Theoretical Physics II B - Quantum Mechanics: Frank Krauss
Theoretical Physics II B - Quantum Mechanics: Frank Krauss
14.2.2013
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
0
1
and therefore
~
1
0
E =
for |E+ i = |i =
and |E i = |i =
0
1
2
(b) The time evolution operator is given by
i
t0 )
U(t,
t0 ) = exp H(t
~
h
0)
exp i(tt
0
2
h
i
=
0)
0
exp i(tt
2
= ~
H
2
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
1
0
9.1 (d) The time evolution of the expectation value can in this case be
written as
D E
hSx i = Sx
=
~
~
c c exp [it] + c c exp [it] = cos (t) ,
2
2
and similarly
D E
hSy i = Sy
=
~
~
ic c exp [it] + ic c exp [it] = sin (t) ,
2
2
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
h(t)|(t)i = (t0 ) U
(t, t0 )U(t,
t0 ) (t0 ) = h(t0 )|(t0 )i ,
i.e. the norm of a state ket does not change during time evolution.
Instead, time evolution merely acts like a phase factor on the state
ket, rotating it in Hilbert space.
Even more, phase differences between different kets are invariant:
D
E
h(t)|(t)i = (t0 ) U
(t, t0 )U(t,
t0 ) (t0 ) = h(t0 )|(t0 )i ,
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
(t) O
=
(t0 ) U
(t, t0 )O
t0 ) (t0 ) .
(t)
Theres two extreme ways to interpret this:
1. Schr
odinger picture:
(t, t0 )O(t
0 )U(t,
(t)O
(S) U(t)
U
E
U(t)
(H) .
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
(t)
(H) (t)
U
dO
(S) U(t)
(t)O
(S) U(t)
=
O
+U
dt
t
t
i (S)
i (S)
= + U (t)H O U(t) U (t)O H U(t)
~
~
i (S)
i (S)
= + U (t)H U(t)U (t)O U(t) U
(t)O U(t)U (t)H U(t)
~
~
h
i
h
i
i (H)
i (H)
(t)H
U(t)
,
= O
(t), U
= O
(t), H
~
~
where in going to the last expression use has been made from the
does not depend explicitly on time,
fact that hif H
i
h
i
H
= 0.
U = exp i Ht/~
and U,
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
=
O (t), H
dt
i~
is strikingly similar to the classical equations of motion in the same
setup (explicitly time-independent Hamiltonians), which, using
Poisson brackets, can be written as
dO
= [O, H]classical
dt
leading to the assumption
[ , ]quantum
[ , ]classical
i~
It is worth noting, though, that this stretches to observables, such as
spin, which do not have any classical analogue.
However, analogue above indicates that in many aspects the
dynamics in the Heisenberg picture and their interpretation are
closer in spirit to classical physics. There is also no notion of a state
ket of any dynamical consequence.
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
Reminder: Hamiltonian
From classical Hamiltonian to ladder operators:
m 2 2
1
1
p2
+
x = ~ N +
= ~ a+ a +
.
H=
2m
2
2
2
Commutators of creation and annihilation operators:
h
i
h
i
a = a , H,
a = ~a .
[a+ , a ] = 1 , N,
Connection to position and momentum operators:
r
r
m
x i p
~
~m
a =
[a+ + a ] , p = i
[a+ a ] .
, x =
2m
2
2~m
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
Therefore:
r
~
x(t) =
[exp (it) a+ (0) + exp (it) a (0)]
2m
r
~
[cos(t)(a+ + a ) + i sin(t)(a+ a )]
=
2m
sin(t)
= cos(t) x(0) +
p(0) .
m
and similarly
p(t) = cos(t) p(0) m sin(t) x(0) .
They look like their classical analogue: the position and momentum
operators x and p oscillate with frequency .
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
Alternative derivation
Alternatively, can also apply time-evolution operator directly:
#
"
#
"
i Ht
i Ht
x(0) exp
x(t) = U (t)
x (0)U(t) = exp
~
~
Using the Baker-Hausdorff formula
h
i h h
ii
)A
exp(i G
) = A
+ i G
, A
+ G
, G
, A
+ ...
exp(i G
and by repeatedly identifying
h
i
h
i
p (0)
= i~
= i~m
x(0)
p(0)
H,
and H,
x (0)
m
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
p(t)
sin(t)
p(0)
m
cos(t) p(0) m sin(t) x(0) ,
cos(t) x(0) +
one would maybe naively expect that also the expectation values of
the corresponding observables oscillate in a similar fashion.
This however is not true: Consider the expectation value with
respect to the nth eigenstate, |n i:
r
~
hn |
x | n i =
hn |[a+ + a ]| n i = 0 ,
2m
because the creation and annihilation operators and thus the
position and momentum operators have only non-diagonal entries in
this base.
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
c0 c1 0 a (t) 1 + c1 c0 1 a+ (t) 0
6= 0
h |
x | i =
2m
is non-vanishing and will indeed lead to some oscillatory movement.
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
Coherent states
Following the logic above, a state b|i could be constructed as a
superposition of energy eigenstates, such that it most closely
imitates the classical oscillator.
Such a coherent state is defined by the eigenvalue equation for the
non-Hermitian annihilation operator a :
a |i = |i ,
which clearly must be a superposition of all energy eigenstates:
|i =
n=0
nn
exp(
n) ,
n!
Learning outcomes
Heisenberg vs. Schr
odinger picture:
Heisenberg picture
Stationary
State kets
Observables
Moving
O
U)
=U
(O(t)
Moving oppositely
|bk i)
(|bk (t)i = U
Base kets
Schr
odinger picture
Moving
|i)
(|(t)i = U
Stationary
Stationary
Zt
0
i
i
0 0 H is t indep.
U(t) = exp
dt H(t )
exp Ht .
~
~
0
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10
Control questions
10.1 Consider, once again, the Hamiltonian
= eB Sz = Sz .
H
mc
already encountered in the control questions to the last lecture.
(a) Write the Heisenberg E.o.M. for the three time-dependent spin
operators Sx, y , z (t) and solve them.
(b) For the states |1 i = |i and | i = 12 [|i |i] write down the
Schr
odinger equation and solve it explicitly, i.e. give expressions for
these three states as functions of time in the Schr
odinger picture.
(c) Compare the time evolution of the expectation values of Sx,z with
respect to those three states in both pictures and check that they
coincide.
F. Krauss
Theoretical Physics II B Quantum Mechanics[1cm] Lecture 10