrigeration Systems
1.

If the system is able to run -- collect system data and operating conditions prior to retrofit.

2.

Recover the R-12 from the entire system.

3.

Perform any maintenance, repair or component replacements, and change filter/driers. If


needed (for low temperatures) remove mineral oil from the system and replace with an
equivalent amount of alkylbenzene oil.

4.

Evacuate the system to manufacturers specifications.

5.

Charge the system with the proper amount of the blend (usually 80% to 85% of the
original R-12 charge by weight). Be sure to remove liquid refrigerant from the cylinder to
get the proper composition (but flash the refrigerant before feeding into a running system).

6.

Operate the system and record new system operation data. Make adjustments to controls
as needed to ensure proper operation.

7.

Label the system with the new refrigerant and lubricant type.

Most common areas that require adjustment or attention:

TXV valve adjustment / superheat setting (use Vapor side of PT chart)


Pressure controls (cut in / cut out)
Pressure related switches or controls - difference from R-12 pressures
Irregular frost formation with high glide blends
High discharge pressure or temperature, high amps in high ambient
temperature conditions (abuse of compressor)

Refrigerant Reference Guide

92

5th Edition 2010

R-12 to R-416A
General Retrofit Procedure: Reciprocating AC and Refrigeration Systems
1.

If the system is able to run -- collect system data and operating conditions prior to retrofit.

2.

Recover the R-12 from the entire system.

3.

Perform any maintenance, repair or component replacements, and change filter/driers. If


needed (for complicated piping, large hold-up volumes) remove mineral oil from the
system and replace with an equivalent amount of polyolester lubricant.

4.

Evacuate the system to manufacturers specifications.

5.

Charge the system with the proper amount of the blend (about 90% R-12 charge by
weight). Be sure to remove liquid refrigerant from the cylinder to get the proper
composition (but flash the refrigerant before feeding into a running system).

6.

Operate the system and record new system operation data. Make adjustments to controls
as needed to ensure proper operation. Cap tube systems may need slight charge
adjustment to achieve proper operation.

7.

Label the system with the new refrigerant and lubricant type.

Most common areas that require adjustment or attention:

TXV valve adjustment / superheat setting (use Vapor side of PT chart)


Pressure controls (cut in / cut out)
Pressure related switches or controls - lower from R-12 pressures
Loss of capacity at lower evaporator temperatures / longer run times

Refrigerant Reference Guide

93

5th Edition 2010

R-22 to R-407A, R-407C


General Retrofit Procedure: AC and Refrigeration Systems
1.

Collect baseline data for operation of the system with existing R-22 charge. Make note of
any obvious performance problems with the system.

2.

Leak check the system while still charged with R-22 to identify any repairs needed
during the retrofit process.

3.

Change the lubricant in the compressor to the oil specified by the manufacturer.
For hermetic compressors this may require removal of the compressor.

4.

Replace any oil in auxiliary components such as oil separators or in oil feed system.

5.

Disconnect electrical power to system and properly recover the R-22 charge. Record
the amount of R-22 recovered.

6.

Perform any required maintenance or repair operations previously identified,


including:
replacement of seals and gaskets
pressure controls (cut in / cut out)
pressure related switches or controls - difference from R-22 pressures
leak repairs
filter drier replacement
compressor oil change

7.

If desired, pressurize and leak check the system by preferred method. Evacuate the system
down to 250 microns and confirm that it holds.

8.

Charge the system with the retrofit blend to about 90% to 95% of the recovered R-22
charge size. Make sure the refrigerant is removed from the cylinder as a liquid.

9.

Restart the system and allow it to come to normal operating conditions. Compare the new
operation data to the R-22 run time data. Adjust operation as needed.

10.

Check superheat on the TXVs and adjust as necessary.


Note: The temperature glide of a blend will likely affect TXVs by showing a lower than
expected superheat value. (Reference TXV section- page 102 - 104)

11.

Label the system with identification stickers showing the new refrigerant and oil charge.

Refrigerant Reference Guide

94

5th Edition 2010

R-22 to R-422B, R-422D


General Retrofit Procedure: AC and Refrigeration Systems
1.

Collect baseline data for operation of the system with existing R-22 charge. Make note of
any obvious performance problems with the system.

2.

Leak check the system while still charged with R-22 to identify any repairs needed
during the retrofit process.

3.

Change the lubricant in the compressor to the oil specified by the manufacturer. Oil
return is determined by a number of design and operating conditions. In some systems
a small amount, up to 10%, of POE may need to be added to assist in oil return.

4.

Disconnect electrical power to system and properly recover the R-22 charge. Record
the amount of R-22 recovered.

5.

Perform any required maintenance or repair operations previously identified,


including:
replacement of seals and gaskets
pressure controls (cut in / cut out)
pressure related switches or controls - difference from R-22 pressures
leak repairs
filter drier replacement
compressor oil change
replace TXV, TXV element, and refrigerant distributor nozzle as required

6.

If desired, pressurize and leak check the system by preferred method. Evacuate the system
down to 250 microns and confirm that it holds.

7.

Charge the system with the retrofit blend to about 90% to 95% of the recovered R-22
charge size. Make sure the refrigerant is removed from the cylinder as a liquid.

8.

Restart the system and allow it to come to normal operating conditions. Compare the new
operation data to the R-22 run time data. Adjust operation as needed.

9.

Check superheat on the TXVs and adjust as necessary.


Note: The temperature glide of a blend will likely affect TXVs by showing a lower than
expected superheat value. (Reference TXV section - page 102- 104)

10.

Label the system with identification stickers showing the new refrigerant and oil charge.

Refrigerant Reference Guide

95

5th Edition 2010

R-22 to R-404A, R-507, R-422A/C


General Retrofit Procedure: Refrigeration Systems
1.

If the system is able to run - collect system data and operating conditions prior to retrofit.

2.

If an oil change is indicated (R-404A, R-507, possible R-422A/C), isolate the compressor and
recover the R-22. Change the lubricant in the compressor to polyolester (POE). For
hermetic compressors, this may require removal of the compressor.

3.

Replace any oil in auxiliary components such as oil separators or oil feed systems.

4.

Close the system and run with R-22 for 24 hours to circulate the POE and flush the
mineral oil back to the compressor.

5.

Repeat steps 2-4 until residual mineral oil level is below manufacturers recommendations
(typically 5%). If the unit is not operational, then perform the oil flushing procedure
immediately after startup.

6.

Recover the R-22 from the entire system.

7.

Perform any maintenance, repair, or component replacements, especially TXVs, and


change filter/driers.

8.

Evacuate the system to manufacturers specifications.

9.

Charge the system with the proper amount of the blend (usually 85% to 95% of the
original R-22 charge by weight). Be sure to remove liquid refrigerant from the cylinder
to get the proper composition (but flash the refrigerant before feeding into a running
system).

10.

Operate the system and record new system operation data. Make adjustments to
controls as needed to ensure proper operation.

11.

Label the system with the new refrigerant and lubricant type.

Most Common Areas that Require Adjustment or Attention:

TXV valve replacement / superheat setting (use Vapor side of PT chart)


Pressure controls (cut in / cut out)
Pressure related switches or controls - difference from R-22 pressures
Changing the lubricant to POE (R-404A / R-507)

Refrigerant Reference Guide

96

5th Edition 2010

R-500 to R-401A/B, R-409A, R-414B


General Retrofit Procedure: Reciprocating AC and Transport Refrigeration Systems
1.

If the system is able to run - collect system data and operating conditions prior to retrofit.

2.

Recover the R-500 from the entire system.

3.

Perform any maintenance, repair, or component replacements and change filter/driers.


If needed (for low temperatures) remove mineral oil from the system and replace with an
equivalent amount of alkylbenzene oil.

4.

Evacuate the system to manufacturers specifications.

5.

Charge the system with the proper amount of the blend (usually 85% to 95% of the
original R-22 charge by weight). Be sure to remove liquid refrigerant from the cylinder
to get the proper composition (but flash the refrigerant before feeding into a running
system).

6.

Operate the system and record new system operation data. Make adjustments to controls
as needed to ensure proper operation.

7.

Label the system with the new refrigerant and lubricant type.

Most Common Areas that Require Adjustment or Attention:

TXV valve adjustment/ superheat setting (use Vapor side of PT chart)


Pressure related switches or controls - most have lower pressure than R-500

Refrigerant Reference Guide

97

5th Edition 2010

R-502 to R-402A/B, R-408A


General Retrofit Procedure: Refrigeration Systems and Ice Machines
1.

If the system is able to run - collect system data and operating conditions prior to retrofit.

2.

Recover the R-502 from the entire system.

3.

Perform any maintenance, repair or component replacements and change filter/driers.


If oil return has been a problem with R-502, remove mineral oil from the system and replace
with an equivalent amount of alkylbenzene oil.

4.

Evacuate the system to manufacturers specifications.

5.

Charge the system with the proper amount of the blend (usually 80% to 85% of the
original R-502 charge by weight). Be sure to remove liquid refrigerant from the cylinder
to get the proper composition (but flash the refrigerant before feeding into a running
system).

6.

Operate the system and record new system operation data. Make adjustments to controls
as needed to ensure proper operation.

7.

Label the system with the new refrigerant and lubricant type.

Most Common Areas that Require Adjustment or Attention:

TXV valve adjustment/ superheat setting (use Vapor side of PT chart)


Pressure controls (cut in / cut out)
Pressure related switches or controls - difference from R-502 pressures

Refrigerant Reference Guide

98

5th Edition 2010

R-502 to R-404A, R-507


General Retrofit Procedure: Refrigeration Systems
1.

If the system is able to run - collect system data and operating conditions prior to retrofit.

2.

Isolate the compressor and recover the R-502. Change the lubricant in the compressor to
polyolester (POE). For hermetic compressors, this may require removal of the compressor.

3.

Replace any oil in auxiliary components, such as oil separators or oil feed systems.

4.

Close the system and run with R-502 for 24 hours to circulate the POE and flush the
mineral oil back to the compressor.

5.

Repeat steps 2-4 until residual mineral oil level is below manufacturers recommendations
(typically 5%). (If the unit is not operational then perform the oil flushing procedure
immediately after startup with R-404A/R-507.)

6.

Recover the R-502 from the entire system.

7.

Perform any maintenance, repair or component replacements and change filter/driers.

8.

Evacuate the system to manufacturers specifications.

9.

Charge the system with the proper amount of R-404A or R-507 (usually 85% to 90% of the
original R-502 charge by weight).

10.

Operate the system and record new system operation data. Make adjustments to controls
as needed to ensure proper operation.

11.

Label the system with the new refrigerant and lubricant type.

Most Common Areas that Require Adjustment or Attention:

Changing the lubricant to POE


TXV valve adjustment/ superheat setting

Refrigerant Reference Guide

99

5th Edition 2010

R-502, R-402A, R-402B or R-408A to R-422C


General Retrofit Procedure: Refrigeration Systems
1.

If the system is able to run - collect system data and operating conditions prior to retrofit.

2.

Recover the refrigerant charge from the entire system.

3.

If there are large system components that may retain oil as a non-miscible layer, then
replace at least 50% of the oil with polyolester (POE) lubricant.

4.

Perform any maintenance, repair, or component replacements and change filter/driers.

5.

Evacuate the system to manufacturers specifications.

6.

Charge the system with the proper amount of R-422C (about 90% to 95% of
the original R-502 charge by weight, or about the same charge as R-402A/B, or about
105% of the R-408A charge).

7.

Operate the system and record new system operation data. Make adjustments to controls
as needed to ensure proper operation.

8.

Label the system with the new refrigerant and lubricant type.

Most Common Areas that Require Adjustment or Attention:

Small addition of POE in some cases


Slight TXV valve adjustment/ superheat setting

Refrigerant Reference Guide

100

5th Edition 2010

R-13 and R-503 to R-23 or R-508B


General Retrofit Procedure: Cascade Systems - High Side
Follow guidelines for high stage refrigerant.

General Retrofit Procedure: Cascade Systems - Low Side


1.

If the system is able to run - collect system data and operating conditions prior to retrofit.

2.

Recover the refrigerant charge from the low stage. Special recovery equipment and
cylinders are required to accommodate the high pressure of these refrigerants.

3.

Replace mineral oil or alkylbenzene with POE lubricant. Low residual mineral oil is
important for circulation.

4.

Perform any maintenance, repair or component replacements and change filter/driers.

5.

Evacuate the system to manufacturers specifications.

6.

Charge the system according to manufacturers specifications, with the proper amount of
hydrocarbon additive (if required), then the proper amount of refrigerant. (see notes below)

7.

Operate the system and record new system operation data. Make adjustments to controls
as needed to ensure proper operation.

8.

Label the system with the new refrigerant and lubricant type.

Performance Changes upon Retrofitting (-120F evap. -30F cond.)


Product

Capacity

Efficiency

Suction P
(psig)

Discharge P
(psig)

Discharge T
(F)

R-13
to R-23

100
104

100
91

12
13

104
123

198
280

R-503
to R-508B

100
98

100
103

18
18

145
147

225
186

Expansion Tanks should be adequate upon retrofit.


Static Charge Adjustment
R-13 to R-23: increase up to 30%
R13 to R-508B: increase up to 7%
R-503 to R-508B: decrease down to -8%
If indicated, charge hydrocarbons from 5% to 10% of the refrigerant static charge
Refrigerant Reference Guide

101

5th Edition 2010

Sizing Thermostatic Expansion Devices (TXV)


Some refrigerants will have very similar run-time capacity and pressure drop across a TXV while others
may be different enough from R-22 that the valve will become undersized. TXV capacity is determined
by: (1) three system conditions: evaporator refrigerant saturation temperature, liquid refrigerant temperature entering the TXV and the pressure drop across the TXV port, and (2) thermodynamic properties
of the refrigerant.
It cannot be assumed that the TXV capacity will remain the same after converting a R-22 system to an
alternative refrigerant because in some cases the TXV capacity will be reduced when used with the
alternative refrigerant. Since each refrigerant has its own pressure/temperature characteristics, some
R-22 alternative refrigerants might require the use of a TXV with a R-404A thermostatic element.
Regardless of whether the TXV is replaced, for maximum evaporator efficiency, the superheat should be
checked and set to the equipment manufacturers specification.
The nominal capacity of a Thermostatic Expansion Valve (TXV) is simply the capacity at the conditions
it is rated. For high pressure refrigerants, such as R-22 or its alternatives, the AHRI industry standard
rating point is: 40F evaporator temperature, 100F liquid temperature, and a 100 psi pressure drop
across the TXV port. If any of these conditions change, the valves capacity will also change.
Table 1 shows the capacities of a nominal 2 ton R-22 TXV when used with R-22, R-407A, and R-407C.
Capacities are shown at varying evaporator temperatures, but in each instance the standard rating
conditions of 100F liquid temperature and a 100 psi pressure drop across the TXV port are used
in conjunction with the various evaporator temperatures. Note the highlighted nominal capacities
for the three refrigerants listed and how they differ. This is the result of differing thermodynamic
properties between the three refrigerants.
Nominal TXV Capacities

Table 1

Refrigerant
Valve Nominal
Type Capacity

R-22

R-407C

R-407A

Recommended Thermostatic Charges


VC, VCP100, VGA
VZ, VZP
40 20 0 -10 -20 -40
2.00 2.18 1.91

1.96 1.75 1.31

VC, VCP100, VGA


40 20 0

VZ, VZP40
-10 -20 -40

1.87 2.00 1.71

1.74 1.54 1.12

NC, NCP100, NGA


40 20 0
1.84

1.97 1.70

If a specific application is utilizing a liquid temperature or pressure drop across the TXV port which
is different than the AHRI rating condition, the correction factors in Table 2 and/or Table 3 would be
applied to the capacity listed in Table 1 to determine the actual TXV capacity.
Liquid Correction Factors

Table 2
Liquid Temperature Entering TXV F
Valve Type
R-22
R-407A
R-407C

Refrigerant Reference Guide

10

20

30 40 50 60 70 80 90
Correction Factor, CF Liquid Temperature

100

110

1.56

1.51

1.45

1.40

1.34

1.29

1.23

1.17

1.12

1.06

1.00

0.94

1.75

1.68

1.61

1.53

1.46

1.39

1.31

1.24

1.16

1.08

1.00

0.92

1.69

1.62

1.55

1.49

1.42

1.35

1.28

1.21

1.14

1.07

1.00

0.93

102

5th Edition 2010

Sizing Thermostatic Expansion Devices (TXV)


Pressure Drop Correction Factors

Table 3
Evaporator
Temperature
(F)

30

50

75

40
20 & 0
-10 & -20
-40

0.55
0.49
0.45
0.41

0.71
0.63
0.58
0.53

0.87
0.77
0.71
0.65

Pressure Drop Across TXV (PSI)


100
125
150
175
200
Correction Factor, CF Pressure Drop

225

250

275

1.00
0.89
0.82
0.76

1.50
1.34
1.22
1.13

1.58
1.41
1.29
1.20

1.66
1.48
1.35
1.25

1.12
1.00
0.91
0.85

1.22
1.10
1.00
0.93

1.32
1.18
1.08
1.00

1.41
1.26
1.15
1.07

For example: An R-22 application, operating at +20F is being retrofitted to R-407C. The evaporator capacity is 24,000 Btu/hr and the evaporator has a nominal 2 ton R-22 TXV installed. The
application is designed to operate at 100F condensing, with a 90F liquid temperature.
The nominal capacity of the TXV for R-407C can be calculated as follows:

Nominal capacity at +20F (from Table1): 1.97 tons.

Corrected for liquid temperature at 90F (from Table 2): 1.97 x 1.07 = 2.10 tons.

To determine the correct pressure drop across the TXV port, the difference between the corresponding pressures at the condensing temperature and evaporator pressure must be used:

223 psi (100F condenser saturation) - 37 psi (20F evaporator saturation ) = 186 psi.

The pressure drop through the refrigerant distributor and feeder tubes, the evaporator, and the
frictional line loss in the piping between the condenser (where the pressure value is determined
based on the condenser saturation temperature) and the TXV inlet must also be considered
when determining the actual pressure drop across the TXV port.
For this example, we will assume
the above
mentioned
pressure drop to be 36 psi.
Liquid
Correction
Factors

The actual pressure drop across the TXV port will be: 186 psi - 36 psi = 150 psi.

Actual TXV capacity at the design condition for this application:


2.10 tons (corrected for liquid temperature) x 1.10 (from Table 3) = 2.31 tons.

This would represent the TXV capacity at the design condition in the summer time.

To ensure that the TXV has sufficient capacity, a similar sizing exercise must be undertaken at
the low ambient condensing temperature expected in the winter months. If the system utilizes
fan cycling or head pressure control valves and fixes the minimum condensing temperature at
70F (137.5 psi), the TXV capacity will also need to be considered at this condition.

Refrigerant Reference Guide

103

5th Edition 2010

Sizing Thermostatic Expansion Devices (TXV)

For most applications the correction factors listed in Table 4 can be used to determine if the
existing R22- TXV will have sufficient capacity when used with the retrofit refrigerant of choice.

Table 4

Capacity Multipliers for R-22 Alternative Refrigerants

Refrigerants
Evaporator Condensing Liquid
Temp (F) Temp (F) Temp (F)

40
20
0
-20

105
105
70
105
70
105
70

95
95
60
95
60
95
60

Capacity Multiplier*
R-22

R-417A

R-422B

R-422D

R-424A

R-438A

1.00
1.00
1.00
1.00
1.00
1.00
1.00

0.75
0.72
0.82
0.69
0.77
0.67
0.74

0.74
0.71
0.83
0.68
0.77
0.66
0.74

0.72
0.69
0.83
0.66
0.77
0.64
0.74

0.72
0.69
0.83
0.66
0.77
0.64
0.74

0.88
0.85
1.00
0.81
0.92
0.79
0.88

R-407A R-407C

1.04
1.01
1.20
0.98
1.11
0.96
1.06

1.07
1.04
1.22
1.00
1.13
0.97
1.07

* Apply Capacity Multiplier to the TXVs R-22 rating to determine approximate TXV rating with
the service retrofit replacement refrigerant. A total 40 psi pressure loss across the TXV from the
refrigerant distributor and liquid line is assumed in the capacity multiplier caculation.
Thermodynamic data provided by NIST Refprop v8.0

Capacity and correction factors courtesy of Sporlan Division - Parker Hannifin

Refrigerant Reference Guide

104

5th Edition 2010

3. Refrigerant Management Services


Page
106 - 110

Analytical Testing Services

Cylinder Refurbishing Progam

111

Refrigerant Recovery Containers

112

Refrigerant Reclamation Program

113 - 114

EZ One Shot Recovery Cylinder

115 - 116

Refrigerant Banking Program

117 - 118

Guidelines for Maximum Shipping


Weights for Recovery Containers

Refrigerant Reference Guide

105

119

5th Edition 2010

NRI SERVICES
ANALYTICAL TESTING SERVICE
National Refrigerants, Inc. analytical testing service offers easy-to-use
sample kits for:
Refrigerant
Refrigerant Oil
Halon
Specialty Testing/ GC-MS
Refrigerant - Testing to AHRI Standard 700 Specifications.
Refrigeration Oil - Testing oil quality as indication of system condition.
Halon Testing - Testing to Military/ASTM/ISO Specifications.
Sampling Kit Features

Easy to use, single use, new sample cylinders


High-pressure sample cylinder rated to 400 psig suitable for most alternative refrigerants and blends
Instructions included for proper sampling procedures
All analysis forms and necessary DOT labeling included
Pre-paid return postage to NRIs analytical laboratory for non-hazardous samples
All analysis reports are returned with written commentary and recommendations
Same day results available upon request for additional fee
Sample cylinders available for very high pressure (VHP) refrigerants like R-508B and R-503

REFRIGERANTS

NON-CONDENSABLE GAS

Part # NRIHPN - High pressure refrigerant analysis


Part # NRILP - Low pressure refrigerant analysis
Testing liquid phase to AHRI 700 Specifications for
Fluorocarbon Refrigerants for one or more of the
following:

Part # NRINCN*
Testing vapor phase to AHRI 700 Specifications for
Fluorocarbon Refrigerants; (Requires a vapor-only
sample taken from the source vapor phase)
*Not applicable to R-11, R-113, R-123

IDENTIFICATION (Infrared Spectroscopy)


MOISTURE
ACIDITY
HIGH BOILING RESIDUE/OIL CONTENT
PARTICULATES/SOLIDS
PURITY (Gas Chromatography)/Impurity listing
CHLORIDE

LUBRICANTS
Part # NRIOA (Oil Analysis)
Testing of lubricant for one or more of the following:
IDENTIFICATION (Infrared Spectroscopy)
MOISTURE / ACIDITY
APPEARANCE
VISCOSITY
METALS / ADDITIVES by ICP
RESIDUAL MINERAL OIL (as requested)
FLUORIDE, CHLORIDE and CONDUCTIVITY
(as requested, extra cost)

Refrigerant Reference Guide

HALONS
Testing to MILITARY / ASTM / ISO Specifications

LAB CAPABILITIES
- Purity / Impurities
- Water
- Halogen Ion
- Non-Absorbable Gas
- High Boiling Residue
- Suspended Matter
- Acidity
- Color
- Free Halogen
- Viscosity
- FT-IR
- Flash Point

106

- Pack/Cap Col. GC, FID, TCD, GC-MS


- KF Coulometric Titration
- Ag+ Qualitative / Visual / ISE
- Packed Col. GC TCD
- Evaporation/Gravimetric/Volumetric
- Visual Observation / Gravimetric
- Aqueous Extraction / Base Titration
- APHA Color Comparison
- Iodimetry / S203 - Titration
- Cannon-Fenske
- Transmission / ATR
- Closed Cup

5th Edition 2010

LAB USE ONLY


LAB NOTEBOOK NO:
SAMPLE ID#

REQUEST FOR REFRIGERANT ANALYSIS


Complete this form and attach to the filled test cylinder. Follow cylinder filling instructions on reverse side.
One form must be completed for each sample submitted.

At time of sampling:

Company:
Address:

no

yes

System running?

Temperature of sample:
System Serial #

Job Location:
Phone #

Type of oil in system:

Fax#

Contact:

Sample is:

Email Address:

Sample ID:

PO #

Submitted by:

UR Store #
REFRIGERANT

R-11
R-12
R-22
R-113
R-114
R-123
R-124
R-125
R-134a
R-142b
R-401A/B
R-402A/B
R-403B

R-404A
R-407A/B/C/D
R-408A
R-409A
R-410A/B
R-416A
R-417A
R-422A/B/C/D
R-500
R-502
R-507
R-509
OTHER

SAMPLE TAKEN FROM


Vapor Phase at:
Liquid Line
Condenser
Evaporator
Compressor-Suction

SOURCE OF SAMPLE
New factory filled cylinders
Used-Refrigerant drum or
cylinder
Centrifugal refrigerant system
with purge unit
Centrifugal refrigerant system
without purge unit
Reciprocating refrigerant system
Hermetic
Open
Rotary System
Other:

REASON FOR ANALYSIS REQUEST


Air / Water leak suspected
Evidence of corrosion
Oil sludged or darkened
Excessive head pressure
Suspect excess oil evaporator
Compressor burn-out
Desire condition of refrigerant
Other

cond. vapor

vapor

Date:
APPLICATION
Evaporator temperature:
Condensing medium
Evaporator type:
DX:
Flooded:
Shell & Tube
System Size:
HP
Tons
Refrigerant Charge:

lbs.

ANALYSIS DESIRED
Moisture - ppm
High boiling residue (oil)-%
Acidity - ppm as HC1
Identification - IR
Purity - GC
Particulates
Chloride

Comments or special requests:

Compressor-Discharge
Receiver

liquid

Ship Sample to:

Recovery / Recycle Unit


Recovery Cylinder / Drum
Other

Refrigerant Reference Guide

ANALYTICAL LABORATORY
661 Kenyon Avenue
Rosenhayn, NJ 08352

107

Sampling Procedures
on reverse side

5th Edition 2010

CYLINDER SAMPLING PROCEDURES


Liquid Phase
(Refer to Figure 1.)
1. Use a heat gun, or otherwise dry the connection at the sample
source, C.
2. Connect a vacuum gauge to the sample cylinder or otherwise
ensure that the sample cylinder is a full vacuum (-30Hg). Tare
weigh the cylinder to the nearest ounce.
3. Connect a clean, dry, flex transfer line to the refrigerant source
at point C. Dry the sample cylinder at point A.
4. Carefully open valve C and purge a small amount of liquid
phase through the line. Then immediately connect the line to
the sample cylinder at point A.
5. Open valve B. Then slowly open valve C as to fill the cylinder
to about 85-90% volume capacity. Close valves C and B.
NOTE: External cooling of the sample cylinder may be necessary to sample the refrigerant.
6. Disconnect the flex line at A and re-weigh the cylinder to
ensure sufficient sample has been taken.
7. Soap bubble check the sample cylinder valve and valve connection to the cylinder for any leaks.

C
A

Vapor Phase
(Refer to Figure 2.)
1. Connect as shown and then with valve C closed and valve B
opened, slowly open valve A until the gauge reads -30 in. Hg.
2. Close valve A.
3. Slowly open valve C as to bring the pressure to slightly above
1 atm. Close valve C.
4. Open valve A until full vacuum is attained. Close valve A.
5. Wait 5 minutes to ensure there are no leaks. Gauge should
hold full vacuum.
6. Slowly open valve C and bring cylinder to either full headspace
pressure or to a maximum of 100 psig, whichever comes first.
Do not exceed 100 psig. Close valve C and B.
7. Disconnect sample cylinder and soap bubble check for leaks.
8. Submit for NCG analysis.

C
A

Checklist
Did you remember to:
Tightly close all valves?
Weigh cylinder to make sure a sufficient sample was taken?
Completely fill out the Request for Refrigerant Analysis Form
(on reverse side)?
Provide your FAX number and email address so we can return your test results?

Refrigerant Reference Guide

108

Analysis Request Form


on reverse side

5th Edition 2010

ID #

LAB USE ONLY

REQUEST FOR OIL ANALYSIS


Complete this form and attach to the filled test cylinder. Follow cylinder filling instructions on reverse side.
One form must be completed for each sample submitted.

COMPRESSOR INFORMATION

Company:

Hermetic?

Attn:
Address

No

Yes

Centrifugal

Rotary

Reciprocating

Screw

Other (describe)
Job Location:
Phone #

*Compressor serial no:


Fax#

Oil mfr/brand or type/grade:

Email address:
PO #

Last date of oil change:


Hours operating since last oil change:

UR Store #

Sump Cap:

Sample ID:

Gal:

Qt:

L:

Oil additive present:

Date sample taken:

Compressor mfr/brand:

PLEASE CHECK TESTS REQUIRED

SYSTEM INFORMATION
Unit mfr/model:

Identification of type of oil


Residual mineral oil in POE oil

Unit serial no:

Residual mineral oil in AB oil

Refrigerant:

REASON FOR ANALYSIS REQUEST

Compressor-Discharge

Acidity

No. filter/driers

Appearance Unit

Viscosity

Moisture

Wear Metals

Last date of filter/drier change:


Retrofit in progress: Yes

Other (explain below

No

If YES, please complete below:

Comments or special requests:

Original oil type:


New oil type:
*required for historical data reporting

Ship Sample to:

Sampling instructions
on reverse side

ANALYTICAL LABORATORY
661 Kenyon Avenue
Rosenhayn, NJ 08352

Refrigerant Reference Guide

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5th Edition 2010

NATIONAL REFRIGERANTS, INC.


OIL LABORATORY
This kit contains:
(1) Sample bottle
(1) Identification label
(1) Sample
MAR
How to use this service:

1.

Collecting Samples:
Oil should be taken from the unit immediately after shutdown, and/or while
running at operating temperature so as to obtain a representative sample. The
sample should be taken from the crankcase at the drain plug. Upon opening
the plug, drain off a small amount of oil before taking the sample as to avoid
contamination. Once drawn, allow the sample to de-gas before tightening the
lid. Fill the container about 3/4 full.
NOTE: Synthetic oils are hygroscopic and must be sampled without excessive exposure to ambient air, i.e., attach the lid securely immediately follow
ing the degassing period.

2.

Identification Labels:
Fill out a label completely for each compressor sampled. Print your name, job,
compressor serial number and sampling date on the label.

3.

Sample Request Form:


Be sure to include all of the information requested (hours since oil change,
hours since new/overhauled, or last major repair, oil type, etc.) Include all unit/
component information.

4.

Sending the Sample:


Be sure the identification label is attached to the sample bottle. Be sure the
sample bottle lid is securely tightened. Fold the sample request form and place
it around the other bottle inside the pre-addressed mailing box. Always use
first class postage, air freight or overnight (FedEx, etc.) for quick service.
Return Sample to:

ANALYTICAL LABORATORY
661 Kenyon Avenue
Rosenhayn, NJ 08352

Refrigerant Reference Guide

Oil Analysis Request Form


on reverse side

110

5th Edition 2010

NRI SERVICES

Recovery Cylinder Hydrotest & Refurbish


Program
Refrigerant recovery cylinders require a Department of Transportation (DOT) hydrostatic
recertification every 5 years. This requires the cylinder to have a visual, internal and external
examination and a test by interior hydrostatic pressure in a water jacket for determination
of the expansion of the cylinders. NRI is a DOT approved hydrostatic test facility and offers
other cylinder refurbishing services. Below are details of NRIs cylinder refurbishing program
offered to owners of recovery cylinders. Please call for a quotation for any service not listed.

HYDROSTATIC
HYDROS
TIC TES
TEST
Includes:
hydrostatic test
internal drying
test date engraved on collar/body of cylinder

HYDROSTATIC
HYDROS
TIC TES
TEST
T & REFURBISH

Includes:
dip tube replacement
hydrostatic test
internal drying
removal of old paint
dual port valve replacement
application of grey/yellow paint
test date engraved on collar/body of cylinder

The above services are generally available for all cylinders listed below
30 lb. & 50 lb. recovery cylinders (DOT 4BA, 4BW)
125 lb. recovery cylinders (DOT 4BA, 4BW)
240 lb. recovery cylinders (DOT 4BA, 4BW)
1000 lb. recovery cylinders (DOT 4BA, 4BW)
2000 lb. recovery cylinders (DOT 106A, 110A)

Additional work may be necessary for DOT Certification. Customer will be notified before
work begins if additional costs will be incurred. Please call for pricing.

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111

5th Edition 2010

NRI SERVICES

Refrigerant Recovery Containers


Pressurized Recovery Cylinders
Size
30 lb.
40 lb.
50 lb.
50 lb. HP*
50 lb w/float
125 lb.
1000 lb.
2000 lb.

Deposit**
$ 100.00
100.00
100.00
125.00
125.00
200.00
1500.00
4500.00

Recovery Drums for R11, R113 , R123


Size
100 lb. (10 gal)
200 lb. (20 gal)
650 lb. (55 gal)

Drums can be
purchased for
one time use

Very High Pressure Recovery Cylinders


Size
9 lb.
23 lb.
80 lb.

EZ ONE-SHOT disposable cylinder


is rated to 400 psi and is guaranteed
to be rated to recover R410A.
*50 lb. HP cylinder is also rated to
400 psi and can be used to recover
R410A.

Deposit**
$130.00
150.00
200.00

Guidelines
A service fee is charged when cylinders are taken for use by customer.
Cylinder deposits are credited back to customer upon return of cylinder.
Drums for low pressure refrigerant recovery are rated as single trip containers, therefore
they are purchased outright.
National uses its own on-site DOT approved hydrostatic testing equipment. All cylinders are
shipped under vacuum. For the users protection, a plastic shrink wrap covers the valve.
Please read Filling Procedures and Safety Recommendations to ensure proper transfer of
recovered refrigerant in to containers.
National reserves the right to charge a cylinder cleaning fee for cylinders used as receivers
or returned less than 50% full.

** prices subject to change without notice

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5th Edition 2010

NRI SERVICES
INSTRUCTIONS FOR PARTICIPATING IN
NRIS REFRIGERANT RECLAMATION
PROGRAM

5. Refrigerant Contaminants are acceptable with the


following limits:
Purity

1. Obtain a Recovered Refrigerant tag/label and


container(s) from either NRI or an authorized
distributor.

Component
Ratios/Composition -

2. Fill out a Recovered Refrigerant Tag for each


recovery cylinder and a Recovered Refrigerant
Label for each drum. Bill of Lading number must
be written on each label/tag and the appropriate
panel on the EZ ONE-SHOT disposable 30 lb.
recovery cylinder.
3. Fill the containers according to NRI Filling
Instructions.

National Refrigerants, Inc.


661 Kenyon Avenue
Rosenhayn, NJ 08352
or
an authorized NRI Distributor

Not to exceed 20% by weight in


R11, R113 & R123; 10% for all others.

Water

Water exceeding saturation point of


refrigerant requires special processing to separate the free standing
water from the refrigerant; fee will
be charged for each pound of free
water.

Acid

pH must be greater than 2.0 and


less than 12.0; pH level between
2.0 - 5.0 requires special handling
to neutralize acid in the material;
fee will be based on the gross
weight of material

Dyes

Not to exceed 1% by weight

FILLING PROCEDURE
FOR RECOVERED REFRIGERANT

RECOVERED REFRIGERANT
ACCEPTANCE SPECIFICATIONS
1. Only fluorocarbon refrigerants from refrigeration
and air conditioning systems are accepted. Halons
will not be accepted. Fluorocarbons from other
applications, such as solvents or cleaning agents,
are NOT acceptable.
2. Non-Fluorocarbon refrigerants, such as ammonia,
methylene chloride, propane, ethane, sulfur dioxide,
etc. are NOT acceptable. Also, fluorocarbon refrigerants contaminated with hydrocarbons in excess of
0.5% by weight (total hydrocarbons) will not be
accepted.
3. Only one type of refrigerant per container is acceptable. Refrigerant must be shipped in DOT-approved
recovery containers. Refer to AHRI Guideline K. R-11
R-113 and R-123 must be shipped in drums to avoid
additional handling fees.

1. Visually inspect the container to be filled. Use vacuum

pump to pull cylinder into full vacuum. For all cylinders,


leak test with a vacuum gauge. Do not fill a leaking cylinder.
NRI is not responsible for refrigerant recovered into a leaking
cylinder.
2. Place the container on a scale. Note empty weight of container

to determine maximum gross weight. Add the corresponding


maximum refrigerant weight to the tare weight to get the
maximum allowable gross shipping weight. (See guidelines
for Maximum Shipping Weight.)
3. Connect transfer hoses to the container. Make certain hoses

are leak free. If possible, change hoses when recovering


different types of refrigerant to avoid contamination by
unintentionally mixing refrigerants.
4. Open container outlets and begin the transfer process fol-

lowing manufacturers instructions for the recovery unit.


DO NOT LEAVE THE CONTAINER UNATTENDED.
Do not fill more than 80% by volume. It is illegal to
transport an overfilled cylinder.

4. Containers must not exceed Maximum Allowable Gross


Weight as specified in NRIs Cylinder Weight Chart.
Overfilled containers will be subject to a handling fee.

Refrigerant Reference Guide

Must be within AHRI 700 Specifications for allowable composition


(weight). Composition must be
within ASHRAE classification
for toxicity and flammability.

Oil

4. All Material must meet NRI Recovered Refrigerant


Acceptance Specifications. Please see Terms and
Conditions for additional information.
5. Ship your properly filled and tagged containers
to:

99% for all CFCs, HCFCs and HFCs.


R11 may not exceed greater than
0.5% R123 contamination.

113

5th Edition 2010

NRI SERVICES
TERMS AND CONDITIONS

5. When the scale reaches the gross weight limit-stop

the transfer process. Tightly close all valves and


other outlets. Disconnect the transfer hose. AVOID
CONTACT WITH LIQUID REFRIGERANT/OIL
MIXTURES. Immediately replace all valve outlet
caps and other container closures. NRI does not
recommend using a recovered refrigerant cylinder
as a temporary storage container.

1.

All used refrigerants must meet Recovered Refrigerant


Acceptance Specifications. NRI will accept title to shipment only after it has been verified through analysis, in
NRIs laboratory, that these standards have been met.
Off specification material may, at NRIs option, be returned to the customer freight-collect or disposed of in a
manner agreeable to both NRI and the customer at
customers sole expense.

6. Weigh the container. Always use a scale. DO NOT


2. Refrigerant must be shipped in DOT approved contain-

OVERFILL. Write the weight on all appropriate


forms and on the container tag or label.

ers. Any shipments not meeting this specification will be


refused. Containers must be properly skidded and banded
for shipment. Drums must not have any rust, dents, bulges
or leaks. Open-top drums are not acceptable. NRI will not
be liable for any claims, damages, lawsuits, judgements or
liablities caused by or resulting from the fault or negligence
of the shipper.

7. Completely fill out the container tag or label. Be sure

the tag or label indicates the correct refrigerant in the


container. It is illegal to transport a container without
identifying the contents (including empty cylinders).
8. There will be cylinder cleaning charge for all cylinders

3. NRI reserves the right to charge cylinder refurbishing

returned less than 50% full. Check off the For


Cleaning Only box on the hangtag. R11, R113 &
R123 must be shipped in drums to avoid additional
handling fees.

fees for any NRI owned cylinder that is returned damaged


or defaced. A cleaning fee may be charged for each
container that is returned with less than 50% of the
maximum fill weight of recovered refrigerant. Handling
fees may be charged for recovered refrigerant that requires special handling by NRI.

9. NRI recommends the use of the EZ ONE-SHOT

disposable recovery cylinder when the recovered


refrigerant will be returned to a system without
processing.

RECOVERED REFRIGERANT
HANDLING FEES

SAFETY RECOMMENDATIONS

1.

Customers returning recovery cylinders containing recovered refrigerant will be charged a handling fee according
to the current price schedules.

2.

Free standing water


Water exceeding saturation point of refrigerant; requires
special processing to separate the water from the refrigerant; waste must be sent to waste water processing
facility for purification.

1. Only fill cylinders that are currently DOT approved for

fluorocarbon refrigerants. Always inspect the cylinder


for proper pressure rating and latest hydrostatic test
date. Thoroughly check each cylinder and drum for
dents, gouges, bulges, cuts or other imperfections,
which may render it unsafe to hold refrigerant.
2. It is highly recommended to read the Air Conditioning,

Heating & Refrigeration Institute Guideline K -Guideline for Containers for Recovered Fluorocarbon
Refrigerants."

3.

Excessive oil content


Refrigerant oil (mineral or synthetic) that exceeds ARI
Acceptance Specification (10% for high pressure; 30%
for low pressure): fee will be charged for each pound of
oil exceeding Acceptance Specifications.

4.

High acid content


Acid present in the refrigerant at such a concentration
that the pH level of the material is between 2.0 and 5.0
(a pH level below 2.0 would classify the material as hazardous waste according the 40CFR); such material must
be handled as a priority in order to effectively neutralize
the acid in the material

5.

Over-filled container
Cylinders and drums exceeding the maximum Gross
Weight as specified in NRIs Cylinder Weight Chart that
require special handling; these containers must be
handled as a priority as soon as they are received to
prevent injury to NRI or other persons and to prevent
the release of the material in the container to the
atmosphere.

3. Be sure all connections are made tight before

transferring refrigerant into containers. Be sure all


closures are made tight on the container immediately
after filling. Be sure to replace valve outlet caps on
cylinders.
4. Caution: Liquid refrigerant can cause frostbite if skin

contact occurs. Be aware that the refrigerant/oil being


removed from a system may contain contaminants,
which may be harmful to breathe. Avoid contact with
skin. Always provide fresh air when working in
enclosed areas. Avoid breathing vapors. Always
wear safety glasses and gloves (cold resistant for
pressurized refrigerants and rubber-type for R11,
R113 & R123). Avoid contact with clothing.

Refrigerant Reference Guide

114

5th Edition 2010

NRI SERVICES

EZ One-Shot Recovery Cylinder

EZ ONE-SHOT cylinders use DOT-39 disposable cylinder technology to provide


an inexpensive, lightweight cylinder for use in one-time fill recovery situations

Applications for the EZ ONE-SHOT

Temporary storage receiver (where policy


demands clean cylinder for each job)
Single recovery job where gas will need to
be returned or stored
- One 20 to 30 lb. recovery job
- Several smaller jobs at the same site
- Burned gas: avoid contamination of your
everyday recovery cylinder
- Infrequent jobs or products not regularly
recovered: wont tie up a standard cylinder
- Dedicated shop machines
- Download everyday cylinder to return refrigerant

App
pp

Back Flow Prevention Valves


EZ ONE-SHOT cylinders are equipped with
back flow prevention devices inside the valves.
THE CYLINDERS ARE SHIPPED WITH THE
VALVES OPEN.
Cylinders must be evacuated before use, but after
hoses are connected.
Once the cylinder valve is closed for the first
time, the back flow prevention device seats in the
valve. No more refrigerant can be added to the
cylinder through that valve.
Be sure that all recovery operations are complete
before closing both valves to the cylinder.

One-Time Fill
One-time fill means that once refrigerant has been put
into the cylinder and then removed, the cylinder may
no longer be used for further recovery operations. It
must be scrapped or disposed of properly. Recovering
refrigerant with an EZ ONE-SHOT recovery cylinder
is considered the first filling operation. Recovery from
several units, one after the other, until the cylinder is
full represents one filling operation (for example, a
dedicated shop machine).

EZ ONE-SHOT recovery cylinders are subject to the same regulations as the disposable refrigerant cylinders that refrigerant is
supplied in. Federal law forbids transportation if REFILLED. Federal law also requires that cylinders be filled and transport ed in the
box provided. Penalty up to $500,000 fine and 5 years imprisonment (49 U.S.C. 5124).

Refrigerant Reference Guide

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5th Edition 2010

NRI SERVICES
Procedures for Using EZ ONE-SHOT Recovery Cylinder
Figure 1: Evacuate Cylinder
If performing liquid recovery, arrange hoses as in

dicated in Fig. 2.
If performing vapor recovery, arrange hoses as
indicated in Fig. 3.
Evacuate cylinder with vacuum pump through a
gauge set placed in the vapor line, or through an
access port on the recovery machine, if available.

Do not close cylinder valves.


Figure 2: Liquid Recovery
Recovery machine draws vapor from the cylinder and
uses this vapor to push liquid out of the system back
into the cylinder.

Vapor valve is at top of cylinder

Liquid valve is at bottom


If also performing vapor recovery:

Close liquid valve when the sight glass clears,


BEFORE turning off the recovery machine.

Use gauge set on vapor line to transfer hoses on


recovery machine to configuration in Fig. 3.

Figure 3: Vapor Recovery


Vapor recovery operations are performed normally,
with access to the cylinder only through the vapor
valve. Close bottom valve on cylinder.
Complete all recovery operations, including purging
procedures for the recovery unit, before closing the
vapor valve.
Once cylinder valves are closed no more refrigerant can be added to the cylinder.

Maximum Shipping Weight of Recovered Refrigerant in EZ ONE-SHOT Recovery Cylinder


Refrigerant
R-12
R-22
R-114
R-134a
R-401A/B
R-402A/B
R-404A

Max Shipping Wt./lbs.

Refrigerant

39
36
43
36
36
34
31

R-407A/B/C
R-408A
R-409A
R-410A
R-500
R-502
R-507

Max Shipping Wt./lbs.


35
33
37
33
36
36
31

The information contained herein is based on technical data which we believe to be reliable and is intended for use by persons having technical skill,
at their own discretion and risk. National Refrigerants, Inc. makes no warranties, either expressed or implied, regarding the merchantability or fitness
of this product and assumes no liability for consequential damages resulting from the use or misuse of this product.

Refrigerant Reference Guide

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NRI SERVICES

What is Refrigerant Banking?


This program, designed by NRI, is aimed at helping companies
guarantee their future refrigerant needs. Recent changes in the
refrigerant industry have caused refrigerant supply and pricing
to rapidly change. Now is the time to begin managing your existing
inventories. NRI is an EPA and AHRI certified reclamation facility
with a world-class Analytical Laboratory that will ensure that all
refrigerant returned to you

meets or exceeds AHRI 700 Specifications.

Now is the time to take advantage of this program!

Its your refrigerant, your investment - dont waste it!


NRI will clean and store your recovered refrigerant for you at TODAYS price.
You will have access to your refrigerant when you need it without paying TOMORROWS price.
Dont sell or give away your valuable asset -- BANK it for YOURSELF!

Program Highlights

An initial deposit of 1,000 pounds of recovered refrigerant is required to open


an account.
Refrigerant must meet NRIs Recovered Refrigerant Acceptance Specifications.
Customer is invoiced for the total weight of refrigerant that can be recertified
and restored to AHRI 700 Specifications.
Storage fees are charged on a monthly basis.
Withdrawals can be made 30 days after the initial deposit. A faxed, written or E-mail
request is all that is needed for the refrigerant to be made available. All withdrawal
requests are processed immediately.
Refrigerant withdrawals are available at over 275 locations around the United States.
Monthly activity statements, including all deposits and withdrawals, are sent along with
your monthly storage invoice.

All rates, terms and prices are subject to change. Prices do not include sales tax, if any. NRI reserves the right to alter its program upon 30 days notice.1/2010

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NRI SERVICES
REFRIGERANT BANKING PROGRAM
Initial Deposit
An initial deposit of 1000 pounds of refrigerant is required to open an account. This can be
comprised of different types of refrigerant. Refrigerant must meet NRIs Recovered Refrigerant
Acceptance Specifications.
Future Deposit
After the initial deposit of a minimum of 1000 pounds, subsequent deposits are accepted for a
minimum of 500 pounds per deposit.
Deposits of low pressure refrigerants are accepted in 100 pound drums and larger.
Deposits of high pressure refrigerants are accepted in 125 pound cylinders and larger.
CYLINDERS LESS THAN 125 LBS. ARE NOT ELIGIBLE FOR BANKING.
Minimum Balance
If during the course of any month, customer account balance falls below a total of 1000 pounds,
NRI may purchase the balance of refrigerants as outlined below.
Charges
NRI will invoice you for the cleaning repurification of the total weight of verified refrigerant that
can be recertified and restored to AHRI 700 Specifications plus any contaminant/disposal fees.
A nominal charge for disposable 30 lb. and 50lb. cylinders is charged at time of withdrawal.
Please call for current pricing.
Handling Fees/Disposal Charges
Oil Disposal greater than 20% (low pressure)
Oil Disposal greater than 10% (high pressure)
Free Standing Water

High Acid Content


Mixed Refrigerant
Over-filled container

Disposal charges for contaminants above accepted levels will be determined on a case-by-case basis.

Storage
The net reclaimed refrigerant is placed in bulk storage. A storage fee is billed on a monthly basis.
Withdrawal
A faxed or written authorization is required for withdrawal of refrigerant from the bank.
Upon receipt of the withdrawal authorization at NRI, product will be made available as soon
as reasonably possible for pick up or shipment. Customer will be responsible for freight on
all shipments.
Reports
A banking report and invoice will be issued to the customer monthly.
NRI Purchase
If, at a later date, the customer does not require the banked refrigerant, NRI may purchase
same at a mutually agreed upon price.

All rates, terms and prices are subject to change. Prices do not include sales tax, if any. NRI reserves the right to alter its program upon 30 days notice.

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NRI SERVICES
Guidelines for Maximum Shipping Weights for Recovered Refrigerant Containers
Cylinder Size
Water Capacity

30 lb.

One Shot
30 lb.

40 lb.

50 lb.*

125 lb.

1/2 ton

ton

26.2 lbs.

29.7 lbs.

38.1 lbs.

47.7 lbs.

123 lbs.

1000 lbs.

1600 lbs.

Maximum Refrigerant Weight Allowed


R-12
R-22
R-500
R-502
R-114
R-134a
R-401B
R-402A
R-402B
R-403B
R-404A
R-407A
R-407C
R-408A
R-409A
R-410A
R-416A
R-417A
R-422A
R-422B
R-422C
R-422D
R-507

*
*
*
*
*
*
*
***
**
**
**
**
**
**
*
****
*
*
***
***
***
***
***

24
22
21
22
28
22
22
21
21
19
18
21
21
19
23
19
25
20
18
21
20
20
18

28
25
25
25
32
25
25
24
24
22
20
24
23
22
26
22
29
22
21
24
23
23
20

45
40
39
40
51
41
40
39
38
35
33
39
38
35
42
35
46
36
34
38
36
37
33

36
32
31
32
41
32
32
31
30
28
26
31
30
28
34
28
37
29
27
30
29
30
26

117
103
102
103
133
106
103
99
97
91
85
99
97
90
109
89
120
94
88
98
93
96
85

*includes 50F and 50HP


1523
1342
1337
1347
1740
1382
1334
1294
1267
1177
1100
1292
1264
1176
1420
1162
1566
1231
1157
1268
1213
1243
1100

952
839
836
842
1088
864
857
809
792
736
688
808
790
735
888
726
979
770
723
793
758
777
688

Minimum cylinder service pressure required (psig) for each different refrigerant is indicated above by*
260 psig = *
300 psig = **
350 psig = ***
400 psig = ****
Low Pressure
Containers

Drum
Size

R11, R113, R123

100 lbs
200 lbs
650 lbs

Very High Pressure


Cylinders

Max Allowable
Refrigerant Wt
90 lbs
180 lbs
585 lbs

Average Drum
Tare Wt
10 lbs
20 lbs
65 lbs

Max Gross
Shipping Wt
100 lbs
200 lbs
650 lbs

RC9
RC23
RC80
avg tw 20
avg tw 30
avg tw 140
Recovered Refrigerant Weight + Tare Weight of Cylinder = Maximum Gross Shipping Weight

Ref Wt / Ship Wt
Ref Wt / Ship Wt
Ref Wt / Ship Wt
R13
14
34
19
49
74
211
R23
11
31
15
45
58
198
R503
12
32
16
46
64
206
R508B
12
32
17
47
65
205
R13B1
17
37
12
52
89
229
IMPORTANT: The tare weights listed in this guideline are only average weights. In order to determine actual gross shipping
weight, the tare weight of each individual cylinder must be used.
Always use a scale when filling any cylinder. DO NOT OVERFILL
(rev 4/2010)

Refrigerant Reference Guide

119

5th Edition 2010

Refrigerant Reference Guide

120

5th Edition 2010

4. Additional Technical Literature


Page

Glossary of Terms

122 - 125

Lubricant Cross Reference

126 - 127

Lubricants

128 - 131

Coil Cleaners and Chemicals

132 - 134

Propylene Glycol

Refrigerant Reference Guide

135

121

5th Edition 2010

Glossary of Terms
Alkylbenzene Oil - A synthetic refrigeration
oil similar to mineral oil; it offers better low
temperature mixing with HCFCs.

Class II - Chemicals listed in the Clean Air Act


having an ozone depletion potential of less
than 0.2. All of the HCFCs are considered
Class II.

Appliance - Any device that contains and uses


a Class I or Class II substance as a refrigerant
and is used for household or commercial
purposes, including any air conditioner,
refrigerator, chiller or freezer.

Commercial Refrigeration - The refrigeration


appliances used in the retail food and cold
storage warehouse sectors. Retail food
includes the refrigeration equipment found in
supermarkets, convenience stores, restaurants
and other food service establishments. Cold
storage includes the equipment used to store
meat, produce, dairy, and other perishable
goods, usually in very large facilities.

Azeotrope - A mixture of two or more


refrigerants that acts as a single fluid. The
components of azeotropic mixtures will not
separate under normal operating conditions.
Blend - A mixture of two or more refrigerant
components.

Direct Expansion - A system design that


meters refrigerant into the evaporator with
the intention that it will all boil to vapor by
the time it reaches the end. Orifice plates,
capillary tubes, automatic expansion valves,
and TXVs are all expansion devices that
provide for direct expansion of refrigerant
in the evaporator.

Brazed - Joined by fusion using very high


heat; equivalent of hard soldering.
Capacity - The measure of heat energy
removed by a system per hour. The capacity
is very dependent on running and ambient
conditions and it is typically quoted for a
compressor or system at some standard
rating condition.

Disposal - The process leading to and


including (1) the discharge, deposit, dumping
or placing of any discarded appliance into or
on any land or water, (2) the disassembly of
any appliance for discharge, deposit, dumping
or placing of its discarded component parts
into or on any land or water, or (3) the disassembly of any appliance for reuse of its
component parts.

Centrifugal Air Conditioning - Compressor


technology used in larger air conditioning
chillers, based on a rotating impeller to spin
refrigerant to a higher pressure/temperature.
CFC - Chloro-Fluoro-Carbon; a refrigerant
comprised of carbon atoms connected to
only chlorine and fluorine atoms. The
common CFCs are R-11, R-12, R-13, R-113,
R-114 and R-115.

Efficiency - Ratio of the work output to the


energy input.
Elastomer - Material which can be stretched
or squeezed and, immediately on release of
the stress, returns to its approximate
dimensions.

Class I - Chemicals listed in the Clean Air Act


having an ozone depletion potential of 0.2 or
higher. These include CFCs, halons, carbon
tetrachloride, methyl chloroform, and bromine
compounds.

Refrigerant Reference Guide

122

5th Edition 2010

Glossary of Terms
Equilibrium - Liquid and Vapor phases of
refrigerant existing in contact with each other
at a saturated pressure/temperature condition.
For blends, the composition of the vapor will
contain more of the higher pressure
components.
Flooded Evaporator Systems - A system
design that allows the refrigerant to boil in a
pool in the evaporator, which cools the water,
glycol, or product that is circulating through
tubing or panels in the boiling pool, and only
the vapor that is boiled goes back to the
compressor.
Fractionation - Change in composition of a
blend by preferential evaporation of the more
volatile component(s) or condensation of the
less volatile component(s).
Global Warming or Greenhouse EffectOccurs when carbon dioxide and other gases,
including refrigerants, build up in the atmosphere. These gases allow sunlight to pass
through to the earth; however, the gases trap
heat energy from the earth and the planets
average temperature is raised.
Global Warming Potential or GWP A relative measure of how effective a chemical
is at retaining heat in the atmosphere. The
value shows the effect of an equivalent
number of kilograms of CO2 on global
warming.
HC - Hydrocarbon refrigerants, used primarily
as additives in blends. They will help promote
circulation of mineral oil when the blend
components will not accomplish this alone.
HCFC - Hydro-Chloro-Fluoro-Carbon; a
refrigerant comprised of carbon atoms
connected to chlorine, fluorine, and hydrogen

Refrigerant Reference Guide

HCFC (continued)
atoms. The common HCFCs are R-22, R-123,
R-124, R-142b.
HFC - Hydro-Fluoro-Carbon; a refrigerant
comprised of carbon atoms connected to
fluorine and hydrogen only. The common
HFCs are R-134a, R-125, R-143a, R-152a, R-32
and R-23.
High Ambient Air Conditioning - An air
conditioning application where the surrounding air temperatures are higher than normal,
which requires a slightly lower refrigerant
pressure and very large condensing surface
in order to work correctly. (Example: crane
control room in a steel mill.)
High Pressure Appliance - An appliance
that uses a refrigerant with a boiling point
between -50C (-55F) and 10C (40F) at
atmospheric pressure. This definition includes,
but is not limited to, appliances that use R-12,
R-22, R-114, R-500 or R-502.
High Temperature Refrigeration Refrigeration applications where the evaporator temperature normally runs higher
than 30F.
Household Appliance - The standard
refrigerator/freezer found in most kitchens,
as well as small freezer appliances sold to
homeowners.
Hygroscopic- A tendency for refrigeration
oils to absorb moisture from the atmosphere.
Industrial Process Refrigeration - Complex,
customized appliances used in the chemical,
pharmaceutical, petrochemical and manufacturing industries. This sector also includes
industrial ice machines and ice rinks.

123

5th Edition 2010

Glossary of Terms
Oil Flushing - The process of changing from
one type of lubricant (typically mineral oil or
alkylbenzene) to another type (typically POE),
which involves the removal of an oil charge and
replacement with the new oil type. Successive
oil changes will quickly lower the concentration
of the original oil type.

Low-Loss Fitting - Any device that is intended


to establish a connection between hoses,
appliances, or recovery or recycling machines,
which is designed to close automatically or
will be closed manually when disconnected,
thereby minimizing the release of refrigerant
from hoses, appliances, and recovery / recycling
machines.

Opening an Appliance - Any service,


maintenance, or repair on an appliance that
could be reasonably expected to release
refrigerant from the appliance to the atmosphere
unless the refrigerant was previously recovered
from the appliance.

Low-Pressure Appliance - An appliance that


uses a refrigerant with a boiling point above
10C (40F) at atmospheric pressure. This
definition includes, but is not limited to,
equipment utilizing R-11, R-113, and R-123.

Ozone Depletion - The interruption by free


chlorine radicals of the normal ozone creation/
breakdown process which occurs in the upper
atmosphere. The free chlorine causes ozone
molecules to come apart, then ties up the free
oxygen used to make for ozone. The result is a
net decrease in the ozone concentration.

Low Temperature Refrigeration - Refrigeration applications that normally run evaporator


temperatures between -40F and 0F.
Medium Temperature Refrigeration Refrigeration applications that normally run
evaporator temperatures between
0F and 40F.

Poly-Alkylene-Glycol (PAG) Oil - A general


term that applies to a family of synthetic oils
based on polyalkylene glycols chemistry. PAGs
are used primarily with HFC refrigerants in the
automotive air conditioning industry.

Mineral Oil - Traditional refrigeration oil,


refined from petroleum products. Generally
not compatible with new HFC refrigerants.
Miscibility - Ability of a gas or liquid to dissolve
uniformly (mix) in another gas or liquid.

Process Stub - A length of tubing that provides


access to the refrigerant inside an appliance and
that can be resealed at the conclusion of repair
or service.

Motor Vehicle Air Conditioner (MVAC) - Any


appliance that is contained in a motor vehicle
and is used to cool the driver's or passengers
compartment. MVAC is regulated under the
Clean Air Act Section 609.

Propylene Glycol - A type of heat transfer fluid


used in secondary loop chillers. Because of the
low toxicity of propylene glycol, this product is
often used when failure of the cooling piping
might allow contact of the glycol with food
products.

MVAC-Like Appliance - Air conditioning


equipment used to cool the drivers or
passengers compartment of a non-road
vehicle. The system is similar in construction to
MVAC equipment; however R-22 equipment is
excluded from this definition.

Refrigerant Reference Guide

Pump-Down (Out) - The withdrawal of all


refrigerant from the low side of a system by
pumping it into either the condenser or the
liquid receiver.
124

5th Edition 2010

Glossary of Terms
Reclaim - To reprocess refrigerant to at least
the purity specified in the AHRI Standard 700,
Specifications for Fluorocarbon Refrigerants,
and to verify this purity using the specified
analytical methods.

System-Dependent Recovery Equipment Recovery equipment that requires the


assistance of components contained in an
appliance to remove the refrigerant.
Temperature Glide - the change in temperature from when a blend first starts boiling
in an evaporator to when it reaches saturated
vapor at the end of the evaporator.

Recovery - To remove refrigerant from a


system, regardless of condition, and store it
in an external container without necessarily
testing or processing the refrigerant in any way.

TXV (or TEV) - Thermal Expansion Valve,


which is used to meter the flow of refrigerant
from the liquid line into the evaporator and
provide the correct pressure drop.

Recovery Efficiency -The percentage of


refrigerant recovered compared to the total
amount in the appliance.
Recycle - To extract refrigerant from an
appliance to attempt to clean water, oil,
acidity and particulates from it. These
procedures may not necessarily return
the refrigerant to AHRI 700 purity. The
refrigerant may be returned to the same
system after recycling.

Very Low Temperature or Ultra Low


Temperature Refrigeration - Refrigeration
applications that normally run evaporator
temperatures below -60F. These applications
will often use a cascade or 2 stage refrigeration
system.

Repair - Fix what is wrong with a broken system


without changing the type of refrigerant.
Replace - Install a new piece of equipment in
the same application instead of repair or retrofit.
Retrofit - The replacement of the original
refrigerant in a system with a different refrigerant, which may involve changing valves, oil,
other components, or adjusting controls in
some manner.

Weight Percent - The relative amount of each


component in a refrigerant blend on a mass
basis (the pounds of each component relative
to the total pounds in the blend).
Zeotrope - A blend that behaves normally as
a mixture of refrigerants. The properties are
a combination of the individual component
properties, and the vapor composition is
different from the liquid, which promotes
fractionation and temperature glide effects.
(see Section 2)

Self-Contained Recovery Equipment Recovery equipment that is capable of


removing refrigerant from an appliance
without the assistance of components within
the appliance.
Small Appliances - Any self-contained,
hermetic appliance that contains 5 pounds
or less of refrigerant.

Refrigerant Reference Guide

125

5th Edition 2010

Lubricants
Cross Reference
National Lubricants
Product Name

OEM PART #

Lubricant Type

York A

Mineral Oil/Capella

300 SUS/68 ISO

National WF 68

York C

Mineral Oil

300 SUS/68 ISO

National 300

York D

Mineral Oil

150 SUS/32 ISO

National 150

York E

Mineral Oil

500 SUS/100 ISO

National 500

York F

Mineral Oil

150 SUS/32 IS0

National 150

York G

Polyolester

320 ISO (very heavy)

CP 4214-320

York H

Polyolester

300 SUS/68 ISO

National PE 68

York J

Polyolester

200 SUS/46 ISO

Solest 46

York K

Polyolester

150 SUS/32 ISO

National PE 32

York L

Polyolester

120 SUS (very heavy)

Solest 120

York O

Polyolester

150 SUS/32 ISO

National PE 32

York P

Polyolester

750 SUS/150 ISO

CP 4214-150

York S

Polyolester

500 SUS/100 ISO

Solest 100

Trane 15

Pale Mineral Oil

300 SUS/68 ISO

National 300

Trane 22

White Mineral Oil

300 SUS/68 ISO

Trane 31

Pale Oil w/ Silicone

300 SUS/68 ISO

National 300

Trane 32

Pale Mineral Oil

150 SUS/32 ISO

National 150

Trane 37

Polyolester

300 SUS/68 ISO

National PE 68

Trane 42

Pale Oil w/ Phosphate

150 SUS/32 ISO

Trane 43

Pale Mineral Oil

150 SUS/32 ISO

National 150

Trane 45

Pale Mineral OIl

300 SUS/68 ISO

National 300

Trane 48

Polyolester

300 SUS/68 ISO

National PE 68

Trane 78

Polyolester

150 SUS/32ISO

National PE 32

Maneurop 160 SZ

Polyolester

150 SUS/32 ISO

National PE 32

Viscosity

Equivalent Lubricant

McQuay Polyolester Specifications


McQuay CE050, 063, 079, 087

Mobil EAL Arctic 22, Emkarate RL22N

McQuay CE100, 126

Mobil EAL Arctic 32, Emkarate Rl32H


National PE 32

McQuay SLIC
Refrigerant Reference Guide

PlanetElf AWF 68, Emkarate RL68HP


126

5th Edition 2010

Lubricants
Cross Reference
National Lubricants
Product Name
Part #
Mineral Oil
1501G
NL 150

Viscosity

Equivalent Part #

150 SUS/32 ISO

Calumet C3, Suniso 3GS

York D, F - Trane 32, 43

NL 300

3001G

300 SUS/68 ISO

Calumet C4, Sunios 4GS

York C - Trane 15, 45

NL 500

5001G

500 SUS/100 ISO Calumet C5, Suniso 5GS

NL WF 32

WF 32

150 SUS/32 IS0

Texaco WF 32

NL WF 68

1 TD

300 SUS/68 ISO

Texaco WF 68

NL AKB 150

150AKB1G

150 SUS/32 ISO

Zerol 150, Soltex 150

NL AKB 200R

200AKB1G

200 SUS/46 ISO

Zerol 200TD

NL AKB 300

300AKB1G

300 SUS/68 ISO

Zerol 300, Soltex 300

NL PE 32

PE321G

150 SUS/32 ISO

Ultra 32-3MAF,
Castrol SW32

York K, O

NL PE 68

PE681G

300 SUS/68 ISO

Emkarate 68H,
Castrol SW68

York H - Trane 48

OEM Part #

York E

Alkylbenzene
Lubricants

Polyolester
Lubricants

NuCalgon
Product Name

Part #

Viscosity

Equivalent Lubricant

C3

430307

150 SUS/32 ISO

National 150 (1501G)

C4

430407

300 SUS/68 ISO

National 300 (3001g)

C5

460507

500 SUS/100 ISO

National 500 (5001G)

Zerol 150

431007

150 SUS/32 IS0

National AKB 150 (150AKB1G)

Zerol 200TD

430807

200 SUS/46 ISO

National AKB 200R (200AKB1G)

Zerol 300

431107

300 SUS/68 ISO

National AKB 300 (300AKB1G)

Emkarate RL32H

431446

150 SUS/32 ISO

National PE 32 (PE321G)

Emkarate RL68H

431646

300 SUS/68 ISO

National PE 68 (PE681G)

Refrigerant Reference Guide

127

5th Edition 2010

LUBRICANTS
for the

HVAC/R Industry

MINERAL OIL

Naphthenic Mineral Oils (pale oils) are


the traditional choice for lubrication in air conditioning and refrigeration compressors. They are
used primarily in systems designed for CFCs (R-12,
R-502) and HCFCs (R-22, retrofit blends).
Mineral Oils are made from the highest quality
base stocks and provide outstanding performance
and protection in compressors. Available in
150 SUS, 300 SUS and 500 SUS viscosities, these
products can be used in most reciprocating, scroll,
screw and many centrifugal compressors on the
market today.

Mineral Oils perform well over a wide temperature range. They have very good chemical
stability and provide very good protection and
lubrication at higher compressor temperatures.
In addition, they have low wax content and have
chemical characteristics that promote a low pour
point and good oil return to the compressor at low
evaporator temperatures. Naphthenic Mineral Oils
do a very good job of preventing system deposits
compared to paraffinic (white) mineral oils.

Available Sizes & Part Numbers


1501G
3001G
5001G

1 Gallon

5 Gallon

1505G
3005G
5005G

55 Gallon

15055G
30055G
50055G

TYPICAL PROPERTIES
Property
Viscosity, SUS @ 100F
Flash Point, F
Pour Point, F
Floc Point, F
Color Gardner
Specific Gravity

Refrigerant Reference Guide

Test Method
ASTM D445
ASTM D92
ASTM D97
ASHRAE 86
ASTM D1500
ASTM D1250

128

150

300

500

155
350
-50
-72
<0.5
0.904

325
400
-30
-56
<0.5
0.910

510
405
-15
-51
<0.5
0.916

5th Edition 2010

LUBRICANTS
quality Lubricant Products
for the

HVAC/R Industry

ALKYLBENZENE

Alkylbenzene (AKB) synthetic refrigeration


lubricants provide outstanding performance for extended drain intervals and better thermal stability compared
to traditional mineral oil. They can be used in systems
designed for CFCs (R-12, R-502) and HCFCs (R-22,
retrofit blends).
Alkylbenzenes are made from the highest
quality synthetic base stocks and provide outstanding
performance and protection in compressors. These
synthetic lubricants do not contain wax and can survive
longer than mineral oils at high compressor discharge
temperatures. Alkylbenzenes typically run cleaner in
systems than mineral based oils. Available in 150 SUS,
200 SUS and 300 SUS viscosities, these products can be
used in most reciprocating, rotary vane, and scroll
compressors on the market today.
Alkylbenzenes are particularly well suited
for use in retrofit projects. In some cases, equipment
manufacturers suggest the replacement of some mineral
oil with alkylbenzene when using HCFC-based retrofit
blends. During HFC retrofit projects, using alkylbenzene
for initial oil flushing helps remove mineral oil and contaminants in preparation for a final POE flush, thus
saving money on POE.

Available Sizes & Part Numbers

AKB 200R meets the strict retrofit recommendations imposed by some equipment manufacturers,
such as Copeland.

1 Gallon

150AKB1G
200AKB1G
300AKB1G

5 Gallon

150AKB5G
200AKB5G
300AKB5G

55 Gallon

150AKB55G
200AKB55G
300AKB55G

TYPICAL PROPERTIES
Property
Viscosity, SUS @ 100F
Color Gardner
Flash Point, F
Pour Point, F
Refractive Index

Refrigerant Reference Guide

Test Method

AKB150

ASTM D445
ASTM D1500
ASTM D92
ASTM D97

150
1
347
-49
1.4864

129

AKB200R
205
<1
365
-49
1.4857

AKB300
280
1
365
-49
1.4841

5th Edition 2010

LUBRICANTS
for the

HVAC/

Industry

POLYOLESTER

Polyolester (POE)

synthetic refrigeration
lubricant is recommended for use with all new HFC
refrigerants such as R-404A and R-410A. It is also
compatible with HCFC refrigerants and can be used
with confidence in systems containing R-22 or HCFC
based blends

POEs are made from the highest quality base


stocks and provide outstanding performance in a
wide variety of air conditioning and refrigeration
compressors. Available in 32 cSt and 68 cSt viscosities,
these products can be used in most reciprocating, scroll,
screw and many centrifugal compressors on the market
today.
POEs perform well over a wide temperature range.
They provide maximum protection and lubrication at
higher compressor temperatures. In addition, good
refrigerant miscibility at low evaporator temperatures
will help promote oil return to the compressor.

Available Sizes and Part Numbers

POEs are based on the most current industrystandard formulations. These lubricants contain no
extra antiwear additives that can leave deposits. They
are compatible with existing mineral oil and alkylbenzene
lubricants, making them excellent for retrofitting older
systems to HFC refrigerants.

1 Pint

PE321P
PE681P

1 Quart

PE321Q
PE681Q

1 Gallon

PE321G
PE681G

5 Gallon

PE685G

TYPICAL PROPERTIES
Property
Viscosity, cSt @ 104F
Viscosity, cSt @ 212F
Flash Point, F
Pour Point, F
Total acid number, mgKOH/g
Miscibility Temp, F
Density, g/ml @ 68F

Refrigerant Reference Guide

Test Method

PE32

PE68

ASTM D445
ASTM D445
ASTM D92
ASTM D97
ASTM D664

32
5.8
496.5
-51
<0.02
-44
0.977

68
9.3
518
-38.2
<0.02
-15
0.980

-ASTM D1298

130

5th Edition 2010

LUBRICANTS
Quality Solest Lubricant Products
Solest products are high quality polyolester synthetic lubricants designed for use with
air conditioning and industrial refrigeration compressors. These new products extend the
viscosity range of synthetic lubricants available from NRI. The Solest lubricants are
excellent choices for initial fill, service, and retrofit applications.

Product Line
Solest LT 32

specifically designed for very low temperature applications; provides good miscibility
with R-404A, eliminating the need to use two lubricants in a cascade system

Solest 46

used in centrifugal, reciprocating, and rotary vane compressors

Solest 68

can be used in a wide variety of compressor units

Solest 100

used primarily in scroll and screw compressors

Solest 120

provides good oil return in screw applications

Solest 150 &


Solest 170

these two lubricants are used mainly in Bitzer and Carlyle screw compressors

Solest 220

mostly used in large srew type applications with R-134a

CP-4214-320

a complex ester lubricant that cannot be used with HFC refrigerants; provides good
oil return in R-22 screw type applications

Solest 370

used in screw type applications with HFC refrigerants

Alkylbenzene
500E

alkylbenzene based lubricant; provides good miscibility with HCFC refrigerants and
has the higher viscosity needed to work well with screw compressors

Product

Viscosity

Solest LT 32
Solest 46
Solest 68
Solest 100
Solest 120
Solest 150
Solest 170

32 ISO/150 SUS

Solest 220
CP-4214-320
Solest 370
AKB 500 E

46 ISO/200 SUS
68 ISO/300 SUS
100 ISO/500 SUS
120 ISO/600 SUS
150 ISO/700 SUS
170 ISO/800 SUS

220 ISO/1000 SUS


320 ISO/1500 SUS
370 ISO/1700 SUS
100 ISO/500 SUS

Equivalent to
OEM Part No.
York K
York J
York H - Trane 37 - Frick 13
York S
York L
York P
York P

Castrol SW220
York G

Solest Lubricants
are available in
the following
sizes

1 gallon
5 gallon
55 gallon

BVA 100E

Solest is a registered trademark of CPI Engineering Services Inc.

Refrigerant Reference Guide

131

5th Edition 2010

NATIONAL CHEMICALS &


COIL CLEANERS

Coil Cleaners
Available in 1 gallon,
2 1/2 gallon, and
55 gallon containers

Part No. KN1GN, KN2GN


Part No. MK1GN, MK2GN
Part No. AN1GN, AN2GN

Part No. KF1GN, KF2GN

AlkaKleen

Part No. KB1GN, KB2GN

MultiKleen

Strongest non-acid cleaner and brightener


Removes grease, smoke, and insects

Multi-purpose alkaline cleaner


For use on filters, electronic air filters, fan
blades, and metal cabinets

KleenFoam

KleenCoil

Non-acid indoor evaporator cleaner


Self rinsing

KleenBrite

Extra heavy foam


Removes stubborn deposits
Outdoor non-acid cleaner

Acid based Cleaner


Fast acting formula makes fins look
like new
AlkaKleen

KleenFoam

MultiKleen

KleenBrite

KleenCoil

Outdoor

Outdoor

Outdoor

Outdoor

Indoor

Air Filters

Oil and Grease

Cooking Grease

Corrosion and Oxides

Dirt and Grime

Dust and Lint

Best to Use On
Condenser Coils
Evaporator Coils

Best to Remove

Mineral Deposits, Salt and Scale

x
x

Bugs

Grass and Cottonwood

Tobacco Stains

Foaming

Brightening

Major Features
x
x

Non-Rinsing

Refrigerant Reference Guide

x
x

132

5th Edition 2010

NATIONAL CHEMICALS &


COIL CLEANERS
National Product
Name

Nu-Calgon

Virginia KMP

Rectorseal
Stewart Hall

Specialty
Chemical

Vapco

Coil Cleaners

OUTDOOR
Alka Kleen

Alka Brite
Nu Brite

Alki Foam

Renewz

Free Foam

Plus

Kleen Brite (Acid)

Cal Brite

Acti Brite

Con Coil

Coil Kleen

Blu Brite

Kleen Foam

Foam Brite

Foam Max

Renewz

Foam Power

Foaminator

Multi Kleen

HD Cal Clean,
TriPowr

ProKlean MPC

Triple D

Acti Klean

Coil Rite

Power-Plus

Power Clean

Coil Klean
(Aerosol)

Renewz

Foam Plus

Foaminator

KO Dirt Blaster

Blow Out

Zipp

Saf-T-Kleen

Degreaser

Contact Cleaner

Electric Contact
Cleaner

INDOOR
Evap Kleen
(Aerosol)

Coil Power &


Evap Power
Evap Foam
(Aerosol)

Blast Kleen

Nu Blast

Blast-A-Coil

Electric Motor
Cleaner
Electric Contact
Cleaner
HD Degreasing
Solvent

Em Degreasing
Solvent
Electric Contact
Cleaner

Switch & Contact


Cleaner
Switch & Contact
Cleaner

Degreasing
Solvent ef

Virginia 10N

Continental #1

Degreaser

Scale Remover &


Inhibitor

Liquid Scale
Dissolver

Liquid Scale
Remover

Liquid Descalit

DScale

Scale Remover

Degreasers, Cleaners
and Scale Removers

Kleen Coil

WHY USE A COIL CLEANER?

HOW CAN YOU CALCULATE DILUTION LEVELS?

Dirty or blocked coils will result in reduced


air flow and poor heat transfer. Equipment
could run hotter, reducing its useful lifetime,
increasing operating costs and reducing
comfort or refrigeration capacity. Properly
cleaning the coils will keep equipment
running at peak performance.

Concentrated coil cleaners are meant to be diluted


with water. Using the concentrate straight from the
bottle or strong mixtures on lightly soiled coils can
result in damage to the surface being cleaned.
Extremely dirty coils require a higher content of
the coil cleaner versus water to get the desired
cleaning.
Moderately soiled coils can be cleaned with an
equal amount of coil cleaner and water content.
Slightly soiled coils can be cleaned with a higher
water content to coil cleaner content to get the
desired cleaning.

HOW DO COIL CLEANERS REALLY WORK?


The two active ingredients are soap and an acid or
alkaline based surface brightener.
The soaps job is obvious -- to break up and carry
away dirt and grease.
The surface brighteners job is also straightforward:
Air, moisture and other chemicals will react with
aluminum coil surfaces to form layers that can
collect dirt and reduce heat transfer. The strong
alkaline or acid compounds in the coil cleaner
will chemically clean the layers away until bright
metal is exposed, returning the coil surface to its
original design performance.

WHAT IS THE DIFFERENCE BETWEEN


TYPES OF COIL CLEANERS?

CAN COIL CLEANERS BE USED TO CLEAN


OTHER SURFACES?
Indoor coils, cabinets, air filters and fan blades can
be cleaned with a diluted concentrate. Each
coil cleaner has a dilution chart on the bottle
as a guideline.

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They will all clean and treat the surface of the coil.
The major differences are:
Acid or Alkaline based (acid for strong surface
treatment, alkaline for general brightening)
Formulation
Amount and type of soap
Color

5th Edition 2010

NATIONAL CHEMICALS AND


COIL CLEANERS
Aerosol Products

PART #
BlastKleen

N4880

EvapKleen

N4890

BlastKleen instantly penetrates and dissolves grease, oil and


dirt deposits from refrigeration condenser coils. Due to its
ability to evaporate quickly, it does not need to be rinsed off
the coils.
EvapKleen is a foaming, no-rinse product used to clean either
condenser or evaporator coils

N4835

Energized Electrical Cleaner is a self rinsing solvent that cleans


and protects electric motors, generators, oil burners, and fans
from corrosion.

HD Solvent

NDS17OZ

HD Solvent is an environmentally friendly heavy duty cleaner


and degreaser used where washing or flushing is not possible.

MultiKleen

N4860

MultiKleen spray is used to clean condenser or evaporator coils,


metal cabinets, refrigeration parts and components.

Spray Adhesive

N4820

Electric Contact Cleaner

N4830

Spray Adhesive is used for forming temporary or permanent


bonds between most surfaces. It can be used on paper, foil,
cardboard, cloth, leather, glass, Mylar, acetate sheet, foam rubber,
urethane foam, Styrofoam and light metal sections.

Silicone Spray

N4840

Penetrating Lubricant

N4855

Energized Electrical
Cleaner

Electric Contact Cleaner lubricates and protects electrical


contacts from corrosion. It helps to restore and maintain the
original efficiency of electrical contacts.
Silicone Spray contains FDA approved ingredients allowing it to
be used in food-processing applications. It prevents sticking and
grinding on ice-machines, freezing plates, feed racks, conveyors,
dairy machinery, knives and other processing equipment.
Penetrating Lubricant has penetrating and lubricating properties
that prevent the accumulation of rust and corrosion.

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2nd Edition 2010

NATIONAL CHEMICALS &


COIL CLEANERS

PROPYLENE GLYCOL
Inhibited Propylene Glycol heat transfer fluid contains DOWFROST *blended to different
concentrations. It contains a performance additive that prevents metal corrosion, lowers
maintenance cost, and improves heat transfer. It also provides freeze and burst protection based
on the type of application.
Inhibited Propylene Glycol has a low toxicity level, so it can be used in applications that have
contact with food or beverage products such as immersion freezing and packaging carbonated
beverages. It is also used for secondary cooling and heating applications, and for various defrosting
and dehumidifying applications.
Based on the desired application temperature, the amount of propylene glycol can be calculated
with the following formula:
Volume of PG required = (System Volume) * (percentage of PG based on Table 1 value)* (0.01)
T
A
B
L
E
1

Temperature
F
20
10
0
-10
-20
-30
-40
-50
-60

For Burst Protection


Volume %

For Freeze Protection


Volume %
PG35%
49
80
99
-

PG40%
43
70
86
-

PG70%
25
40
49
58
63
69
74
78
82

PG96%
18
29
36
42
46
50
54
57
60

PG35%
33
55
66
77
82
91
96
96
96

PG40%
29
48
58
67
72
79
84
84
84

PG70% PG96%
16
12
27
20
33
24
38
28
41
30
45
33
48
35
48
35
48
35

D
Y
E

PART #
55PG35D
5PG40
55PG40
1PG70
5PG70
55PG70

CONCENTRATION
35%
40%
40%
70%
70%
70%

CONTAINER SIZE
55 gallon
5 gallon
55 gallon
1 gallon
5 gallon
55 gallon

N
O

5PG96
55PG96

5 gallon
55 gallon

D
Y
E

PROPYL55G

96%
96%
Uninhibited USP Food Grade
Kosher 99.9%

B
L
U
E

55 gallon

* Trademark of The Dow Chemical Company (DOW) or an affiliated company of Dow.

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136

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4. Regulatory & Legislative Issues


The following section is a compilation of
EPA publications relating to the HVAC/R industry.

For further information on these publications,


or any other regulatory questions, contact the
EPA Stratospheric Hotline at
1-800-296-1996
or visit the EPA Website:
www.epa.gov/ozone

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Regulatory Update
Complying With Section 608 Regulations
This section provides an overview of the refrigerant recycling requirements of Section 608 of the Clean Air
Act of 1990, as amended (CAA), including final regulations published on May 14, 1993 (58 FR 28660),
August 19, 1994 (59 FR 42950), November 9, 1994 (59 FR 55912), and July 24, 2003 (68 FR 43786). This section
also describes the prohibition on intentional refrigerant venting that became effective on July 1, 1992.
Overview
Prohibition on Venting
Regulatory Requirements
Service Practice Requirements
Evacuation Requirements
Exceptions to Evacuation Requirements
Reclamation Requirement
Refrigerant Recovery and Recycling Equipment Certification
Refrigerant Leaks
Technician Certification
Refrigerant Sales Restrictions
Certification by Owners of Refrigerant Recovery and Recycling Equipment
Refrigerant Reclaimer Certification
Safe Disposal Requirements
For Further Information

Overview
Under Section 608 of the CAA, EPA has established regulations (40 CFR Part 82, Subpart F) that:
Require service practices that maximize recovery and recycling of ozone-depleting
substances (both chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs)
and their blends) during the servicing and disposal of air-conditioning and refrigeration
equipment.
Set certification requirements for refrigerant recycling and recovery equipment, technicians,
and refrigerant reclaimers.
Restrict the sale of refrigerant to certified technicians.
Require persons servicing or disposing of air-conditioning and refrigeration equipment
to certify to EPA that they have acquired refrigerant recovery and/or recycling equipment
and are complying with the requirements of the rule.
Require the repair of substantial leaks in air-conditioning and refrigeration equipment with
a refrigerant charge greater than 50 pounds.
Establish safe disposal requirement to ensure removal of refrigerants from goods that
enter the waste stream with the charge intact (e.g., motor vehicle air conditioners, home
refrigerators, and room air conditioners.

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Regulatory Update
The Prohibition on Venting
Effective July 1, 1992, Section 608 of the Act prohibits individuals from intentionally venting ozonedepleting substances used as refrigerants (generally CFCs and HCFCs) into the atmosphere while
maintaining, servicing, repairing, or disposing of air-conditioning or refrigeration equipment
(appliances). Only four types of releases are permitted under the prohibition.
1. De minimis quantities of refrigerant released in the course of making good faith attempts
to recapture and recycle or safely dispose of refrigerant.
2. Refrigerants emitted in the course of normal operation of air-conditioning and refrigeration
equipment (as opposed to during the maintenance, servicing, repair or disposal of this
equipment) such as from mechanical purging and leaks. However, EPA requires the repair
of leaks above a certain size in large equipment. (see Refrigerant Leaks)
3. Releases of CFCs or HCFCs that are not used as refrigerants. For instance, mixtures of nitrogen
and R-22 that are used as holding charges or as leak test gases may be released.
4. Small releases of refrigerant that result from purging hoses or from connecting or disconnecting
hoses to charge or service appliances will not be considered violations of the prohibition on
venting. However, recovery and recycling equipment manufactured after November 15, 1993,
must be equipped with low-loss fittings.

Regulatory Requirements
Service Practice Requirements
1. Evacuation Requirements
Technicians are required to evacuate air-conditioning and refrigeration equipment to established vacuum
levels when opening the equipment for maintenance, service, repair, or disposal. If the technicians recovery
and/or recycling equipment was manufactured any time before November 15, 1993, the air-conditioning
and refrigeration equipment must be evacuated to the levels described in the first column of Table 1. If the
technicians recovery or recycling equipment was manufactured on or after November 15, 1993, the air-conditioning and refrigeration equipment must be evacuated to the levels described in the second column of
Table 1, and the recovery or recycling equipment must have been certified by an EPA -approved equipment
testing organization.
Technicians repairing small appliances, such as household refrigerators, window air conditioners, and water
coolers, must recover:
80 percent of the refrigerant when
the technician uses recovery or recycling equipment manufactured before November 15, 1993, or
the compressor in the appliance is not operating; OR
90 percent of the refrigerant when
the technician uses recovery or recycling equipment manufactured after November 15, 1993, and
the compressor in the appliance is operating
In order to ensure that they are recovering the correct percentage of refrigerant, technicians must use the
recovery equipment according to the directions of its manufacturer. Technicians may also satisfy recovery
requirements by evacuating the small appliance to four inches of mercury vacuum.

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Regulatory Update
Required Levels of Evacuation
REQUIRED LEVELS OF EVACUATION FOR APPLIANCES EXCEPT FOR
SMALL APPLIANCES, MVACS, AND MVAC-LIKE APPLIANCES
TABLE 1

Inches of Mercury Vacuum* Using


Equipment Manufactured:
On or after
Before
Nov.15, 1993
Nov. 15,1993

Type of Appliance
HCFC-22 appliance** normally containing less than 200
pounds of refrigerant

HCFC-22 appliance** normally containing 200 pounds or


more of refrigerant

10

Other high-pressure appliance** normally containing less


than 200 pounds of refrigerant (CFC-12,-500, -502 -114)

10

Other high-pressure appliance** normally containing 200


pounds or more of refrigerant (CFC-12, -500, -502, -114)

15

Very high pressure appliance (CFC-13 -503)

Low pressure appliance (CFC-11, HCFC-123)

25

25 mm Hg absolute

*Relative to standard atmospheric pressure of 29.9 Hg


** Or isolated component of such an appliance

2. Exceptions to Evacuation Requirements


EPA has established limited exceptions to its evacuation requirements for 1) repairs to refrigeration and airconditioning equipment and 2) repairs that are not major and that are not followed by an evacuation of the
equipment to the environment.
If, due to leaks, evacuation to the levels in Table 1 is not attainable, or would substantially contaminate the
refrigerant being recovered, the persons opening the appliance must:
isolate leaking from non-leaking components wherever possible;
evacuate non-leaking components to the levels in Table 1; and
evacuate leaking components to the lowest level that can be attained without
substantially contaminating the refrigerant. This level cannot exceed 0 psig.
If evacuation of the equipment to the environment is not to be performed when repairs are complete, and if
the repair is not major, then the appliance must:
be evacuated to at least 0 psig before it is opened if it is a high or very-high pressure
appliance, or
be pressurized to 0 psig before it is opened if it is a low-pressure appliance. Methods that
require subsequent purging (e.g., nitrogen) cannot be used except with appliances containing R-113.

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Regulatory Update
3. Reclamation Requirement
EPA has also established that refrigerant recovered and/or recycled can be returned to the same system or
other systems owned by the same person without restriction.
If refrigerant changes ownership, it must be reclaimed (i.e., cleaned to the AHRI 700-1193 Standard of purity)
by an EPA certified refrigerant reclaimer.

Refrigerant Recovery and Recycling Equipment Certification


The Agency has established a certification program for refrigerant recovery and recycling equipment. EPA
required that manufacturers or importers of refrigerant recovery and recycling equipment manufactured on
or after November 15, 1993, have their equipment tested by an EPA-approved testing organization to ensure
that it meets EPA requirements. Equipment intended for use with air-conditioning and refrigeration equipment
must be tested under EPA requirements based upon the AHRI 740 test protocol (i.e., EPA Appendices B and B1
to 40 CFR 82 subpart F). Recycling and recovery equipment intended for use with small appliances must be
tested under EPA Appendix C or alternatively under requirements bases upon the AHRI 740 test protocol
(i.e., Appendices B and B1 to 40 CFR 82 subpart F).
The Agency requires recovery efficiency standards that vary depending on the size and type of air-conditioning
or refrigeration equipment being serviced. For recovery and recycling equipment intended for use with airconditioning and refrigeration equipment besides small appliances, these standards are the same as those in
the second column of Table 1. Recovery equipment intended for use with small appliances must be able to
recover 90 percent of the refrigerant in the small appliance when the compressor is not operating.
EPA has approved both the Air-conditioning, Heating, and Refrigeration Institute (AHRI) and Underwriters
Laboratories (UL) to certify recycling and recovery equipment. Certified equipment can be identified by a label
reading: This equipment has been certified by ARI/UL to meet EPAs minimum requirements for recycling and/
or recovery equipment intended for use with (appropriate category of appliance -- e.g., small appliances, HCFC
appliances containing less than 200 pounds of refrigerant, all high-pressure appliances, etc.). Lists of certified
equipment may be obtained by contacting AHRI at 703-5248800 and UL at 708-272-8800 ext. 42371.

Refrigerant Leaks
Owners or operators of refrigeration and air-conditioning equipment with refrigerant charges greater than 50
pounds are required to repair leaks within 30 days when those leaks result in the loss of more than a certain
percentage of the equipments refrigerant charge over a year. For the commercial (e.g. grocery stores and
warehouses) and industrial process refrigeration sectors, leaks must be repaired within 30 days when the
equipment leaks at a rate that would release 35 percent or more of the charge over a year. For all other sectors,
including comfort cooling (such as building chillers), leaks must be repaired when the appliance leaks at a rate
that would release 15 percent or more of the charge over a year.
The trigger for repair requirements is the current leak rate projected over a consecutive 12-month period rather
than the total quantity of refrigerant lost. For instance, owners or operators of a commercial refrigeration system
containing 100 pounds of charge must repair leaks if they find that the system has lost 10 pounds of charge over
the past month; although 10 pounds represents only 10 percent of the system charge in this case, a leak rate of
10 pounds per month would result in the release of over 100 percent of the charge over the year. To track leak
rates, owners or operators of air-conditioning and refrigeration equipment with more than 50 pounds of charge
must keep records of the quantity of refrigerant added to their equipment during servicing and maintenance
procedures. Owners or operators are required to repair leaks within 30 days of discovery. This requirement is

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Regulatory Update
Refrigerant Leaks (continued)
waived if, within 30 days of discovery, owners develop a one-year retrofit or retirement plan for the leaking
equipment. Owners of industrial process refrigeration equipment may qualify for additional time under certain
circumstances. For example, if an industrial process shutdown is required to repair a leak, owners have 120 days
to repair the leak. Owners of industrial process refrigeration equipment should reference the Compliance
Assistance Guidance Document for Industrial Process Refrigeration Leak Repair for additional information
concerning time extensions and pertinent recordkeeping and reporting requirements.
The leak repair regulations do not apply to refrigeration and air-conditioning equipment with refrigerant
charge sizes less than 50 pounds (such as residential split air-conditioning systems). However, smaller
equipment is not exempt from the refrigerant venting prohibition. EPA regulations prohibit the intentional
release of all refrigerants during the maintenance, service, repair, or disposal of air-conditioning and
refrigeration equipment.

Technician Certification
EPA has established a technician certification program for persons (technicians) who perform maintenance,
service, repair, or disposal that could be reasonably expected to release refrigerants into the atmosphere. The
definition of technician specifically includes and excludes certain activities as follows:
Included:
attaching and detaching hoses and gauges to and from the appliance to measure pressure within
the appliance;
adding refrigerant to (for example topping off) or removing refrigerant from the appliance.
any other activity that violates the integrity of the MVAC-like appliances, and small appliances.
In addition, apprentices are exempt from certification requirements provided the apprentice is closely and
continually supervised by a certified technician.
The Agency has developed four types of certification:
1. For servicing small appliances (Type I)
2. For servicing or disposing of high or very high-pressure appliances, except small appliances and
MVACs (Type II)
3. For servicing or disposing of low-pressure appliances (Type III).
4. For servicing all types of equipment (Universal).
Technicians are required to pass an EPA-approved test given by an EPA-approved certifying organization to
become certified under the mandatory program. Section 608 Technician Certification credentials do not expire.

Technician Certification (Section 608): Steps for Replacing a Lost Card


Step 1. Is your testing organization that issued your certification still in business? Check the list of certifying
organizations that are still operating.
Yes, my organization is still operating.
Go to that organization and get a replacement card. They are required to maintain records of people
issued cards.
No. - Go to 2 (next page)

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Regulatory Update
Technician Certification (Section 608): Steps for Replacing a Lost Card (continued)
Step 2. Do you have documentation from your original testing organization that demonstrates successful
completion of the Section 608 Technician Certification exam? Do you or a current or former employer have a
copy of your lost card?
Yes. I have documentation from my original testing organization.
Go to the list of certifying organizations that will replace cards. Send a copy of your documentation to
one of the organizations (who have volunteered to make cards for people who cant get them from their
certifying organization) on the list. They will issue you a new card and they will maintain a record of your
certification.
No. - Go to 3 below.
Step 3. Is the record of your certification in our centralized files which were compiled from data submitted by
certifying organizations that have gone out of business? Go to the list of certifying organizations that have closed.
Yes, the record of my certification is in the data submitted by companies that have gone out of business.
Download and complete the Assistance with Obtaining a Replacement Card form (PDF, 1 pp., 14K, about
PDF). After completing the form mail or fax it to the Section 608 Technician Certification Program Manager. Once it is received EPA will contact you with information on how to obtain a replacement card.
No. - Go to 4 below
Step 4. If you cannot answer yes to any of the steps above, EPA will not issue a replacement card. You will need
to retake the Section certification test. Please go to the Section 608 Technician Certification Programs page to
find testing organizations which meet your needs.

Refrigerant Sales Restrictions


The sale of ozone-depleting refrigerant (such as R-11, R-12, and R-22) in any size container has been restricted to
technicians certified either under the program described in Technician Certification above or under EPAs motor
vehicle air conditioning regulations. The sales restriction covers ozone-depleting refrigerant contained in bulk
containers, such as cans, cylinders, or drums.
The restriction excludes refrigerant contained in refrigerators or air conditioners with fully assembled refrigerant
circuits(such as household refrigerators, window air conditioners, and packaged air conditioners), and HFC
refrigerants (such as R-134a and R-410A).
Under Section 609 of the Clean Air Act, sales of CFC-12 in containers smaller than 20 pounds are restricted
solely to technicians certified under EPAs motor vehicle air-conditioning regulations (i.e., Section 609 certified
technicians). Technicians certified under EPAs stationary refrigeration and air-conditioning equipment
(i.e., Section 608 certified technicians) may buy containers of CFC-12 larger than 20 pounds.
Section 609 technicians are only allowed to purchase refrigerants that are suitable for use in motor vehicle airconditioners. Effective September 22, 2003, EPA has restricted the sale of ozone-depleting refrigerants, approved
for use in stationary refrigeration and air-conditioning equipment, to Section 608 certified technicians. Therefore,
the sale of ozone-depleting refrigerants (such as HCFC-22) that are approved for use in stationary equipment but
not for use in motor vehicle air-conditioners is restricted to Section 608 certified technicians.

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Regulatory Update
Certification by Owners of Refrigerant Recovery and Recycling Equipment
EPA requires that persons servicing, disposing, or recycling air-conditioning and refrigeration equipment
certify to the appropriate EPA Regional Office that they have acquired (built, bought, or leased) refrigerant
recovery or recycling equipment and that they are complying with the applicable requirements of this rule.
This certification must be signed by the owner of the owner of the equipment or another responsible officer
and sent to the appropriate EPA Regional Office. Although owners of recycling and recovery equipment are
required to list the number of trucks based at their shops, they do not need to have a piece of recycling or
recovery equipment for every truck. Owners do have to send in a new form each time they add recycling or
recovery equipment to their inventory.

Refrigerant Reclaimer Certification


Refrigerant reclaimers are companies that reprocess used refrigerant back to virgin specifications. EPA restricts
the resale of used refrigerant to a new owner, unless it has been reclaimed by an EPA certified refrigerant
reclaimer. Reclaimers are required to return refrigerant to the purity level specified in AHRI Standard 700 (an
industry-set purity standard) and to verify this purity using the laboratory protocol set forth in the same standard.
In order to be recognized by EPA, refrigerant reclaimers must certify to the Section 608 Recycling Program Manager
at EPA headquarters that they are complying with these requirements and that the information given is true and
correct. Certification must also include the name and address of the reclaimer and a list of equipment used to
process and to analyze the refrigerant.

Safe Disposal Requirements


Refrigeration and air-conditioning equipment that is typically dismantled on-site before disposal (e.g., retail
food refrigeration, central residential air conditioning, chillers, and industrial process refrigeration) has to have
the refrigerant recovered in accordance with EPA s requirements for servicing prior to their disposal. However,
equipment that typically enters the waste stream with the charge intact, (e.g. motor vehicle air conditioners,
household refrigerators and freezers, and room air conditioners) are subject to special safe disposal requirements.
Under these requirements, the final person in the disposal chain (e.g., a scrap metal recycler or landfill owner) is
responsible for ensuring that refrigerant is recovered from equipment before the final disposal of the equipment.
If the final person in the disposal chain accepts appliances that no longer hold a refrigerant charge, that person is
responsible for maintaining a signed statement from whom the appliance/s is being accepted. The signed statement must include the name and address of the person who recovered the refrigerant, and the date that the
refrigerant was recovered, or a copy of a contract stating that the refrigerant will be removed prior to delivery.
EPA does not mandate a sticker as a form of verification that the refrigerant has been removed prior to disposal
of the appliance. Such stickers do not relieve the final disposer of their responsibility to recover any remaining
refrigerant in the appliance, unless the sticker consists of a signed statement that includes the name and address
of the person who recovered the refrigerant, and the date that the refrigerant was recovered.
Technician certification is not required for individuals removing refrigerant from small appliances, motor vehicle
air conditioners, and motor vehicle-like air conditioners, when preparing them for disposal. However, the
equipment used to recover refrigerant from appliances prior to their final disposal must meet the same performance standards as refrigerant recovery equipment used prior to servicing. Persons involved in the final disposal
of appliances must certify to their EPA Regional Office that they have obtained and are properly using EPA
certified refrigerant recovery equipment.

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Regulatory Updates
Major Recordkeeping Requirements
Technicians

servicing appliances that contain 50 or more pounds of refrigerant must provide the
owner with an invoice that indicates the amount of refrigerant added to the appliance.
Technicians must also keep a copy of their proof of certification at their place of business.

Owners or Operators of appliances that contain 50 or more pounds of refrigerant must keep servicing records
documenting the date and type of service, as well as the quantity of refrigerant added.
Wholesalers

who sell CFC and HCFC refrigerants must retain invoices that indicate the name of
the purchases, the date of sale, and the quantity of refrigerant purchased.

Reclaimers

must maintain records of the names and addresses of persons sending them material
for reclamation and the quantity of material send to them for reclamation. This information must be maintained on a transactional basis. Within 30 days of the end of the
calendar year, reclaimers must report to EPA the total quantity of material sent to them
that year for reclamation, the mass of refrigerant reclaimed that year, and the mass of
waste products generated that year.

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2010 HCFC RULES

EPA Final HCFC Rules Summary


1) Allocation Rule - Adjustments to the Allowance System for Controlling HCFC Production,
Import & Export allocates the production and import of HCFCs including R-22,
R-142b, R-123 and R-124 for 2010 through 2014.
2) Precharged Equipment Rule - Ban of the Sale or Distribution of Precharged Equipment
establishes regulations related to the sale or distribution or offer for sale or distribution
in interstate commerce of air conditioning and refrigeration appliances containing
R-22, R-142b and blends containing these refrigerants beginning January 1, 2010.

EPA definition of Appliance, Component and Manufactured:


Appliance:

Any device which contains and uses a refrigerant and which is used for household or
commercial purposes, including air conditioners, refrigerators, chillers and freezers.

Component:

Any portion of the refrigerant circuitry that is necessary for the appliance to function
in its intended purpose (examples: condenser, evaporator, compressor, TXV, line set, coil)

Manufactured: The date of manufacture is when the appliance meets the following four criteria:
1) Refrigerant circuit is complete and
2) Appliance is charged with refrigerant and
3) Appliance can function and
4) Appliance is ready for use for its intended purpose

Allocation Rule
EPA is allocating 80% of the estimated quantity of R-22 needed for aftermarket servicing in 2010
and will decrease the allocation each year so that the supply of R-22 will be less than the estimated
demand. EPA will issue allocations for 2015-2019 at a later date based on projected servicing
demand for those years.
Virgin R-123 and R-124 are allowed in newly manufactured appliances until January 1,2020.
As indicated in the chart below, reclaimed R-22 will be necessary to meet the continued servicing needs
of the installed equipment base:
Estimated R-22 Demand for Service
EPA Virgin R-22 Allocation
Shortfall to be filled with Reclaim R-22

2010
137.7 M
110.2 M
27.55M

2011
127.6 M
100 M
27.55 M

2012
117.2 M
89.7 M
27.55 M

2013
106.7 M
79.1 M
27.55 M

2014
96 M
68.6 M
27.55 M

All numbers in pounds

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2010 HCFC RULES


Precharged Equipment Rule
The Precharged Equipment Rule prohibits the precharging of all air conditioning and
refrigeration appliances and components by OEMs beginning January 1, 2010.

The prohibition ....

Does not apply to precharged appliances and components that were manufactured
prior to January 1, 2010

Does not prohibit the sale or distribution of pre-2010 inventory

Allows uncharged components to be charged with virgin or reclaimed


refrigerant if used for service only

Allows the sale and distribution of uncharged appliances and components


Allows use of reclaimed R-22 to field charge appliances manufactured after
January 1, 2010

Precharged Appliances & Components manufactured before January 1, 2010

No restriction on sale or distribution


Precharged components can only be used to service existing appliances
Virgin or reclaimed refrigerant can be used to service existing appliances

Appliances & Components manufactured after January 1, 2010

Appliances cannot be initially charged with virgin refrigerant, reclaimed refrigerant is okay
Components can be charged with virgin refrigerant if being used for service of existing
appliance; otherwise, charge only with reclaimed refrigerant

Important Exceptions
1)

Virgin R-22 may be used for the onsite manufacture (i.e. installation) of appliances
for a specific project if the components being used on that project were manufactured
before January 1, 2010 and if a building permit or contract was issued and dated prior to
January 1, 2010. Projects that qualify for this exception must be completed by December 31, 2011.

2)

Thermostatic expansion valve (TXV) manufacturers can use R-22 manufactured before
January 1, 2010 to produce precharged TXVs until January 1, 2015.

For more information, please visit EPAs website: http://www.epa.gov/ozone/strathome.html

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NOTES

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