SAFETY DATA SHEET

1. Identification
Product identifier

LPS CFC Free (Aerosol)

Other means of identification

Part Number

03116

Recommended use

A fast drying industrial cleaning solvent designed to remove soil and other contaminants.

Recommended restrictions

None known.

Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Manufacturer
Company name
Address
Country
In Case of Emergency
Website
E-mail

LPS Laboratories, a division of Illinois Tool Works, Inc.

4647 Hugh Howell Rd.
Tucker, GA 30084
(U.S.A.)
Tel: +1 770-243-8800
1-800-424-9300 (inside U.S.)
+001 703-527-3887 (outside U.S.)
www.lpslabs.com
[email protected]

2. Hazard(s) identification
Physical hazards

Flammable aerosols

Category 1

Health hazards

Skin corrosion/irritation

Category 2

Serious eye damage/eye irritation

Category 2

Reproductive toxicity (fertility)

Category 2

Specific target organ toxicity, single exposure Category 3 narcotic effects

Specific target organ toxicity, repeated
exposure
OSHA defined hazards

Category 2

Not classified.

Label elements

Signal word

Danger

Hazard statement

Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. May
cause damage to organs through prolonged or repeated exposure by skin contact. Extremely
flammable aerosol. Suspected of damaging fertility or the unborn child.

Precautionary statement
Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid
breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Use only outdoors or
in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.
Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or
burn, even after use.

Response

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed
or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you
feel unwell. Specific treatment (see this label). If skin irritation occurs: Get medical
advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated
clothing and wash before reuse.

Storage

Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from
sunlight. Do not expose to temperatures exceeding 50C/122F.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations.

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Hazard(s) not otherwise

classified (HNOC)
Supplemental information
Precautionary statement
Prevention
Response

Not classified.

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and
receiving equipment. These alone may be insufficient to remove static electricity.
Eliminate all ignition sources if safe to do so.

81.79% of the mixture consists of component(s) of unknown acute oral toxicity. 92.33% of the mixture consists of component(s) of
unknown acute hazards to the aquatic environment.

3. Composition/information on ingredients
Mixtures
Hazardous components
Chemical name

CAS number

2-Methylpentane

107-83-5

40 - < 50

2,3-Dimethylbutane

79-29-8

10 - < 20

3-Methylpentane

96-14-0

10 - < 20

67-63-0

10 - < 20

2,2-Dimethylbutane

75-83-2

5 - < 10

Carbon Dioxide

124-38-9

3-<5

N-hexane

110-54-3

Isopropanol

Common name and synonyms

ISOPROPYL ALCOHOL (IPA)

Other components below reportable levels

1-<3
5 - < 10

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or
artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance.
Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device. Call a physician if symptoms develop or persist.

Skin contact

Wash off immediately with soap and plenty of water while removing all contaminated clothes and
shoes. Get medical attention if irritation develops and persists.

Eye contact

Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses.
Call a physician or Poison Control Center immediately.

Ingestion

Call a physician or poison control center immediately. Only induce vomiting at the instruction of
medical personnel. Never give anything by mouth to an unconscious person. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs.

Most important
symptoms/effects, acute and
delayed

Irritation of eyes and mucous membranes. Symptoms may include stinging, tearing, redness,
swelling, and blurred vision. Defatting of the skin. Vapors have a narcotic effect and may cause
headache, fatigue, dizziness and nausea. Narcosis. Behavioral changes. Prolonged exposure may
cause chronic effects.

Indication of immediate
medical attention and special
treatment needed

Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.

General information

Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. In the case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible). Wash contaminated clothing before reuse.

5. Fire-fighting measures
Suitable extinguishing media

Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide,
sand or earth may be used for small fires only.

Unsuitable extinguishing
media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from

the chemical

By heating and fire, harmful vapors/gases may be formed. Vapors may form explosive mixtures
with air. Vapors may travel considerable distance to a source of ignition and flash back.

Special protective equipment

and precautions for firefighters

Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protective
clothing will only provide limited protection.

Fire-fighting
equipment/instructions

In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and
consider the hazards of other involved materials. Move containers from fire area if you can do so
without risk. Water runoff can cause environmental damage.

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Specific methods

Use standard firefighting procedures and consider the hazards of other involved materials. Move
container from fire area if it can be done without risk. In the event of fire and/or explosion do not
breathe fumes.

6. Accidental release measures

Personal precautions,
protective equipment and
emergency procedures

Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.
Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in
immediate area). Wear appropriate personal protective equipment. Do not touch damaged
containers or spilled material unless wearing appropriate protective clothing. Ventilate closed
spaces before entering them. Use appropriate containment to avoid environmental contamination.
Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container
for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be
contained. Use personal protection recommended in Section 8 of the SDS.

Methods and materials for

containment and cleaning up

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material. This material is classified as a water pollutant
under the Clean Water Act and should be prevented from contaminating soil or from entering
sewage and drainage systems which lead to waterways.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Use foam to blanket spilled material. Following
product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills in original containers for re-use. For waste disposal, see section 13 of the SDS.

Environmental precautions

Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic
environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid
discharge into drains, water courses or onto the ground. Use appropriate containment to avoid
environmental contamination.

7. Handling and storage

Precautions for safe handling

Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Vapors may form explosive mixtures with air. Do not handle, store or open near
an open flame, sources of heat or sources of ignition. Protect material from direct sunlight.
Minimize fire risks from flammable and combustible materials (including combustible dust and
static accumulating liquids) or dangerous reactions with incompatible materials. Use non-sparking
tools and explosion-proof equipment.
Do not breathe mist or vapor. Do not taste or swallow. Avoid contact with skin. Avoid contact with
eyes. Avoid contact during pregnancy/while nursing. Avoid prolonged exposure.
Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good
industrial hygiene practices. When using, do not eat, drink or smoke. Wash hands thoroughly after
handling. Avoid release to the environment. Do not empty into drains.

Conditions for safe storage,

including any incompatibilities

Level 3 Aerosol.
Store locked up. Keep away from heat, sparks and open flame. Eliminate sources of ignition.
Keep container tightly closed. Store in a cool, dry place out of direct sunlight. Store in a
well-ventilated place. Keep in an area equipped with sprinklers.

8. Exposure controls/personal protection

Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type

Value

Carbon Dioxide (CAS

124-38-9)

PEL

Isopropanol (CAS 67-63-0)

PEL

N-hexane (CAS 110-54-3)

PEL

US. ACGIH Threshold Limit Values

Components

Type

Value

STEL

1000 ppm

2,2-Dimethylbutane (CAS
75-83-2)
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9000 mg/m3
5000 ppm
980 mg/m3
400 ppm
1800 mg/m3
500 ppm

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US. ACGIH Threshold Limit Values

Components
2,3-Dimethylbutane (CAS
79-29-8)
2-Methylpentane (CAS
107-83-5)
3-Methylpentane (CAS
96-14-0)
Carbon Dioxide (CAS
124-38-9)
Isopropanol (CAS 67-63-0)
N-hexane (CAS 110-54-3)

Type

Value

TWA
STEL

500 ppm
1000 ppm

TWA
STEL

500 ppm
1000 ppm

TWA
STEL

500 ppm
1000 ppm

TWA
STEL

500 ppm
30000 ppm

TWA
STEL
TWA
TWA

5000 ppm
400 ppm
200 ppm
50 ppm

US. NIOSH: Pocket Guide to Chemical Hazards

Components
Type
Carbon Dioxide (CAS
124-38-9)

Value

STEL

54000 mg/m3
30000 ppm
9000 mg/m3
5000 ppm
1225 mg/m3
500 ppm
980 mg/m3
400 ppm
180 mg/m3
50 ppm

TWA
Isopropanol (CAS 67-63-0)

STEL
TWA

N-hexane (CAS 110-54-3)

TWA

Biological limit values

ACGIH Biological Exposure Indices
Components
Value

Determinant

Isopropanol (CAS 67-63-0) 40 mg/l

N-hexane (CAS 110-54-3) 0.4 mg/l

Acetone
2,5-Hexanedion,
without
hydrolysis
* - For sampling details, please see the source document.

Specimen
Urine
Urine

Sampling Time
*
*

Exposure guidelines
US - California OELs: Skin designation
N-hexane (CAS 110-54-3)
US ACGIH Threshold Limit Values: Skin designation
N-hexane (CAS 110-54-3)
Appropriate engineering
controls

Can be absorbed through the skin.

Can be absorbed through the skin.

Explosion-proof general and local exhaust ventilation. Provide eyewash station.

Individual protection measures, such as personal protective equipment

Eye/face protection
Wear safety glasses with side shields (or goggles). Eye wash fountain is recommended.
Skin protection
Hand protection
Other

For prolonged or repeated skin contact use suitable protective gloves. Chemical resistant gloves
are recommended.
Avoid contact with the skin. Wear appropriate chemical resistant clothing. Chemical resistant
gloves.

Respiratory protection

No personal respiratory protective equipment normally required. Use a NIOSH/MSHA approved

respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits.

Thermal hazards

None known.

General hygiene
considerations

When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance

Liquid.

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Physical state

Gas.

Form

Aerosol.

Color

Clear water-white

Odor

Solvent.

Odor threshold

Not available.

pH

Not available.

Melting point/freezing point

Not available.

Initial boiling point and boiling

range

140.9 F (60.5 C) dispensed liquid

Flash point

< 1.40 F (< -17.00 C) Tag Closed Cup

Evaporation rate

< 1 (Ethyl Ether = 1)

Flammability (solid, gas)

Not available.

Upper/lower flammability or explosive limits

Flammability limit - lower
(%)

0.6 %

Flammability limit - upper

(%)

7%

Explosive limit - lower (%)

Not available.

Explosive limit - upper (%)

Not available.

Vapor pressure

352.53 mm Hg @ 38C

Vapor density

~3 (air = 1)

Relative density

Not available.

Solubility(ies)

< 10 % w/w

Partition coefficient
(n-octanol/water)

<1

Auto-ignition temperature

582.8 F (306 C)

Decomposition temperature

Not available.

Viscosity

< 3 cSt @ 25C

Other information
Heat of combustion

> 30 kJ/g

Percent volatile

100 %

Specific gravity

0.64 - 0.67 @ 20C

VOC (Weight %)

96.2 % per U.S, State and Federal Consumer Product Regulations; 669 g/L per SCAQMD Rule 102

10. Stability and reactivity

Reactivity

Avoid contact with oxidizing agents (e.g. nitric acid, peroxides and chromates).

Chemical stability

Risk of ignition. Instability caused by elevated temperatures.

Possibility of hazardous
reactions

Hazardous polymerization does not occur.

Conditions to avoid

Avoid temperatures exceeding the flash point.

Incompatible materials

Strong oxidizing agents. Isocyanates. Acids. Chlorine.

Hazardous decomposition
products

Carbon oxides.

11. Toxicological information

Information on likely routes of exposure
Ingestion

Based on available data, the classification criteria are not met.

Inhalation

Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea.

Skin contact

Causes skin irritation. Frequent or prolonged contact may defat and dry the skin, leading to
discomfort and dermatitis.

Eye contact

Causes serious eye irritation.

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Symptoms related to the

physical, chemical and
toxicological characteristics

Skin irritation. Defatting of the skin. Irritating to eyes and respiratory system. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Vapors have a narcotic effect and
may cause headache, fatigue, dizziness and nausea. Symptoms of overexposure may be
headache, dizziness, tiredness, nausea and vomiting.

Information on toxicological effects

Acute toxicity
Components

Based on available data, the classification criteria are not met.

Species

Test Results

Acute
Dermal
LD50

Rabbit

12800 mg/kg

Oral
LD50

Dog

4797 mg/kg

Mouse

3600 mg/kg

Isopropanol (CAS 67-63-0)

4.5 g/kg
Rabbit

6410 mg/kg
5.03 g/kg

Rat

5045 mg/kg
4.7 g/kg

Other
LD50

Mouse

1509 mg/kg

Rat

1099 mg/kg

Acute
Inhalation
LC50

Mouse

48000 mg/l, 4 Hours

Oral
LD50

Rat

24 mg/kg

Wistar rat

49 mg/kg

N-hexane (CAS 110-54-3)

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation

Causes skin irritation.

Serious eye damage/eye

irritation

Causes serious eye irritation.

Respiratory sensitization

Based on available data, the classification criteria are not met.

Skin sensitization

Based on available data, the classification criteria are not met.

Germ cell mutagenicity

No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.

Carcinogenicity

Based on available data, the classification criteria are not met.

ACGIH Carcinogens
Isopropanol (CAS 67-63-0)

A4 Not classifiable as a human carcinogen.

Reproductive toxicity

Suspected of damaging fertility. Suspected of damaging the unborn child.

Specific target organ toxicity single exposure

Narcotic effects.

Specific target organ toxicity repeated exposure

Causes damage to organs through prolonged or repeated exposure.

Aspiration hazard

Based on available data, the classification criteria are not met.

Chronic effects

Prolonged exposure may cause chronic effects. Causes damage to organs through prolonged or
repeated exposure.

Further information

Symptoms may be delayed.

12. Ecological information

Ecotoxicity

Toxic to aquatic life with long lasting effects.

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Components

Species

Test Results

LC50

Bluegill (Lepomis macrochirus)

> 1400 mg/l, 96 hours

LC50

Fathead minnow (Pimephales promelas) 2.101 - 2.981 mg/l, 96 hours

Isopropanol (CAS 67-63-0)

Aquatic
Fish
N-hexane (CAS 110-54-3)
Aquatic
Fish

* Estimates for product may be based on additional component data not shown.
Persistence and degradability

Not inherently biodegradable.

Bioaccumulative potential

No data available for this product.

Partition coefficient n-octanol / water (log Kow)

LPS CFC Free (Aerosol)
Isopropanol
2,3-Dimethylbutane
3-Methylpentane
2-Methylpentane
2,2-Dimethylbutane
N-hexane

<1
0.05
3.42
3.6
3.74
3.82
3.9

Mobility in soil

Readily absorbed into soil.

Other adverse effects

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions

Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material
and its container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.

Hazardous waste code

D001: Waste Flammable material with a flash point <140 F

D003: Waste Reactive material

Waste from residues / unused

products

Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).

Contaminated packaging

Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport information

DOT
UN number
UN proper shipping name
Transport hazard class(es)
Subsidiary class(es)
Packing group
Special precautions for user
Labels required
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Subsidiary class(es)
Packaging group
Environmental hazards
Labels required
ERG Code
Special precautions for user
IMDG
UN number
UN proper shipping name
Transport hazard class(es)

UN1950
Aerosols, flammable, MARINE POLLUTANT
2.1
Not available.
Not available.
Read safety instructions, SDS and emergency procedures before handling.
2.1
306
None
None
UN1950
Aerosols, flammable
2.1
Not available.
No
Not available.
2X
Read safety instructions, SDS and emergency procedures before handling.
UN1950
AEROSOLS, flammable, MARINE POLLUTANT
2.1

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Subsidiary class(es)
Packaging group
Environmental hazards
Marine pollutant
Labels required
EmS
Special precautions for user

Not available.
Yes
2.1
F-D, S-U
Read safety instructions, SDS and emergency procedures before handling.

Transport in bulk according to

Annex II of MARPOL 73/78 and
the IBC Code

Not applicable.

General information

DOT Regulated Marine Pollutant. IMDG Regulated Marine Pollutant.

DOT

IATA; IMDG

Marine pollutant

15. Regulatory information

US federal regulations

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

Standard, 29 CFR 1910.1200.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
N-hexane (CAS 110-54-3)
LISTED
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
SARA 304 Emergency release notification
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No

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SARA 302 Extremely

hazardous substance

No

SARA 311/312 Hazardous

chemical

Yes

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
N-hexane (CAS 110-54-3)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA)

Not regulated.

Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Not listed.
Food and Drug
Administration (FDA)

Not regulated.

US state regulations
US. Massachusetts RTK - Substance List
2,2-Dimethylbutane (CAS 75-83-2)
2,3-Dimethylbutane (CAS 79-29-8)
2-Methylpentane (CAS 107-83-5)
3-Methylpentane (CAS 96-14-0)
Carbon Dioxide (CAS 124-38-9)
Isopropanol (CAS 67-63-0)
N-hexane (CAS 110-54-3)
US. New Jersey Worker and Community Right-to-Know Act
N-hexane (CAS 110-54-3)
500 lbs
US. Pennsylvania RTK - Hazardous Substances
2,2-Dimethylbutane (CAS 75-83-2)
2,3-Dimethylbutane (CAS 79-29-8)
2-Methylpentane (CAS 107-83-5)
3-Methylpentane (CAS 96-14-0)
Carbon Dioxide (CAS 124-38-9)
Isopropanol (CAS 67-63-0)
N-hexane (CAS 110-54-3)
US. Rhode Island RTK
Isopropanol (CAS 67-63-0)
N-hexane (CAS 110-54-3)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any
chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region
Australia

Inventory name
Australian Inventory of Chemical Substances (AICS)

On inventory (yes/no)*
Yes

Canada

Domestic Substances List (DSL)

Canada

Non-Domestic Substances List (NDSL)

China

Inventory of Existing Chemical Substances in China (IECSC)

Yes

Europe

European Inventory of Existing Commercial Chemical

Substances (EINECS)

Yes

Europe

European List of Notified Chemical Substances (ELINCS)

Japan

Inventory of Existing and New Chemical Substances (ENCS)

Yes

Korea

Existing Chemicals List (ECL)

Yes

New Zealand

New Zealand Inventory

Yes

Philippines

Philippine Inventory of Chemicals and Chemical Substances

(PICCS)

Yes

United States & Puerto Rico

Toxic Substances Control Act (TSCA) Inventory

Yes

Yes
No

No

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date

05-10-2013

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Version #

01

Further information

Not available.

HMIS ratings

Health: 1*
Flammability: 4
Physical hazard: 2

NFPA ratings

Health: 1
Flammability: 3
Instability: 0

Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

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