Effective Medium Theories PDF
Effective Medium Theories PDF
Effective Medium Theories PDF
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Theoretical Models
During the last four decades, many theoretical models
have appeared which try to describe the elastic and
transport properties of rocks.
Some are mathematically elegant (complicated).
Most are extreme idealizations of the complexity of real
rocks
129
Inclusion Models
?
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M = f1 M1 + f 2 M 2 + f 3 M 3 + ...
where
V = fQ Q + f F F + fC C ... + f W W + fO O + f G G
1
1
1
1
R = f QQ1 + f F 1
+
f
...+
f
+
f
+
f
F
C C
W W
O O
G G
Since these are upper and lower bounds, an estimate of the actual value is
sometimes taken as the average of the two, known as the Voigt-Reuss-Hill
average:
MV + MR
MVRH =
132
The Voigt and Reuss averages are interpreted as the ratio of average stress
and average strain within the composite.
The stress and strain are generally unknown in the composite and are expected
to be nonuniform. The upper bound (Voigt) is found assuming that the strain is
everywhere uniform. The lower bound (Reuss) is found assuming that the
stress is everywhere uniform.
Geometric interpretations:
E = f i E i
E = =
f f ( )
E
1
fi
=
Ei
E
i i
133
VP =
Wet sediment:
Gas-charged sediment:
4
K +
3
P-wave velocity
= (1 )solid + brine
1
K =
+
K
K
solid
brine
K = 5.05GPa
= 1.99 g /cc
V = 1.59 km /s
K = 0.74 GPa
= 1.88 g /cc
V = 0.63 km /s
= 0.4; Sw = 0.7; Kqtz = 37; Kw = 2.2; Kgas = 0.1 GPa; qtz = 2.65; w = 1.0; gas = 0.1 g /cc
134
Voigt
Reuss
water
Velocity-porosity relationship in clastic sediments compared with the Voigt and Reuss
bounds. Virtually all of the points indeed fall between the bounds. Furthermore, the
suspensions, which are isostress materials (points with porosity > 40%) fall very close
to the Reuss bound.
Data from Hamilton (1956), Yin et al. (1988), Han et al. (1986). Compiled by Marion, D., 1990, Ph.D.
dissertation, Stanford
Univ.
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Reuss
water
5% gas
Velocity-porosity relationship in clastic sediments compared with the Voigt and Reuss
bounds. Virtually all of the points indeed fall between the bounds. Furthermore, the
suspensions, which are isostress materials (points with porosity > 40%) fall very close
to the Reuss bound.
Data from Hamilton (1956), Yin et al. (1988), Han et al. (1986). Compiled by Marion, D., 1990, Ph.D.
dissertation, Stanford
Univ.
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Hashin-Shtrikman Bounds
The narrowest possible bounds on moduli that we can estimate for an isotropic
material, knowing only the volume fractions of the constituents, are the HashinShtrikman bounds. (The Voigt-Reuss bounds are wider.) For a mixture of 2
materials:
f2
K HS = K 1 +
(K 2 K1 )
HS = 1 +
+ f1 K 1 + 1
3
f2
2 f1 (K1 + 2 1 )
+
4
5 1 K 1 + 1
( 2 1 ) 1
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Hashin-Shtrikman Bounds
A more general form that applies when more than two phases are
being mixed (Berryman, 1993):
K HS + = ( max ), K HS = ( min )
where
(z) =
K( r) +
( z) =
1
(r) + z
(K , ) =
4
z
3
4
z
3
9K + 8
6 K + 2
indicates volume average over the spatially varying K(r), (r) of the
constituents.
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G13
139
d2
d3
t=
D
V
t = t1 + t2 + t 3
D d1 d2 d3
= +
+
V V1 V2 V3
1 d1 / D d2 / D d3 / D
=
+
+
V
V1
V2
V3
1 f1 f 2 f 3
= + +
V V1 V2 V3
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rock is isotropic
rock must be fluid-saturated
rock should be at high effective pressure
works best with primary porosity
works best at intermediate porosity
must be careful of mixed mineralogy (clay)
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V = (1 )2Vmineral + Vfluid
< 37%
1
2 =
2 +
2
V fluidVfluid mineralVmineral
1 0.47 1 0.37 1
=
+
V
0.10 V37
0.10 V47
> 47%
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B A F
F F C
0 0 0
0 0 0
0 0 0
where
0
0
D
0
0
0
0
0
D
0
0
0
0
0
4 ( + )
1
A=
+
+ 2
+ 2
2
1
B=
+
+ 2
+ 2
C=
1
+ 2
F=
1
+ 2
D=
1
M = (A B)
2
+ 2
+ 2
+ 2
M=
, are the isotropic elastic constants of the individual layers. The brackets
indicate averages of the enclosed properties, weighted by their volumetric
proportions. This is often called the Backus average.
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ij = S ijkl kl
ij = c ijkl kl
kl
kl
elastic compliances
1
A B F
2
B A F
3
F F C
4 = 0 0 0
5
0 0 0
6
0 0 0
0
0
0
D
0
0
0
0
0
0
D
0
0
0
0
0
0
M
e1
e2
e3
e4
e5
e6
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Example: We observe Vp, Vs, and density at a well and compute a synthetic seismic
trace, as usual. Predict how the seismic will change if the fluid changes -- either over
time at the same position, or if we move laterally away from the well and encounter
different fluids in roughly the same rocks.
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Initial
??
After
production
148
ij(1), u(1)
149
limit as
1
1 Vpore
1
=
+
K dry K mineral Vbulk
Assumptions
minerals behave elastically
friction and viscosity not important
assumes a single average mineral
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1
1 =
+
K dry K mineral K
where
1
1 v pore
=
K v pore
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1 =
1
+
K sat K mineral K
where
K = K +
K mineral K fluid
K mineral K fluid
K + K fluid
Pore space
compressibility
modified by fluids.
So we see that changing the pore fluid has the effect of changing the pore space
compressibility of the rock. The fluid modulus term is always just added to K
When we have a stiff rock with high velocity, then its value of K is large, and
changes in K fluid do not have much effect. But a soft rock with small velocity will
have a small K and changes in K fluid will have a much larger effect.
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Gassmann's Relations
Ksat
K mineral K sat
Kdry
K fluid
=
+
Kmineral Kdry (Kmineral Kfluid )
1
sat
dry
water
oil
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1 K dry
+
2
K fluid K min K min
1
K min
1
K
fluid
1
K min
1
K dry
K sat =
1 1
1 1
+ 1
K dry K min K fluid K min K min K dry
1 = 1 +
K sat K min
K minK fluid
K +
K min K fluid
K min
+ 1 K min
K fluid
K min K sat
+
1
K fluid K min
K sat
K dry =
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VP1, VS1, 1
4 2
K1 = 1VP21 VS1
2
1 = 1VS1
K2
K fl 2
K1
K fl 1
fl 2
2 = (1 ) min + fl 2 = 1 + (fl 2 fl 1 )
K2 +
VP =
3 2
VS =
2
2
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Vp (km/s)
2.45
sandstone
porosity = 30%
2.4
2.35
2.3
patchy
homogeneous
2.25
2.2
2.15
0.2
0.4
0.6
0.8
Oil Saturation
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K
e
1 / KReuss = Sw / Kw + So / Ko + Sg / Kg
Brie, et al.SPE 30595
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+Pp
-Pp
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K
mineral fluid Kfluid
K mineral K fluid
Kfluid
= 0.6
K mineral
~ 3 contours.
C
C
161
K1 = VP2 VS2
3
1 = VS2
and then compute the change of bulk modulus with fluids using the usual
expression:
Kdry
Ksat
K fluid
=
+
K mineral K sat Kmineral Kdry (Kmineral Kfluid )
The problem is that we usually don't know Vs.
One approach is to guess Vs, and then proceed.
We have also found that a reasonably good approximation to Gassmann
is
Mdry
Msat
Mfluid
+
Mmineral M sat Mmineral Mdry (Mmineral Mfluid)
M = V p2
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Vp-saturated,
saturated, From Approximate Gassmann
Predictions of saturated rock Vp from dry rock Vp are virtually the same
for the approximate and exact forms of Gassmanns relations.
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(laboratory)
Pressure
depth (m)
oil to water
1300
G.12
brine at
increased Pp
oil at
increased Pp
original
oil
1350
2.5
Vp (km/s)
Calculated using Gassmann via dry lab data from Troll (Blangy, 1992). Virgin condition taken as low frequency,
oil saturated at Peff=30 Mpa Pressure drop to Peff=10 MPa, then fluid substitution to brine.
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Koil = 1., Kbrine = 2.2
depth (m)
Pressure
oil to water
1300
G.12
brine at
increased Pp
oil at
increased Pp
original
oil
1350
2.5
Vp (km/s)
Calculated using Gassmann from dry lab data from Troll (Blangy, 1992). Virgin condition taken as low
frequency, oil saturated at Peff=30 MPa. Pressure drop to Peff=10 MPa, then fluid substitution to gas.
Koil = 1., Kbrine = 2.2
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depth (m)
1250
1300
brine at
decreased Pp
original
oil
frame effect
decreased Peff
oil at
decreased Pp
1350
1.8
2.4
Vp (km/s)
Calculated using Gassmann from dry lab data from Troll (Blangy, 1992). Virgin condition taken as low
frequency, oil saturated at Peff=25 MPa. Pore pressure drop to Peff=30 MPa, then fluid substitution to
brine. Koil = 1., Kbrine = 2.2
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S
(
=
(S
)
)+ (
(dry)
ij
0
Sij0 (Skl(dry)
Skl )
(dry)
0
S
fl
0 )
where
)
S(dry
ijkl effective elastic compliance tensor of dry rock
)
S(sat
ijkl effective elastic compliance tensor of rock saturated with pore fluid
0
effective elastic compliance tensor of mineral
Sijkl
fl
porosity
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Noiriel, 2005
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CaMg(CO3)2 + Ca2+
[Mg2+] [CaCO3]2
Kcd=
[Ca2+] [CaMg(CO3)2]
Kcd=
[Mg2+]
[Ca2+]
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Calcite dissolution
Case B
Transformation Anhydrite Gypsum
Tucker et al., 1990
Case C
Gypsum dissolution
dolomite dissolution
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Dissolution and mineral transformation affect the elastic moduli in a way that opposes the
high-frequency dispersion mechanisms. Thus, Gassmann fluid substitution may either
overestimate or fit high-frequency, saturated velocities, depending on the balancing of
chemical processes against dispersion mechanisms.
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Marion (1990) discovered a simple, semi-empirical way to solve the fluid substitution problem. The
Hashin-Shtrikman bounds define the range of velocities possible for a given volume mix of two
phases, either liquid or solid. The vertical position within the bounds, d/D, is a measure of the
relative geometry of the two phases. For a given rock, the bounds can be computed for any two
pore phases, 0 and 1. If we assume that d/D remains constant with a change of fluids, then a
measured velocity with one fluid will determine d/D, which can be used to predict the velocity relative
to the bounds for any other pore phase.
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4000
measured parowax
P-Velocity (m/s)
3800
3600
BAM
calculated
parowax
3400
3200
3000
measured dry
2800
0
20
40
60
80
100
120
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G.8
Temperature ( C)
Velocity in Massilon sandstone saturated with parowax. Data from Wang (1988). Wax saturated
velocities were predicted using BAM, from Wang's measured velocities in the dry rock and in wax (from
Marion, 1990)
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G.9
Velocity in dry and saturated Westerly granite. Data from Nur and Simmons (1969).
Saturated velocities were predicted using BAM, from measured velocities in the dry rock
(from Marion, 1990)
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1
1
K dry
K mineral
1
1 v pore
=
K v pore
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Mathematicians have worked out in great detail the 3-D deformation field
U, of an oblate spheroid (penny-shaped crack) under applied stress. For
example, the displacement of the crack face is:
U(r) =
c
K mineral
4 1 2
3 1 2
1 cr
We can easily integrate to get the pore volume change and the dry
modulus:
16 1 2
Nc 3
1
1 =
1
+
K dry K mineral
K mineral V bulk
9 1 2
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=
K dry K mineral 9(1 2v ) Vbulk
2
1
1 16(1 v )
1 +
=
N 3
c
Vbulk
3
4
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Nc 3
=
Vbulk
This is called the Crack Density Parameter, and has the interpretation of the
number of cracks per unit volume.
Example: 2 cracks per small cell. Each crack about 2/3 the length of a cell.
c
= 0.07
L
v = L3
2c
L
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16(1 v 2 ) Nc 3
1
1
=
+
K dry K mineral 9Kmineral (1 2v ) Vbulk
An idealized ellipsoidal crack will close when the amount of
deformation equals the original crack width:
solving gives:
U =b
close Kmineral
3 (1 2v )
4 (1 v 2 )
Kmineral
We generally model rocks as having a distribution of cracks with
different aspect ratios. As the pressure is increased, more and more
of them close, causing the rock to become stiffer.
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(K
*
KT
*
KT
Km + m
N
3
Km)
= x i (Ki K m )P mi
4 i =1
*
K KT + m
3
m )
(m + m ) =
*
KT
+ m
x (
)
i
m )Qmi
i=1
(9K + 8 )
6 (K + 2 )
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16(1 v 2 ) Nc 3
= K mineral 1
9
(
1
2v
)
V
bulk
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Self-Consistent Approximations
OConnell and Budiansky (1974) model for medium with randomly
oriented thin dry cracks
16 1 v *2
SC
= 1
*
K
9 1 2v SC
K *SC
*
*
*
SC
32 (1 v SC )(5 v SC )
= 1
45
(2 v *SC )
K and are the bulk and shear moduli of the uncracked medium, is
the Poissons ratio, and is the crack density parameter. The
calculations are simplified by the approximation:
16
*
v SC v 1
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Self-Consistent Approximations
Berrymans (1980) model for N-phase composites
N
x (K
i
K * )P *i = 0
* )Q*i = 0
i=1
N
x (
i
i=1
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d
[ K * ( y )] = ( K 2 K *) P (*2) ( y )
dy
d
(1 y ) [ * ( y )] = ( 2 *)Q (*2) ( y )
dy
(1 y )
Coupled differential equations with initial conditions K*(0) = K1 and *(0) = 1, where
K1, 1 = bulk and shear moduli of the initial host material (phase 1)
K2, 2 = bulk and shear moduli of the incrementally added inclusions (phase 2)
y = concentration of phase 2
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35
30
25
20
15
10
5
0
0
0.2
0.4
0.6
0.8
porosity
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