Types: For Other Uses, See Wax (Disambiguation)

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Wax
From Wikipedia, the free encyclopedia

For other uses, see Wax (disambiguation).


Waxes are a class of chemical compounds that are malleable near ambient temperatures. They are also a
type of lipid. Characteristically, they melt above 45 C (113 F) to give a low viscosity liquid. Waxes are
insoluble in water but soluble in organic, nonpolar solvents. All waxes are organic compounds, both synthetic
and naturally occurring.

Types
Waxes are organic compounds that characteristically consist of long alkyl chains. Natural waxes may
contain esters of carboxylic acids and long chain alcohols or mixtures of substituted hydrocarbons, such as
long chain fatty acids and primary alcohols. Synthetic waxes are long-chain hydrocarbons lacking functional
groups.

Plant and animal waxes


Waxes are synthesized by many plants and animals. Those of animal origin typically consist of wax esters
derived from a variety of carboxylic acids and fatty alcohols. In waxes of plant origin characteristic mixtures of
unesterified hydrocarbons may predominate over esters.[1] The composition depends not only on species, but
also on geographic location of the organism. Because they are mixtures, naturally produced waxes are softer
and melt at lower temperatures than the pure components.
Animal waxes
The most commonly known animal wax is beeswax, but other insects secrete waxes. A major component of the
beeswax used in constructing honeycombs is the ester myricyl palmitate which is an ester of triacontanol and
palmitic acid. Its melting point is 62-65 C. Spermaceti occurs in large amounts in the head oil of the sperm
whale. One of its main constituents is cetyl palmitate, another ester of a fatty acid and a fatty alcohol. Lanolin is
a wax obtained from wool, consisting of esters of sterols.[2]
Plant waxes
Plants secrete waxes into and on the surface of their cuticles as a way to control evaporation, wettability and
hydration.[3] The epicuticular waxes of plants are mixtures of substituted long-chain aliphatic hydrocarbons,
containing alkanes, alkyl esters, fatty acids, primary and secondary alcohols, diols, ketones, aldehydes.[1] From
the commercial perspective, the most important plant wax is Carnauba wax, a hard wax obtained from the
Brazilian palm Copernicia prunifera. Containing the ester myricyl cerotate, it has many applications, such as
confectionery and other food coatings, car and furniture polish, floss coating, surfboard wax, and other uses.
Other more specialized vegetable waxes include candelilla wax and ouricury wax.

Petroleum derived waxes


See also: Paraffin wax
Although many natural waxes contain esters, paraffin waxes are hydrocarbons, mixtures of alkanes usually in a

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