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    ARKEMA COATEX Presentation COADIS 123 K Hidrophobic Dispersant PDF

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    Jose E Batista
    New paint formulations are required to meet low-VOC or 0-VOC regulations. Associated risks are loosing in terms of film resistance against wet scrub, stain, early rain, acid, alkali burn out. Such issues can be addressed thanks to the use of an efficient and hydrophobic dispersing agent.

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    ARKEMA COATEX Presentation COADIS 123 K Hidrophobic Dispersant PDF

    Uploaded by

    Jose E Batista
    1K views22 pages
    New paint formulations are required to meet low-VOC or 0-VOC regulations. Associated risks are loosing in terms of film resistance against wet scrub, stain, early rain, acid, alkali burn out. Such issues can be addressed thanks to the use of an efficient and hydrophobic dispersing agent.

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    ARKEMA COATEX Presentation COADIS 123 K Hidrophobic dispersant.pdf

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    New paint formulations are required to meet low-VOC or 0-VOC regulations. Associated risks are loosing in terms of film resistance against wet scrub, stain, early rain, acid, alkali burn out. Such issues can be addressed thanks to the use of an efficient and hydrophobic dispersing agent.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    1K views22 pages

    ARKEMA COATEX Presentation COADIS 123 K Hidrophobic Dispersant PDF

    Uploaded by

    Jose E Batista
    New paint formulations are required to meet low-VOC or 0-VOC regulations. Associated risks are loosing in terms of film resistance against wet scrub, stain, early rain, acid, alkali burn out. Such issues can be addressed thanks to the use of an efficient and hydrophobic dispersing agent.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 22
    At a glance
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    The key takeaways from the document are that a new hydrophobic dispersing agent, CoadisTM 123 K, can help improve various paint properties like scrub resistance, stain resistance, early rain resistance, acid and alkali resistance when used in low-VOC or 0-VOC paint formulations.

    New paint formulations required to meet low-VOC or 0-VOC regulations may face issues like losing film resistance against wet scrub, stain, early rain, acid, alkali burn out. There could also be possible impact on properties like color acceptance and gloss development.

    A hydrophobic dispersing agent like CoadisTM 123 K can help address these issues thanks to its efficient and hydrophobic properties. It can provide benefits like better water resistance, scrub resistance and maintaining pigment positioning for better opacity and properties.

    Add drops of vitamins to your formulations

    Possibilities offered by a unique hydrophobic dispersant

    European Coatings Show Nremberg


    April 2015
    Dr. Denis Ruhlmann

    Unique hydrophobic dispersant


    water resistance and much more
    New paint formulations are required to meet low-VOC or 0-VOC regulations.
    Associated risks are loosing in terms of film resistance against wet scrub, stain, early
    rain, acid, alkali burn out
    Possible impact on paint properties such as color acceptance and gloss
    development

    Such issues can be addressed thanks to the use of an efficient and hydrophobic
    dispersing agent.

    Content

     Dispersing theory
     Dispersant introduction
     Case studies
     Wrap up

    Steric and Ionic Dispersants


    Repulsive energy between particles depends on the nature of the dispersant
    d

    Steric Dispersants
    (comb polymers)

    Ionic Dispersants

    +
    +

    dc

    dc

    +
    +

    In can long term pigment stabilization


    Prevents flocculation and
    acceleration of settling

    Maintains steric spacing and best


    pigment positioning for opacity until
    the latest phases of film drying

    Dispersing technologies

    Eggshell

    Satin

    Semi gloss

    Gloss

    Coadis 123 K

    Water Resistance

    Matt

    Pigment
    Paste

    Potassium salt

    Coadis BR 3 Coadis BR 85
    Potassium salt

    Ecodis P 90
    Ammonium salt

    Ecodis P 50
    Sodium salt

    Ecodis P 30
    Sodium salt

    Coarse
    Fillers

    CaCO3 CLAY

    Fine
    TiO2 ZnO

    Fe2O3

    Oxide
    pigments

    Organic
    pigment

    Case Studies
     Interior wall paints PVC=40%
    Scrub resistance
    Stain resistance
    Tint strength

     Exterior wall paints PVC=60%


    Early water resistance
    Acid rain resistance
    Tint strength

     Exterior primer
    Alkali burnout and Salting out resistance

     High gloss alkyd emulsion paints

    Letdown

    Millbase

    PVC=40% interior wall paint

    Ingredient
    Water
    Biocide
    Neutralizing agent
    Polyacrylate dispersant
    Coadis 123 K
    Defoamer
    Rutile TiO2
    CaCO3
    Calcined clay
    Texanol
    Encor 662 (styrene acrylic)
    Defoamer
    Water
    Rheotech 3800
    Coapur 3025

    Reference
    132
    1,7
    4,6
    10,6
    0
    1,8
    176
    114,4
    114,4
    10,6
    387
    1,8
    36,3
    5,3
    3,5

    Coadis 123 K
    132
    1,7
    4,6
    5
    5
    1,8
    176
    114,4
    114,4
    10,6
    387
    1,8
    36,9
    5,3
    3,5

    Total

    1000

    1000

    PVC=40% interior wall paint


    Scrub Resistance
    1600 cycles

    2000
    1500
    1000
    500
    0
    reference

    Coadis 123 K

    reference

    Coadis 123 K

    The scrub resistance obtained with Coadis 123 K is much higher than
    with the current polyacrylate

    PVC=40% interior wall paint


    Scrub Resistance
    Water + detergent

    Hydrophilic dispersant : Water


    easily penetrates into the paint
    film
     Poor scrub resistance

    Water + detergent
    Binder

    Substrate

    Binder

    Substrate

    Hydrophobic
    barrier

    Hydrophobic dispersant : Water stays


    at the paint film surface
     Better scrub resistance

    PVC=40% interior wall paint


    Scrub Resistance

    5 liquid stains drops and 1 brushed solid stain are applied on the panels
    After 2 hours, they are moved away by water rinsing and by tissue absorption
    Using a scrub machine and 2% of washing powder solution, panels are brushed 200 times
    and dried
    Anti stain resistance is expressed as a score

    10

    PVC=40% interior wall paint


    Tint Strength

    108%

    Black pigment
    106%
    104%

    Blue pigment
    Red pigment

    102%
    100%
    98%
    96%
    Reference

    123 K

    Reference

    123 K

    Reference

    123 K

    Tinting strength of reference paint is set at 100%.


    Higher than 100% means a higher tint strength

    11

    PVC=40% interior wall paint


    Tint Strength
    No color change after finger rub
    up with Coadis 123 K for the
    tested three color,
    E of paint with Coadis 123 K
    all lower than 0.5,
    Tinting strength of formulas with
    Coadis 123 K is better.

    Reference

    12

    Coadis 123 K

    Letdown

    Millbase

    60% PVC exterior wall paint

    13

    Ingredient
    Water
    Biocide
    Polyacrylic dispersant
    Coadis 123 K
    Propylene glycol
    Surfactant
    Texanol
    Defoamer
    Rutile TiO2
    Hydreous clay
    Calcined clay
    HEC
    Neutralizing agent
    Water
    Encor 2741 (acrylic)
    Celocor
    Defoamer
    Rheotech 3800

    Reference
    190
    1,5
    6
    0
    16
    5
    15
    4
    150
    80
    140
    4
    2
    90,5
    210
    80
    4
    2

    Coadis 123 K
    use
    181
    1,5
    0
    15
    16
    5
    15
    4
    150
    80
    140
    4
    2
    90,5
    210
    80
    4
    2

    Total

    1000

    1000

    60% PVC exterior wall paint


    Early rain resistance
    1 - White paint is applied on a black surface

    2 wait 30 minutes
    3 - Water is sprayed on the fresh coating

    14

    60% PVC exterior wall paint


    Early rain resistance
    With Coadis 123 K

    Resistant
    15

    Reference with
    polyacrylate

    Not resistant

    60% PVC exterior wall paint


    Acid rain resistance
    Coadis 123 K

    Ammonium polyacrylate

    Experimental
    Acid rain solution
    made of nitric acid
    and sulfuric acid for a
    pH value of 3.5
    Paint tinted with 4%
    of iron red and
    applied on cement
    panels at 200 m wet
    Panel held vertically
    and poured with acid
    rain solution 40 times
    Note visual difference
    between panels

    16

    60% PVC exterior wall paint


    Tint strength
    Black pigment

    130%

    Blue pigment

    120%
    110%

    Red pigment

    100%
    90%
    80%
    Reference

    17

    123 K

    Reference

    123 K

    Coadis 123 K reference

    Reference

    123 K

    Exterior Primer PVC=40%

    Reference
    Water
    200
    Biocide
    1
    Polyacrylic dispersant
    5
    Coadis 123 K
    0
    Neutralizing agent
    1
    Propylene glycol
    20
    Texanol
    23
    Defoamer
    1
    Surfactant
    1,5
    Rutile TiO2
    45
    Talc
    260
    HEC
    6
    Water
    104,5
    Encor 2740 (styrene acrylic) 330
    Defoamer
    2

    Coadis 123 K
    use
    197
    1
    0
    8
    1
    20
    23
    1
    1,5
    45
    260
    6
    104,5
    330
    2

    Total

    1000

    Letdown

    Millbase

    Ingredient

    18

    1000

    Exterior Primer PVC=40%

    Alkali burnout and Salting out resistance


    Experimental
    Coadis 123 K

    Ammonium salt

    0.4 g of 2% PVA/iron blue


    solution is brushed on the
    primer, paraffin is used to seal
    to edges
    Coated cement panels are
    dipped into a blend made of 2%
    NaOH water solution (alkaline
    solution) and a salt solution
    made of Na2SO4 / NaCl / water
    (5:10:85)
    After 24 hours, the
    appearance of the surface is
    examined to detect any iron
    blue area having turned white,
    what would characterize a weak
    resistance

    19

    High gloss alkyd emulsion paint

    Ingredient

    Millbase

    Letdown

    Water
    Multipurpose dispersant (40%)
    Coadis 123 K (24%)
    Biocide
    Neutralizing agent
    Coapur XS 22 (25%)
    Defoamer
    Rutile TiO2
    Synaqua 4804
    Water based drier

    68,6
    8,8
    /
    2
    0,5
    35
    2
    265
    615
    3,1

    62,8
    /
    14,6
    2
    0,5
    35
    2
    265
    615
    3,1

    Total (g)

    1000

    1000

    9
    10

    9
    10

    89.5
    95.0

    89.0
    95.8

    Leveling (ASTM D4062)


    Sag resistance (ASTM D4400)
    Gloss after 3 days
    20
    60
    20

    Conclusion
     The different possibilities offered by the unique hydrophobic
    dispersant Coadis 123 K
    Early rain resistance
    Extending painting season

    Color acceptance

    Scrub resistance

    Stain resistance

    Gloss

    Surfactant leaching
    Acid and alkali resistance

    21

    Thanks for your attention


    and for your questions
    Visit us on the Arkema booth 328 Hall 4A

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